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SDS Sheet 0076320Printer Friendly View
Safety Data Sheet Date of Issue: 5/7/2015. |Revision Date: 5/7/2015. |Revision Number: 1.05 Imperial Supplies Part Number: 0076320 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: WHITE LIGHTNINGÂ® 3006 Original Formula All Purpose Adhesive Caulk Almond CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company: THE SHERWIN-WILLIAMS CO. Consumer Group - Industrial Cleveland, OH 44115 Phone: (800) 241-5295 1.4. Emergency Telephone Number Emergency | (216) 566-2917, (800) 424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) CARCINOGENICIT|Category 2 Y | SPECIFIC |Category 2 TARGET ORGAN | TOXICITY | (REPEATED | EXPOSURE) | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Health | | | | | |Hazard | | | | | Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |Suspected of causing cancer. |May cause damage to organs through prolonged or |repeated exposure. Precautionary Statements |General (GHS-US) |Read label before use. Keep out of reach of |children. If medical advice is needed, have product |container or label at hand. |Prevention |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Use personal protective equipment as |required. Do not breathe vapor. |Response |Get medical attention if you feel unwell. IF exposed |or concerned: Get medical |Attention. |Storage |Store locked up. |Disposal |Dispose of contents and container in accordance with |all local, regional, national and international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Diethylene Glycol Dibenzoate |120-55-8 |3.0 | Titanium Dioxide |13463-67-7 |1.2 | Ethylene Glycol |107-21-1 |1.2 | | | | | | | There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. First-aid Measures After Skin Contact: Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. First-aid Measures After Ingestion: Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: No known significant effects or critical hazards. Over-exposure signs/symptoms: No specific data. Symptoms/Injuries After Skin Contact: No known significant effects or critical hazards. Over-exposure signs/symptoms: No specific data. Symptoms/Injuries After Eye Contact: No known significant effects or critical hazards. Over-exposure signs/symptoms: No specific data. Symptoms/Injuries After Ingestion: No known significant effects or critical hazards. Over-exposure signs/symptoms: No specific data. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use an extinguishing agent suitable for the surrounding fire. Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: In a fire or if heated, a pressure increase will occur and the container may burst. Explosion Hazard: Decomposition products may include the following materials: carbon dioxide, carbon monoxide, metal oxide/oxides Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Protection During Firefighting: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Emergency Procedures: If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Small spill: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill: Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Hygiene Measures: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits Ingredient name Exposure limits Titanium Dioxide Ethylene Glycol ACGIH TLV (United States, 4/2014). TWA: 10 mg/mÂ³ 8 hours. OSHA PEL (United States, 2/2013). TWA: 15 mg/mÂ³ 8 hours. Form: Total dust ACGIH TLV (United States, 4/2014). C: 100 mg/mÂ³ Form: Aerosol Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 8.2. Exposure Controls Appropriate Engineering |If user operations generate dust, fumes, gas, vapor Controls |or mist, use process enclosures, local exhaust |ventilation or other engineering controls to keep |worker exposure to airborne contaminants below any |recommended or statutory limits. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Chemical-resistant, impervious gloves complying with |an approved standard should be worn at all times |when handling chemical products if a risk assessment |indicates this is necessary. Considering the |parameters specified by the glove manufacturer, |check during use that the gloves are still retaining |their protective properties. It should be noted that |the time to breakthrough for any glove material may |be different for different glove manufacturers. In |the case of mixtures, consisting of several |substances, the protection time of the gloves cannot |be accurately estimated. Eye Protection |Safety eyewear complying with an approved standard |should be used when a risk |assessment indicates this is necessary to avoid |exposure to liquid splashes, mists, |gases or dusts. If contact is possible, the |following protection should be worn, unless the |assessment indicates a higher degree of protection: |safety glasses with sideshields. Skin and Body Protection |Personal protective equipment for the body should be |selected based on the task being performed and the |risks involved and should be approved by a |specialist before handling this product. |Other skin protection : Appropriate footwear and any |additional skin protection measures should be |selected based on the task being performed and the |risks involved and should be approved by a |specialist before handling this product. Respiratory Protection |Use a properly fitted, air-purifying or air-fed |respirator complying with an approved standard if a |risk assessment indicates this is necessary. |Respirator selection must be based on known or |anticipated exposure levels, the hazards of the |product and the safe working limits of the selected |respirator. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Not available. Odor Threshold |Not available. pH |8 Relative Evaporation Rate |0.09 (butyl acetate = 1) (butylacetate=1) | Melting Point |Not available. Freezing Point | Boiling Point |100Â°C (212Â°F) Flash Point |Closed cup: >93.3Â°C (>199.9Â°F) Auto-ignition Temperature |Not available. Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |0.31 kPa (2.333 mm Hg) [at 20Â°C] Relative Vapor Density at 20 Â°C | Relative Density |1.64 Specific Gravity | Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Kinematic (room temperature): >0.205 cm2/s |(>20.5 cSt) |Kinematic (40Â°C (104Â°F)): >0.205 cm2/s (>20.5 |cSt) Lower Flammable Limit |3.2% Upper Flammable Limit |15.3% 9.2. Other Information Aerosol product: Heat of combustion: 0.000002355 kJ/g SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No specific test data related to reactivity available for this product or its ingredients. 10.2 Chemical Stability The product is stable. 10.3 Possibility of Hazardous Reactions Under normal conditions of storage and use, hazardous reactions will not occur. 10.4 Conditions to Avoid No specific data. 10.5 Incompatible Materials No specific data. 10.6 Hazardous Decomposition Products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Route ATE value Oral 24988 mg/kg Skin Corrosion/Irritation: Serious Eye Damage/Irritation: No known significant effects or critical hazards. Respiratory or Skin Sensitization: No known significant effects or critical hazards. Germ Cell Mutagenicity: Not available. Carcinogenicity: Not available. Reproductive Toxicity: Not available. Specific Target Organ Toxicity (Single Exposure): Name Category Route of Exposure Target organs Ethylene Glycol Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Specific Target Organ Toxicity (Repeated Exposure): Name Category Route of Exposure Target organs Ethylene Glycol Category 2 Not determined Not determined Aspiration Hazard: Not available. Symptoms/Injuries After Inhalation: No specific data. Symptoms/Injuries After Skin Contact: No specific data. Symptoms/Injuries After Eye Contact: No specific data. Symptoms/Injuries After Ingestion: No specific data. Chronic Symptoms: General : May cause damage to organs through prolonged or repeated exposure. Carcinogenicity: Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Product/ingredient name Result Species Exposure Titanium Dioxide Ethylene Glycol Acute LC50 >1000000 ?g/l Marine water Acute LC50 6900000 ?g/l Fresh water Acute LC50 41000000 ?g/l Fresh water Acute LC50 8050000 ?g/l Fresh water Fish - Fundulus heteroclitus Crustaceans - Ceriodaphnia dubia - Neonate Daphnia - Daphnia magna - Neonate Fish - Pimephales promelas 96 hours 48 hours 48 hours 48 hours 12.2. Persistence and Degradability Product/ingredient name Aquatic half-life Photolysis Biodegradability Ethylene Glycol - - Readily 12.3. Bioaccumulative Potential Product/ingredient name LogPow BCF Potential Titanium Dioxide - 352 low 12.4. Mobility in Soil Soil/water partition coefficient (KOC): Not available. 12.5. Other Adverse Effects No known significant effects or critical hazards. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number|Not regulated. | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number|Not regulated. Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number|Not regulated. |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> California Prop. 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |5/7/2015. Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.