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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Marvel Air Tool Oil CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Engine Oil Additive - Fuel additive (EPA Registered) 1.3. Name, Address, and Telephone of the Responsible Party Company Marvel Oil Company, Inc. 625 Willowbrook Centre Parkway Willowbrook, Illinois 60527 Phone: 1(630)455-3700 1.4. Emergency Telephone Number Emergency |Phone Number: 1(630)455-3700 number |Fax Number: 1(630)455-3868 |Transportation: 1(800)424-9300 (CHEMTREC) |Medical Assistance: Call your local Poison Control Center SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |3 liquid | Skin |2 irritation | Reproductive |2 Toxicity | Aspiration |1 toxicity | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Exclamation Mark |Health Hazard Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Flammable liquid and vapor. Causes skin irritation. |Suspected of damaging fertility of the un-born |child. May be fatal if swallowed and enters airways. Precautionary Statements |Keep away from heat, sparks, open flames or hot (GHS-US) |surfaces. Do not smoke. Keep containers tightly |closed. Ground all containers and receiving |equipment. Use explosion proof electrical, |ventilation, and lighting equipment. Use only |non-sparking tools. Take precautionary measures |against static discharge. Wear protective gloves, |clothing, eye glasses and face shield. Do not handle |until all safety precautions have been read and |understood. Wash hands thoroughly after handling. If |exposed, get medical attention. If on skin or hair, |remove immediately all contaminated clothing and |launder before re-use. Wash skin with soap and |water. If skin irritation occurs, get medical |attention. If swallowed, immediately call a poison |control center or doctor. Do NOT induce vomiting. |Store in a well ventilated place. Dispose of |contents and container in accordance with all local, |state, national and international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Petroleum Distillates |64742-52-5 |60-100% | (Hydrotreated Heavy Naphthenic) | | | Petroleum Distillates (Stoddard |8052-41-3 |10-30% | Solvent) | | | Tricresyl Phosphate |1330-78-5 |0.1-1.0%| Ortho Dichlorobenzene |95-50-1 |0.1-1.0%| Para Dichlorobenzene |106-46-7 |<0.1% | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove to fresh air and promote deep breathing. Get medical attention if effects persist or you feel un-well. First-aid Measures After Skin Contact: In case of skin contact, wash thoroughly with soap and water. Remove contaminated clothing and footwear. Launder clothing before re-use. Call a physician if irritation develops or persists. First-aid Measures After Eye Contact: In case of eye contact, immediately flush eyes with plenty of water. Remove contact lenses if worn. If irritation persists, get medical attention First-aid Measures After Ingestion: If swallowed, do not induce vomiting. Never give anything by mouth to an unconscious person. Immediately call a poison control center or physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: May cause respiratory tract irritation. Vapors may cause drowsiness or dizziness. Symptoms/Injuries After Skin Contact: Cause skin irritation. Symptoms may include redness, edema, drying, defatting, and cracking of skin. Symptoms/Injuries After Eye Contact: May cause temporary eye irritation. Symptoms may include discomfort or pain, excess blinking and tearing, with redness and swelling. Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea, and vomiting. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Symptoms may not appear immediately. Seek medical attention if effects develop or persist and you feel un-well. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Carbon dioxide, dry chemical, and alcohol foam Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: CO2, CO, and hydrocarbons Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Keep up wind of fire. Wear full firefighting turn out gear (full bunker gear) and respiratory protection (SCBA). Cool closed containers exposed to fire with water. See Section 8 for personal protection. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate all source of ignition. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Contain and absorb spill with inert material. Place in suitable container for disposal. Do not flush to sewer or allow to enter waterways. See section 8 for PPE. Methods for Cleaning Up: Take up material and place in a suitable container. Vapors may be heavier than air and may travel along the ground to a distant source of ignition. Provide adequate ventilation. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Keep away from source of ignition. Do not smoke. Take precaution to eliminate static discharge. Avoid contact with skin and eyes. Avoid breathing vapor or mist. Do not swallow. Do not eat or drink while handling. Wash hands with soap and water after handling. Use only non-sparking tools. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep out of reach of children. Store in a well ventilated place. Do not store above 49�C (120�F). 7.3. Specific End Use(s) Shelf Life: Shelf life is considered to be 7 - 10 years when properly stored. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Limits 8 hr TWA: (OSHA PEL) (ACGIH TWA) Petroleum Distillates (Hydrotreated Heavy not applicable not applicable Naphthenic) Petroleum Distillates (Stoddard Solvent) 500 ppm 100 ppm Tricresyl Phosphate not applicable not applicable Ortho Dichlorobenzene 50 ppm 25 ppm Para Dichlorobenzene 75 ppm 10 ppm 8.2. Exposure Controls Appropriate Engineering |Use adequate ventilation to keep exposure below Controls |recommended limits. Ensure that eye wash station and |safety shower are close to work station. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear chemical resistant gloves to prevent skin |contact. Eye Protection |Wear safety glasses or splash goggles to prevent eye |contact. Skin and Body Protection |Wear suitable protective clothing. Respiratory Protection |Provide good ventilation. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |thin liquid Appearance | Odor |typical oily Odor Threshold |not available pH |not applicable - oil based product Relative Evaporation Rate |not available (butylacetate=1) | Melting Point |-51?C (-60?F) Freezing Point |-51?C (-60?F) Boiling Point |not available Flash Point |53?C (128?F) Auto-ignition Temperature |not available Decomposition Temperature | Flammability (solid, gas) |not applicable Vapor Pressure |not available Relative Vapor Density at 20 �C |not available Relative Density | Specific Gravity |0.876 Solubility |Insoluble (Water) Partition coefficient: |not available n-octanol/water | Viscosity |2.0 - 3.0 cSt Lower Flammable Limit |not available Upper Flammable Limit |not available 9.2. Other Information % NVM by Weight: 75.0% % VOC Content (California): 24.92% SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Does not react under normal conditions 10.2 Chemical Stability Stable 10.3 Possibility of Hazardous Reactions Does not react under normal conditions 10.4 Conditions to Avoid Heat and incompatible materials 10.5 Incompatible Materials Strong oxidizers such as bleach and peroxides 10.6 Hazardous Decomposition Products CO2, CO and hydrocarbons SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Causes skin irritation Serious Eye Damage/Irritation: Based on available data, classification data are not met Respiratory or Skin Sensitization: Based on available data, classification data are not met Germ Cell Mutagenicity: Based on available data, classification data are not met Carcinogenicity: Based on available data, classification data are not met o-Dichlorobenzene (95-50-1) IARC Group 3 - Not Classified p-dichlorobenzene (106-46-7) IARC Group 2B - Possible carcinogen to humans. NTP 1-Evidence of Carcinogenicity 3, Reasonably anticipated to be a human Carcinogen Reproductive Toxicity: Suspected of damaging fertility of un-born child Specific Target Organ Toxicity (Single Exposure): Based on available data, classification data are not met Specific Target Organ Toxicity (Repeated Exposure): Based on available data, classification data are not met Aspiration Hazard: May be fatal if swallowed and enters air ways. Symptoms/Injuries After Inhalation: May cause respiratory tract irritation. Vapors may cause drowsiness and dizziness. Symptoms/Injuries After Skin Contact: Cause skin irritation. Symptoms may include redness, edema, drying, defatting, and cracking of skin. Symptoms/Injuries After Eye Contact: May cause temporary eye irritation. Symptoms may include discomfort or pain, excess blinking and tearing, with redness and swelling. Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea, and vomiting. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Not recommended for release into aquatic systems without treatment 12.2. Persistence and Degradability Not established 12.3. Bioaccumulative Potential Not established 12.4. Mobility in Soil Not established 12.5. Other Adverse Effects None known SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste Disposal Method: Dispose of in accordance with local, state and federal regulations Waste Disposal Vessel: Metal drums are recommended. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |All ingredients are commercially available |and listed by the manufacturer under TSCA. 15.2 US State Regulations <COMPONENT> The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the SDS may also be applicable for state requirements. For details on your regulatory requirements, contact the appropriate agency in your state. California Prop 65: CAS Number Concentration State Code p-Dichlorobenzene (106-46-7) <0.1% Cancer SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |March 10, 2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.