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Safety Data Sheet Date of Issue: 11/26/14 |Revision Date: |Revision Number: 52.00 Imperial Supplies Part Number: 0077590 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 3M Heavy Drip-Chek Sealer, PN 08531 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Automotive, Sealant 1.3. Name, Address, and Telephone of the Responsible Party Company: 3M Automotive Aftermarket 3M Center, St. Paul, MN 55144-1000, USA Phone: 1-888-364-3577 1.4. Emergency Telephone Number Emergency | 1-800-364-3577 or (651) 737-6501 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 2. Liquid | Serious Eye |Category 2A. Damage/Irritat| ion | Skin |Category 2. Corrosion/Irri| tation | Reproductive |Category 1B. Toxicity | Carcinogenicit|Category 2. y | Specific |Category 3. Target Organ | Toxicity | (central | nervous | system) | Specific |Category 1. Target Organ | Toxicity | (repeated | exposure) | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Exclamat|Health | | | | |ion Mark|Hazard | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Highly flammable liquid and vapor. |Causes serious eye irritation. |Causes skin irritation. |May cause drowsiness or dizziness. |May damage fertility or the unborn child. |Suspected of causing cancer. |Causes damage to organs through prolonged or |repeated exposure: |nervous system | |sensory organs | Precautionary Statements |General: (GHS-US) |Keep out of reach of children. |Prevention: |Obtain special instructions before use. |Do not handle until all safety precautions have been |read and understood. |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. |Ground/bond container and receiving equipment. |Use only non-sparking tools. |Take precautionary measures against static |discharge. |Keep container tightly closed. |Use explosion-proof electrical/ventilating/lighting |equipment. |Do not breathe dust/fume/gas/mist/vapors/spray. |Use only outdoors or in a well-ventilated area. |Wear protective gloves and eye/face protection. |Do not eat, drink or smoke when using this product. |Wash thoroughly after handling. |Response: |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention. |IF ON SKIN (or hair): Take off immediately all |contaminated clothing. Rinse skin with water/shower. | |IF ON SKIN: Wash with plenty of soap and water. |If skin irritation occurs: Get medical |advice/attention. |Take off contaminated clothing and wash it before |reuse. |Call a POISON CENTER or doctor/physician if you feel |unwell. |In case of fire: Use a fire fighting agent suitable |for flammable liquids such as dry chemical or carbon |dioxide to extinguish. |Storage: |Store in a well-ventilated place. Keep cool. |Keep container tightly closed. |Store locked up. |Disposal: |Dispose of contents/container in accordance with |applicable local/regional/national/international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None. 2.4. Unknown Acute Toxicity (GHS-US) 12% of the mixture consists of ingredients of unknown acute dermal toxicity. 34% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Toluene |108-88-3 |30 - 60 | | |Trade | | |Secret *| Acrylonitrile-Butadiene Polymer |9003-18-3 |10 - 30 | | |Trade | | |Secret *| Formaldehyde, Polymer With |68037-42-3 |5 - 15 | 4-(1,1- | |Trade | Dimethylethyl)Phenol, Magnesium | |Secret *| Oxide Complex | | | N-Amyl Acetate |628-63-7 |7 - 13 | | |Trade | | |Secret *| 2-Methylbutyl Acetate |624-41-9 |3 - 7 | | |Trade | | |Secret *| Synthetic Amorphous Silica, |112945-52-5 |3 - 7 | Fumed, Crystalline Free | |Trade | | |Secret *| Salicylic Acid |69-72-7 |1 - 5 | | |Trade | | |Secret *| Titanium Dioxide |13463-67-7 |0.5 - | | |1.5 | | |Trade | | |Secret *| Zinc Oxide |1314-13-2 |0.5 - | | |1.5 | | |Trade | | |Secret *| Ethylbenzene |100-41-4 |< 0.5 | | |Trade | | |Secret *| Benzene |71-43-2 |< 0.1 | | |Trade | | |Secret *| Carbon Black |1333-86-4 |< 0.05 | | |Trade | | |Secret *| Formaldehyde |50-00-0 |< 0.05 | | |Trade | | |Secret *| *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. First-aid Measures After Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. First-aid Measures After Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. First-aid Measures After Ingestion: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See Section 11.1. Information on toxicological effects. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Not applicable. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid breathing of vapors created during cure cycle. Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from acids. Store away from oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) Ethylbenzene 100-41-4 CMRG TWA:25 ppm;STEL:75 ppm Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin SILICA, AMORPHOUS 112945-52- 5 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Zinc Oxide 1314-13-2 OSHA TWA(as fume):5 mg/m3;TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Zinc Oxide 1314-13-2 ACGIH TWA(respirable fraction):2 mg/m3;STEL(respirable fraction):10 mg/m3 Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3 Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5 mg/m3 Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Formaldehyde 50-00-0 ACGIH CEIL:0.3 ppm A2: Suspected human carcin., Sensitizer Formaldehyde 50-00-0 CMRG TWA:0.5 ppm Formaldehyde 50-00-0 OSHA TWA:0.75 ppm;STEL:2 ppm 29 CFR 1910.1048 2-Methylbutyl Acetate 624-41-9 ACGIH TWA:50 ppm;STEL:100 ppm N-Amyl Acetate 628-63-7 ACGIH TWA:50 ppm;STEL:100 ppm N-Amyl Acetate 628-63-7 OSHA TWA:525 mg/m3(100 ppm) Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 ppm;STEL:5 ppm;CEIL:25 ppm 29 CFR 1910.1028 Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm A1: Confirmed human carcin., Skin Notation 8.2. Exposure Controls Appropriate Engineering |Provide ventilated enclosure for heat curing. Curing Controls |enclosures must be exhausted to outdoors or to a |suitable emission control device. Use general |dilution ventilation and/or local exhaust |ventilation to control airborne exposures to below |relevant Exposure Limits and/or control |dust/fume/gas/mist/vapors/spray. If ventilation is |not adequate, use respiratory protection equipment. |Use explosion-proof ventilation equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Select and use gloves and/or protective clothing |approved to relevant local standards to prevent skin |contact based on the results of an exposure |assessment. Selection should be based on use factors |such as exposure levels, concentration of the |substance or mixture, frequency and duration, |physical challenges such as temperature extremes, |and other use conditions. Consult with your glove |and/or protective clothing manufacturer for |selection of appropriate compatible |gloves/protective clothing. Note: Nitrile gloves |may be worn over polymer laminate gloves to improve |dexterity. Gloves made from the following |material(s) are recommended: Fluoroelastomer |Polymer laminate. Eye Protection |Select and use eye/face protection to prevent |contact based on the results of an exposure |assessment. The following eye/face protection(s) |are recommended: Indirect Vented Goggles. Skin and Body Protection |Select and use gloves and/or protective clothing |approved to relevant local standards to prevent skin |contact based on the results of an exposure |assessment. Selection should be based on use factors |such as exposure levels, concentration of the |substance or mixture, frequency and duration, |physical challenges such as temperature extremes, |and other use conditions. Consult with your glove |and/or protective clothing manufacturer for |selection of appropriate compatible |gloves/protective clothing. Note: Nitrile gloves |may be worn over polymer laminate gloves to improve |dexterity. Gloves made from the following |material(s) are recommended: Fluoroelastomer |Polymer laminate. Respiratory Protection |An exposure assessment may be needed to decide if a |respirator is required. If a respirator is needed, |use respirators as part of a full respiratory |protection program. Based on the results of the |exposure assessment, select from the following |respirator type(s) to reduce inhalation exposure: |Half facepiece or full facepiece air-purifying |respirator suitable for organic vapors and |particulates For questions about suitability for a |specific application, consult with your respirator |manufacturer. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance | Odor |Solvent odor; Gray viscous liquid Odor Threshold |No Data Available pH |Not Applicable Relative Evaporation Rate |6.00 [Ref Std: ETHER=1] (butylacetate=1) | Melting Point |No Data Available Freezing Point | Boiling Point |232 �F [Details: Toluene] Flash Point |40 �F [Test Method: Tagliabue Closed Cup] Auto-ignition Temperature |No Data Available Decomposition Temperature |No Data Available Flammability (solid, gas) |Not Applicable Vapor Pressure |25.19 mmHg [@ 68 �F] Relative Vapor Density at 20 �C |4.0 [Ref Std: AIR=1] Relative Density |0.97 g/ml Specific Gravity |0.97 [Ref Std: WATER=1] Solubility |Solubility in Water Nil |Solubility- non-water No Data Available Partition coefficient: |No Data Available n-octanol/water | Viscosity |Approximately 100,000 centipoise [@ 73.4 �F ] Lower Flammable Limit |1.00 % volume Upper Flammable Limit |7.00 % volume 9.2. Other Information Volatile Organic Compounds: 649 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds: 66.9 % weight [Test Method: calculated per CARB title 2] Percent volatile: 66.9 % weight VOC Less H2O & Exempt Solvents: 649 g/l [Test Method: calculated SCAQMD rule 443.1] Solids Content: 33.9 % weight SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Sparks and/or flames. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Substance Condition None known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Reproductive Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Specific Target Organ Toxicity (Single Exposure): Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Specific Target Organ Toxicity (Repeated Exposure): Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Aspiration Hazard: Symptoms/Injuries After Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Symptoms/Injuries After Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Symptoms/Injuries After Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Symptoms/Injuries After Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Chemical fate information: Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Contact 3M for more information. Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 30 - 60 Zinc Oxide (ZINC COMPOUNDS) 1314-13-2 0.5 - 1.5 Ethylbenzene 100-41-4 < 0.5 Benzene 71-43-2 < 0.1 Benzene (Benzene) 71-43-2 < 0.1 SARA Section 311/312 Hazard Classes |Fire Hazard - Yes Pressure Hazard - No |Reactivity Hazard - No Immediate Hazard - Yes |Delayed Hazard - Yes Toxic Substances Control Act (TSCA) |The components of this product are in |compliance with the chemical notification |requirements of TSCA. 15.2 US State Regulations <COMPONENT> California Proposition 65 Ingredient C.A.S. No. Classification Acrylonitrile 107-13-1 Carcinogen Cumene 98-82-8 Carcinogen Ethylbenzene 100-41-4 Carcinogen Toluene 108-88-3 Female reproductive toxin Toluene 108-88-3 Developmental Toxin Carbon Black 1333-86-4 Carcinogen Titanium Dioxide 13463-67-7 Carcinogen Formaldehyde 50-00-0 Carcinogen Benzene 71-43-2 Male reproductive toxin Benzene 71-43-2 Carcinogen Benzene 71-43-2 Developmental Toxin WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.