Register Now    |    Login

National Distributor of Quality Maintenance Supplies Since 1958


Track Order Status

Sheet 0076700

Printer Friendly View
SECTION 1: IDENTIFICATION                                                       

1.1.  Product Identifier
Product Form:                                                                   
Product Name: Sika� Primer-206 G+P                                              
CAS No:                                                                         

1.2.  Intended Use of the Product
Use of the substance/mixture: For further information, refer to the product     
technical data sheet.                                                           

1.3.  Name, Address, and Telephone of the Responsible Party
Sika Corporation                                                                
201 Polito Avenue                                                               
Lyndhurst, NJ 07071                                                             
Phone: (201) 933-8800                                                           

1.4.  Emergency Telephone Number
Emergency     |CHEMTREC: 800-424-9300                                           
number        |INTERNATIONAL: 703-527-3887                                      

SECTION 2: HAZARDS IDENTIFICATION                                               

2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flammable     |Category 2    
liquids       |              
Eye irritation|Category 2A   
Respiratory   |Category 1    
sensitization |              
Skin          |Category 1    
sensitization |              
Carcinogenicit|Category 2    
y             |              
Specific      |Category 3,   
target organ  |Central       
systemic      |nervous system
toxicity -    |              
single        |              
exposure      |              

2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame |Health Hazard |Exclamation Mark
Signal Word (GHS-US)         |Danger                                            
Hazard Statements (GHS-US)   |H225 Highly flammable liquid and vapor.           
                             |H317 May cause an allergic skin reaction.         
                             |H319 Causes serious eye irritation.               
                             |H334 May cause allergy or asthma symptoms or      
                             |breathing difficulties if inhaled.                
                             |H336 May cause drowsiness or dizziness.           
                             |H351 Suspected of causing cancer.                 
Precautionary Statements     |Prevention:                                       
(GHS-US)                     |P201 Obtain special instructions before use.      
                             |P202 Do not handle until all safety precautions
                             |been read and understood.                         
                             |P210 Keep away from heat/sparks/open flames/hot   
                             |surfaces. - No smoking.                           
                             |P233 Keep container tightly closed.               
                             |P240 Ground/bond container and receiving
                             |P241 Use explosion-proof electrical/ ventilating/ 
                             |lighting/ equipment.                              
                             |P242 Use only non-sparking tools.                 
                             |P243 Take precautionary measures against static   
                             |P261 Avoid breathing dust/ fume/ gas/ mist/
                             |P264 Wash skin thoroughly after handling.         
                             |P271 Use only outdoors or in a well-ventilated
                             |P272 Contaminated work clothing should not be     
                             |allowed out of the workplace.                     
                             |P280 Wear protective gloves/ eye protection/ face 
                             |P281 Use personal protective equipment as
                             |P285 In case of inadequate ventilation wear       
                             |respiratory protection.                           
                             |P303 + P361 + P353 IF ON SKIN (or hair): Remove/  
                             |Take off immediately all contaminated clothing.   
                             |Rinse skin with water/ shower.                    
                             |P304 + P340 IF INHALED: Remove victim to fresh air
                             |and keep at rest in a position comfortable for    
                             |P305 + P351 + P338 IF IN EYES: Rinse cautiously
                             |water for several minutes. Remove contact lenses,
                             |present and easy to do. Continue rinsing.         
                             |P308 + P313 IF exposed or concerned: Get medical  
                             |advice/ attention.                                
                             |P333 + P313 If skin irritation or rash occurs: Get
                             |medical advice/ attention.                        
                             |P337 + P313 If eye irritation persists: Get
                             |advice/ attention.                                
                             |P363 Wash contaminated clothing before reuse.     
                             |P370 + P378 In case of fire: Use dry sand, dry    
                             |chemical or alcohol-resistant foam for extinction.
                             |P403 + P233 Store in a well-ventilated place. Keep
                             |container tightly closed.                         
                             |P403 + P235 Store in a well-ventilated place. Keep
                             |P405 Store locked up.                             
                             |P501 Dispose of contents/ container to an approved
                             |waste disposal plant.                             

2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                           

2.4.  Unknown Acute Toxicity (GHS-US)


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
                                |                     |        |(GHS-US)        
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                

Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
                                |                     |        |(GHS-US)        
Ethyl acetate                   |141-78-6             |>= 50 - |                
                                |                     |<= 100 %|                
Carbon black                    |1333-86-4            |>= 5 - <|                
                                |                     |10 %    |                
Hexamethylene-1,6-diisocyanate  |28182-81-2           |>= 5 - <|                
homopolymer                     |                     |10 %    |                
Tris(p-isocyanatophenyl)        |4151-51-3            |>= 5 - <|                
thiophosphate                   |                     |10 %    |                
Isophorondiisocyanate           |53880-05-0           |>= 5 - <|                
homopolymer                     |                     |10 %    |                
n-Butyl acetate                 |123-86-4             |>= 2 - <|                
                                |                     |5 %     |                
2-Methoxy-1-methylethyl acetate |108-65-6             |>= 1 - <|                
                                |                     |2 %     |                
Ethylbenzene                    |100-41-4             |>= 0 - <|                
                                |                     |1 %     |                

SECTION 4: FIRST AID MEASURES                                                   

4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
First-aid Measures After Inhalation: Move to fresh air. Consult a physician
significant exposure.                                                           
First-aid Measures After Skin Contact: Take off contaminated clothing and shoes 
immediately. Wash off with soap and plenty of water.  If symptoms persist, call
First-aid Measures After Eye Contact: Immediately flush eye(s) with plenty of   
water. Remove contact lenses. Keep eye wide open while rinsing. If eye
persists, consult a specialist.                                                 
First-aid Measures After Ingestion: Clean mouth with water and drink afterwards 
plenty of water. Do not give milk or alcoholic beverages. Never give anything by
mouth to an unconscious person. Obtain medical attention.                       

4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: Irritant effects sensitizing effects. Asthmatic appearance.  
Respiratory disorder. Allergic reactions. Excessive lachrymation. Loss of
Vertigo. See Section 11 for more detailed information on health effects  and    
Symptoms/Injuries After Inhalation:                                             
Symptoms/Injuries After Skin Contact:                                           
Symptoms/Injuries After Eye Contact:                                            
Symptoms/Injuries After Ingestion:                                              
Chronic Symptoms:                                                               

4.3.  Indication of Any Immediate Medical Attention and Special Treatment

SECTION 5: FIRE-FIGHTING MEASURES                                               

5.1.  Extinguishing Media
Suitable Extinguishing Media: Alcohol-resistant foam Carbon dioxide (CO2)  Dry  
Unsuitable Extinguishing Media: Water, High volume water jet                    

5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Do not use a solid water stream as it may scatter and spread fire. 
Explosion Hazard:                                                               

5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
Firefighting Instructions: Use water spray to cool unopened containers.  Collect
contaminated fire extinguishing water separately. This  must not be discharged  
into drains.  Fire residues and contaminated fire extinguishing water must  be  
disposed of in accordance with local regulations.                               
Protection During Firefighting: In the event of fire, wear self-contained       
breathing apparatus.                                                            

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          

6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Use personal protective equipment. Remove all sources of      
ignition. Deny access to unprotected persons.  Beware of vapors accumulating to 
form explosive  concentrations. Vapors can accumulate in low areas.             

6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
Emergency Procedures:                                                           

6.1.2.      For Emergency Responders
Protective Equipment:                                                           
Emergency Procedures:                                                           

6.2.  Environmental Precautions
Prevent product from entering drains. If the product contaminates rivers and
or drains inform  respective authorities.  Local authorities should be advised
significant spillages  cannot be contained.                                     

6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
Methods for Cleaning Up: Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,  vermiculite) and
in container for disposal according to  local / national regulations (see

6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      

SECTION 7: HANDLING AND STORAGE                                                 

7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid formation of aerosol. Do not breathe   
vapors or spray mist. Avoid exceeding the given occupational exposure limits
section 8). Do not get in eyes, on skin, or on clothing. For personal protection
see section 8.  Persons with a history of skin sensitization problems or 
allergies, chronic or recurrent respiratory disease should not be employed in
process in which this mixture is being used. Smoking, eating and drinking should
be prohibited in the  application area. Take precautionary measures against
discharge. Open drum carefully as content may be under pressure.  Take necessary
action to avoid static electricity discharge  (which might cause ignition of    
organic vapors). Follow standard hygiene measures when handling chemical        
Hygiene Measures:                                                               

7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
Storage Conditions: Store in original container. Store in cool place.  Keep in a
well-ventilated place.  Containers which are opened must be carefully resealed
kept upright to prevent leakage.  Observe label precautions.  Store in
with local regulations.                                                         

7.3.  Specific End Use(s)


8.1.  Control Parameters
Basis **                                                                        
Exposure limit(s)* /                                                            
Form of exposure                                                                
Ethyl acetate                                                                   
400 ppm                                                                         
OSHA Z-1                                                                        
400 ppm                                                                         
1,400 mg/m3                                                                     
OSHA P0                                                                         
400 ppm                                                                         
1,400 mg/m3                                                                     
Carbon black                                                                    
3.5 mg/m3                                                                       
OSHA Z-1                                                                        
3.5 mg/m3                                                                       
OSHA P0                                                                         
3.5 mg/m3                                                                       
n-Butyl acetate                                                                 
150 ppm                                                                         
200 ppm                                                                         
OSHA Z-1                                                                        
150 ppm                                                                         
710 mg/m3                                                                       
OSHA P0                                                                         
150 ppm                                                                         
710 mg/m3                                                                       
OSHA P0                                                                         
200 ppm                                                                         
950 mg/m3                                                                       
100 ppm                                                                         
125 ppm                                                                         
OSHA Z-1                                                                        
100 ppm                                                                         
435 mg/m3                                                                       
OSHA P0                                                                         
100 ppm                                                                         
435 mg/m3                                                                       
OSHA P0                                                                         
125 ppm                                                                         
545 mg/m3                                                                       
*The above mentioned values are in accordance with the legislation in effect at 
the date of the release of this safety data sheet.                              
ACGIH. Threshold Limit Values (TLV)                                             
OSHA P0. Table Z-1, Limit for Air Contaminat (1989 Vacated Values)              
OSHA P1. Permissible Exposure Limits (PEL), Table Z-1, Limit for Air Contaminant
OSHA P2. Permissible Exposure Limits (PEL), Table Z-2                           
OSHA Z3. Table Z-3, Mineral Dust                                                

8.2.  Exposure Controls
Appropriate Engineering      |Use of adequate ventilation should be sufficient
Controls                     |control worker exposure to airborne contaminants.
                             |the use of this  product generates dust, fumes,
                             |vapor or mist, use  process enclosures, local     
                             |exhaust ventilation or other  engineering controls
                             |to keep worker exposure below any  recommended or 
                             |statutory limits.  The engineering controls also  
                             |need to keep gas, vapor or dust  concentrations   
                             |below any lower explosive limits.                 
Personal Protective Equipment|                                                  
Materials for Protective     |                                                  
Clothing                     |                                                  
Hand Protection              |Chemical-resistant, impervious gloves complying
                             |an approved standard should be worn at all times  
                             |when handling  chemical products if a risk        
                             |assessment indicates this is  necessary.          
Eye Protection               |Safety eyewear complying with an approved standard
                             |should be used when a risk assessment indicates
                             |is necessary.                                     
Skin and Body Protection     |Choose body protection in relation to its type, to
                             |the concentration and amount of dangerous         
                             |substances, and to the specific work place.       
Respiratory Protection       |Use a properly fitted NIOSH approved air-purifying
                             |or air-fed respirator complying with an approved  
                             |standard if a risk  assessment indicates this is  
                             |necessary. The filter class for the respirator
                             |be suitable for the  maximum expected contaminant 
                             |concentration  (gas/vapor/aerosol/particulates)
                             |may arise when handling  the product. If this     
                             |concentration is exceeded, self-contained 
                             |apparatus must be used.                           
Thermal Hazard Protection    |                                                  

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     

9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |                                           
Appearance                          |liquid                                     
Odor                                |ester-like                                 
Odor Threshold                      |no data available                          
pH                                  |ca. 7                                      
Relative Evaporation Rate           |no data available                          
(butylacetate=1)                    |                                           
Melting Point                       |no data available                          
Freezing Point                      |no data available                          
Boiling Point                       |> 171 �F (> 77 �C)                         
Flash Point                         |25 �F (-4 �C)                              
Auto-ignition Temperature           |no data available                          
Decomposition Temperature           |no data available                          
Flammability (solid, gas)           |no data available                          
Vapor Pressure                      |75.000 mmHg (99.9915 hpa)                  
Relative Vapor Density at 20 �C     |no data available                          
Relative Density                    |ca.1.02 g/cm3 at 68 �F (20 �C)             
Specific Gravity                    |                                           
Solubility                          |Note: insoluble                            
Partition coefficient:              |no data available                          
n-octanol/water                     |                                           
Viscosity                           |Dynamic: no data available                 
                                    |Kinematic: > 7 mm2/s at 104 �F (40 �C)     
Lower Flammable Limit               |2.1 %(V)                                   
Upper Flammable Limit               |11.5 %(V)                                  

9.2.  Other Information
Volatile organic compounds (VOC) content: 619 g/l                               

SECTION 10: STABILITY AND REACTIVITY                                            

10.1      Reactivity
No dangerous reaction known under conditions of normal use.                     

10.2      Chemical Stability
The product is chemically stable.                                               

10.3      Possibility of Hazardous Reactions
Stable under recommended storage conditions. Vapors may form explosive mixture  
with air.                                                                       

10.4      Conditions to Avoid
Heat, flames and sparks.                                                        

10.5      Incompatible Materials
No data available                                                               

10.6      Hazardous Decomposition Products

SECTION 11: TOXICOLOGICAL INFORMATION                                           

11.1. Information on Toxicological Effects
Acute Toxicity: Product                                                         
Acute oral toxicity: No data available                                          
Acute inhalation toxicity: No data available                                    
Acute dermal toxicity: No data available                                        
Skin Corrosion/Irritation: Product                                              
No data available                                                               
Serious Eye Damage/Irritation: Product                                          
Causes serious eye irritation.                                                  
Respiratory or Skin Sensitization: Product                                      
May cause an allergic skin reaction.                                            
May cause allergy or asthma symptoms or breathing difficulties if inhaled.      
Germ Cell Mutagenicity: Product                                                 
Mutagenicity: No data available                                                 
Carcinogenicity: Product                                                        
Carcinogenicity: Suspected of causing cancer.                                   
IARC Group 2B: Possibly carcinogenic to humans                                  
Carbon black 1333-86-4                                                          
Ethylbenzene 100-41-4                                                           
NTP: Not applicable                                                             
Reproductive Toxicity:Reproductive Toxicity/Fertility                           
Reproductive toxicity: No data available                                        
Reproductive Toxicity/Development/Teratogenicity                                
Teratogenicity: No data available                                               
Specific Target Organ Toxicity (Single Exposure): Product                       
Assessment: May cause drowsiness or dizziness.                                  
Specific Target Organ Toxicity (Repeated Exposure): Reports have associated     
repeated and prolonged exposure to some of the chemicals in this product  with  
permanent brain,liver, kidney and nervous system damage. Intentional misuse by  
deliberate  concentration and inhalation of vapors may be harmful or fatal. 
sensitized, a severe allergic reaction may occur when subsequently exposed to
low levels.                                                                     
Assessment: No data available                                                   
Aspiration Hazard: Product                                                      
No data available                                                               
Symptoms/Injuries After Inhalation:                                             
Symptoms/Injuries After Skin Contact:                                           
Symptoms/Injuries After Eye Contact:                                            
Symptoms/Injuries After Ingestion:                                              
Chronic Symptoms:                                                               

SECTION 12: ECOLOGICAL INFORMATION                                              

12.1. Toxicity
Carbon black       1333-86-4      Toxicity to fish                              
Species: Brachydanio rerio (zebrafish)                                          
Dose: > 1,000 mg/l                                                              
Exposure time: 96 h                                                             
n-butyl acetate   123-86-4        Toxicity to fish:                             
Species: Fish                                                                   
Dose: 18 mg/l                                                                   
Exposure time: 96 h                                                             
Toxicity to daphnia and other aquatic invertebrates:                            
Species: Daphnia magna (Water flea)                                             
Dose: 44 mg/l                                                                   
Exposure time: 48 h                                                             
Toxicity to algae:                                                              
Species: Desmodesmus subspicatus (green algae)                                  
Dose: 647.7 mg/l                                                                
Exposure time: 72 h                                                             

12.2. Persistence and Degradability

12.3. Bioaccumulative Potential

12.4. Mobility in Soil

12.5. Other Adverse Effects

13.1. Waste treatment methods
Waste Disposal Recommendations: Waste from residues : Disposal of this product, 
solutions and any by-products should at all times comply with the requirements
environmental  protection and waste disposal legislation and any regional  local
authority requirements.                                                         
Additional Information: Contaminated packaging: Empty containers should be taken
to an approved waste handling site for recycling or disposal.                   

SECTION 14: TRANSPORT INFORMATION                                               

14.1 In Accordance with DOT
Proper Shipping Name |Resin solution                                            
Hazard Class         |3                      |<PICTOGRAM PHRASE>                
Identification Number|UN1866                 |                                  
Label Codes          |3                      |                                  
ERG Number           |127                                                       

14.2 In Accordance with IMDG
Proper Shipping Name |RESIN SOLUTION                                            
Hazard Class         |3                                                         
Identification Number|UN1866                                                    
Label Codes          |3                     |<PICTOGRAM PHRASE>                 
ntification Of The   |                      |                                   
Substance/m          |                      |                                   
EmS-No. (Fire)       |F-E                   |                                   
EmS-No. (Spillage)   |S-E                   |                                   

14.3 In Accordance with IATA
Proper Shipping Name |Resin solution                                            
Identification Number|UN1866                 |<PICTOGRAM PHRASE>                
Hazard Class         |3                      |                                  
Label Codes          |3                      |                                  
ntification Of The   |                       |                                  
Substance/m          |                       |                                  
ERG Code (IATA)      |                                                          

SECTION 15: REGULATORY INFORMATION                                              

15.1      US Federal Regulations
SARA 302: SARA 302: No chemicals in this material are subject to the reporting  
requirements of SARA Title III, Section 302.                                    
SARA 313: This material does not contain any chemical components with known CAS 
numbers that exceed the  threshold (De Minimis) reporting levels established by 
SARA  Title III, Section 313.                                                   
SARA Section 311/312 Hazard Classes |Acute Health Hazard                        
                                    |Chronic Health Hazard                      
                                    |Fire Hazard                                
Toxic Substances Control Act (TSCA) |All chemical substances in this product are
                                    |either listed on the TSCA Inventory or are
                                    |compliance with a TSCA Inventory 

15.2      US State Regulations
California Prop 65 WARNING! This product contains a chemical known in the State
California to cause cancer. WARNING: This product contains a chemical known in
State of California to cause birth defects or other reproductive  harm.         


Revision date   |06/12/2014                                                     
Other           |This document has been prepared in accordance with the SDS     
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
GHS Full Text Phrases:                                                          
----|                               |                                           
--  |                               |                                           
----|                               |                                           
--  |                               |                                           
----|                               |                                           
--  |                               |                                           
----|                               |                                           
--  |                               |                                           
----|                               |                                           
--  |                               |                                           

Grainger disclaimer.


The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.