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SDS Sheet 0076190Printer Friendly View
Safety Data Sheet Date of Issue: 07/27/15 |Revision Date: |Revision Number: 20.00 Imperial Supplies Part Number: 0076190 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: General Physical Form: Solid Specific Physical Form: Viscous putty Product Name: 3M Strip-Calk (Black). PN 08578 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Automotive, Caulk for use in seams, joints, and openings. 1.3. Name, Address, and Telephone of the Responsible Party Company: 3M Division: Automotive Aftermarket 3M Center, St. Paul, MN 55144-1000, USA Phone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency Telephone Number Emergency | 1-800-364-3577 or (651) 737-6501 (24 hours) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 1A Sensitizer | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamat| | | | | |ion Mark| | | | | Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |May cause an allergic skin reaction. Precautionary Statements |General: (GHS-US) |Keep out of reach of children. |Prevention: |Avoid breathing dust/fume/gas/mist/vapors/spray. |Wear protective gloves. |Contaminated work clothing must not be allowed out |of the workplace. |Response: |If ON SKIN: Wash with plenty of soap and water. |If skin irritation or rash occurs: Get medical |advice/attention. |Wash contaminated clothing before reuse. |Disposal: |Dispose of contents/container in accordance with |applicable local/regional/national/international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None. 2.4. Unknown Acute Toxicity (GHS-US) 19% of the mixture consists of ingredients of unknown acute oral toxicity. 25% of the mixture consists of ingredients of unknown acute dermal toxicity 96% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Vitreous Calcium Magnesium |Mixture |15 - 40 | Aluminum Silicate Glass Fiber | |Trade | | |Secret *| Oxide Glass Chemicals |65997-17-3 |15 - 40 | | |Trade | | |Secret *| Kaolin |1332-58-7 |15 - 40 | | |Trade | | |Secret *| Polybutylene |9003-29-6 |10- 30 | | |Trade | | |Secret *| Aluminum Silicate |1327-36-2 |< 6 | | |Trade | | |Secret *| Carbon Black |1333-86-4 |1 - 5 | | |Trade | | |Secret *| Aluminum Stearate |637-12-7 |0.5 - | | |1.5 | | |Trade | | |Secrete | | |* | Silica |7631-86-9 |0.5 - | | |1.5 | | |Trade | | |Secret *| Quartz Silica |14808-60-7 |0.1 - 1| | |Trade | | |Secret *| Rheological Additive |Mixture |0.1 - 1| | |Trade | | |Secret *| Talc |14807-96-6 |<0.5 | | |Trade | | |Secret *| 4.4'-Thiobis(6-Tert-Butyl-M-Cres|96-69-5 |<0.5 | ol) | |Trade | | |Secret *| Chromium |7440-47-3 |0 < 0.1 | | |Trade | | |Secret *| Titanium Dioxide |13463-67-7 |< 0.5 | | |Trade | | |Secret *| *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. First-aid Measures After Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. First-aid Measures After Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. First-aid Measures After Ingestion: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See Section 11.1 Information on toxicological effects. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Not applicable. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: None inherent in this product. Explosion Hazard: Hazardous Decomposition or By-Products Substance Condition C arbon monoxide During Combustion Carbon dioxide During Combustion Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: No special protective actions for fire-fighters are anticipated. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors. in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Collect as much of the spilled material as possible. Place in a closed container approved tor transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat. drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: No special storage requirements. Storage Conditions: 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits If a component is disclosed in section 3 but docs not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Aluminum, insoluble compounds 1327-36-2 ACGIH TWA(respirable fraction): 1 mg/m3 A4: Not class. as human carcin Kaolin 1332-58-7 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin KAOLIN. TOTAL DUST 1332-58-7 OS HA TWA(as total dust): 15 mg/m3:TWA (respirable fraction):5 mg/m3 Carbon Black 1335-86-4 ACGIH TWA(inhalable fraction ):3 mg/m3 A3: Confirmed animal carcin Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3 Carbon Black 1333-86-4 OS HA TWA:3.5 mg m3 Titanium Dioxide 13463-67-7 ACGIH TWA: 10 mg/m3 A4: Not class, as human carcin Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5 mg/m3 Titanium Dioxide 13463-67-7 OS HA TWA(as total dust): 15 mg/m3 Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class, as human carcin Talc 14807-96-6 CMRG TWA(as respirable dust):0.5 mg/m3 Talc 14807-96-6 OS HA TWA concentration (as total dust):0,3 mg/m3TWA concentration( respirable):0.1 mg/m 3(2.4 millions of particles/cu.ft)TWA 20 millions of particles/cu. ft. Quartz Silica 14808-60-7 ACGIH TWA(respirable fraction):0.025 mg/m3 Quartz Silica 14808-60-7 OSHA TWA concentration (as total dust):0,3 mg/m3TWA concentration( respirable):0.1 mg/m 3(2.4 millions of particles/cu.ft)TWA 20 millions of particles/cu. ft. Aluminum, insoluble compounds 63742-7 ACGIH TWA( respirable fraction): 1 mg/m3 A4: Not class, as human carein Oxide Glass Chemicals 65997-17-3 Manufacturer determined TWA(as dust): 10 mg/m3 Chromium 7440-47-3 Manufacturer determined TWA(as dust): 0.5 mg/m3 A4: Not class, as human carcin Chromium 7440-47-3 OSHA TWA(as Cr):l mg/m3 Silica 7631-86-9 CMRG TWA (as respirablc dust):3 mg/m3 SILICA, AMORPHOUS 7631-86-9 OSHA TWA concentration:0.8 mg/m3:TWA:20 millions of particles/cu. ft. 4.4'-Thiobis(6-Tert-Butyl-M-Cresol) 96-69-5 ACGIH TWA(inhalable fraction):1 mg/m3 A4: Not class, as human carcin 4.4'-Thiobis(6-Tert-Butyl-M-Cresol) 96-69-5 OSHA TWA (as total dust): 15 mg/m3; TWA( respirable fraction):5 mg/m3 8.2. Exposure Controls Appropriate Engineering |Use general dilution ventilation and/or local Controls |exhaust ventilation to control airborne exposures to |below relevant exposure Limits and/or control |dust/fume/gas/mist/vapors/spray. If ventilation is |not adequate, use respiratory protection equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |None required. Skin and Body Protection |Select and use gloves and/or protective clothing |approved to relevant local standards to prevent skin |contact based on the results of an exposure |assessment. Selection should be based on use factors |such as exposure levels, concentration of the |substance or mixture, frequency and duration, |physical challenges such as temperature extremes, |and other use conditions. Consult with your glove |and/or protective clothing manufacturer for |selection of appropriate compatible |gloves/protective clothing. Note: Nitrile gloves may |be worn over polymer laminate gloves to improve |dexterity. Gloves made from the following |material(s) are recommended: Polymer laminate. Respiratory Protection |Under normal use conditions, airborne exposures are |not expected to be significant enough to require |respiratory protection. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Solid Appearance | Odor |Black, soft putty Odor Threshold |No Data available pH |Not Applicable Relative Evaporation Rate |Not Applicable (butylacetate=1) | Melting Point |No Data available Freezing Point | Boiling Point |Not Applicable Flash Point |No flash point Auto-ignition Temperature |No Data available Decomposition Temperature |No Data available Flammability (solid, gas) |Not Classified Vapor Pressure |Not Applicable Relative Vapor Density at 20 Â°C |Not Applicable Relative Density | Specific Gravity |1.920[Ref. Std: WATER = 1] Solubility |No Data available Partition coefficient: | n-octanol/water | Viscosity | Lower Flammable Limit |Not Applicable Upper Flammable Limit |Not Applicable 9.2. Other Information Volatile Organic Compounds: 0 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds: 0 % weight[Test Method, calculated per (CARB title 2] Percent volatile: 0% weight VOC less H20 & Exempt Solvents: 0 g/l [Test Method: calculated SCAQMD rule 443.1] Solid Content: 77.6 % weight SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity This material is considered to be non reactive under normal use conditions. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Sparks and/or flames. 10.5 Incompatible Materials Not determined. 10.6 Hazardous Decomposition Products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): For the component/components, either no data are currently available or the data are not sufficient for classification. Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: For the Component/Components. either no data are currently available or the data are not sufficient for classification. Symptoms/Injuries After Inhalation: No known health effects. Symptoms/Injuries After Skin Contact: Dermal Defatting: Signs/symptoms may include localized redness, itching, drying and cracking of skin. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Symptoms/Injuries After Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Symptoms/Injuries After Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicologieal information on this material and/or its components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Chemical fate information: Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/ container in accordance with the local/regional/national/inte rnational regulations.Dispose of waste product in a permitted industrial waste fac ility. As a disposal alternative, incinerate in a permitted waste incineration fac ility. Proper destruction may require the use of additional fuel during incinerati on processes. Empty drums/barrels/containers used for transporting and handling ha zardous chemicals (chemical substances/mixtures/preparations classified as Hazardo us as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous waste s. unless otherwise defined by applicable waste regulations Consult with the respecti ve regulating authorities to determine the available treatment and disposal facilities. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations Contact 3M for more information. SARA Section 311/312 Hazard Classes |Fire Hazard - Yes Pressure Hazard - No |Reactivity Hazard - No Immediate Hazard - |Yes Delayed Hazard - No Toxic Substances Control Act (TSCA) |The components of this product are in |compliance with the chemical notification |requirements of TSCA. |Contact 3M for more information. 15.2 US State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification SILICA. CRYSTALLINE (AIRBORNE None Carcinogen PARTICLES OF RESPIRABLE SIZE) Carbon Black 1333-86-4 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.