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Sheet 0076640 Printer Friendly View
Safety Data Sheet
Date of Issue: |Revision Date: 07/01/2013 |Revision Number:
Imperial Supplies Part Number: 0076640
SECTION 1: IDENTIFICATION
1.1. Product Identifier
Product Form:
Product Name: Urethane Windshield Sealer
CAS No:
Synonyms:
1.2. Intended Use of the Product
Use of the substance/mixture:
1.3. Name, Address, and Telephone of the Responsible Party
Company
Saint-Gobain Abrasives, Inc.
1 New Bond Street
Worcester, MA 01615
Phone Number: 508-795-5000
1.4. Emergency Telephone Number
Emergency | 508-795-5000
number |
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
Classification (GHS-US)
|
|
|
2.2. Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) | | | | | |
Signal Word (GHS-US) |
Hazard Statements (GHS-US) |
Precautionary Statements |
(GHS-US) |
2.3. Other Hazards
Other Hazards Not Contributing to the Classification:
2.4. Unknown Acute Toxicity (GHS-US)
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
Name |Product identifier |% |Classification
| | |(GHS-US)
| | |
| | |
| | |
| | |
| | |
Full text of H-phrases: See Section 16
3.2. Mixture
Name |Product identifier |% |Classification
| | |(GHS-US)
Polyeurethane pre-polymer |Not Applicable |60 - 100|
| |by |
| |weight |
Methylene bisphenyldiisocyanate |101-68-8 |0.1 - 1 |
| |by |
| |weight |
Carbon black |1333-86-4 |10 - 30 |
| |by |
| |weight |
Hydro treated light petroleum |64742-47-8 |1 - 5 by|
distillates | |weight |
Toluene |108-88-3 |1 - 5 by|
| |weight |
SECTION 4: FIRST AID MEASURES
4.1. Description of First Aid Measures
First-aid Measures General:
First-aid Measures After Inhalation: If inhaled, remove to fresh air. If not
breathing, give artificial respiration or give oxygen by trained personnel. Seek
immediate medical attention.
First-aid Measures After Skin Contact: Immediately wash skin with soap and plenty
of water. Get medical attention if irritation develops or persists.
First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water
for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating
the eyelids with fingers. Get immediate medical attention.
First-aid Measures After Ingestion: If swallowed, do NOT Induce vomiting. Call a
physician or poison control center immediately. Never give anything by mouth to an
unconscious person.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:
Symptoms/Injuries After Inhalation: Prolonged or excessive inhalation may cause
respiratory tract irritation.
Symptoms/Injuries After Skin Contact: May cause irritation.
Symptoms/Injuries After Eye Contact: May cause irritation.
Symptoms/Injuries After Ingestion: Harmful if swallowed. Ingestion can cause
nausea, vomiting, diarrhea and gastrointestinal irritation.
Chronic Symptoms:
4.3. Indication of Any Immediate Medical Attention and Special Treatment
Needed
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media: Use foam, alcohol foam, carbon dioxide (C02), dry
chemical and Water Fog when fighting fires involving this material.
Unsuitable Extinguishing Media:
5.2. Special Hazards Arising From the Substance or Mixture
Fire Hazard:
Explosion Hazard:
Reactivity:
5.3. Advice for Firefighters
Precautionary Measures Fire:
Firefighting Instructions: Evacuate area of unprotected personnel. Use cold water
spray to cool fire exposed containers to minimize risk of rupture. Do not enter
confined fire space without full protective gear. If possible, contain fire
run-off water.
Protection During Firefighting: As in any fire, wear Self-Contained Breathing
Apparatus (SCBA), MSHA/NIOSH (approved or equivalent) and full protective gear.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:
6.1.1. For Non-emergency Personnel
Protective Equipment:
Emergency Procedures:
6.1.2. For Emergency Responders
Protective Equipment:
Emergency Procedures:
6.2. Environmental Precautions:
Use proper personal protective equipment as listed in Section 8.
6.3. Methods and Material for Containment and Cleaning Up
For Containment:
Methods for Cleaning Up: Remove all sources of Ignition. Absorb spill with inert
material (e.g., dry sand or earth), then place in a chemical waste container.
Provide ventilation. Collect spill with a non-sparking tool. Place into a suitable
container for disposal.
6.4. Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Additional Hazards When Processed:
Hygiene Measures: Wash thoroughly after handling. Avoid contact with eyes and
skin. Avoid inhaling vapor or mist.
7.2. Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:
Storage Conditions: Store in a cool, dry, well ventilated area away from sources
of heat, combustible materials, and incompatible substances. Keep container
tightly dosed when not in use.
7.3. Specific End Use(s)
Special Handling Procedures: Provide appropriate ventilation/respiratory
protection against decomposition products (see Section 10) during welding/flame
cutting operations and to protect against dust during sanding/grinding of cured
product.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
EXPOSURE GUIDELINES:
Methylene bisphenyldiisocyanate:
Guideline ACGIH: 0.005 ppm
TLV-TWA: 0.005 ppm
Guideline OSHA: PEL-Ceiling/Peak: 0.02 ppm
Toluene:
Guideline ACGIH: TLV-TWA: 20 ppm
Guideline OSHA: PEL-TWA: 200 ppm PEL-Ceiling/Peak: 300 ppm PEL-Ceiling/Peak: 500
ppm Peak
8.2. Exposure Controls
Appropriate Engineering |Use appropriate engineering control such as process
Controls |enclosures, local exhaust ventilation, or other
|engineering controls to control airborne levels
|below recommended exposure limits. Good general
|ventilation should be sufficient to control airborne
|levels. Where such systems are not effective wear
|suitable personal protective equipment, which
|performs satisfactorily and meets OSHA or other
|recognized standards. Consult with local procedures
|for selection, training, inspection and maintenance
|of the personal protective equipment.
Personal Protective Equipment|Other Protective: Facilities storing or utilizing
|this material should be equipped with an eyewash
|facility and a safety shower.
Materials for Protective |
Clothing |
Hand Protection |Use nitrile or butyl rubber gloves
|(chemical-resistant).
Eye Protection |Wear appropriate protective glasses or splash
|goggles as described by 29 CFR 1910.133, OSHA eye
|and face protection regulation, or the European
|standard EN 166.
Skin and Body Protection |Chemical-resistant gloves and chemical goggles,
|face-shield and synthetic apron or coveralls should
|be used to prevent contact with eyes, skin or
|clothing.
Respiratory Protection |A NIOSH approved air-purifying respirator with an
|organic vapor cartridge or canister may be
|permissible under certain circumstances where
|airborne concentrations are expected to exceed
|exposure limits. Protection provided by air
|purifying respirators is limited. Use a positive
|pressure air supplied respirator if there is any
|potential for an uncontrolled release, exposure
|levels are not known, or any other circumstances
|where air purifying respirators may not provide
|adequate protection.
Thermal Hazard Protection |
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
Physical State |Paste.
Appearance |
Odor |Vinegar/Acetic acid
Odor Threshold |
pH |Not determined.
Relative Evaporation Rate (butyl |Slower than butyl acetate.
acetate=1) |
Melting Point |Not determined.
Freezing Point |
Boiling Point |Range: 4 to 111 Deg C
Flash Point |140�F (60�C)
Auto-ignition Temperature |Not determined.
Decomposition Temperature |
Flammability (solid, gas) |
Vapor Pressure |8 mm Hg
Relative Vapor Density at 20 �C |4.11
Relative Density |
Specific Gravity |1.200
Solubility |Not determined.
Partition coefficient: |
n-octanol/water |
Viscosity |
Lower Flammable Limit |0.6%
Upper Flammable Limit |7.1%
9.2. Other Information
VOC Content: Lbs VOC/Gal (-H2O & Ex Solv): 0.40 Lbs VOC/Gal: 0.40
SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity
10.2 Chemical Stability:
Stable under normal temperatures and pressures.
10.3 Possibility of Hazardous Reactions
10.4 Conditions to Avoid
Heat, flames, Ignition sources, and sparks. Incompatible materials. Freezing or
temperatures below 0�C (32�F). Temperatures above 120 �F.
10.5 Incompatible Materials
Oxidizing agents. Strong acids and alkalis.
10.6 Hazardous Decomposition Products
Carbon monoxide, carbon dioxide, oxides of nitrogen and cyanide.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects
Acute Toxicity:
Skin Corrosion/Irritation:
Serious Eye Damage/Irritation:
Respiratory or Skin Sensitization:
Germ Cell Mutagenicity:
Carcinogenicity:
Reproductive Toxicity:
Specific Target Organ Toxicity (Single Exposure):
Specific Target Organ Toxicity (Repeated Exposure):
Aspiration Hazard:
Symptoms/Injuries After Inhalation: Methylene bisphenyldiisocyanate: Rat LC50: 178
mg/m3 [Details of toxic effects not repotted otherthan lethal dose value].
Symptoms/Injuries After Skin Contact: Methylene bisphenyldiisocyanate: Oral - Rat
LD50: 9200 mg/kg [Behavioral - Somnolence (general depressed activity} Behavioral
-Ataxia Nutritional and Gross. Metabolic - Body temperature decrease].
Oral - Mouse LD50: 2200 mg/kg [Details of toxic effects not reported other than
lethal dose value].
Carbon black: Oral - Rat LD50: >15400 mg/kg [Behavioral - Somnolence (general
depressed activity)] Administration onto the skin - Rabbit LD50: >3 gm/kg [Details
of toxic effects not reported other than lethal dose value].
Symptoms/Injuries After Eye Contact: Methylene bisphenyldiisocyanate: Eye: Eye -
Rabbit Standard Draize test.: 100 mg.
Symptoms/Injuries After Ingestion: Methylene bisphenyldiisocyanate: Oral - Rat
LD50: 9200 mg/kg [Behavioral - Somnolence (general depressed activity} Behavioral
-Ataxia Nutritional and Gross .Metabolic - Body temperature decrease].
Oral - Mouse LD50: 2200 mg/kg [Details of toxic effects not reported other than
lethal dose value].
Carbon black: Oral - Rat LD50: >15400 mg/kg [Behavioral - Somnolence (general
depressed activity)].
Chronic Symptoms:
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
No ecotoxicity data was found for the product.
12.2. Persistence and Degradability
12.3. Bioaccumulative Potential
12.4. Mobility in Soil
12.5. Other Adverse Effects
Environmental Fate: No environmental information found for this product.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Consult with the US EPA Guidelines listed In 40
CFR Part 261.3 for the classifications of hazardous waste prior to disposal.
Furthermore, consult with your state and local waste requirements or guidelines,
if applicable, to ensure compliance. Arrange disposal in accordance to the EPA
and/or state and local guidelines.
Additional Information:
SECTION 14: TRANSPORT INFORMATION
14.1 In Accordance with DOT
Proper Shipping Name |Flammable liquid, n.o.s.
Hazard Class | |<PICTOGRAM PHRASE>
Identification Number|Non regulated. |
Label Codes | |
ERG Number |
14.2 In Accordance with IMDG
Proper Shipping Name |
Hazard Class |
Identification Number|
Label Codes | |<PICTOGRAM PHRASE>
ntification Of The | |
Substance/m | |
EmS-No. (Fire) | |
EmS-No. (Spillage) | |
14.3 In Accordance with IATA
Proper Shipping Name |
Identification Number| |<PICTOGRAM PHRASE>
Hazard Class | |
Label Codes | |
ntification Of The | |
Substance/m | |
ERG Code (IATA) |
SECTION 15: REGULATORY INFORMATION
15.1 US Federal Regulations
<COMPONENT>
SARA Section 311/312 Hazard Classes |
Toxic Substances Control Act (TSCA) |Methylene bisphenyldiisocyanate: Listed.
|Carbon black: Listed.
15.2 US State Regulations
California PROP 65:
WARNING: This product contains chemical(s) known to the State of California to
cause cancer and birth defects or other reproductive harm.
Methylene bisphenyldiisocyanate: EPCRA - 40 CFR Part 372 - (SARA Title III)
Section 313 Listed Chemical.
Carbon black: Listed: cancer.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision date |July 01, 2013
Other |This document has been prepared in accordance with the SDS
Information |requirements of the OSHA Hazard Communication Standard 29 CFR
|1910.1200.
GHS Full Text Phrases:
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Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance. |