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Safety Data Sheet Date of Issue: |Revision Date: 03/01/2013 |Revision Number: Imperial Supplies Part Number: 0077270 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: PVC Rigid Film CAS No: Not applicable. Synonyms: Plastic Film, Rigid Film 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Nan Ya Plastics Corporation USA 2081 FM 102 Rd. Wharton, Texas 77488 Phone: (281) 727-7300 1.4. Emergency Telephone Number Emergency |(800) 424-9300 (CHEMTREC) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | Signal Word (GHS-US) | Hazard Statements (GHS-US) | Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) PVC resin |9002-86-2 |80-85% | Proprietary |Mixture |15-20% | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: If inhaled smoke from burning plastics, remove to fresh air. If symptoms develop, seek immediate medical attention. First-aid Measures After Skin Contact: If burned by hot plastics, get medical attention immediately. First-aid Measures After Eye Contact: Immediately flush eyes with water for at least 15 minutes. Do not rub the eyes. If irritation develops, consult a physician. First-aid Measures After Ingestion: Unlikely. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Smoke from a fire emergency may cause respiratory irritation. Symptoms/Injuries After Skin Contact: Hot melted plastics from a fire may cause burns to skin. Symptoms/Injuries After Eye Contact: Smoke from a fire emergency may cause eye irritation. Symptoms/Injuries After Ingestion: Unlikely. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to Physician: Treat symptomatically and supportively. Other Instructions: Never give anything by mouth to an unconscious person. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Dry Chemical, Foam, Water, or Carbon Dioxide. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: PVC will not continue to burn after ignition without an external fire source. However, when forced to burn, the major gaseous products of the combustion of PVC are carbon monoxide, carbon dioxide, and hydrogen chloride. Explosion Hazard: PVC will not continue to burn after ignition without an external fire source. However, when forced to burn, the major gaseous products of the combustion of PVC are carbon monoxide, carbon dioxide, and hydrogen chloride. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: In the event of a fire, wear NIOSH approved, positive pressure, self-contained breathing apparatus (SCBA) and full protective clothing. Evacuate all personnel from danger area. Use dry chemical, foam, water, or carbon dioxide to extinguish fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Response to Spills: Not Applicable. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Use with care. Wear Gloves if necessary when cutting or fabricating film. Hygiene Measures: Do not eat, drink, or smoke in work area. Wash hands thoroughly after handling, especially before eating, drinking, smoking, chewing, or using restroom facility. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in cool dry, well ventilated area away from sources of extreme heat or fire. 7.3. Specific End Use(s) Container Use: Not Applicable. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines: No. Components OSHA-PEL ACGIH-TLV P PVC Film Not Applicable Not Applicable 8.2. Exposure Controls Appropriate Engineering |Ventilation Requirements- Local Exhaust Controls |Specific X General Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Wear safety glasses during film cutting or |fabricating process. Skin and Body Protection |Wear gloves when cutting or fabricating film by |hand. Respiratory Protection |Fire Fighters should wear NIOSH approved |self-contained breathing apparatus (SCBA) during |fire emergency. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Solid Sheet Appearance | Odor |Insignificant Odor Threshold | pH |Not Applicable. Relative Evaporation Rate |None (Butyl Acetate = 1) (butylacetate=1) | Melting Point |Not Established. Freezing Point |Not Applicable. Boiling Point |Not Applicable. Flash Point |Not Applicable. Auto-ignition Temperature |Not Applicable. Decomposition Temperature | Flammability (solid, gas) | Vapor Pressure |Not Applicable. Relative Vapor Density at 20 �C |Not Applicable (Air = 1) Relative Density | Specific Gravity |1.32~1.45 (Water = 1) Solubility |None. Partition coefficient: | n-octanol/water | Viscosity | Lower Flammable Limit |Not Applicable. Upper Flammable Limit |Not Applicable. 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable. 10.2 Chemical Stability 10.3 Possibility of Hazardous Reactions Hazardous Polymerization:: Will not occur. 10.4 Conditions to Avoid Fire or Extreme Heat. 10.5 Incompatible Materials 10.6 Hazardous Decomposition Products If burned it will generate carbon dioxide, carbon monoxide, and hydrogen chloride. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects No Data is available on the adverse effects of this product on the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: It must be disposed of in accordance with Federal, State and Local environmental control regulations. Additional Information: Recycling of PVC film should be encouraged where possible. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not Listed. Hazard Class |Not regulated |<PICTOGRAM PHRASE> Identification Number|Not Applicable | Label Codes |Not Applicable | ERG Number |Not Applicable 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> OSHA Status: Not Listed, Non-Hazardous. EPA Clean Air Act Status: Not Listed. SARA Title III: PVC Film. EPA Clean Water Act Status: Not Listed. CERCLA RQ: Not Listed. Sec. 302* - None. Sec. 313** - None. *Reportable quantity of extremely hazardous substance, Sec 302. Threshold planning quantity, extremely hazardous substance, Sec. 302. **Toxic Chemical. Sec 313, Category as required by Sec. 313 (40CRF372.65C). Must be used on Toxic Release Inventory form. RCRA Status: It is the responsibility of the product user to determine at the time of disposal whether a material containing this product or derived from this product should be classified as a hazardous waste. (40CFR261.20~24). Other Regulatory Information: Chemicals are specifically listed by individual states; other product-specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements, you should contact the appropriate agency in your state. SARA Section 311/312 Hazard Classes |None. Toxic Substances Control Act (TSCA) |All ingredients are listed on TSCA Inventory |(40CFR710). 15.2 US State Regulations <COMPONENT> SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.