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Manus Products, Inc. MANUS-BOND 73-A Silicone White, Aluminum, Clear, Black 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT IDENTIFICAITON Brand Name MANUS-BOND 73-A; White, Aluminum, Clear, Black General Description Silicone Elastomer Physical Form Paste Odor Acetic acid odor NFPA Profile Health 2 Flammability 1 Instability/Reactivity 0 Note: NFPA=National Fire Protection Association 2. OSHA Hazardous Components CHEMICAL NAME CAS NUMBER WEIGHT % Methyltriacetoxysilane 4253-34-3 1.0-5.0 Ethyltriacetoxysilane 17689-77-9 1.0-5.0 The above components are hazardous as defined in 29 CFR 1910.1200. 3. EFFECTS OF OVEREXPOSURE Acute Effects Inhalation: Irritates respiratory passages very slightly. Eye: Direct contact may cause moderate irritation. Skin: May cause moderate irritation. Oral: Low ingestion hazard in normal use. Prolonged/ Repeated Exposure Effects Skin: No known applicable information. Inhalation: No known applicable information. Oral: No known applicable information. Signs and Symptoms of Overexposure No known applicable information Medical Conditions Aggravated by Exposure No known applicable information The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information. 4. FIRST AID MEASURES Inhalation: No first aid should be needed. Eye: Immediately flush with water for 15 minutes. Get medical attention. Skin: Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get medical attention if irritation or other ill effects develop or persist. Oral: No first aid should be needed. Comments: Treat according to person's conditions and specifics of exposure. 5. FIRE FIGHTING MEASURES Flash Point: Not applicable Auto ignition Temperature: Not determined Flammability Limits in Air: Not determined Extinguishing Media: On large fires use dry chemical, foam or water spray. ON small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire-exposed containers. Firefighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. Unusual Fire Hazards: None Hazardous Decomposition Products Thermal breakdown of this product during fore or very high heat conditions may evolve the following hazardous decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde. 6. ACCIDENTAL RELEASE MEASURES Containment/Clean up: Observe all personal protection equipment recommendations described in Section 5 and 8.wip up or scrape up and contain for salvage or disposal. Clean area as appropriate since some silicone materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbent or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to release and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. Note: See section 8 for Personal Protective Equipment for Spills. 7. HANDLING AND STORAGE Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Do not breathe vapor. Keep container closed. Do not take internally. Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Component Exposure Limits CAS Number Component Name Exposure Limits 17689-77-9 Ethyltriacetoxysilane See acetic acid comments. 4253-34-3 Methyltriacetoxysilane See acetic acid comments. Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm. Engineering Controls Local Ventilation: Recommended. General Ventilation: Recommended. Personal Protective Equipment for Routine Handling Inhalation: No respiratory protection should be needed. Eyes: Use proper protection-safety glasses as a minimum. Suitable Gloves: Silver Shield (R). 4H (R). Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Suitable Respirator: None should be needed. Personal Protective Equipment for Spills Eyes: Use proper protection-safety glasses as a minimum. Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Inhalation/Suitable Respiratory: No respiratory protection should be needed. Precautionary Measures: Avoid eye contact. Avoid skin contact. Use reasonable care. Comments: Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. When heated to temperatures above 150C in the presence of air, product can form formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and respiratory sensitizer, and an irritant to the eyes, nose, throat, skin and digestive system. Safe handling conditions may be maintained by keeping vapor concentrations within the OSHA Permissible Exposure Limit for formaldehyde. Note: These precautions are for room temperature handling. Use at elevated temperatures or aerosol/spray applications may require added precautions. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical Form Paste Color White, Alum, Clear, Black Odor Acetic acid odor Freezing/Melting Point Not determined Boiling Point Not determined pH Not determined Vapor Density Not determined Vapor Pressure @ 25'C Not determined Volatile Content Not determined Specific Gravity @ 25C 1.032 Water Solubility Not determined Viscosity Not determined Note: The above information is intended for use in preparing product specifications. 10. STABILITY AND REACTIVITY Chemical Stability: Stable. Hazardous Polymerization: Hazardous polymerization will not occur. Conditions to Avoid: None. Materials to Avoid: Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form as described in Section 8. 11. TOXICOLOGICAL INFORMATION Special Hazard Information on Components No known applicable information. 12. ECOLOGICAL INFORMATION Environmental Fate and Distribution No specific information is available. Environmental Effects No specific information is available Fate and Effects in Waste Water Treatment Plants No specific information is available. Ecotoxicity Classification Criteria Hazard High Medium Low Parameters(LC50 or EC50) Acute Aquatic <=1 >1 and <=1-- >100 Toxicity (mg/L) Acute Terrestrial <=100 >100 and <=2--- >2000 Toxicity This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993. This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the section concerning the overall ecological safety of this material. 13. DISPOSAL CONSIDERATIONS RCRA Hazard Class (40 CRF 261) When a decision is made to discard this material, as received, is it classified as hazardous waste? No State or local laws may impose additional regulatory requirements regarding disposal. 14. TRASNPORT INFORMATION DOT Road Shipment Information (49 CRF 172.101) Not subject to DOT. Ocean Shipment (IMDG) Not subject to IMDG code. Air Shipment (ICAO) Not subject to IATA regulations. 15. REGUALTORY INFORMATION Contents of this MSDS comply with OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. EPA Sara Title III Chemical Listings Section 302 Extremely Hazardous Substances: None. Section 304 CERCLA Hazardous Substances: None. Section 312 Hazard Class: Acute: Yes Chronic: No Fire: No Pressure: No Reactive: NO Section313 Toxic Chemicals: None present or none present in regulated quantities. Supplemental State Compliance Information California Warning: this product contains the following chemical(s) listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other reproductive harm. None known. Massachusetts CAS Number Wt% Component Name 7631-86-9 10.0-30.0 Silica, amorphous New Jersey CAS NUMBER Wt% Component 70131-67-8 >60.0 Dimethyl siloxane, hydroxy-terminated 7631-86-9 10.0-30.0 Silica, amorphous 4253-34-3 1.0-5.0 Methyltriacetoxysilane 63148-62-9 1.0-5.0 Polydimethylsiloxane (White, Aluminum, Black only) 17689-77-9 1.0-5.0 Ethyltriacetoxysilane 133-86-4 <=0.9 Carbon Black (Black only) Pennsylvania CAS Number Wt% Component Name 70131-67-8 >60.0 Dimethyl siloxane, hydroxyl-terminated 7631-86-9 10.0-30.0 Silica, amorphous PREPARATION INFORMATION Prepared by: Manus Chemical Safety and Health Department MSDS No: MANUS-BOND 73-A Silicone Date Prepared: December,2009 Date of Issue: December, 2009 Supersedes: November, 2006
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.