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Safety Data Sheet Date of Issue: |Revision Date: 5/21/2015 |Revision Number: Imperial Supplies Part Number: 0076800 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Imperial Supplies Imperial Clear RTV Silicone 8oz can CAS No: Synonyms: 7680CL10 1.2. Intended Use of the Product Use of the substance/mixture: Refer to Technical Data 1.3. Name, Address, and Telephone of the Responsible Party Company SOUDAL Accumetric 350 Ring Road Elizabethtown, KY, 42701 USA Phone: (270) 769-3385 1.4. Emergency Telephone Number Emergency | (800) 424-9300 Chemtrec number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) EYE |Category 2A DAMAGE/IRRITAT| ION | GASES UNDER |Liquefied gas PRESSURE | SKIN |Category 2 CORROSION/IRRI| TATION | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas |Exclamat| | | | |Cylinder|ion Mark| | | | Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |Causes serious eye irritation |Causes skin irritation |Contains gas under pressure; may explode if heated Precautionary Statements |Response: If eye irritation persists: Get medical (GHS-US) |advice/attention. |If in eyes: Rinse cautiously with water for several |minutes. |Remove contact lenses, if present and easy to do. |Continue |rinsing. |If on skin: Wash with plenty of soap and water. |If skin irritation occurs: Get medical |advice/attention. |Take off contaminated clothing and wash it before |reuse. |Prevention: Wash hands thoroughly after handling. |Wear eye protection/face protection. |Wear protective gloves. |Storage: Protect from sunlight. Store in a |well-ventilated place. |Disposal : N/A 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Ethyltriacetoxysilane |17689-77-9 |1% - 5% | Methyltriacetoxysilane |4253-34-3 |1% - 5% | Difluoroethane (propellant) |75-37-6 |1% - 5% | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: If symptoms are experienced remove source of contamination or move victim to fresh air. If irritation persists, obtain medical advice. First-aid Measures After Skin Contact: Remove contaminated clothing, shoes, and leather goods (e.g. watchbands, belts). Quickly and gently blot or brush away excess chemical. Flush with lukewarm gently flowing water for 15 minutes. If irritation persists, repeat flushing. If irritation persists, obtain medical advice. First-aid Measures After Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes while holding the eyelids open. Obtain medical attention. First-aid Measures After Ingestion: If irritation or discomfort occur, obtain medical advice. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: N/A Unsuitable Extinguishing Media: N/A 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: None known Explosion Hazard: None known Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Self-contained breathing apparatus and protective clothing should be worn when fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Steps to be taken in case of spill or release: Observe all personal protection equipment recommendations. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled materials, even in small quantities, may present a slip hazard. Methods for Cleaning Up: Final cleaning may require steam, solvents or detergents. Dispose of saturated absorbent or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Use with adequate ventilation. Product evolves acetic acid when exposed to water or humid air. Provide ventilation during use to acetic acid within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Avoid breathing vapor. Keep container closed. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture.This material in its finely divided form presents an explosion hazard. Follow NFPA 654 (for chemical dusts) or 484 (for metal dusts) as appropriate for managing dust hazards to minimize secondary explosion potential. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational Exposure Limits Ingredient Name ACGIH TLV OSHA PEL STEL Ethyltriacetoxysilane TWA 10ppm TWA 10ppm 15ppm Methyltriacetoxysilane TWA 10ppm TWA 10ppm 15ppm Difluoroethane (propellant) N/A N/A N/A 8.2. Exposure Controls Appropriate Engineering |Local Ventilation: Recommended General Ventilation: Controls |Recommended Personal Protective Equipment|Goggles, Gloves Materials for Protective | Clothing | Hand Protection | Eye Protection |Use proper protection - safety glasses as a minimum. Skin and Body Protection |Wash at mealtimes and end of shift. Contaminated |clothing and shoes should be removed as soon as |practical and throughly cleaned before reuse. |Chemical protective gloves are recommended. Suitable |Gloves: Handle in accordance with good industrial |hygiene and safety practices. Respiratory Protection |Respiratory protection is not needed under ambient |conditions. If vapor is generated when material is |heated or handled, the following is advised. General |and local exhaust ventilation is recommended to |maintain vapor exposures below recommended limits. |Where concentrations are above recommended limits or |are unknown, appropriate respiratory protection |should be worn. Follow OSHA respirator regulations |(29 CFR 1910.134) and use NIOSH/MSHA approved |respirators. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Paste Appearance | Odor |Acetic Acid Odor Odor Threshold |Not available pH |Not available Relative Evaporation Rate |Not available (butylacetate=1) | Melting Point |Not available Freezing Point | Boiling Point |Not available Flash Point |>100C >212F Closed Cup Auto-ignition Temperature |Not available Decomposition Temperature |Not available Flammability (solid, gas) |Not available Vapor Pressure |Not available Relative Vapor Density at 20 Â°C |Not available Relative Density |N/A Specific Gravity |1.007 Solubility |Not available Partition coefficient: |There is no data available n-octanol/water | Viscosity |Not available Lower Flammable Limit |N/A Upper Flammable Limit |N/A 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability Stable 10.3 Possibility of Hazardous Reactions 10.4 Conditions to Avoid None known 10.5 Incompatible Materials Oxidizing material can cause a reaction. Water, moisture or humid air can cause hazardous vapors to form as described in Section 8. 10.6 Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Formaldehyde Silicon dioxide. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Environmental Effects: Complete information is not yet available. Environmental Fate and Distribution: Complete information is not yet available. Fate and Effects in Waste Water Treatment Plants: Complete information is not yet available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: RCRA Hazard Class (40 CFR 261): When a decision is made to discard this material, as received, is it classified as a hazardous waste? NO State or local laws may impose additional regulatory requirements regarding disposal. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable (each not exceeding 1 L capacity) (1, |1-Difluoroethane) Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations DEA List I Chemicals (Precursor Chemicals) Not listed DEA List II Chemicals (Essential Chemicals) Not listed SARA Section 311/312 Hazard Classes |Sudden release of pressure Immediate (acute) |health hazard Toxic Substances Control Act (TSCA) |All components are listed or exempted. 15.2 US State Regulations <COMPONENT> Massachusetts The following components are listed: Silicon dioxide; 1,1-Difluoroethane New York None of the components are listed. New Jersey The following components are listed: 1,1-Difluoroethane Pennsylvania The following components are listed: Silicon dioxide California Prop. 65 No products were found. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |5/21/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.