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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 3M Urethane Seam Sealer, Gray, PN 08361, 08362 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Automotive, Adhesive/Sealant 1.3. Name, Address, and Telephone of the Responsible Party Company 3M DIVISION: Automotive Aftermarket 3M Center, St. Paul, MN 55144-1000, USA Phone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency Telephone Number Emergency | 1-800-364-3577 or (651) 737-6501 (24 hours) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Serious Eye |Category 2A. Damage/Irritat| ion | Respiratory |Category 1. Sensitizer | Skin |Category 1. Sensitizer | Carcinogenicit|Category 2. y | Specific |Category 1. Target Organ | Toxicity | (single | exposure) | Specific |Category 1. Target Organ | Toxicity | (repeated | exposure) | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Health Hazard Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Causes serious eye irritation. |May cause allergy or asthma symptoms or breathing |difficulties if inhaled. |May cause an allergic skin reaction. |Suspected of causing cancer. |Causes damage to organs: sensory organs |Causes damage to organs through prolonged or |repeated exposure: nervous system |May cause damage to organs through prolonged or |repeated exposure: sensory organs Precautionary Statements |General: (GHS-US) |Keep out of reach of children. | |Prevention: |Obtain special instructions before use. |Do not handle until all safety precautions have been |read and understood. |Do not breathe dust/fume/gas/mist/vapors/spray. |In case of inadequate ventilation wear respiratory |protection. |Wear protective gloves and eye/face protection. |Do not eat, drink or smoke when using this product. |Wash thoroughly after handling. |Contaminated work clothing must not be allowed out |of the workplace. | |Response: |IF INHALED: If breathing is difficult, remove person |to fresh air and keep comfortable for breathing. |If experiencing respiratory symptoms: Call a POISON |CENTER or doctor/physician. |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention. |IF ON SKIN: Wash with plenty of soap and water. |If skin irritation or rash occurs: Get medical |advice/attention. |Wash contaminated clothing before reuse. |Get medical advice/attention if you feel unwell. | |Storage: |Store locked up. | |Disposal: |Dispose of contents/container in accordance with |applicable local/regional/national/international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Urethane Polymer |68130-40-5 |15 - 40 | | |Trade | | |Secret *| Poly (Vinyl Chloride) |9002-86-2 |10 - 30 | | |Trade | | |Secret *| Sulfonic Acids, C10-18-Alkane, |70775-94-9 |10 - 30 | Ph Esters | |Trade | | |Secret *| Xylene |1330-20-7 |4 - 10 | | |Trade | | |Secret *| Titanium Dioxide |13463-67-7 |1 - 5 | | |Trade | | |Secret *| Calcium Oxide |1305-78-8 |1 - 5 | | |Trade | | |Secret *| Ethylbenzene |100-41-4 |1 - 5 | | |Trade | | |Secret *| Hydrotreated Light Petroleum |64742-47-8 |0.5 - | Distillates | |1.5 | | |Trade | | |Secret *| P,P'-Methylenebis(phenyl |101-68-8 |< 0.2 | isocyanate) | |Trade | | |Secret *| SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. First-aid Measures After Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. First-aid Measures After Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. First-aid Measures After Ingestion: If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Not applicable SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: DO NOT USE WATER In case of fire: Use a carbon dioxide or dry chemical extinguisher to extinguish. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: No special protective actions for fire-fighters are anticipated. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental Precautions Avoid release to the environment. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Collect as much of the spilled material as possible. Place in a container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Clean up residue. Dispose of collected material as soon as possible. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Keep away from reactive metals (eg. Aluminum, zinc etc.) to avoid the formation of hydrogen gas that could create an explosion hazard. Use personal protective equipment (gloves, respirators, etc.) as required. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Keep cool. Protect from sunlight. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store in a dry place. Store away from amines. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA: 20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 OSHA TWA: 435 mg/m3(100 ppm) Ethylbenzene 100-41-4 CMRG TWA: 25 ppm;STEL:75 ppm FREE ISOCYANATES 101-68-8 Manufacturer determined TWA: 0.005 ppm; STEL: 0.02 ppm P,P'-Methylenebis(phenyl isocyanate) 101-68-8 OSHA CEIL: 0.2 mg/m3(0.02 ppm) P,P'-Methylenebis(phenyl isocyanate) 101-68-8 ACGIH TWA:0.005 ppm Calcium Oxide 1305-78-8 ACGIH TWA: 2 mg/m3 Calcium Oxide 1305-78-8 OSHA TWA: 5 mg/m3 Xylene 1330-20-7 CMRG TWA: 50 ppm; STEL: 75 ppm Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm) Xylene 1330-20-7 ACGIH TWA: 100 ppm; STEL: 150 ppm A4: Not class. as human carcin Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust): 5 mg/m3 Hydrotreated Light Petroleum Distillates 64742-47-8 CMRG TWA: 165 ppm Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., Skin Notation Poly (Vinyl Chloride) 9002-86-2 ACGIH TWA(respirable fraction): 1 mg/m3 A4: Not class. as human carcin 8.2. Exposure Controls Appropriate Engineering |Provide local exhaust ventilation at transfer Controls |points. Provide ventilated enclosure for heat |curing. Curing enclosures must be exhausted to |outdoors or to a suitable emission control device. |Provide ventilation adequate to maintain dust |concentration below minimum explosive |concentrations. Use general dilution ventilation |and/or local exhaust ventilation to control airborne |exposures to below relevant Exposure Limits and/or |control dust/fume/gas/mist/vapors/spray. If |ventilation is not adequate, use respiratory |protection equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Select and use eye/face protection to prevent |contact based on the results of an exposure |assessment. The following eye/face protection(s) are |recommended: Indirect Vented Goggles. Skin and Body Protection |Hand Protection: Select and use gloves and/or |protective clothing approved to relevant local |standards to prevent skin contact based on the |results of an exposure assessment. Selection should |be based on use factors such as exposure levels, |concentration of the substance or mixture, frequency |and duration, physical challenges such as |temperature extremes, and other use conditions. |Consult with your glove and/or protective clothing |manufacturer for selection of appropriate compatible |gloves/protective Clothing. Gloves made from the |following material(s) are recommended: Nitrile |Rubber Natural Rubber. If this product is used in a |manner that presents a higher potential for exposure |(eg. spraying, high splash potential etc.), then use |of protective coveralls may be necessary. Select and |use body protection to prevent contact based on the |results of an exposure assessment. The following |protective clothing material(s) are recommended: |Apron - Nitrile. Respiratory Protection |An exposure assessment may be needed to decide if a |respirator is required. If a respirator is needed, |use respirators as part of a full respiratory |protection program. Based on the results of the |exposure assessment, select from the following |respirator type(s) to reduce inhalation exposure: |Half facepiece or full facepiece air-purifying |respirator suitable for organic vapors and |particulates For questions about suitability for a |specific application, consult with your respirator |manufacturer. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Solid Appearance | Odor |Solvent odor, black paste. Odor Threshold |No Data Available pH |Not Applicable Relative Evaporation Rate |Not Applicable (butylacetate=1) | Melting Point |Not Applicable Freezing Point | Boiling Point |137 �C Flash Point |No flash point Auto-ignition Temperature |> 200 �C Decomposition Temperature |No Data Available Flammability (solid, gas) |Not Classified Vapor Pressure |No Data Available Relative Vapor Density at 20 �C |4 [Ref Std: AIR=1] Relative Density | Specific Gravity |1.17 [Ref Std: WATER=1] Solubility |Negligible Partition coefficient: | n-octanol/water | Viscosity |No Data Available Lower Flammable Limit |0.6 % volume Upper Flammable Limit |7 % volume 9.2. Other Information Volatile Organic Compounds 108 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 9.3 % weight [Test Method: calculated per CARB title 2] Percent volatile 9.3 % weight [Details: Excluding exempt compounds] VOC Less H2O & Exempt Solvents 108 g/l [Test Method: tested per EPA method 24] SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Heat. High shear and high temperature conditions. Sparks and/or flames. Temperatures above the boiling point. 10.5 Incompatible Materials Amines, Alcohols, Water, Reaction with water, alcohols, and amines is not hazardous if container can vent to the atmosphere to prevent pressure Buildup. Accelerators, Alkali and alkaline earth metals, Reactive metals, Reducing agents, Strong acids, Strong bases, Strong oxidizing agents. Al or Mg powder and high/shear temperature conditions. Combustibles. Finely divided active metals 10.6 Hazardous Decomposition Products None known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Serious Eye Damage/Irritation: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations Contact 3M for more information. Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Xylene 1330-20-7 4 - 10 Xylene (Benzene, dimethyl-) 1330-20-7 4 - 10 Xylene (Benzene, 1,2-dimethyl-) 1330-20-7 4 - 10 Xylene (Benzene, 1,3-dimethyl-) 1330-20-7 4 - 10 Xylene (Benzene, 1,4-dimethyl-) 1330-20-7 4 - 10 Ethylbenzene 100-41-4 1 - 5 SARA Section 311/312 Hazard Classes |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No |Immediate Hazard - Yes |Delayed Hazard - Yes Toxic Substances Control Act (TSCA) |The components of this product are in |compliance with the chemical notification |requirements of TSCA. 15.2 US State Regulations California Proposition 65 Ingredient C.A.S. No. Classification Ethylbenzene 100-41-4 Carcinogen Titanium Dioxide 13463-67-7 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.