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SDS Sheet 0075990

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: Sikaflex®-227                                                     
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: For further information, refer to the product     
 
technical data sheet.                                                           
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Sika Corporation                                                                
 
201 Polito Avenue                                                               
 
Lyndhurst, NJ 07071                                                             
 
USA                                                                             
 
Phone: (201) 933-8800                                                           
 


1.4.  Emergency Telephone Number
Emergency     |800-424-9300, 703-527-3887                                       
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Respiratory   |Category 1    
sensitization |              
Skin          |Category 1    
sensitization |              
Carcinogenicit|Category 1A   
y             |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Health Hazard
        
Signal Word (GHS-US)         |Danger                                            
 
Hazard Statements (GHS-US)   |H317 May cause an allergic skin reaction.         
 
                             |H334 May cause allergy or asthma symptoms or      
 
                             |breathing difficulties if inhaled.                
 
                             |H350 May cause cancer.                            
 
Precautionary Statements     |Prevention:                                       
 
(GHS-US)                     |P201 Obtain special instructions before use.      
 
                             |P202 Do not handle until all safety precautions
have
                             |been read and understood.                         
 
                             |P261 Avoid breathing dust/ fume/ gas/ mist/
vapors/ 
                             |spray.                                            
 
                             |P272 Contaminated work clothing should not be     
 
                             |allowed out of the workplace.                     
 
                             |P280 Wear protective gloves.                      
 
                             |P281 Use personal protective equipment as
required. 
                             |P285 In case of inadequate ventilation wear       
 
                             |respiratory Protection.                           
 
                             |Response:                                         
 
                             |P302 + P352 IF ON SKIN: Wash with plenty of soap
and
                             |water.                                            
 
                             |P304 + P341 IF INHALED: If breathing is difficult,
 
                             |remove victim to fresh air and keep at rest in a  
 
                             |position comfortable for breathing.               
 
                             |P308 + P313 IF exposed or concerned: Get medical  
 
                             |advice/ attention.                                
 
                             |P333 + P313 If skin irritation or rash occurs: Get
 
                             |medical advice/ attention.                        
 
                             |P363 Wash contaminated clothing before reuse.     
 
                             |Storage:                                          
 
                             |P405 Store locked up.                             
 
                             |Disposal:                                         
 
                             |P501 Dispose of contents/ container to an approved
 
                             |waste disposal plant.                             
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                           
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
titanium dioxide                |13463-67-7           |>= 2 - <|                
 
                                |                     |5 %     |                
 
xylene                          |1330-20-7            |>= 2 - <|                
 
                                |                     |5 %     |                
 
ethylbenzene                    |100-41-4             |>= 0 - <|                
 
                                |                     |1 %     |                
 
4,4'-methylenediphenyl          |101-68-8             |>= 0 - <|                
 
diisocyanate                    |                     |1 %     |                
 
Carbon black                    |1333-86-4            |>= 0 - <|                
 
                                |                     |1 %     |                
 
Quartz (SiO2)                   |14808-60-7           |>= 0 - <|                
 
                                |                     |1 %     |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Move to fresh air. Consult a physician
after 
significant exposure.                                                           
 
First-aid Measures After Skin Contact: Take off contaminated clothing and shoes 
 
immediately. Wash off with soap and plenty of water. If symptoms persist, call a
 
physician.                                                                      
 
First-aid Measures After Eye Contact: Remove contact lenses. Keep eye wide open 
 
while rinsing. If eye irritation persists, consult a specialist.                
 
First-aid Measures After Ingestion: If swallowed: Clean mouth with water and
drink
afterwards plenty of water. Induce vomiting immediately and call a physician. Do
 
not give milk or alcoholic beverages. Never give anything by mouth to an        
 
unconscious person.                                                             
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: Sensitizing effects carcinogenic effects. Asthmatic
appearance.
Allergic reactions. See Section 11 for more detailed information on health
effects
and symptoms.                                                                   
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Protection of first-aiders: Move out of dangerous area. Consult a physician.
Show 
this material safety data sheet to the doctor in Attendance.                    
 
Notes to physician: Treat symptomatically.                                      
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use extinguishing measures that are appropriate to
 
local circumstances and the surrounding environment.                            
 
Unsuitable Extinguishing Media:                                                 
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:                                                                    
 
Explosion Hazard:                                                               
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions: Collect contaminated fire extinguishing water        
 
separately. This must not be discharged into drains. Fire residues and          
 
contaminated fire extinguishing water must be disposed of in accordance with
local
regulations.                                                                    
 
Protection During Firefighting: In the event of fire, wear self-contained       
 
breathing apparatus.                                                            
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Use personal protective equipment. Deny access to unprotected 
 
persons.                                                                        
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Do not flush into surface water or sanitary sewer system. If the product        
 
contaminates rivers and lakes or drains inform respective authorities. Local    
 
authorities should be advised if significant spillages cannot be contained.     
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up: Soak up with inert absorbent material (e.g. sand,
silica 
gel, acid binder, universal binder, sawdust). Keep in suitable, closed
containers 
for disposal.                                                                   
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Do not breathe vapors or spray mist. Avoid   
 
exceeding the given occupational exposure limits (see section 8). Do not get in 
 
eyes, on skin, or on clothing. For personal protection see section 8. Persons
with
a history of skin sensitization problems or asthma, allergies, chronic or       
 
recurrent respiratory disease should not be employed in any process in which
this 
mixture is being used. Smoking, eating and drinking should be prohibited in the 
 
application area. Follow standard hygiene measures when handling chemical       
 
products.                                                                       
 
Hygiene Measures: Avoid contact with skin, eyes and clothing. Wash hands before 
 
breaks and immediately after handling the                                       
 
Product. Remove contaminated clothing and protective equipment before entering  
 
eating areas. Wash thoroughly after handling.                                   
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Prevent unauthorized access. Store in original container.
Keep
container tightly closed in a dry and well-ventilated place. Observe label      
 
precautions. Store in accordance with local regulations.                        
 
Materials to avoid : no data available.                                         
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Component                                                                       
 
CAS-No.                                                                         
 
Basis **                                                                        
 
Value                                                                           
 
Exposure limit(s)* /                                                            
 
Form of exposure                                                                
 
                                                                                
 
titanium dioxide                                                                
 
13463-67-7                                                                      
 
ACGIH                                                                           
 
TWA                                                                             
 
10 mg/m3                                                                        
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA P0                                                                         
 
TWA                                                                             
 
10 mg/m3                                                                        
 
Total                                                                           
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA Z-1                                                                        
 
TWA                                                                             
 
15 mg/m3                                                                        
 
total dust                                                                      
 
                                                                                
 
xylene                                                                          
 
1330-20-7                                                                       
 
OSHA Z-1                                                                        
 
TWA                                                                             
 
100 ppm                                                                         
 
435 mg/m3                                                                       
 
                                                                                
 
                                                                                
 
                                                                                
 
ACGIH                                                                           
 
TWA                                                                             
 
100 ppm                                                                         
 
                                                                                
 
                                                                                
 
                                                                                
 
ACGIH                                                                           
 
STEL                                                                            
 
150 ppm                                                                         
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA P0                                                                         
 
STEL                                                                            
 
150 ppm                                                                         
 
655 mg/m3                                                                       
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA P0                                                                         
 
TWA                                                                             
 
100 ppm                                                                         
 
435 mg/m3                                                                       
 
                                                                                
 
ethylbenzene                                                                    
 
100-41-4                                                                        
 
ACGIH                                                                           
 
TWA                                                                             
 
100 ppm                                                                         
 
                                                                                
 
                                                                                
 
                                                                                
 
ACGIH                                                                           
 
STEL                                                                            
 
125 ppm                                                                         
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA Z-1                                                                        
 
TWA                                                                             
 
100 ppm                                                                         
 
435 mg/m3                                                                       
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA P0                                                                         
 
TWA                                                                             
 
100 ppm                                                                         
 
435 mg/m3                                                                       
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA P0                                                                         
 
STEL                                                                            
 
125 ppm                                                                         
 
545 mg/m3                                                                       
 
                                                                                
 
Carbon black                                                                    
 
1333-86-4                                                                       
 
ACGIH                                                                           
 
TWA                                                                             
 
3.5 mg/m3                                                                       
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA Z-1                                                                        
 
TWA                                                                             
 
3.5 mg/m3                                                                       
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA P0                                                                         
 
TWA                                                                             
 
3.5 mg/m3                                                                       
 
                                                                                
 
Quartz (SiO2)                                                                   
 
14808-60-7                                                                      
 
ACGIH                                                                           
 
TWA                                                                             
 
0.025 mg/m3                                                                     
 
Respirable fraction                                                             
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA Z-3                                                                        
 
TWA                                                                             
 
30 mg/m3 / %SiO2+2                                                              
 
total dust                                                                      
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA Z-3                                                                        
 
TWA                                                                             
 
10 mg/m3 / %SiO2+2                                                              
 
respirable                                                                      
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA Z-3                                                                        
 
TWA                                                                             
 
250 mppcf / %SiO2+5                                                             
 
respirable                                                                      
 
                                                                                
 
                                                                                
 
                                                                                
 
OSHA P0                                                                         
 
TWA                                                                             
 
0.1 mg/m3 Respirable fraction                                                   
 
                                                                                
 
*The above mentioned values are in accordance with the legislation in effect at 
 
the date of the release of this safety data sheet.                              
 
**Basis                                                                         
 
ACGIH. Threshold Limit Values (TLV)                                             
 
OSHA P0. Table Z-1, Limit for Air Contaminat (1989 Vacated Values)              
 
OSHA P1. Permissible Exposure Limits (PEL), Table Z-1, Limit for Air Contaminant
 
OSHA P2. Permissible Exposure Limits (PEL), Table Z-2                           
 
OSHA Z3. Table Z-3, Mineral Dust                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Use of adequate ventilation should be sufficient
to 
Controls                     |control worker exposure to airborne contaminants.
If
                             |the use of this product generates dust, fumes,
gas, 
                             |vapor or mist, use process enclosures, local
exhaust
                             |ventilation or other                              
 
                             |engineering controls to keep worker exposure below
 
                             |any recommended or statutory limits.              
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Remarks: Chemical-resistant, impervious gloves    
 
                             |complying with an approved standard should be worn
 
                             |at all times when handling chemical products if a 
 
                             |risk assessment indicates this is necessary.      
 
Eye Protection               |Safety eyewear complying with an approved standard
 
                             |should be used when a risk assessment indicates
this
                             |is necessary.                                     
 
Skin and Body Protection     |Choose body protection in relation to its type, to
 
                             |the concentration and amount of dangerous         
 
                             |substances, and to the specific work-place.       
 
Respiratory Protection       |Use a properly fitted NIOSH approved air-purifying
 
                             |or air-fed respirator complying with an approved  
 
                             |standard if a risk assessment indicates this is   
 
                             |necessary. The filter class for the respirator
must 
                             |be suitable for the maximum expected contaminant  
 
                             |concentration (gas/vapor/aerosol/particulates)
that 
                             |may arise when handling the product. If this      
 
                             |concentration is exceeded, self-contained
breathing 
                             |apparatus must be used.                           
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |                                           
 
Appearance                          |paste                                      
 
Odor                                |hydrocarbon-like                           
 
Odor Threshold                      |no data available                          
 
pH                                  |Note: not applicable                       
 
Relative Evaporation Rate           |no data available                          
 
(butylacetate=1)                    |                                           
 
Melting Point                       |no data available                          
 
Freezing Point                      |no data available                          
 
Boiling Point                       |no data available                          
 
Flash Point                         |Note: not applicable                       
 
Auto-ignition Temperature           |not applicable                             
 
Decomposition Temperature           |no data available                          
 
Flammability (solid, gas)           |no data available                          
 
Vapor Pressure                      |no data available                          
 
Relative Vapor Density at 20 °C     |no data available                          
 
Relative Density                    |                                           
 
Specific Gravity                    |                                           
 
Solubility                          |Note: insoluble                            
 
Partition coefficient:              |no data available                          
 
n-octanol/water                     |                                           
 
Viscosity                           |Viscosity, kinematic : > 20.5 mm2/s at 104
°F
                                    |(40 °C)                                    
 
Lower Flammable Limit               |no data available                          
 
Upper Flammable Limit               |no data available                          
 


9.2.  Other Information
Volatile organic compounds (VOC) content: 52 g/l                                
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No dangerous reaction known under conditions of normal use.                     
 


10.2      Chemical Stability
The product is chemically stable.                                               
 


10.3      Possibility of Hazardous Reactions
Stable under recommended storage conditions.                                    
 


10.4      Conditions to Avoid
no data available.                                                              
 


10.5      Incompatible Materials
no data available.                                                              
 


10.6      Hazardous Decomposition Products
                                                                                
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Acute oral toxicity: no data available.                                         
 
Acute inhalation toxicity: no data available.                                   
 
Acute dermal toxicity: no data available.                                       
 
Skin Corrosion/Irritation: no data available.                                   
 
Serious Eye Damage/Irritation: no data available.                               
 
Respiratory or Skin Sensitization: May cause an allergic skin reaction. May
cause 
allergy or asthma symptoms or breathing difficulties if inhaled.                
 
Germ Cell Mutagenicity: no data available.                                      
 
Carcinogenicity: May cause cancer.                                              
 
Reproductive Toxicity: no data available.                                       
 
Specific Target Organ Toxicity (Single Exposure): Assessment: no data available.
 
Specific Target Organ Toxicity (Repeated Exposure): Reports have associated     
 
repeated and prolonged exposure to some of the chemicals in this product with   
 
permanent brain,liver, kidney and nervous system damage. Intentional misuse by  
 
deliberate concentration and inhalation of vapors may be harmful or fatal. Once 
 
sensitized, a severe allergic reaction may occur when subsequently exposed to
very
low levels.                                                                     
 
Assessment: no data available.                                                  
 
Aspiration Hazard: no data available.                                           
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
                                                                                
 


12.2. Persistence and Degradability
                                                                                
 


12.3. Bioaccumulative Potential
                                                                                
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
Other information: Do not empty into drains; dispose of this material and its   
 
container in a safe way. Avoid dispersal of spilled material and runoff and     
 
contact with soil, waterways, drains and sewers.                                
 
Component:                                                                      
 
Carbon black           1333-86-4           Toxicity to fish:                    
 
LC50                                                                            
 
Species: Brachydanio rerio (zebrafish)                                          
 
Dose: > 1,000 mg/l                                                              
 
Exposure time: 96 h                                                             
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Disposal of this product, solutions and any     
 
by-products should at all times comply with the requirements of environmental   
 
protection and waste disposal legislation and any regional local authority      
 
requirements.                                                                   
 
Additional Information:                                                         
 
Contaminated packaging: Empty containers should be taken to an approved waste   
 
handling site for recycling or disposal.                                        
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |Not dangerous goods                                       
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |Not dangerous goods                                       
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Not dangerous goods                                       
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
EPCRA - Emergency Planning and Community Right-to-Know:                         
 
CERCLA Reportable Quantity: This material does not contain any components with a
 
CERCLA RQ.                                                                      
 
                                                                                
 
SARA304 Reportable Quantity: This material does not contain any components with
a 
section 304 EHS RQ.                                                             
 
                                                                                
 
SARA 302: SARA 302: No chemicals in this material are subject to the reporting  
 
requirements of SARA Title III, Section 302.                                    
 
                                                                                
 
SARA 313: The following components are subject to reporting levels established
by 
SARA Title III, Section 313:                                                    
 
xylene                  1330-20-7                 3.21%                         
 
                                                                                
 
Clean Air Act:                                                                  
 
Ozone-Depletion Potential: This product neither contains, nor was manufactured  
 
with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 
 
(40 CFR 82, Subpt. A, App.A + B).                                               
 
The following chemical(s) are listed as HAP under the U.S. Clean Air Act,
Section 
12 (40 CFR 61):                                                                 
 
xylene                   1330-20-7               3.21%                          
 
This product does not contain any chemicals listed under the U.S. Clean Air Act 
 
Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).    
 
SARA Section 311/312 Hazard Classes |Chronic Health Hazard                      
 
                                    |Acute Health Hazard                        
 
Toxic Substances Control Act (TSCA) |All chemical substances in this product are
 
                                    |either listed on the TSCA Inventory or are
in
                                    |compliance with a TSCA Inventory exemption.
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Prop 65: WARNING! This product contains a chemical known in the State
 
of California to cause cancer.                                                  
 
WARNING: This product contains a chemical known in the State of California to   
 
cause birth defects or other reproductive harm.                                 
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |08/22/2014                                                     
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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--  |                               |                                           
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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