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SDS Sheet 0076780

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: Imperial Supplies Imperial Black Gasket Maker 8oz can             
 
CAS No:                                                                         
 
Synonyms: 7678BK10                                                              
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Refer to Technical Data                           
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Dynatex Inc.                                                                    
 
350 Ring Road                                                                   
 
Elizabethtown, KY, 42701                                                        
 
USA                                                                             
 
Phone: (270) 769-3385                                                           
 


1.4.  Emergency Telephone Number
Emergency     |(800) 424-9300                                                   
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
EYE           |Category 2A   
DAMAGE/IRRITAT|              
ION           |              
GASES UNDER   |Liquefied gas 
PRESSURE      |              
SKIN          |Category 2    
CORROSION/IRRI|              
TATION        |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Gas Cylinder |Exclamation Mark
       
Signal Word (GHS-US)         |Warning                                           
 
Hazard Statements (GHS-US)   |Causes serious eye irritation                     
 
                             |Causes skin irritation                            
 
                             |Contains gas under pressure; may explode if heated
 
Precautionary Statements     |Response                                          
 
(GHS-US)                     |If eye irritation persists: Get medical           
 
                             |advice/attention.                                 
 
                             |If in eyes: Rinse cautiously with water for
several 
                             |minutes.                                          
 
                             |Remove contact lenses, if present and easy to do. 
 
                             |Continue rinsing.                                 
 
                             |If on skin: Wash with plenty of soap and water.   
 
                             |If skin irritation occurs: Get medical            
 
                             |advice/attention.                                 
 
                             |Read label before use.                            
 
                             |Take off contaminated clothing and wash it before 
 
                             |reuse.                                            
 
                             |Prevention                                        
 
                             |Wash hands thoroughly after handling.             
 
                             |Wear eye protection/face protection.              
 
                             |Wear protective gloves.                           
 
                             |Storage                                           
 
                             |Protect from sunlight. Store in a well-ventilated 
 
                             |place.                                            
 
                             |Disposal                                          
 
                             |N/A                                               
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None known.               
 


2.4.  Unknown Acute Toxicity (GHS-US)
0%                                                                              
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Difluoroethane (propellant)     |75-37-6              |1% - 5% |                
 
Methyltriacetoxysilane          |4253-34-3            |1% - 5% |                
 
Ethyltriacetoxysilane           |17689-77-9           |1% - 5% |                
 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General: Treat according to person's condition and specifics
of
exposure.                                                                       
 
First-aid Measures After Inhalation: Remove to fresh air. No first aid should be
 
needed.                                                                         
 
First-aid Measures After Skin Contact: Remove from skin and wash throughly with 
 
soap and water or waterless cleanser. Get medical attention if irritation or
other
ill effects develop or persist.                                                 
 
First-aid Measures After Eye Contact: Immediately flush with water for 15
minutes.
Seek medical attention.                                                         
 
First-aid Measures After Ingestion: No first aid should be needed.              
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
                                                                                
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: On large fires use dry chemical, foam, or water   
 
spray. On small fires use carbon dioxide, dry chemical or water spray. Water can
 
be used to cool fire exposed containers.                                        
 
Unsuitable Extinguishing Media: N/A                                             
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:                                                                    
 
Explosion Hazard:                                                               
 
Comment: When temperatures above 150¡C in the presence of air, product can form 
 
formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and
 
respiratory sensitizer, and an irritant to the eyes, nose, throat, skin and     
 
digestive system. Safe handling conditions may be maintained by keeping vapor   
 
concentrations within the OSHA Permissible Exposure Limits for formaldehyde.    
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions: Self-contained breathing apparatus and protective    
 
clothing should be worn when fighting large fires involving chemicals. Determine
 
the need to evacuate or isolate the area according to your local emergency plan.
 
Use water spray to keep fire exposed containers cool.                           
 
Protection During Firefighting: Thermal breakdown of this product during fire or
 
very high heat conditions may evolve the following hazardous decomposition      
 
products: Carbon oxides and traces of incompletely burned carbon compounds      
 
Formaldehyde Silicon dioxide.                                                   
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:                                                               
 
Precautionary Measures: Avoid eye contact. Avoid skin contact. Use reasonable   
 
care.                                                                           
 
Comment: Product evolves acetic acid when exposed to water or humid air. Provide
 
ventilation during use to control acetic acid within exposure guidelines or use 
 
respiratory protection. When heated to temperatures above 150C (300F) in the    
 
presence of air, product can form formaldehyde vapors. Physical and health
hazard 
information is readily available on the Material Safety Data Sheet.             
 
Note: These precautions are for room temperature handling. Use at elevated      
 
temperatures or aerosol/spray applications may require added precautions. For   
 
further information regarding aerosol inhalation toxicity, please refer to the  
 
guidance document regarding the use of silicone-based materials in aerosol      
 
applications that has been developed by the silicone industry (www.SEHSC.com).  
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
                                                                                
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up:                                                        
 
Steps to be taken in case of spill or release: Determine whether to evacuate or 
 
isolate the area according to your local emergency plan. Observe all personal   
 
protection equipment recommendations described in Sections 5 and 8. For large   
 
spills, provide diking or other appropriate containment to keep material from   
 
spreading. If diked material can be pumped, store recovered material in         
 
appropriate container. For small spills, wipe up or scrape up and contain for   
 
salvage or disposal. Clean area as appropriate since spilled material, even in  
 
small quantities, may present a slip hazard. Final cleaning may require the use
of
steam, solvents or detergents. Dispose of saturated absorbent or cleaning       
 
materials appropriately, since spontaneous heating may occur. Local, state and  
 
federal laws and regulations may apply to releases and disposal of this
material, 
as well as those materials and items employed in the cleanup of releases. You
will
need to determine which federal, state and local laws and regulations are       
 
applicable. Sections 13 and 15 of this MSDS provide information regarding
certain 
federal and state requirements.                                                 
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Use adequate ventilation. Product evolves    
 
acetic acid when exposed to water or humid air. Provide ventilation during use
to 
control acetic acid within exposure guidelines or use respiratory protection.   
 
Avoid eye contact. Avoid skin contact.                                          
 
Hygiene Measures:                                                               
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Use reasonable care and store away from oxidizing materials.
 
Keep container closed and store away from water or moisture. This material in
its 
finely divided form presents an explosion hazard. Follow NFPA 654 (for chemical 
 
dusts) or 484 (for metal dusts) as appropriate for managing dust hazards to     
 
minimize secondary explosion potential. Do not store at temperatures above 120F.
 
Do not puncture or incinerate containers. Keep out of reach of children. Store
in 
accordance with NFPA 30B for Level 1 Aerosols.                                  
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Occupational Exposure Limits:                                                   
 
Ingredient Name                                                                 
 
ACGIH                                                                           
 
TLV                                                                             
 
OSHA                                                                            
 
PEL                                                                             
 
STEL                                                                            
 
                                                                                
 
Difluoroethane (propellant)                                                     
 
N/A                                                                             
 
                                                                                
 
N/A                                                                             
 
                                                                                
 
N/A                                                                             
 
                                                                                
 
Methyltriacetoxysilane                                                          
 
TWA                                                                             
 
10ppm                                                                           
 
TWA                                                                             
 
10ppm                                                                           
 
15ppm                                                                           
 
                                                                                
 
Ethyltriacetoxysilane                                                           
 
TWA                                                                             
 
10ppm                                                                           
 
TWA                                                                             
 
10ppm                                                                           
 
15ppm                                                                           
 
                                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Acetic acid is formed upon contact with water or  
 
Controls                     |humid air. Provide adequate ventilation to control
 
                             |exposures within guidelines of OSHA PEL: TWA 10
ppm 
                             |and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.           
 
Personal Protective Equipment|Goggles, Gloves.                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Safety goggles or glasses with side shields are   
 
                             |recommended.                                      
 
Skin and Body Protection     |Wash at mealtimes and end of shift. Contaminated  
 
                             |clothing and shoes should be removed as soon as   
 
                             |practical and throughly cleaned before reuse.     
 
                             |Chemical protective gloves are recommended.
Suitable
                             |Gloves: Silver Shield¨ 4H¨.                       
 
Respiratory Protection       |No respiratory protection should be needed with
good
                             |local ventilation.                                
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 
9.1. Information on Basic Physical and Chemical Properties                      
 
Physical State                      |Paste                                      
 
Appearance                          |                                           
 
Odor                                |Acetic Acid Odor                           
 
Odor Threshold                      |Not available                              
 
pH                                  |Not available                              
 
Relative Evaporation Rate           |Not available                              
 
(butylacetate=1)                    |                                           
 
Melting Point                       |Not available                              
 
Freezing Point                      |                                           
 
Boiling Point                       |Not available                              
 
Flash Point                         |>100C, >212F Closed Cup                    
 
Auto-ignition Temperature           |Not available                              
 
Decomposition Temperature           |Not available                              
 
Flammability (solid, gas)           |Not available                              
 
Vapor Pressure                      |Not available                              
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |                                           
 
Specific Gravity                    |1.007                                      
 
Solubility                          |Not available                              
 
Partition coefficient:              |There is no data available                 
 
n-octanol/water                     |                                           
 
Viscosity                           |Not available                              
 
Lower Flammable Limit               |                                           
 
Upper Flammable Limit               |                                           
 


9.2.  Other Information
                                                                                
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
                                                                                
 


10.2      Chemical Stability
Stable.                                                                         
 


10.3      Possibility of Hazardous Reactions
Will not occur.                                                                 
 


10.4      Conditions to Avoid
None known.                                                                     
 


10.5      Incompatible Materials
Oxidizing material can cause a reaction. Water, moisture or humid air can cause 
 
hazardous vapors to form as described in Section 8.                             
 


10.6      Hazardous Decomposition Products
                                                                                
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity: No known applicable information.                                
 
Skin Corrosion/Irritation:                                                      
 
Serious Eye Damage/Irritation:                                                  
 
Respiratory or Skin Sensitization:                                              
 
Germ Cell Mutagenicity:                                                         
 
Carcinogenicity:                                                                
 
Reproductive Toxicity:                                                          
 
Specific Target Organ Toxicity (Single Exposure):                               
 
Specific Target Organ Toxicity (Repeated Exposure):                             
 
Aspiration Hazard:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
                                                                                
 


12.2. Persistence and Degradability
                                                                                
 


12.3. Bioaccumulative Potential
                                                                                
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
Environmental Fate and Distribution: Complete information is not yet available. 
 
Environmental Effects: Complete information is not yet available.               
 
Fate and Effects in Waste Water Treatment Plants: Complete information is not
yet 
available.                                                                      
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: We make no guarantee or warranty of any kind
that 
the use or disposal of this product complies with all local, state, or federal  
 
laws. It is also the obligation of each user of the product mentioned herein to 
 
determine and comply with the requirements of all applicable statutes. This     
 
product is not known to be regulated under RCRA regulations. Disposal of unused 
 
portions of this product and process waste containing this product should be
done 
only after a careful evaluation and in compliance with all federal, local and   
 
state laws.                                                                     
 
Additional Information:                                                         
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |Aerosols, Flammable (each not exceeding 1L capacity) (1,  
 
                     |1-Difluoroethane)                                         
 
Hazard Class         |2.1                    |<PICTOGRAM PHRASE>                
 
Identification Number|UN1950                 |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |                                                          
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |                                                          
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
DEA List I Chemicals (Precursor Chemicals) Not listed DEA List II Chemicals     
 
(Essential Chemicals) Not listed.                                               
 
SARA Title III: SARA 302/304 Composition/information on ingredients No products 
 
were found SARA 304 RQ Not applicable.                                          
 
Clean Air Act (CAA): Section 112 Regulated Flammable Substances
1,1-Difluoroethane
Section 112 (b) Hazardous Air Pollutants (HAPs) Not listed Section 602 Class I  
 
Substances Not listed Section 602 Class II Substances: Not listed.              
 
SARA Section 311/312 Hazard Classes |Sudden release of pressure Immediate
(acute) 
                                    |health hazard                              
 
Toxic Substances Control Act (TSCA) |All components are listed or exempted.     
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
Massachusetts The following components are listed: Silicon dioxide;             
 
1,1-Difluoroethane New York None of the components are listed. New Jersey The   
 
following components are listed: 1,1- Difluoroethane Pennsylvania The following 
 
components are listed: Silicon dioxide California Prop. 65 No products were
found.
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |5/21/2015                                                      
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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