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Safety Data Sheet Date of Issue: |Revision Date: 3/19/2015 |Revision Number: Imperial Supplies Part Number: 0076770 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Imperial Supplies Imperial Instant Black Gasket Maker 8oz can CAS No: Synonyms: 7677BK10 1.2. Intended Use of the Product Use of the substance/mixture: Refer to Technical Data 1.3. Name, Address, and Telephone of the Responsible Party Company Dynatex Inc. 350 Ring Road Elizabethtown, KY, 42701 USA Phone: (270) 769-3385 1.4. Emergency Telephone Number Emergency |(800) 424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) CARCINOGENICIT|Category 2 Y | EYE |Category 2B DAMAGE/IRRITAT| ION | SENSITIZATION |Category 1B - SKIN | SPECIFIC |Category 2 TARGET ORGAN | TOXICITY | (Repeated | Exposure) | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Health |Exclamat| | | | |Hazard |ion Mark| | | | Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |Causes eye irritation |May cause an allergic skin reaction |May cause damage to organs through prolonged or |repeated exposure. |Suspected of causing cancer. Precautionary Statements |Response (GHS-US) |Get medical advice/attention if you feel unwell. |If exposed or concerned: Get medical |advice/attention. |If eye irritation persists: Get medical |advice/attention. |If in eyes: Rinse cautiously with water for several |minutes. |Remove contact lenses, if present and easy to do. |Continue rinsing. |If on skin: Wash with plenty of soap and water. |If skin irritation or rash occurs: Get medical |advice/attention. |Wash contaminated clothing before reuse. |Prevention |Avoid breathing dust/fume/gas/mist/ vapors/spray. |Contaminated work clothing must not be allowed out |of the workplace. |Do not breathe dust/fume/gas/mist/ vapors/spray. |Do not handle until all safety precautions have been |read and understood. |Obtain special instructions before use. |Wash hands thoroughly after handling. |Wear protective gloves. |Wear protective gloves/protective clothing/eye |protection/face protection. |Storage |Store locked up. |Disposal |Dispose of contents and container in accordance with |all local, regional, national and international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) 0% SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Carbon Black |1333-86-4 |0.1% - | | |Max | Titanium Dioxide |13463-67-7 |0.1% - | | |Max | Dimethylpolysiloxane |63148-62-9 |1% - 5% | Difluoroethane (propellant) |75-37-6 |1% - 5% | Methyl Oximino Silane |22984-54-9 |5% - 10%| SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove to fresh air. No first aid should be needed. First-aid Measures After Skin Contact: Remove from skin and wash throughly with soap and water or waterless cleanser. Get medical attention if irritation or other ill effects develop or persist. First-aid Measures After Eye Contact: Immediately flush with water for 15 minutes. Seek medical attention. First-aid Measures After Ingestion: No first aid should be needed. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: On large fires use dry chemical, foam, or water spray. On small fires use carbon dioxide, dry chemical or water spray. Water can be used to cool fire exposed containers. Unsuitable Extinguishing Media: N/A 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: None known. Explosion Hazard: None known. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Self-contained reathing apparatus and protective clothing should be worn when fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Precautionary Measures: Avoid eye contact. Avoid skin contact. Avoid breathing vapor. Keep container closed. Do not take internally. Use reasonable care. Comment: Product evolves methyl ethyl ketoxime (MEKO) when exposed to water or humid air. Provide ventilation during use to control methyl ethyl ketoxime within the exposure guidelines or use respiratory protection. Note: These precautions are for room temperature handling. Use at elevated temperatures or aerosol/spray applications may require added precautions. For further information regarding aerosol inhalation toxicity, please refer to the guidance document regarding the use of silicone-based materials in aerosol applications that has been developed by the silicone industry (www.SEHSC.com). 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Steps to be taken in case of spill or release: Determine whether to evacuate or isolate the area according to your local emergency plan. Observe all personal protection equipment recommendations described in Sections 5 and 8. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. For small spills, wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled material, even in small quantities, may present a slip hazard. Final cleaning may require the use of steam, solvents or detergents. Dispose of saturated absorbent or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid eye contact. Avoid skin contact. Avoid breathing vapor. Keep container closed. Do not take internally. Use reasonable care. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container closed and store in a cool, well ventilated area, away from water or moisture. Other Precautions: Product evolves methyl ethyl ketoxime (MEKO) when exposed to water or humid air. Provide ventilation during use to control MEKO within the exposure guidelines or use respiratory protection. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational Exposure Limits: Ingredient Name ACGIH TLV OSHA PEL STEL Carbon Black N/A N/A N/A Titanium Dioxide N/A N/A N/A Dimethylpolysiloxane 3.5 mg/m� 3.5 mg/m� N/A Difluoroethane (propellant) 10 mg/m3 15 mg/m3 N/A Methyl Oximino Silane N/A N/A N/A 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment|Goggles, Gloves. Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety goggles or glasses with side shields are |recommended. Skin and Body Protection |Wash at mealtimes and end of shift. Contaminated |clothing and shoes should be removed as soon as |practical and throughly cleaned before reuse. |Chemical protective gloves are recommended. |Suitable Gloves: Silver Shield� 4H�. Respiratory Protection |Not applicable with good local exhaust. Use NIOSH |approved respirator if there is a potential to |exceed exposure limits. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Paste Appearance | Odor |Slight medicinal Odor Threshold |N/A pH |Not applicable Relative Evaporation Rate |N/A (butylacetate=1) | Melting Point |Not determined Freezing Point | Boiling Point |Not applicable Flash Point |Not applicable Auto-ignition Temperature |N/A Decomposition Temperature |N/A Flammability (solid, gas) |N/A Vapor Pressure |Not applicable Relative Vapor Density at 20 �C |Not applicable Relative Density |N/A Specific Gravity |1.04 Solubility |None in water Partition coefficient: |N/A n-octanol/water | Viscosity |Not applicable Lower Flammable Limit |N/A Upper Flammable Limit |N/A 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Will not occur. 10.4 Conditions to Avoid Exposure to air or moisture until ready to use; releases about 4%methylethylketoxime (MEKO). 10.5 Incompatible Materials 10.6 Hazardous Decomposition Products SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Acute Oral LD50 > 10,000 mg/kg Acute Dermal LD50 None found. Acute Inhalation LC50 None found Ames Test: Unknown EPA. Hazard Class: Eye Irritant CPSC Classification: Eye Irritant. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Environmental Effects: Complete information is not yet available. Environmental Fate and Distribution: Complete information is not yet available. Fate and Effects in Waste Water Treatment Plants: Complete information is not yet available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: We make no guarantee or warranty of any kind that the use or disposal of this product complies with all local, state, or federal laws. It is also the obligation of each user of the product mentioned herein to determine and comply with the requirements of all applicable statutes. This product is not known to be regulated under RCRA regulations. Disposal of unused portions of this product and process waste containing this product should be done only after a careful evaluation and in compliance with all federal, local and state laws. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |N/A Hazard Class |N/A |<PICTOGRAM PHRASE> Identification Number|N/A | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not subject to IMDG code. Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not subject to IATA regulations. Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> The contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. SARA Title III Section 302 Extremely Hazardous Substances: None. SARA Titre III Section 304 CERCLA Substances Dangereuses: None SARA Title III Section 313 Toxic Chemicals: None present or none present in regulated quantities. SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |All chemical substances found in this product |comply with the Toxic Substances Control Act |inventory reporting requirements. 15.2 US State Regulations <COMPONENT> California Proposition 65: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other reproductive harm: None known. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |3/19/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.