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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Imperial Supplies Imperial Black Gasket Maker 8oz can CAS No: Synonyms: 7678BK10 1.2. Intended Use of the Product Use of the substance/mixture: Refer to Technical Data 1.3. Name, Address, and Telephone of the Responsible Party Company Dynatex Inc. 350 Ring Road Elizabethtown, KY, 42701 USA Phone: (270) 769-3385 1.4. Emergency Telephone Number Emergency |(800) 424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) EYE |Category 2A DAMAGE/IRRITAT| ION | GASES UNDER |Liquefied gas PRESSURE | SKIN |Category 2 CORROSION/IRRI| TATION | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas Cylinder |Exclamation Mark Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |Causes serious eye irritation |Causes skin irritation |Contains gas under pressure; may explode if heated Precautionary Statements |Response (GHS-US) |If eye irritation persists: Get medical |advice/attention. |If in eyes: Rinse cautiously with water for several |minutes. |Remove contact lenses, if present and easy to do. |Continue rinsing. |If on skin: Wash with plenty of soap and water. |If skin irritation occurs: Get medical |advice/attention. |Read label before use. |Take off contaminated clothing and wash it before |reuse. |Prevention |Wash hands thoroughly after handling. |Wear eye protection/face protection. |Wear protective gloves. |Storage |Protect from sunlight. Store in a well-ventilated |place. |Disposal |N/A 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) 0% SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Difluoroethane (propellant) |75-37-6 |1% - 5% | Methyltriacetoxysilane |4253-34-3 |1% - 5% | Ethyltriacetoxysilane |17689-77-9 |1% - 5% | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Treat according to person's condition and specifics of exposure. First-aid Measures After Inhalation: Remove to fresh air. No first aid should be needed. First-aid Measures After Skin Contact: Remove from skin and wash throughly with soap and water or waterless cleanser. Get medical attention if irritation or other ill effects develop or persist. First-aid Measures After Eye Contact: Immediately flush with water for 15 minutes. Seek medical attention. First-aid Measures After Ingestion: No first aid should be needed. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: On large fires use dry chemical, foam, or water spray. On small fires use carbon dioxide, dry chemical or water spray. Water can be used to cool fire exposed containers. Unsuitable Extinguishing Media: N/A 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Comment: When temperatures above 150Â¡C in the presence of air, product can form formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and respiratory sensitizer, and an irritant to the eyes, nose, throat, skin and digestive system. Safe handling conditions may be maintained by keeping vapor concentrations within the OSHA Permissible Exposure Limits for formaldehyde. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Self-contained breathing apparatus and protective clothing should be worn when fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. Protection During Firefighting: Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous decomposition products: Carbon oxides and traces of incompletely burned carbon compounds Formaldehyde Silicon dioxide. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Precautionary Measures: Avoid eye contact. Avoid skin contact. Use reasonable care. Comment: Product evolves acetic acid when exposed to water or humid air. Provide ventilation during use to control acetic acid within exposure guidelines or use respiratory protection. When heated to temperatures above 150C (300F) in the presence of air, product can form formaldehyde vapors. Physical and health hazard information is readily available on the Material Safety Data Sheet. Note: These precautions are for room temperature handling. Use at elevated temperatures or aerosol/spray applications may require added precautions. For further information regarding aerosol inhalation toxicity, please refer to the guidance document regarding the use of silicone-based materials in aerosol applications that has been developed by the silicone industry (www.SEHSC.com). 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Steps to be taken in case of spill or release: Determine whether to evacuate or isolate the area according to your local emergency plan. Observe all personal protection equipment recommendations described in Sections 5 and 8. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. For small spills, wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled material, even in small quantities, may present a slip hazard. Final cleaning may require the use of steam, solvents or detergents. Dispose of saturated absorbent or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Use adequate ventilation. Product evolves acetic acid when exposed to water or humid air. Provide ventilation during use to control acetic acid within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture. This material in its finely divided form presents an explosion hazard. Follow NFPA 654 (for chemical dusts) or 484 (for metal dusts) as appropriate for managing dust hazards to minimize secondary explosion potential. Do not store at temperatures above 120F. Do not puncture or incinerate containers. Keep out of reach of children. Store in accordance with NFPA 30B for Level 1 Aerosols. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational Exposure Limits: Ingredient Name ACGIH TLV OSHA PEL STEL Difluoroethane (propellant) N/A N/A N/A Methyltriacetoxysilane TWA 10ppm TWA 10ppm 15ppm Ethyltriacetoxysilane TWA 10ppm TWA 10ppm 15ppm 8.2. Exposure Controls Appropriate Engineering |Acetic acid is formed upon contact with water or Controls |humid air. Provide adequate ventilation to control |exposures within guidelines of OSHA PEL: TWA 10 ppm |and ACGIH TLV: TWA 10 ppm, STEL 15 ppm. Personal Protective Equipment|Goggles, Gloves. Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety goggles or glasses with side shields are |recommended. Skin and Body Protection |Wash at mealtimes and end of shift. Contaminated |clothing and shoes should be removed as soon as |practical and throughly cleaned before reuse. |Chemical protective gloves are recommended. Suitable |Gloves: Silver ShieldÂ¨ 4HÂ¨. Respiratory Protection |No respiratory protection should be needed with good |local ventilation. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Paste Appearance | Odor |Acetic Acid Odor Odor Threshold |Not available pH |Not available Relative Evaporation Rate |Not available (butylacetate=1) | Melting Point |Not available Freezing Point | Boiling Point |Not available Flash Point |>100C, >212F Closed Cup Auto-ignition Temperature |Not available Decomposition Temperature |Not available Flammability (solid, gas) |Not available Vapor Pressure |Not available Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |1.007 Solubility |Not available Partition coefficient: |There is no data available n-octanol/water | Viscosity |Not available Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Will not occur. 10.4 Conditions to Avoid None known. 10.5 Incompatible Materials Oxidizing material can cause a reaction. Water, moisture or humid air can cause hazardous vapors to form as described in Section 8. 10.6 Hazardous Decomposition Products SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: No known applicable information. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Environmental Fate and Distribution: Complete information is not yet available. Environmental Effects: Complete information is not yet available. Fate and Effects in Waste Water Treatment Plants: Complete information is not yet available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: We make no guarantee or warranty of any kind that the use or disposal of this product complies with all local, state, or federal laws. It is also the obligation of each user of the product mentioned herein to determine and comply with the requirements of all applicable statutes. This product is not known to be regulated under RCRA regulations. Disposal of unused portions of this product and process waste containing this product should be done only after a careful evaluation and in compliance with all federal, local and state laws. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, Flammable (each not exceeding 1L capacity) (1, |1-Difluoroethane) Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> DEA List I Chemicals (Precursor Chemicals) Not listed DEA List II Chemicals (Essential Chemicals) Not listed. SARA Title III: SARA 302/304 Composition/information on ingredients No products were found SARA 304 RQ Not applicable. Clean Air Act (CAA): Section 112 Regulated Flammable Substances 1,1-Difluoroethane Section 112 (b) Hazardous Air Pollutants (HAPs) Not listed Section 602 Class I Substances Not listed Section 602 Class II Substances: Not listed. SARA Section 311/312 Hazard Classes |Sudden release of pressure Immediate (acute) |health hazard Toxic Substances Control Act (TSCA) |All components are listed or exempted. 15.2 US State Regulations <COMPONENT> Massachusetts The following components are listed: Silicon dioxide; 1,1-Difluoroethane New York None of the components are listed. New Jersey The following components are listed: 1,1- Difluoroethane Pennsylvania The following components are listed: Silicon dioxide California Prop. 65 No products were found. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |5/21/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.