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SDS Sheet 0076190

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Safety Data Sheet                                                                 
Date of Issue: 07/27/15    |Revision Date:             |Revision Number: 20.00    
Imperial Supplies Part Number: 0076190                                            

SECTION 1: IDENTIFICATION                                                         


1.1.  Product Identifier
Product Form:                                                                     
General Physical Form: Solid                                                      
Specific Physical Form: Viscous putty                                             
Product Name:  3M Strip-Calk (Black). PN 08578                                    
CAS No:                                                                           
Synonyms:                                                                         


1.2.  Intended Use of the Product
Use of the substance/mixture: Automotive, Caulk for use in seams, joints, and     
openings.                                                                         


1.3.  Name, Address, and Telephone of the Responsible Party
Company: 3M                                                                       
Division: Automotive Aftermarket                                                  
3M Center,                                                                        
St. Paul,                                                                         
MN 55144-1000, USA                                                                
Phone: 1-888-3M HELPS (1-888-364-3577)                                            


1.4.  Emergency Telephone Number
Emergency     | 1-800-364-3577 or (651) 737-6501 (24 hours)                       
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Skin          |Category 1A   
Sensitizer    |              
              |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamat|        |        |        |        |        
                             |ion Mark|        |        |        |        |        
Signal Word (GHS-US)         |Warning                                             
Hazard Statements (GHS-US)   |May cause an allergic skin reaction.                
Precautionary Statements     |General:                                            
(GHS-US)                     |Keep out of reach of children.                      
                             |Prevention:                                         
                             |Avoid breathing dust/fume/gas/mist/vapors/spray.    
                             |Wear protective gloves.                             
                             |Contaminated work clothing must not be allowed out  
                             |of the workplace.                                   
                             |Response:                                           
                             |If ON SKIN: Wash with plenty of soap and water.     
                             |If skin irritation or rash occurs: Get medical      
                             |advice/attention.                                   
                             |Wash contaminated clothing before reuse.            
                             |Disposal:                                           
                             |Dispose of contents/container in accordance with    
                             |applicable local/regional/national/international    
                             |regulations.                                        


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:  None.                      


2.4.  Unknown Acute Toxicity (GHS-US)
19% of the mixture consists of ingredients of unknown acute oral toxicity.        
25% of the mixture consists of ingredients of unknown acute dermal toxicity       
96% of the mixture consists of ingredients of unknown acute inhalation toxicity.  

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
Vitreous Calcium Magnesium      |Mixture              |15 - 40 |                  
Aluminum Silicate Glass Fiber   |                     |Trade   |                  
                                |                     |Secret *|                  
Oxide Glass Chemicals           |65997-17-3           |15 - 40 |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Kaolin                          |1332-58-7            |15 - 40 |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Polybutylene                    |9003-29-6            |10- 30  |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Aluminum Silicate               |1327-36-2            |< 6     |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Carbon Black                    |1333-86-4            |1 - 5   |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Aluminum Stearate               |637-12-7             |0.5 -   |                  
                                |                     |1.5     |                  
                                |                     |Trade   |                  
                                |                     |Secrete |                  
                                |                     |*       |                  
Silica                          |7631-86-9            |0.5 -   |                  
                                |                     |1.5     |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Quartz Silica                   |14808-60-7           |0.1 -  1|                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Rheological Additive            |Mixture              |0.1 -  1|                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Talc                            |14807-96-6           |<0.5    |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
4.4'-Thiobis(6-Tert-Butyl-M-Cres|96-69-5              |<0.5    |                  
ol)                             |                     |Trade   |                  
                                |                     |Secret *|                  
Chromium                        |7440-47-3            |0 < 0.1 |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Titanium Dioxide                |13463-67-7           |< 0.5   |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  


*The specific chemical identity and/or exact percentage (concentration) of
this composition has been withheld as a trade secret.

SECTION 4: FIRST AID MEASURES                                                     


4.1.  Description of First Aid Measures
First-aid Measures General:                                                       
First-aid Measures After Inhalation: Remove person to fresh air. If you feel      
unwell, get medical attention.                                                    
First-aid Measures After Skin Contact: Immediately wash with soap and water.      
Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.                                                                
First-aid Measures After Eye Contact: Flush with large amounts of water. Remove   
contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get    
medical attention.                                                                
First-aid Measures After Ingestion: Rinse mouth. If you feel unwell, get medical  
attention.                                                                        


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: See Section 11.1 Information on toxicological effects.         
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Not applicable.                                                                   

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media:  In case of fire: Use a fire fighting agent suitable
for ordinary combustible material such as water or foam to extinguish.            
Unsuitable Extinguishing Media:                                                   


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: None inherent in this product.                                       
Explosion Hazard:  Hazardous Decomposition or By-Products                         
Substance                                 Condition                               
C arbon monoxide        During Combustion                                         
Carbon dioxide              During Combustion                                     
Reactivity:                                                                       


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions:                                                        
Protection During Firefighting: No special protective actions for fire-fighters   
are anticipated.                                                                  
                                                                                  

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:  Evacuate area. Ventilate the area with fresh air. For large    
spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors. in accordance with good industrial hygiene practice. Refer to     
other sections of this SDS for information regarding physical and health hazards, 
respiratory protection, ventilation, and personal protective equipment.           


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.2.  Environmental Precautions
Avoid release to the environment.                                                 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Collect as much of the spilled material as possible. Place in a  
closed container approved tor transportation by appropriate authorities. Clean up 
residue. Seal the container. Dispose of collected material as soon as possible.   
Methods for Cleaning Up:                                                          


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        


SECTION 7: HANDLING AND STORAGE                                                   


7.1.  Precautions for Safe Handling
Additional Hazards When Processed:  Keep out of reach of children. Avoid breathing
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do  
not eat. drink or smoke when using this product. Wash thoroughly after handling.  
Contaminated work clothing should not be allowed out of the workplace. Avoid      
release to the environment. Wash contaminated clothing before reuse.              
Hygiene Measures:                                                                 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:  No special storage requirements.                             
Storage Conditions:                                                               


7.3.  Specific End Use(s)
                                                                                  

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  


8.1.  Control Parameters
Occupational exposure limits                                                      
If a component is disclosed in section 3 but docs not appear in the table below,  
an occupational exposure limit is not available                                   
for the component.                                                                
Ingredient                                                                        
C.A.S. No.                                                                        
Agency                                                                            
Limit type                                                                        
Additional Comments                                                               
                                                                                  
Aluminum, insoluble compounds                                                     
1327-36-2                                                                         
ACGIH                                                                             
TWA(respirable fraction): 1 mg/m3                                                 
A4: Not class. as human carcin                                                    
                                                                                  
Kaolin                                                                            
1332-58-7                                                                         
ACGIH                                                                             
TWA(respirable fraction):2 mg/m3                                                  
A4: Not class. as human carcin                                                    
                                                                                  
KAOLIN. TOTAL DUST                                                                
1332-58-7                                                                         
OS HA                                                                             
TWA(as total dust): 15 mg/m3:TWA (respirable fraction):5 mg/m3                    
                                                                                  
                                                                                  
Carbon Black                                                                      
1335-86-4                                                                         
ACGIH                                                                             
TWA(inhalable fraction ):3 mg/m3                                                  
A3: Confirmed animal carcin                                                       
                                                                                  
Carbon Black                                                                      
1333-86-4                                                                         
CMRG                                                                              
TWA:0.5 mg/m3                                                                     
                                                                                  
                                                                                  
Carbon Black                                                                      
1333-86-4                                                                         
OS HA                                                                             
TWA:3.5 mg m3                                                                     
                                                                                  
                                                                                  
Titanium Dioxide                                                                  
13463-67-7                                                                        
ACGIH                                                                             
TWA: 10 mg/m3                                                                     
A4: Not class, as human carcin                                                    
                                                                                  
Titanium Dioxide                                                                  
13463-67-7                                                                        
CMRG                                                                              
TWA(as respirable dust):5 mg/m3                                                   
                                                                                  
                                                                                  
Titanium Dioxide                                                                  
13463-67-7                                                                        
OS HA                                                                             
TWA(as total dust):                                                               
15 mg/m3                                                                          
                                                                                  
                                                                                  
Talc                                                                              
14807-96-6                                                                        
ACGIH                                                                             
TWA(respirable fraction):2 mg/m3                                                  
A4: Not class, as human carcin                                                    
                                                                                  
Talc                                                                              
14807-96-6                                                                        
CMRG                                                                              
TWA(as respirable dust):0.5 mg/m3                                                 
                                                                                  
                                                                                  
Talc                                                                              
14807-96-6                                                                        
OS HA                                                                             
TWA concentration (as total dust):0,3 mg/m3TWA concentration( respirable):0.1 mg/m
3(2.4 millions of particles/cu.ft)TWA 20 millions of particles/cu. ft.            
                                                                                  
                                                                                  
Quartz Silica                                                                     
14808-60-7                                                                        
ACGIH                                                                             
TWA(respirable fraction):0.025 mg/m3                                              
                                                                                  
                                                                                  
Quartz Silica                                                                     
14808-60-7                                                                        
OSHA                                                                              
TWA concentration (as total dust):0,3 mg/m3TWA concentration( respirable):0.1 mg/m
3(2.4 millions of particles/cu.ft)TWA 20 millions of particles/cu. ft.            
                                                                                  
                                                                                  
Aluminum, insoluble compounds                                                     
63742-7                                                                           
ACGIH                                                                             
TWA( respirable fraction): 1 mg/m3                                                
A4: Not class, as human carein                                                    
                                                                                  
Oxide Glass Chemicals                                                             
65997-17-3                                                                        
Manufacturer determined                                                           
TWA(as dust): 10 mg/m3                                                            
                                                                                  
                                                                                  
Chromium                                                                          
7440-47-3                                                                         
Manufacturer determined                                                           
TWA(as dust): 0.5 mg/m3                                                           
A4: Not class, as human carcin                                                    
                                                                                  
Chromium                                                                          
7440-47-3                                                                         
OSHA                                                                              
TWA(as Cr):l mg/m3                                                                
                                                                                  
                                                                                  
Silica                                                                            
7631-86-9                                                                         
CMRG                                                                              
TWA (as respirablc dust):3 mg/m3                                                  
                                                                                  
                                                                                  
SILICA, AMORPHOUS                                                                 
7631-86-9                                                                         
OSHA                                                                              
TWA concentration:0.8 mg/m3:TWA:20 millions of particles/cu. ft.                  
                                                                                  
                                                                                  
4.4'-Thiobis(6-Tert-Butyl-M-Cresol)                                               
96-69-5                                                                           
ACGIH                                                                             
TWA(inhalable fraction):1 mg/m3                                                   
A4: Not class, as human carcin                                                    
                                                                                  
4.4'-Thiobis(6-Tert-Butyl-M-Cresol)                                               
96-69-5                                                                           
OSHA                                                                              
TWA (as total dust):                                                              
15 mg/m3; TWA( respirable fraction):5 mg/m3                                       
                                                                                  
                                                                                  


8.2.  Exposure Controls
Appropriate Engineering      |Use general dilution ventilation and/or local       
Controls                     |exhaust ventilation to control airborne exposures to
                             |below relevant exposure Limits and/or control       
                             |dust/fume/gas/mist/vapors/spray. If ventilation is  
                             |not adequate, use respiratory protection equipment. 
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |                                                    
Eye Protection               |None required.                                      
Skin and Body Protection     |Select and use gloves and/or protective clothing    
                             |approved to relevant local standards to prevent skin
                             |contact based on the results of an exposure         
                             |assessment. Selection should be based on use factors
                             |such as exposure levels, concentration of the       
                             |substance or mixture, frequency and duration,       
                             |physical challenges such as temperature extremes,   
                             |and other use conditions. Consult with your glove   
                             |and/or protective clothing manufacturer for         
                             |selection of appropriate compatible                 
                             |gloves/protective clothing. Note: Nitrile gloves may
                             |be worn over polymer laminate gloves to improve     
                             |dexterity. Gloves made from the following           
                             |material(s) are recommended: Polymer laminate.      
Respiratory Protection       |Under normal use conditions, airborne exposures are 
                             |not expected to be significant enough to require    
                             |respiratory protection.                             
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Solid                                        
Appearance                          |                                             
Odor                                |Black, soft putty                            
Odor Threshold                      |No Data available                            
pH                                  |Not Applicable                               
Relative Evaporation Rate           |Not Applicable                               
(butylacetate=1)                    |                                             
Melting Point                       |No Data available                            
Freezing Point                      |                                             
Boiling Point                       |Not Applicable                               
Flash Point                         |No flash point                               
Auto-ignition Temperature           |No Data available                            
Decomposition Temperature           |No Data available                            
Flammability (solid, gas)           |Not Classified                               
Vapor Pressure                      |Not Applicable                               
Relative Vapor Density at 20 °C     |Not Applicable                               
Relative Density                    |                                             
Specific Gravity                    |1.920[Ref. Std: WATER = 1]                   
Solubility                          |No Data available                            
Partition coefficient:              |                                             
n-octanol/water                     |                                             
Viscosity                           |                                             
Lower Flammable Limit               |Not Applicable                               
Upper Flammable Limit               |Not Applicable                               


9.2.  Other Information
Volatile Organic Compounds:  0 g/l [Test Method: calculated SCAQMD rule 443.1]    
Volatile Organic Compounds: 0 % weight[Test Method, calculated per (CARB title 2] 
                                                                                  
Percent volatile: 0% weight                                                       
VOC  less H20 & Exempt Solvents: 0 g/l [Test Method: calculated SCAQMD rule 443.1]
                                                                                  
Solid Content: 77.6 % weight                                                      

SECTION 10: STABILITY AND REACTIVITY                                              


10.1      Reactivity
This material is considered to be non reactive under normal use conditions.       


10.2      Chemical Stability
Stable.                                                                           


10.3      Possibility of Hazardous Reactions
Hazardous polymerization will not occur.                                          


10.4      Conditions to Avoid
Sparks and/or flames.                                                             


10.5      Incompatible Materials
Not determined.                                                                   


10.6      Hazardous Decomposition Products
Substance                                                                         
Condition                                                                         
None known.                                                                       
Refer to section 5.2 for hazardous decomposition products during combustion.      

SECTION 11: TOXICOLOGICAL INFORMATION                                             


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                   
Skin Corrosion/Irritation:                                                        
Serious Eye Damage/Irritation:                                                    
Respiratory or Skin Sensitization:                                                
Germ Cell Mutagenicity:                                                           
Carcinogenicity:                                                                  
Reproductive Toxicity:                                                            
Specific Target Organ Toxicity (Single Exposure): For the component/components,   
either no data are currently available or the data are not sufficient for         
classification.                                                                   
Specific Target Organ Toxicity (Repeated Exposure):                               
Aspiration Hazard: For the Component/Components. either no data are currently     
available or the data are not sufficient for classification.                      
Symptoms/Injuries After Inhalation: No known health effects.                      
Symptoms/Injuries After Skin Contact: Dermal Defatting: Signs/symptoms may include
localized redness, itching, drying and cracking of skin. Allergic Skin Reaction   
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and
itching.                                                                          
Symptoms/Injuries After Eye Contact: Contact with the eyes during product use is  
not expected to result in significant irritation.                                 
Symptoms/Injuries After Ingestion: Gastrointestinal Irritation: Signs/symptoms may
include abdominal pain, stomach upset, nausea, vomiting and diarrhea.             
Chronic Symptoms:                                                                 

SECTION 12: ECOLOGICAL INFORMATION                                                


12.1. Toxicity
Please contact the address or phone number listed on the first page of the SDS for
additional ecotoxicologieal information on this material and/or its components.   


12.2. Persistence and Degradability
                                                                                  


12.3. Bioaccumulative Potential
                                                                                  


12.4. Mobility in Soil
                                                                                  


12.5. Other Adverse Effects
Chemical fate information: Please contact the address or phone number listed on   
the first page of the SDS for additional chemical fate information on this        
material and/or its components.                                                   

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations:                                                   
Dispose of contents/ container in accordance with the local/regional/national/inte
rnational regulations.Dispose of waste product in a permitted industrial waste fac
ility. As a disposal alternative, incinerate in a permitted waste incineration fac
ility. Proper destruction may require the use of additional fuel during incinerati
on processes. Empty drums/barrels/containers used for transporting and handling ha
zardous chemicals (chemical substances/mixtures/preparations classified as Hazardo
us as per applicable                                                              
regulations) shall be considered, stored, treated & disposed of as hazardous waste
s.                                                                                
unless otherwise defined by applicable waste regulations Consult with the respecti
ve regulating authorities to determine the                                        
available treatment and disposal facilities.                                      
Additional Information:                                                           

SECTION 14: TRANSPORT INFORMATION                                                 


14.1 In Accordance with DOT
Proper Shipping Name |                                                            
Hazard Class         |                       |<PICTOGRAM PHRASE>                  
Identification Number|                       |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            


14.2 In Accordance with IMDG
Proper Shipping Name |                                                            
Hazard Class         |                                                            
Identification Number|                                                            
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     


14.3 In Accordance with IATA
Proper Shipping Name |                                                            
Identification Number|                       |<PICTOGRAM PHRASE>                   
Hazard Class         |                       |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
Contact 3M for more information.                                                  
SARA Section 311/312 Hazard Classes |Fire Hazard - Yes   Pressure Hazard - No     
                                    |Reactivity Hazard - No   Immediate Hazard -  
                                    |Yes    Delayed Hazard - No                   
Toxic Substances Control Act (TSCA) |The components of this product are in        
                                    |compliance with the chemical notification    
                                    |requirements of TSCA.                        
                                    |Contact 3M for more information.             

15.2      US State Regulations
Contact 3M for more information.                                                  
California Proposition 65                                                         
Ingredient                                         C.A.S. No.                     
Classification                                                                    
SILICA. CRYSTALLINE (AIRBORNE             None                                    
Carcinogen                                                                        
PARTICLES OF RESPIRABLE SIZE)                                                     
Carbon Black                                        1333-86-4                     
Carcinogen                                                                        
WARNING: This product contains a chemical known to the State of California to     
cause cancer.                                                                     
                                                                                  

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION     

Revision date   |                                                                 
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
                |1910.1200.                                                       
GHS Full Text Phrases:                                                            
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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