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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: SikaÂ® Primer-206 G+P CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: For further information, refer to the product technical data sheet. 1.3. Name, Address, and Telephone of the Responsible Party Company Sika Corporation 201 Polito Avenue Lyndhurst, NJ 07071 USA www.sikausa.com Phone: (201) 933-8800 1.4. Emergency Telephone Number Emergency |CHEMTREC: 800-424-9300 number |INTERNATIONAL: 703-527-3887 |firstname.lastname@example.org SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 2 liquids | Eye irritation|Category 2A Respiratory |Category 1 sensitization | Skin |Category 1 sensitization | Carcinogenicit|Category 2 y | Specific |Category 3, target organ |Central systemic |nervous system toxicity - | single | exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H225 Highly flammable liquid and vapor. |H317 May cause an allergic skin reaction. |H319 Causes serious eye irritation. |H334 May cause allergy or asthma symptoms or |breathing difficulties if inhaled. |H336 May cause drowsiness or dizziness. |H351 Suspected of causing cancer. Precautionary Statements |Prevention: (GHS-US) |P201 Obtain special instructions before use. |P202 Do not handle until all safety precautions have |been read and understood. |P210 Keep away from heat/sparks/open flames/hot |surfaces. - No smoking. |P233 Keep container tightly closed. |P240 Ground/bond container and receiving equipment. |P241 Use explosion-proof electrical/ ventilating/ |lighting/ equipment. |P242 Use only non-sparking tools. |P243 Take precautionary measures against static |discharge. |P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ |spray. |P264 Wash skin thoroughly after handling. |P271 Use only outdoors or in a well-ventilated area. | |P272 Contaminated work clothing should not be |allowed out of the workplace. |P280 Wear protective gloves/ eye protection/ face |protection. |P281 Use personal protective equipment as required. |P285 In case of inadequate ventilation wear |respiratory protection. |Response: |P303 + P361 + P353 IF ON SKIN (or hair): Remove/ |Take off immediately all contaminated clothing. |Rinse skin with water/ shower. |P304 + P340 IF INHALED: Remove victim to fresh air |and keep at rest in a position comfortable for |breathing. |P305 + P351 + P338 IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. |P308 + P313 IF exposed or concerned: Get medical |advice/ attention. |P333 + P313 If skin irritation or rash occurs: Get |medical advice/ attention. |P337 + P313 If eye irritation persists: Get medical |advice/ attention. |P363 Wash contaminated clothing before reuse. |P370 + P378 In case of fire: Use dry sand, dry |chemical or alcohol-resistant foam for extinction. |Storage: |P403 + P233 Store in a well-ventilated place. Keep |container tightly closed. |P403 + P235 Store in a well-ventilated place. Keep |cool. |P405 Store locked up. |Disposal: |P501 Dispose of contents/ container to an approved |waste disposal plant. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Ethyl acetate |141-78-6 |>= 50 - | | |<= 100 %| Carbon black |1333-86-4 |>= 5 - <| | |10 % | Hexamethylene-1,6-diisocyanate |28182-81-2 |>= 5 - <| homopolymer | |10 % | Tris(p-isocyanatophenyl) |4151-51-3 |>= 5 - <| thiophosphate | |10 % | Isophorondiisocyanate |53880-05-0 |>= 5 - <| homopolymer | |10 % | n-Butyl acetate |123-86-4 |>= 2 - <| | |5 % | 2-Methoxy-1-methylethyl acetate |108-65-6 |>= 1 - <| | |2 % | Ethylbenzene |100-41-4 |>= 0 - <| | |1 % | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Move to fresh air. Consult a physician after significant exposure. First-aid Measures After Skin Contact: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. First-aid Measures After Eye Contact: Immediately flush eye(s) with plenty of water. Remove contact lenses. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. First-aid Measures After Ingestion: Clean mouth with water and drink afterwards plenty of water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Obtain medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Irritant effects sensitizing effects. Asthmatic appearance. Respiratory disorder. Allergic reactions. Excessive lachrymation. Loss of balance. Vertigo. See Section 11 for more detailed information on health effects and symptoms. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable Extinguishing Media: Water, High volume water jet 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Do not use a solid water stream as it may scatter and spread fire. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Protection During Firefighting: In the event of fire, wear self-contained breathing apparatus. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment. Remove all sources of ignition. Deny access to unprotected persons. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent product from entering drains. If the product contaminates rivers and lakes or drains inform respective authorities. Local authorities should be advised if significant spillages cannot be contained. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid formation of aerosol. Do not breathe vapors or spray mist. Avoid exceeding the given occupational exposure limits (see section 8). Do not get in eyes, on skin, or on clothing. For personal protection see section 8. Persons with a history of skin sensitization problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharge. Open drum carefully as content may be under pressure. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Follow standard hygiene measures when handling chemical products. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in original container. Store in cool place. Keep in a well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Store in accordance with local regulations. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Component CAS-No. Basis ** Value Exposure limit(s)* / Form of exposure Ethyl acetate 141-78-6 ACGIH TWA 400 ppm OSHA Z-1 TWA 400 ppm 1,400 mg/m3 OSHA P0 TWA 400 ppm 1,400 mg/m3 Carbon black 1333-86-4 ACGIH TWA 3.5 mg/m3 OSHA Z-1 TWA 3.5 mg/m3 OSHA P0 TWA 3.5 mg/m3 n-Butyl acetate 123-86-4 ACGIH TWA 150 ppm ACGIH STEL 200 ppm OSHA Z-1 TWA 150 ppm 710 mg/m3 OSHA P0 TWA 150 ppm 710 mg/m3 OSHA P0 STEL 200 ppm 950 mg/m3 Ethylbenzene 100-41-4 ACGIH TWA 100 ppm ACGIH STEL 125 ppm OSHA Z-1 TWA 100 ppm 435 mg/m3 OSHA P0 TWA 100 ppm 435 mg/m3 OSHA P0 STEL 125 ppm 545 mg/m3 *The above mentioned values are in accordance with the legislation in effect at the date of the release of this safety data sheet. **Basis: ACGIH. Threshold Limit Values (TLV) OSHA P0. Table Z-1, Limit for Air Contaminat (1989 Vacated Values) OSHA P1. Permissible Exposure Limits (PEL), Table Z-1, Limit for Air Contaminant OSHA P2. Permissible Exposure Limits (PEL), Table Z-2 OSHA Z3. Table Z-3, Mineral Dust 8.2. Exposure Controls Appropriate Engineering |Use of adequate ventilation should be sufficient to Controls |control worker exposure to airborne contaminants. If |the use of this product generates dust, fumes, gas, |vapor or mist, use process enclosures, local |exhaust ventilation or other engineering controls |to keep worker exposure below any recommended or |statutory limits. The engineering controls also |need to keep gas, vapor or dust concentrations |below any lower explosive limits. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Chemical-resistant, impervious gloves complying with |an approved standard should be worn at all times |when handling chemical products if a risk |assessment indicates this is necessary. Eye Protection |Safety eyewear complying with an approved standard |should be used when a risk assessment indicates this |is necessary. Skin and Body Protection |Choose body protection in relation to its type, to |the concentration and amount of dangerous |substances, and to the specific work place. Respiratory Protection |Use a properly fitted NIOSH approved air-purifying |or air-fed respirator complying with an approved |standard if a risk assessment indicates this is |necessary. The filter class for the respirator must |be suitable for the maximum expected contaminant |concentration (gas/vapor/aerosol/particulates) that |may arise when handling the product. If this |concentration is exceeded, self-contained breathing |apparatus must be used. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |liquid Odor |ester-like Odor Threshold |no data available pH |ca. 7 Relative Evaporation Rate |no data available (butylacetate=1) | Melting Point |no data available Freezing Point |no data available Boiling Point |> 171 Â°F (> 77 Â°C) Flash Point |25 Â°F (-4 Â°C) Auto-ignition Temperature |no data available Decomposition Temperature |no data available Flammability (solid, gas) |no data available Vapor Pressure |75.000 mmHg (99.9915 hpa) Relative Vapor Density at 20 Â°C |no data available Relative Density |ca.1.02 g/cm3 at 68 Â°F (20 Â°C) Specific Gravity | Solubility |Note: insoluble Partition coefficient: |no data available n-octanol/water | Viscosity |Dynamic: no data available |Kinematic: > 7 mm2/s at 104 Â°F (40 Â°C) Lower Flammable Limit |2.1 %(V) Upper Flammable Limit |11.5 %(V) 9.2. Other Information Volatile organic compounds (VOC) content: 619 g/l SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical Stability The product is chemically stable. 10.3 Possibility of Hazardous Reactions Stable under recommended storage conditions. Vapors may form explosive mixture with air. 10.4 Conditions to Avoid Heat, flames and sparks. 10.5 Incompatible Materials No data available 10.6 Hazardous Decomposition Products SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Product Acute oral toxicity: No data available Acute inhalation toxicity: No data available Acute dermal toxicity: No data available Skin Corrosion/Irritation: Product No data available Serious Eye Damage/Irritation: Product Causes serious eye irritation. Respiratory or Skin Sensitization: Product May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Germ Cell Mutagenicity: Product Mutagenicity: No data available Carcinogenicity: Product Carcinogenicity: Suspected of causing cancer. IARC Group 2B: Possibly carcinogenic to humans Carbon black 1333-86-4 Ethylbenzene 100-41-4 NTP: Not applicable Reproductive Toxicity:Reproductive Toxicity/Fertility Product Reproductive toxicity: No data available Reproductive Toxicity/Development/Teratogenicity Product Teratogenicity: No data available Specific Target Organ Toxicity (Single Exposure): Product Assessment: May cause drowsiness or dizziness. Specific Target Organ Toxicity (Repeated Exposure): Reports have associated repeated and prolonged exposure to some of the chemicals in this product with permanent brain,liver, kidney and nervous system damage. Intentional misuse by deliberate concentration and inhalation of vapors may be harmful or fatal. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Product Assessment: No data available Aspiration Hazard: Product No data available Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Component: Carbon black 1333-86-4 Toxicity to fish LC50 Species: Brachydanio rerio (zebrafish) Dose: > 1,000 mg/l Exposure time: 96 h n-butyl acetate 123-86-4 Toxicity to fish: LC50 Species: Fish Dose: 18 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates: EC50 Species: Daphnia magna (Water flea) Dose: 44 mg/l Exposure time: 48 h Toxicity to algae: EC50 Species: Desmodesmus subspicatus (green algae) Dose: 647.7 mg/l Exposure time: 72 h 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste from residues : Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Resin solution Hazard Class |3 |<PICTOGRAM PHRASE> Identification Number|UN1866 | Label Codes |3 | ERG Number |127 14.2 In Accordance with IMDG Proper Shipping Name |RESIN SOLUTION Hazard Class |3 Identification Number|UN1866 Label Codes |3 |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-E | EmS-No. (Spillage) |S-E | 14.3 In Accordance with IATA Proper Shipping Name |Resin solution Identification Number|UN1866 |<PICTOGRAM PHRASE> Hazard Class |3 | Label Codes |3 | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 302: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA Section 311/312 Hazard Classes |Acute Health Hazard |Chronic Health Hazard |Fire Hazard Toxic Substances Control Act (TSCA) |All chemical substances in this product are |either listed on the TSCA Inventory or are in |compliance with a TSCA Inventory exemption. 15.2 US State Regulations <COMPONENT> California Prop 65 WARNING! This product contains a chemical known in the State of California to cause cancer. WARNING: This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |06/12/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.