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Sheet 0077720

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Safety Data Sheet | |
Date of Issue: 07/25/14    |Revision Date:             |Revision Number: 49.03    
Imperial Supplies Part Number: 0077720                                            

SECTION 1: IDENTIFICATION                                                         


1.1.  Product Identifier
Product Form: Paste                                                               
Product Name: 3M Structural Adhesive Part A (Urethane Side), PN 08101             
CAS No:                                                                           
Synonyms:                                                                         


1.2.  Intended Use of the Product
Use of the substance/mixture: Automotive, Accelerator portion of a two-part       
general purpose structural adhesive that may be used for bonding metal, glass and 
plastic.                                                                          


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                           
3M                                                                                
Automotive Aftermarket                                                            
3M Center, St. Paul, MN 55144-1000, USA                                           
Phone: 1-888-3M HELPS (1-888-364-3577)                                            
                                                                                  
Supplier: Imperial Supplies LLC                                                   


1.4.  Emergency Telephone Number
Emergency     | 1-800-364-3577 or (651) 737-6501 (24 hours)                       
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Serious Eye   |Category 2A.  
Damage/Irritat|              
ion           |              
Skin          |Category 2.   
Corrosion/Irri|              
tation        |              
Respiratory   |Category 1.   
Sensitizer    |              
Skin          |Category 1.   
Sensitizer    |              
Specific      |Category 3.   
Target Organ  |              
Toxicity      |              
(respiratory  |              
irritation)   |              
Specific      |Category 1.   
Target Organ  |              
Toxicity      |              
(repeated     |              
exposure)     |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamat|Health  |        |        |        |        
                             |ion mark|hazard  |        |        |        |        
Signal Word (GHS-US)         |Danger                                              
Hazard Statements (GHS-US)   |Hazard Statements                                   
                             |Causes serious eye irritation.                      
                             |Causes skin irritation.                             
                             |May cause allergy or asthma symptoms or breathing   
                             |difficulties if inhaled.                            
                             |May cause an allergic skin reaction.                
                             |May cause respiratory irritation.                   
                             |Causes damage to organs through prolonged or        
                             |repeated exposure: respiratory system               
Precautionary Statements     |General:                                            
(GHS-US)                     |Keep out of reach of children.                      
                             |Prevention:                                         
                             |Do not breathe dust/fume/gas/mist/vapors/spray.     
                             |Use only outdoors or in a well-ventilated area.     
                             |In case of inadequate ventilation wear respiratory  
                             |protection.                                         
                             |Wear eye/face protection.                           
                             |Wear protective gloves.                             
                             |Do not eat, drink or smoke when using this product. 
                             |Wash thoroughly after handling.                     
                             |Contaminated work clothing must not be allowed out  
                             |of the workplace.                                   
                             |Response:                                           
                             |IF INHALED: Remove person to fresh air and keep     
                             |comfortable for breathing.                          
                             |IF INHALED: If breathing is difficult, remove person
                             |to fresh air and keep comfortable for breathing.    
                             |If experiencing respiratory symptoms: Call a POISON 
                             |CENTER or doctor/physician.                         
                             |IF IN EYES: Rinse cautiously with water for several 
                             |minutes. Remove contact lenses, if present and easy 
                             |to do. Continue rinsing.                            
                             |If eye irritation persists: Get medical             
                             |advice/attention.                                   
                             |IF ON SKIN: Wash with plenty of soap and water.     
                             |If skin irritation or rash occurs: Get medical      
                             |advice/attention.                                   
                             |Take off contaminated clothing and wash it before   
                             |reuse.                                              
                             |Get medical advice/attention if you feel unwell.    
                             |Storage:                                            
                             |Store in a well-ventilated place. Keep container    
                             |tightly closed.                                     
                             |Store locked up.                                    
                             |Disposal:                                           
                             |Dispose of contents/container in accordance with    
                             |applicable local/regional/national/international    
                             |regulations.                                        


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Persons previously          
sensitized to isocyanates may develop a cross-sensitization reaction to other     
isocyanates.                                                                      


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                  

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
Polymethylene Polyphenylene     |9016-87-9            |< 30    |                  
Isocyanate                      |                     |Trade   |                  
                                |                     |Secret *|                  
Urethane Prepolymer- N.J.T.S.   |Trade Secret*        |10 - 30 |                  
Registry No. 04499600-7304      |                     |Trade   |                  
                                |                     |Secret *|                  
P,P'-Methylenebis(Phenyl        |101-68-8             |10 - 30 |                  
Isocyanate)                     |                     |Trade   |                  
                                |                     |Secret *|                  
1,1'-Methylenebis(Isocyanatobenz|26447-40-5           |< 5     |                  
ene)                            |                     |Trade   |                  
                                |                     |Secret *|                  
Amorphous Silica                |7631-86-9            |< 1.5   |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Sodium Oxide                    |1313-59-3            |< 0.5   |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Phenyl Isocyanate               |103-71-9             |< 0.5   |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  

*The specific chemical identity and/or exact percentage (concentration) of
this composition has been withheld as a trade secret.
SECTION 4: FIRST AID MEASURES                                                     


4.1.  Description of First Aid Measures
First-aid Measures General:                                                       
First-aid Measures After Inhalation: Remove person to fresh air. If you feel      
unwell, get medical attention.                                                    
First-aid Measures After Skin Contact: Immediately wash with soap and water.      
Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.                                                                
First-aid Measures After Eye Contact: Immediately flush with large amounts of     
water. Remove contact lenses if easy to do. Continue rinsing. Get medical         
attention.                                                                        
First-aid Measures After Ingestion: If Swallowed: Rinse mouth. If you feel unwell,
get medical attention.                                                            


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                                
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Section 11.1. Information on toxicological effects.                               

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Material will not burn. Non-combustible. Use a fire 
fighting agent suitable for surrounding fire.                                     
Unsuitable Extinguishing Media:                                                   


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: None inherent in this product                                        
Explosion Hazard:                                                                 
Reactivity:                                                                       


5.3.  Advice for Firefighters
Precautionary Measures Fire: No special protective actions for fire-fighters are  
anticipated.                                                                      
Firefighting Instructions:                                                        
Protection During Firefighting:                                                   

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Evacuate area. Ventilate the area with fresh air. For large     
spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A   
motor could be an ignition source and could cause flammable gases or vapors in the
spill area to burn or explode. Refer to other sections of this SDS for information
regarding physical and health hazards, respiratory protection, ventilation, and   
personal protective equipment.                                                    


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.2.  Environmental Precautions
Avoid release to the environment.                                                 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:  Contain spill. Pour isocyanate decontaminant solution (90%      
water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10  
minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover
with absorbent material. Working from around the edges of the spill inward, cover 
with bentonite, vermiculite, or commercially available inorganic absorbent        
material. Mix in sufficient absorbent until it appears dry. Remember, adding an   
absorbent material does not remove a physical, health, or environmental hazard.   
Collect as much of the spilled material as possible. Place in a container approved
for transportation by appropriate authorities, but do not seal the container for  
48 hours to avoid pressure build-up.                                              
Methods for Cleaning Up: Clean up residue with an appropriate solvent selected by 
a qualified and authorized person. Ventilate the area with fresh air. Read and    
follow safety precautions on the solvent label and SDS. Dispose of collected      
material as soon as possible.                                                     


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        


SECTION 7: HANDLING AND STORAGE                                                   


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Do not use in a confined area with minimal air 
exchange. Keep out of reach of children. Do not breathe                           
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do  
not eat, drink or smoke when using this product. Wash thoroughly after handling.  
Contaminated work clothing should not be allowed out of the workplace. Avoid      
release to the environment. Wash contaminated clothing before reuse.              
Hygiene Measures:                                                                 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                               
Storage Conditions: Store in a well-ventilated place. Keep container tightly      
closed to prevent contamination with water or air. If contamination is suspected, 
do not reseal container. Store away from amines.                                  


7.3.  Specific End Use(s)
                                                                                  

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  


8.1.  Control Parameters
Ingredient                                                                        
C.A.S. No.                                                                        
Agency                                                                            
Limit type                                                                        
Additional Comments                                                               
                                                                                  
FREE ISOCYANATES                                                                  
101-68-8                                                                          
Manufacturer                                                                      
Determined                                                                        
TWA:0.005 ppm;STEL:0.02 Ppm                                                       
                                                                                  
                                                                                  
P,P'-Methylenebis(Phenyl                                                          
Isocyanate)                                                                       
101-68-8                                                                          
ACGIH                                                                             
TWA:0.005 ppm                                                                     
                                                                                  
                                                                                  
P,P'-Methylenebis(Phenyl Isocyanate)                                              
101-68-8                                                                          
OSHA                                                                              
CEIL:0.2 mg/m3(0.02 ppm)                                                          
                                                                                  
                                                                                  
Talc                                                                              
14807-96-6                                                                        
ACGIH                                                                             
TWA(respirable fraction):2 mg/m3                                                  
A4: Not class. as human Carcin                                                    
                                                                                  
Talc                                                                              
14807-96-6                                                                        
CMRG                                                                              
TWA(as respirable dust):0.5 mg/m3                                                 
                                                                                  
                                                                                  
Talc                                                                              
14807-96-6                                                                        
OSHA                                                                              
TWA concentration(as total dust):0.3 mg/m3;TWA                                    
concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20     
millions oparticles/cu. ft.                                                       
                                                                                  
                                                                                  
FREE ISOCYANATES                                                                  
26447-40-5                                                                        
Manufacturer                                                                      
Determined                                                                        
TWA:0.005 ppm;STEL:0.02 Ppm                                                       
                                                                                  
                                                                                  
Amorphous Silica                                                                  
7631-86-9                                                                         
CMRG                                                                              
TWA(as respirable dust):3 mg/m3                                                   
                                                                                  
                                                                                  
SILICA, AMORPHOUS                                                                 
7631-86-9                                                                         
OSHA                                                                              
TWA concentration:0.8                                                             
mg/m3;TWA:20 millions of                                                          
particles/cu. ft.                                                                 
                                                                                  
                                                                                  
FREE ISOCYANATES                                                                  
9016-87-9                                                                         
Manufacturer                                                                      
Determined                                                                        
TWA:0.005 ppm;STEL:0.02 ppm                                                       
                                                                                  
                                                                                  


8.2.  Exposure Controls
Appropriate Engineering      |Provide ventilated enclosure for heat curing. Curing
Controls                     |enclosures must be exhausted to outdoors or to a    
                             |suitable emission control device. Use general       
                             |dilution ventilation and/or local exhaust           
                             |ventilation to control airborne exposures to below  
                             |relevant Exposure Limits and/or control             
                             |dust/fume/gas/mist/vapors/spray. If ventilation is  
                             |not adequate, use respiratory protection equipment. 
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |                                                    
Eye Protection               |Wear eye/face protection. Select and use eye/face   
                             |protection to prevent contact based on the results  
                             |of an exposure assessment. The following eye/face   
                             |protection(s) are recommended: Indirect Vented      
                             |Goggles.                                            
Skin and Body Protection     |Select and use gloves and/or protective clothing    
                             |approved to relevant local standards to prevent skin
                             |contact based on the results of an exposure         
                             |assessment. Selection should be based on use factors
                             |such as exposure levels, concentration of the       
                             |substance or mixture, frequency and duration,       
                             |physical challenges such as temperature extremes,   
                             |and other use conditions. Consult with your glove   
                             |and/or protective clothing manufacturer for         
                             |selection of appropriate compatible                 
                             |gloves/protective clothing. Wear protective gloves. 
                             |Gloves made from the following material(s) are      
                             |recommended: Butyl Rubber Neoprene If this product  
                             |is used in a manner that presents a higher potential
                             |for exposure (eg. spraying, high splash potential   
                             |etc.), then use of protective coveralls may be      
                             |necessary. Select and use body protection to prevent
                             |contact based on the results of an exposure         
                             |assessment. The following protective clothing       
                             |material(s) are recommended: Apron - Neoprene.      
RespiratoLiquidry Protection |An exposure assessment may be needed to decide if a 
                             |respirator is required. If a respirator is needed,  
                             |use respirators as part of a full respiratory       
                             |protection program. Based on the results of the     
                             |exposure assessment, select from the following      
                             |respirator type(s) to reduce inhalation exposure:   
                             |Half facepiece or full facepiece air-purifying      
                             |respirator suitable for organic vapors and          
                             |particulates. For questions about suitability for a 
                             |specific application, consult with you respirator   
                             |manufacturer.                                       
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid, Paste                                
Appearance                          |                                             
Odor                                |Brown liquid with slight odor                
Odor Threshold                      |No Data Available                            
pH                                  |Not Applicable                               
Relative Evaporation Rate           |Not Applicable                               
(butylacetate=1)                    |                                             
Melting Point                       |No Data Available                            
Freezing Point                      |                                             
Boiling Point                       |406.00 �F [Details: CONDITIONS: @ 5mm Hg]    
Flash Point                         |366.8 �F [Test Method: Tagliabue Closed Cup] 
                                    |[Details: Calculated from RMs]               
Auto-ignition Temperature           |No Data Available                            
Decomposition Temperature           |No Data Available                            
Flammability (solid, gas)           |Not Applicable                               
Vapor Pressure                      |0.0010 mmHg [Details: CONDITIONS: @ 25C]     
Relative Vapor Density at 20 �C     |Not Applicable                               
Relative Density                    |                                             
Specific Gravity                    |1.340 [Ref Std: WATER=1]                     
Solubility                          |Slight (less than 10%)                       
Partition coefficient:              |No Data Available                            
n-octanol/water                     |                                             
Viscosity                           |15,000 - 40,000 centipoise                   
Lower Flammable Limit               |                                             
Upper Flammable Limit               |                                             


9.2.  Other Information
Hazardous Air Pollutants 15.23 % weight [Test Method: Calculated]                 
Volatile Organic Compounds 7 g/l [Test Method: calculated SCAQMD rule 443.1]      
Volatile Organic Compounds 0.5 % weight [Test Method: calculated per CARB title 2]
                                                                                  
Percent volatile 0.5 %                                                            
VOC Less H2O & Exempt Solvents 7 g/l [Test Method: calculated SCAQMD rule 443.1]  

SECTION 10: STABILITY AND REACTIVITY                                              


10.1      Reactivity
This material may be reactive with certain agents under certain conditions - see  
the remaining headings in this section.                                           


10.2      Chemical Stability
Stable.                                                                           


10.3      Possibility of Hazardous Reactions
Hazardous polymerization will not occur.                                          


10.4      Conditions to Avoid
Not determined                                                                    


10.5      Incompatible Materials
Amines. Alcohols. Water. Reaction with water, alcohols, and amines is not         
hazardous if container can vent to the atmosphere to prevent pressure buildup.    


10.6      Hazardous Decomposition Products
Substance                                             Condition                   
Hydrocarbons                               During Combustion                      
Isocyanates                                   During Combustion                   
Carbon monoxide                          During Combustion                        
Carbon dioxide                               During Combustion                    
Hydrogen Cyanide                          During Combustion                       
Oxides of Nitrogen                        During Combustion                       
Toxic Vapor, Gas, Particulate      During Combustion                              

SECTION 11: TOXICOLOGICAL INFORMATION                                             


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                   
Name                                                                              
Route                                                                             
Species                                                                           
Value                                                                             
                                                                                  
Overall product                                                                   
Inhalation-Vapor(4 hr)                                                            
                                                                                  
No data available; calculated ATE 20 - 50 mg/l                                    
                                                                                  
Overall product                                                                   
Ingestion                                                                         
                                                                                  
No data available; calculated ATE > 5,000 mg/kg                                   
                                                                                  
Polymethylene Polyphenylene Isocyanate                                            
Inhalation-Vapor                                                                  
                                                                                  
LC50 estimated to be 10 - 20 mg/l                                                 
                                                                                  
Polymethylene Polyphenylene Isocyanate                                            
Dermal                                                                            
Rabbit                                                                            
LD50 > 5,000 mg/kg                                                                
                                                                                  
Polymethylene Polyphenylene Isocyanate                                            
Inhalation-Dust/Mist (4 hours)                                                    
Rat                                                                               
LC50 0.369 mg/l                                                                   
                                                                                  
Polymethylene Polyphenylene Isocyanate                                            
Ingestion                                                                         
Rat                                                                               
LD50 31,600 mg/kg                                                                 
                                                                                  
Talc                                                                              
Dermal                                                                            
                                                                                  
LD50 Not available                                                                
                                                                                  
Talc                                                                              
Ingestion                                                                         
                                                                                  
LD50 Not available                                                                
                                                                                  
Urethane Prepolymer- N.J.T.S. Registry No. 04499600-7304                          
Dermal                                                                            
                                                                                  
LD50 estimated to be > 5,000 mg/kg                                                
                                                                                  
Urethane Prepolymer- N.J.T.S. Registry No. 04499600-7304                          
Ingestion                                                                         
                                                                                  
LD50 estimated to be 2,000 - 5,000 mg/kg                                          
                                                                                  
P,P'-Methylenebis(Phenyl Isocyanate)                                              
Inhalation-Vapor                                                                  
                                                                                  
LC50 estimated to be 10 - 20 mg/l                                                 
                                                                                  
P,P'-Methylenebis(Phenyl Isocyanate)                                              
Dermal                                                                            
Rabbit                                                                            
LD50 > 5,000 mg/kg                                                                
                                                                                  
P,P'-Methylenebis(Phenyl Isocyanate)                                              
Inhalation-Dust/Mist                                                              
(4 hours)                                                                         
Rat                                                                               
LC50 0.369 mg/l                                                                   
                                                                                  
P,P'-Methylenebis(Phenyl Isocyanate)                                              
Ingestion                                                                         
Rat                                                                               
LD50 31,600 mg/kg                                                                 
                                                                                  
1,1'-Methylenebis(Isocyanatobenzene)                                              
Inhalation-Vapor                                                                  
                                                                                  
LC50 estimated to be 10 - 20 mg/l                                                 
                                                                                  
1,1'-Methylenebis(Isocyanatobenzene)                                              
Dermal                                                                            
Rabbit                                                                            
LD50 > 5,000 mg/kg                                                                
                                                                                  
1,1'-Methylenebis(Isocyanatobenzene)                                              
Inhalation-Dust/Mist-(4 hours)                                                    
Rat                                                                               
LC50 0.369 mg/l                                                                   
                                                                                  
1,1'-Methylenebis(Isocyanatobenzene)                                              
Ingestion                                                                         
Rat                                                                               
LD50 31,600 mg/kg                                                                 
                                                                                  
Amorphous Silica                                                                  
Dermal                                                                            
Rabbit                                                                            
LD50 > 5,000 mg/kg                                                                
                                                                                  
Amorphous Silica                                                                  
Inhalation-Dust/Mist (4 hours)                                                    
Rat                                                                               
LC50 > 0.691 mg/l                                                                 
                                                                                  
Amorphous Silica                                                                  
Ingestion                                                                         
Rat                                                                               
LD50 > 5,110 mg/kg                                                                
                                                                                  
Sodium Oxide                                                                      
Ingestion                                                                         
                                                                                  
LD50 estimated to be 50 - 300 mg/kg                                               
                                                                                  
Skin Corrosion/Irritation:                                                        
Name                                                                              
Species                                                                           
Value                                                                             
                                                                                  
Polymethylene Polyphenylene Isocyanate                                            
Official Classifica tion                                                          
Irritant                                                                          
                                                                                  
Talc                                                                              
Rabbit                                                                            
No significant irritation                                                         
                                                                                  
P,P'-Methylenebis(Phenyl Isocyanate)                                              
Official classification                                                           
Irritant                                                                          
                                                                                  
1,1'-Methylenebis(Isocyanatobenzene)                                              
Official classification                                                           
Irritant                                                                          
                                                                                  
Amorphous Silica                                                                  
Rabbit                                                                            
No significant irritation                                                         
                                                                                  
Serious Eye Damage/Irritation:                                                    
Name                                                                              
Species                                                                           
Value                                                                             
                                                                                  
Polymethylene Polyphenylene Isocyanate                                            
Official classification                                                           
Severe irritant                                                                   
                                                                                  
Talc                                                                              
Rabbit                                                                            
No significant irritation                                                         
                                                                                  
P,P'-Methylenebis(Phenyl Isocyanate)                                              
Official classification                                                           
Severe irritant                                                                   
                                                                                  
1,1'-Methylenebis(Isocyanatobenzene)                                              
Official classification                                                           
Severe irritant                                                                   
                                                                                  
Amorphous Silica                                                                  
Rabbit                                                                            
No significant irritation                                                         
                                                                                  
Respiratory or Skin Sensitization:                                                
Name                                                                              
Species                                                                           
Value                                                                             
                                                                                  
Polymethylene Polyphenylene Isocyanate                                            
Official classification                                                           
Sensitizing                                                                       
                                                                                  
P,P'-Methylenebis(Phenyl Isocyanate)                                              
Official classification                                                           
Sensitizing                                                                       
                                                                                  
1,1'-Methylenebis(Isocyanatobenzene)                                              
Official classification                                                           
Sensitizing                                                                       
                                                                                  
Amorphous Silica                                                                  
Human And animal                                                                  
Not sensitizing                                                                   
                                                                                  
Germ Cell Mutagenicity:                                                           
Name                                                                              
Route                                                                             
Value                                                                             
                                                                                  
Polymethylene Polyphenylene Isocyanate                                            
In Vitro                                                                          
Some positive data exist, but the data are not sufficient for classification      
                                                                                  
Talc                                                                              
In Vitro                                                                          
Not mutagenic                                                                     
                                                                                  
Talc                                                                              
In vivo                                                                           
Not mutagenic                                                                     
                                                                                  
P,P'-Methylenebis(Phenyl Isocyanate)                                              
In Vitro                                                                          
Some positive data exist, but the data are not sufficient for classification      
                                                                                  
1,1'-Methylenebis(Isocyanatobenzene)                                              
In Vitro                                                                          
Some positive data exist, but the data are not sufficient for classification      
                                                                                  
Amorphous Silica                                                                  
In Vitro                                                                          
Not mutagenic                                                                     
                                                                                  
Carcinogenicity:                                                                  
Reproductive Toxicity:                                                            
Specific Target Organ Toxicity (Single Exposure):                                 
Specific Target Organ Toxicity (Repeated Exposure): Respiratory Effects:          
Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, 
increased heart rate, bluish colored skin (cyanosis), sputum production, changes  
in lung function tests, and/or respiratory failure.                               
Aspiration Hazard:                                                                
Symptoms/Injuries After Inhalation: May be harmful if inhaled. Respiratory Tract  
Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache,
hoarseness, and nose and throat pain. Allergic Respiratory Reaction:              
Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of
chest. May cause target organ effects after inhalation.                           
Symptoms/Injuries After Skin Contact: Skin Irritation: Signs/symptoms may include 
localized redness, swelling, itching, dryness, cracking, blistering, and pain.    
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness,   
swelling, blistering, and itching.                                                
Symptoms/Injuries After Eye Contact: Severe Eye Irritation: Signs/symptoms may    
include significant redness, swelling, pain, tearing, cloudy appearance of the    
cornea, and impaired vision.                                                      
Symptoms/Injuries After Ingestion: Gastrointestinal Irritation: Signs/symptoms may
include abdominal pain, stomach upset, nausea, vomiting and diarrhea.             
Chronic Symptoms:                                                                 

SECTION 12: ECOLOGICAL INFORMATION                                                


12.1. Toxicity
Please contact the address or phone number listed on the first page of the SDS for
additional ecotoxicological information on this material and/or its components.   


12.2. Persistence and Degradability
                                                                                  


12.3. Bioaccumulative Potential
                                                                                  


12.4. Mobility in Soil
                                                                                  


12.5. Other Adverse Effects
Chemical fate information: Please contact the address or phone number listed on   
the first page of the SDS for additional chemical fate information on this        
material and/or its components.                                                   

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose of contents/ container in accordance with 
the local/regional/national/international regulations. Incinerate in a permitted  
waste incineration facility. As a disposal alternative, utilize an acceptable     
permitted waste disposal facility. Proper destruction may require the use of      
additional fuel during incineration processes. Empty drums/barrels/containers used
for transporting and handling hazardous chemicals (chemical                       
substances/mixtures/preparations                                                  
classified as Hazardous as per applicable regulations) shall be considered,       
stored, treated & disposed of as hazardous wastes                                 
unless otherwise defined by applicable waste regulations. Consult with the        
respective regulating authorities to determine the                                
available treatment and disposal facilities.                                      
Additional Information:                                                           

SECTION 14: TRANSPORT INFORMATION                                                 


14.1 In Accordance with DOT
Proper Shipping Name |                                                            
Hazard Class         |                       |<PICTOGRAM PHRASE>                  
Identification Number|                       |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            


14.2 In Accordance with IMDG
Proper Shipping Name |                                                            
Hazard Class         |                                                            
Identification Number|                                                            
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     


14.3 In Accordance with IATA
Proper Shipping Name |                                                            
Identification Number|                       |<PICTOGRAM PHRASE>                   
Hazard Class         |                       |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
Contact 3M for more information.                                                  
SARA Section 311/312 Hazard Classes |Fire Hazard - No                             
                                    |Pressure Hazard - No                         
                                    |Reactivity Hazard - No                       
                                    |Immediate Hazard - Yes                       
                                    |Delayed Hazard - Yes                         
Toxic Substances Control Act (TSCA) |The components of this product are in        
                                    |compliance with the chemical notification    
                                    |requirements of TSCA.                        
                                    |Contact 3M for more information.             

15.2      US State Regulations
Contact 3M for more information.                                                  
<COMPONENT>                                                                       
Ingredient                                                                        
C.A.S. No                % by Wt                                                  
Polymethylene Polyphenylene Isocyanate                      9016-87-9             
< 30                                                                              
Polymethylene Polyphenylene Isocyanate                      9016-87-9             
< 30                                                                              
(Benzene, 1,1'-methylenebis[4-isocyanato-)                                        
Polymethylene Polyphenylene Isocyanate                      9016-87-9             
< 30                                                                              
(DIISOCYANATES (CERTAIN CHEMICALS ONLY))                                          
P,P'-Methylenebis(Phenyl Isocyanate)                             101-68-8         
10 - 30                                                                           
P,P'-Methylenebis(Phenyl Isocyanate) (Benzene,                                    
1,1'-methylenebis[4-isocyanato-)                                                  
P,P'-Methylenebis(Phenyl Isocyanate)                              101-68-8        
10 - 30                                                                           
(DIISOCYANATES (CERTAIN CHEMICALS ONLY))                                          
                                                                                  

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION     

Revision date   |                                                                 
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
                |1910.1200.                                                       
GHS Full Text Phrases:                                                            
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             


Grainger disclaimer.

































Safety Data Sheet                                                                 
Date of Issue: 07/25/14    |Revision Date:             |Revision Number: 44.00    
Imperial Supplies Part Number: 0077720                                            

SECTION 1: IDENTIFICATION                                                         


1.1.  Product Identifier
Product Form: Liquid                                                              
Product Name: 3M Structural Adhesive Part B, PN 08101                             
CAS No:                                                                           
Synonyms:                                                                         


1.2.  Intended Use of the Product
Use of the substance/mixture: Automotive, Base portion of a two-part general      
purpose structural adhesive that may be used for bonding metal, glass and plastic.


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                           
3M                                                                                
Automotive Aftermarket                                                            
3M Center, St. Paul, MN 55144-1000, USA                                           
Phone: 1-888-3M HELPS (1-888-364-3577)                                            
                                                                                  
Supplier: Imperial Supplies LLC                                                   


1.4.  Emergency Telephone Number
Emergency     | 1-800-364-3577 or (651) 737-6501 (24 hours)                       
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Serious Eye   |Category 2B.  
Damage/Irritat|              
ion           |              
Skin          |Category 1B.  
Sensitizer    |              
Reproductive  |Category 2.   
Toxicity      |              
Carcinogenicit|Category 2.   
y:            |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamat|Health  |        |        |        |        
                             |ion mark|hazard  |        |        |        |        
Signal Word (GHS-US)         |Warning                                             
Hazard Statements (GHS-US)   |Causes eye irritation.                              
                             |May cause an allergic skin reaction.                
                             |Suspected of damaging fertility or the unborn child.
                             |                                                    
                             |Suspected of causing cancer.                        
Precautionary Statements     |General:                                            
(GHS-US)                     |Keep out of reach of children.                      
                             |Prevention:                                         
                             |Obtain special instructions before use.             
                             |Do not handle until all safety precautions have been
                             |read and understood.                                
                             |Avoid breathing dust/fume/gas/mist/vapors/spray.    
                             |Wear protective gloves.                             
                             |Wash thoroughly after handling.                     
                             |Contaminated work clothing must not be allowed out  
                             |of the workplace.                                   
                             |Response:                                           
                             |IF IN EYES: Rinse cautiously with water for several 
                             |minutes. Remove contact lenses, if present and easy 
                             |to do. Continue rinsing.                            
                             |If eye irritation persists: Get medical             
                             |advice/attention.                                   
                             |IF ON SKIN: Wash with plenty of soap and water.     
                             |If skin irritation or rash occurs: Get medical      
                             |advice/attention.                                   
                             |Wash contaminated clothing before reuse.            
                             |IF exposed or concerned: Get medical                
                             |advice/attention.                                   
                             |Storage:                                            
                             |Store locked up.                                    
                             |Disposal:                                           
                             |Dispose of contents/container in accordance with    
                             |applicable local/regional/national/international    
                             |regulations.                                        


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None.                       
48% of the mixture consists of ingredients of unknown acute oral toxicity.        
49% of the mixture consists of ingredients of unknown acute dermal toxicity.      


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                  

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
Polyester Resin - N.J.T.S.      |Trade Secret*        |40 - 70 |                  
Registry No. 04499600-7301      |                     |Trade   |                  
                                |                     |Secret *|                  
Glycols, Polypropylene          |Trade Secret*        |10 - 30 |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Talc                            |14807-96-6           |10 - 30 |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Titanium Dioxide                |13463-67-7           |5 - 10  |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Trimethylolpropane              |25723-16-4           |3 - 7   |                  
Poly(Oxypropylene) Triether     |                     |Trade   |                  
                                |                     |Secret *|                  
Amorphous Silica                |7631-86-9            |0.1 - 5 |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
4,4'-Methylenebis(2,6-Diethylani|13680-35-8           |0.5 -   |                  
line)                           |                     |1.5     |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  


SECTION 4: FIRST AID MEASURES                                                     


4.1.  Description of First Aid Measures
First-aid Measures General:                                                       
First-aid Measures After Inhalation: Remove person to fresh air. If you feel      
unwell, get medical attention.                                                    
First-aid Measures After Skin Contact: Immediately wash with soap and water.      
Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.                                                                
First-aid Measures After Eye Contact: Flush with large amounts of water. Remove   
contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get    
medical attention.                                                                
First-aid Measures After Ingestion: If Swallowed: Rinse mouth. If you feel unwell,
get medical attention.                                                            


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: See Section 11.1. Information on toxicological effects.        
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Not applicable.                                                                   

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: In case of fire: Use a carbon dioxide or dry        
chemical extinguisher to extinguish.                                              
Unsuitable Extinguishing Media:                                                   


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: None inherent in this product.                                       
Explosion Hazard:                                                                 
Reactivity:                                                                       


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions:                                                        
Protection During Firefighting: No special protective actions for fire-fighters   
are anticipated.                                                                  

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:                                                                 


6.1.1.      For Non-emergency Personnel
Protective Equipment: Evacuate area. Ventilate the area with fresh air. For large 
spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A   
motor could be an ignition source and could cause flammable gases or vapors in the
spill area to burn or explode. Refer to other sections of this SDS for information
regarding physical and health hazards, respiratory protection, ventilation, and   
personal protective equipment.                                                    
Emergency Procedures:                                                             


6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.2.  Environmental Precautions
Avoid release to the environment. For larger spills, cover drains and build dikes 
to prevent entry into sewer systems or bodies of water.                           


6.3.  Methods and Material for Containment and Cleaning Up
For Containment                                                                   
Methods for Cleaning Up: Contain spill. Working from around the edges of the spill
inward, cover with bentonite, vermiculite, or commercially available inorganic    
absorbent material. Mix in sufficient absorbent until it appears dry. Remember,   
adding an absorbent material does not remove a physical, health, or environmental 
hazard. Collect as much of the spilled material as possible. Place in a closed    
container approved for transportation by appropriate authorities. Clean up residue
with an appropriate solvent selected by a qualified and authorized person.        
Ventilate the area with fresh air. Read and follow safety precautions on the      
solvent label and SDS. Seal the container. Dispose of collected material as soon  
as possible.                                                                      


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        


SECTION 7: HANDLING AND STORAGE                                                   


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Keep out of reach of children. Do not handle   
until all safety precautions have been read and understood. Avoid breathing       
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do  
not eat, drink or smoke when using this product. Wash thoroughly after handling.  
Contaminated work clothing should not be allowed out of the workplace. Wash       
contaminated clothing before reuse. Use personal protective equipment (gloves,    
respirators, etc.) as required.                                                   
Hygiene Measures:                                                                 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                               
Storage Conditions: No special storage requirements.                              


7.3.  Specific End Use(s)
                                                                                  

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  


8.1.  Control Parameters
Ingredient                                                                        
C.A.S. No.                                                                        
Agency                                                                            
Limit type                                                                        
Additional Comments                                                               
                                                                                  
Titanium Dioxide                                                                  
13463-67-7                                                                        
ACGIH                                                                             
TWA:10 mg/m3                                                                      
A4: Not class. as human carcin                                                    
                                                                                  
Titanium Dioxide                                                                  
13463-67-7                                                                        
CMRG                                                                              
TWA(as respirable dust):5 mg/m3                                                   
                                                                                  
                                                                                  
Titanium Dioxide                                                                  
13463-67-7                                                                        
OSHA                                                                              
TWA(as total dust):15 mg/m3                                                       
                                                                                  
                                                                                  
Talc                                                                              
14807-96-6                                                                        
ACGIH                                                                             
TWA(respirable fraction):2 mg/m3                                                  
A4: Not class. as human carcin                                                    
                                                                                  
Talc                                                                              
14807-96-6                                                                        
CMRG                                                                              
TWA(as respirable dust):0.5 mg/m3                                                 
                                                                                  
                                                                                  
Talc                                                                              
14807-96-6                                                                        
OSHA                                                                              
TWA concentration(as total dust):0.3 mg/m3;TWA                                    
concentration(respirable):0.1 mg/m3(2.4 millions of                               
particles/cu. ft.);TWA:20 millions of particles/cu. ft.                           
                                                                                  
                                                                                  
Amorphous Silica                                                                  
7631-86-9                                                                         
CMRG                                                                              
TWA(as respirable dust):3 mg/m3                                                   
                                                                                  
                                                                                  
SILICA, AMORPHOUS                                                                 
7631-86-9                                                                         
OSHA                                                                              
TWA concentration:0.8                                                             
mg/m3;TWA:20 millions of particles/cu. ft.                                        
                                                                                  
                                                                                  
Glycols, Polypropylene                                                            
Trade Secret                                                                      
AIHA                                                                              
TWA(as aerosol):10 mg/m3                                                          
                                                                                  
                                                                                  


8.2.  Exposure Controls
Appropriate Engineering      |Use with appropriate local exhaust ventilation.     
Controls                     |Provide ventilated enclosure for heat curing. Curing
                             |enclosures must be exhausted to outdoors or to a    
                             |suitable emission control device. Use general       
                             |dilution ventilation and/or local exhaust           
                             |ventilation to control airborne exposures to below  
                             |relevant Exposure Limits and/or control             
                             |dust/fume/gas/mist/vapors/spray. If ventilation is  
                             |not adequate, use respiratory protection equipment. 
                             |Provide appropriate local exhaust ventilation for   
                             |cutting, grinding, sanding or machining.            
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |                                                    
Eye Protection               |Wear eye/face protection. Select and use eye/face   
                             |protection to prevent contact based on the results  
                             |of an exposure assessment. The following eye/face   
                             |protection(s) are recommended: Indirect Vented      
                             |Goggles.                                            
Skin and Body Protection     |Select and use gloves and/or protective clothing    
                             |approved to relevant local standards to prevent skin
                             |contact based on the results of an exposure         
                             |assessment. Selection should be based on use factors
                             |such as exposure levels, concentration of the       
                             |substance or mixture, frequency and duration,       
                             |physical challenges such as temperature extremes,   
                             |and other use conditions. Consult with your glove   
                             |and/or protective clothing manufacturer for         
                             |selection of appropriate compatible                 
                             |gloves/protective clothing. Wear protective gloves. 
                             |Gloves made from the following material(s) are      
                             |recommended: Nitrile Rubber Polymer laminate If this
                             |product is used in a manner that presents a higher  
                             |potential for exposure (eg. spraying, high splash   
                             |potential etc.), then use of protective coveralls   
                             |may be necessary. Select and use body protection to 
                             |prevent contact based on the results of an exposure 
                             |assessment. The following protective clothing       
                             |material(s) are recommended: Apron - Nitrile.       
Respiratory Protection       |An exposure assessment may be needed to decide if a 
                             |respirator is required. If a respirator is needed,  
                             |use respirators as part of a full respiratory       
                             |protection program. Based on the results of the     
                             |exposure assessment, select from the following      
                             |respirator type(s) to reduce inhalation exposure:   
                             |Half facepiece or full facepiece air-purifying      
                             |respirator suitable for particulates. For questions 
                             |about suitability for a specific application,       
                             |consult with your respirator manufacturer.          
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                       
Appearance                          |                                             
Odor                                |White with resinous odor                     
Odor Threshold                      |No Data Available                            
pH                                  |Not Applicable                               
Relative Evaporation Rate           |Not Applicable                               
(butylacetate=1)                    |                                             
Melting Point                       |No Data Available                            
Freezing Point                      |                                             
Boiling Point                       |Not Applicable                               
Flash Point                         |366.8 Deg F [Test Method: Tagliabue Closed   
                                    |Cup] [Details: Calculated from RMs]          
Auto-ignition Temperature           |No Data Available                            
Decomposition Temperature           |No Data Available                            
Flammability (solid, gas)           |Not Applicable                               
Vapor Pressure                      |Not Applicable                               
Relative Vapor Density at 20 �C     |Not Applicable                               
Relative Density                    |                                             
Specific Gravity                    |1.310 [Ref Std: WATER=1]                     
Solubility                          |                                             
Partition coefficient:              |No Data Available                            
n-octanol/water                     |                                             
Viscosity                           |5,000 - 40,000 centipoise                    
Lower Flammable Limit               |No Data Available                            
Upper Flammable Limit               |No Data Available                            


9.2.  Other Information
Viscosity 5,000 - 40,000 centipoise                                               
Hazardous Air Pollutants 0 % weight [Test Method: Calculated]                     
Volatile Organic Compounds 0 g/l [Test Method: calculated SCAQMD rule 443.1]      
Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2]  
Percent volatile 0.00 %                                                           
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1]  

SECTION 10: STABILITY AND REACTIVITY                                              


10.1      Reactivity
This material is considered to be non reactive under normal use conditions.       


10.2      Chemical Stability
Stable.                                                                           


10.3      Possibility of Hazardous Reactions
Hazardous polymerization will not occur                                           


10.4      Conditions to Avoid
None known.                                                                       


10.5      Incompatible Materials
None known.                                                                       


10.6      Hazardous Decomposition Products
Substance                    Condition                                            
Carbon monoxide     During Combustion                                             
Carbon dioxide          During Combustion                                         

SECTION 11: TOXICOLOGICAL INFORMATION                                             


11.1. Information on Toxicological Effects
Acute Toxicity: The information below may not be consistent with the material     
classification in Section 2 if specific ingredient                                
classifications are mandated by a competent authority. In addition, toxicological 
data on ingredients may not be                                                    
reflected in the material classification and/or the signs and symptoms of         
exposure, because an ingredient may be                                            
present below the threshold for labeling, an ingredient may not be available for  
exposure, or the data may not be                                                  
relevant to the material as a whole.                                              
Skin Corrosion/Irritation:                                                        
Serious Eye Damage/Irritation:                                                    
Respiratory or Skin Sensitization:                                                
Germ Cell Mutagenicity:                                                           
Carcinogenicity: Contains a chemical or chemicals which can cause cancer.         
Ingredient                C.A.S. No.                     Class Description        
Regulation                                                                        
Titanium Dioxide    13463-67-7             Grp. 2B: Possible human carc.          
International Agency for Research on Cancer                                       
Reproductive Toxicity: Contains a chemical or chemicals which can cause birth     
defects or other reproductive harm.                                               
Specific Target Organ Toxicity (Single Exposure):                                 
Specific Target Organ Toxicity (Repeated Exposure):                               
Aspiration Hazard:                                                                
Symptoms/Injuries After Inhalation: Respiratory Tract Irritation: Signs/symptoms  
may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and  
throat pain.                                                                      
Symptoms/Injuries After Skin Contact: Allergic Skin Reaction (non-photo induced): 
Signs/symptoms may include redness, swelling, blistering, and itching.            
Symptoms/Injuries After Eye Contact: Moderate Eye Irritation: Signs/symptoms may  
include redness, swelling, pain, tearing, and blurred or hazy vision.             
Symptoms/Injuries After Ingestion: May be harmful if swallowed.                   
Chronic Symptoms:                                                                 

SECTION 12: ECOLOGICAL INFORMATION                                                


12.1. Toxicity
Please contact the address or phone number listed on the first page of the SDS for
additional ecotoxicological information on this material and/or its components.   


12.2. Persistence and Degradability
                                                                                  


12.3. Bioaccumulative Potential
                                                                                  


12.4. Mobility in Soil
                                                                                  


12.5. Other Adverse Effects
Chemical fate information: Please contact the address or phone number listed on   
the first page of the SDS for additional chemical fate information on this        
material and/or its components.                                                   

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose of contents/ container in accordance with 
the local/regional/national/international regulations. Incinerate in a permitted  
waste incineration facility. Proper destruction may require the use of additional 
fuel during                                                                       
incineration processes. As a disposal alternative, utilize an acceptable permitted
waste disposal facility. Empty drums/barrels/containers used for transporting and 
handling hazardous chemicals (chemical substances/mixtures/preparations           
classified as Hazardous as per applicable regulations) shall be considered,       
stored, treated & disposed of as hazardous wastes                                 
unless otherwise defined by applicable waste regulations. Consult with the        
respective regulating authorities to determine the                                
available treatment and disposal facilities.                                      
Additional Information:                                                           

SECTION 14: TRANSPORT INFORMATION                                                 


14.1 In Accordance with DOT
Proper Shipping Name |                                                            
Hazard Class         |                       |<PICTOGRAM PHRASE>                  
Identification Number|                       |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            


14.2 In Accordance with IMDG
Proper Shipping Name |                                                            
Hazard Class         |                                                            
Identification Number|                                                            
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     


14.3 In Accordance with IATA
Proper Shipping Name |                                                            
Identification Number|                       |<PICTOGRAM PHRASE>                   
Hazard Class         |                       |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
<COMPONENT>Contact 3M for more information.                                       
SARA Section 311/312 Hazard Classes |Fire Hazard - No                             
                                    |Pressure Hazard - No                         
                                    |Reactivity Hazard - No                       
                                    |Immediate Hazard - Yes                       
                                    |Delayed Hazard - Yes                         
Toxic Substances Control Act (TSCA) |                                             

15.2      US State Regulations
Contact 3M for more information.                                                  
<COMPONENT>                                                                       
Titanium Dioxide                   13463-67-7                      Carcinogen     
WARNING: This product contains a chemical known to the State of California to     
cause cancer.                                                                     

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION     

Revision date   |                                                                 
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
                |1910.1200.                                                       
GHS Full Text Phrases:                                                            
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             


Grainger disclaimer.

    

The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.

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