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Safety Data Sheet Date of Issue: |Revision Date: 07/01/2013 |Revision Number: Imperial Supplies Part Number: 0076640 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Urethane Windshield Sealer CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Saint-Gobain Abrasives, Inc. 1 New Bond Street Worcester, MA 01615 Phone Number: 508-795-5000 1.4. Emergency Telephone Number Emergency | 508-795-5000 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | Signal Word (GHS-US) | Hazard Statements (GHS-US) | Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Polyeurethane pre-polymer |Not Applicable |60 - 100| | |by | | |weight | Methylene bisphenyldiisocyanate |101-68-8 |0.1 - 1 | | |by | | |weight | Carbon black |1333-86-4 |10 - 30 | | |by | | |weight | Hydro treated light petroleum |64742-47-8 |1 - 5 by| distillates | |weight | Toluene |108-88-3 |1 - 5 by| | |weight | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. First-aid Measures After Skin Contact: Immediately wash skin with soap and plenty of water. Get medical attention if irritation develops or persists. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get immediate medical attention. First-aid Measures After Ingestion: If swallowed, do NOT Induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Prolonged or excessive inhalation may cause respiratory tract irritation. Symptoms/Injuries After Skin Contact: May cause irritation. Symptoms/Injuries After Eye Contact: May cause irritation. Symptoms/Injuries After Ingestion: Harmful if swallowed. Ingestion can cause nausea, vomiting, diarrhea and gastrointestinal irritation. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use foam, alcohol foam, carbon dioxide (C02), dry chemical and Water Fog when fighting fires involving this material. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire exposed containers to minimize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water. Protection During Firefighting: As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions: Use proper personal protective equipment as listed in Section 8. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Remove all sources of Ignition. Absorb spill with inert material (e.g., dry sand or earth), then place in a chemical waste container. Provide ventilation. Collect spill with a non-sparking tool. Place into a suitable container for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Hygiene Measures: Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid inhaling vapor or mist. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a cool, dry, well ventilated area away from sources of heat, combustible materials, and incompatible substances. Keep container tightly dosed when not in use. 7.3. Specific End Use(s) Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition products (see Section 10) during welding/flame cutting operations and to protect against dust during sanding/grinding of cured product. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters EXPOSURE GUIDELINES: Methylene bisphenyldiisocyanate: Guideline ACGIH: 0.005 ppm TLV-TWA: 0.005 ppm Guideline OSHA: PEL-Ceiling/Peak: 0.02 ppm Toluene: Guideline ACGIH: TLV-TWA: 20 ppm Guideline OSHA: PEL-TWA: 200 ppm PEL-Ceiling/Peak: 300 ppm PEL-Ceiling/Peak: 500 ppm Peak 8.2. Exposure Controls Appropriate Engineering |Use appropriate engineering control such as process Controls |enclosures, local exhaust ventilation, or other |engineering controls to control airborne levels |below recommended exposure limits. Good general |ventilation should be sufficient to control airborne |levels. Where such systems are not effective wear |suitable personal protective equipment, which |performs satisfactorily and meets OSHA or other |recognized standards. Consult with local procedures |for selection, training, inspection and maintenance |of the personal protective equipment. Personal Protective Equipment|Other Protective: Facilities storing or utilizing |this material should be equipped with an eyewash |facility and a safety shower. Materials for Protective | Clothing | Hand Protection |Use nitrile or butyl rubber gloves |(chemical-resistant). Eye Protection |Wear appropriate protective glasses or splash |goggles as described by 29 CFR 1910.133, OSHA eye |and face protection regulation, or the European |standard EN 166. Skin and Body Protection |Chemical-resistant gloves and chemical goggles, |face-shield and synthetic apron or coveralls should |be used to prevent contact with eyes, skin or |clothing. Respiratory Protection |A NIOSH approved air-purifying respirator with an |organic vapor cartridge or canister may be |permissible under certain circumstances where |airborne concentrations are expected to exceed |exposure limits. Protection provided by air |purifying respirators is limited. Use a positive |pressure air supplied respirator if there is any |potential for an uncontrolled release, exposure |levels are not known, or any other circumstances |where air purifying respirators may not provide |adequate protection. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Paste. Appearance | Odor |Vinegar/Acetic acid Odor Threshold | pH |Not determined. Relative Evaporation Rate (butyl |Slower than butyl acetate. acetate=1) | Melting Point |Not determined. Freezing Point | Boiling Point |Range: 4 to 111 Deg C Flash Point |140�F (60�C) Auto-ignition Temperature |Not determined. Decomposition Temperature | Flammability (solid, gas) | Vapor Pressure |8 mm Hg Relative Vapor Density at 20 �C |4.11 Relative Density | Specific Gravity |1.200 Solubility |Not determined. Partition coefficient: | n-octanol/water | Viscosity | Lower Flammable Limit |0.6% Upper Flammable Limit |7.1% 9.2. Other Information VOC Content: Lbs VOC/Gal (-H2O & Ex Solv): 0.40 Lbs VOC/Gal: 0.40 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability: Stable under normal temperatures and pressures. 10.3 Possibility of Hazardous Reactions 10.4 Conditions to Avoid Heat, flames, Ignition sources, and sparks. Incompatible materials. Freezing or temperatures below 0�C (32�F). Temperatures above 120 �F. 10.5 Incompatible Materials Oxidizing agents. Strong acids and alkalis. 10.6 Hazardous Decomposition Products Carbon monoxide, carbon dioxide, oxides of nitrogen and cyanide. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Methylene bisphenyldiisocyanate: Rat LC50: 178 mg/m3 [Details of toxic effects not repotted otherthan lethal dose value]. Symptoms/Injuries After Skin Contact: Methylene bisphenyldiisocyanate: Oral - Rat LD50: 9200 mg/kg [Behavioral - Somnolence (general depressed activity} Behavioral -Ataxia Nutritional and Gross. Metabolic - Body temperature decrease]. Oral - Mouse LD50: 2200 mg/kg [Details of toxic effects not reported other than lethal dose value]. Carbon black: Oral - Rat LD50: >15400 mg/kg [Behavioral - Somnolence (general depressed activity)] Administration onto the skin - Rabbit LD50: >3 gm/kg [Details of toxic effects not reported other than lethal dose value]. Symptoms/Injuries After Eye Contact: Methylene bisphenyldiisocyanate: Eye: Eye - Rabbit Standard Draize test.: 100 mg. Symptoms/Injuries After Ingestion: Methylene bisphenyldiisocyanate: Oral - Rat LD50: 9200 mg/kg [Behavioral - Somnolence (general depressed activity} Behavioral -Ataxia Nutritional and Gross .Metabolic - Body temperature decrease]. Oral - Mouse LD50: 2200 mg/kg [Details of toxic effects not reported other than lethal dose value]. Carbon black: Oral - Rat LD50: >15400 mg/kg [Behavioral - Somnolence (general depressed activity)]. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity No ecotoxicity data was found for the product. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Environmental Fate: No environmental information found for this product. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Consult with the US EPA Guidelines listed In 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Flammable liquid, n.o.s. Hazard Class | |<PICTOGRAM PHRASE> Identification Number|Non regulated. | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |Methylene bisphenyldiisocyanate: Listed. |Carbon black: Listed. 15.2 US State Regulations California PROP 65: WARNING: This product contains chemical(s) known to the State of California to cause cancer and birth defects or other reproductive harm. Methylene bisphenyldiisocyanate: EPCRA - 40 CFR Part 372 - (SARA Title III) Section 313 Listed Chemical. Carbon black: Listed: cancer. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |July 01, 2013 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.