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SDS Sheet 0075810Printer Friendly View
Safety Data Sheet Date of Issue: |Revision Date: 19.03.2015 |Revision Number: 1,00 Imperial Supplies Part Number: 0075810 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Parlite 4220 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Adhesives, sealants 1.3. Name, Address, and Telephone of the Responsible Party Company Parson Adhesives, Inc. MI 48309 Rochester Phone: +1 248-299-5585 1.4. Emergency Telephone Number Emergency |+1 248-299-5585 (Mo-Fr, 08:00-16:00) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Skin Irrit. 2 corrosion/irri| tation | Serious eye |Eye Irrit. 2 damage/eye | irritation | Respiratory/sk|Skin Sens. 1 in | sensitization | Specific |STOT SE 3 target organ | toxicity - | single | exposure | Hazardous to |Aquatic Acute the aquatic |1 environment | Hazardous to |Aquatic the aquatic |Chronic 1 environment | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamat|Environm| | | | |ion Mark|ent | | | | Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |H315 Causes skin irritation. |H317 May cause an allergic skin reaction. |H319 Causes serious eye irritation. |H335 May cause respiratory irritation. |H410 Very toxic to aquatic life with long lasting |effects. Precautionary Statements |P280 Wear protective gloves/protective clothing/eye (GHS-US) |protection/face protection. |P312 Call a POISON CENTER/doctor if you feel unwell. | |P333+P313 If skin irritation or rash occurs: Get |medical advice/attention. |P337+P313 If eye irritation persists: Get medical |advice/attention. |P362+P364 Take off contaminated clothing and wash it |before reuse. |P501 Dispose of contents/container to in accordance |with official regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: No information available. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) 2-hydroxyethyl methacrylate |868-77-9 |45 - < |Eye Irrit. 2, Skin | |50 % |Irrit. 2, Skin | | |Sens. 1 exo-1,7,7-trimethylbicyclo[2.2.1|5888-33-5 |45 - < |Skin Irrit. 2, Eye ]hept-2-yl acrylate | |50 % |Irrit. 2, Skin | | |Sens. 1B, STOT SE | | |3, Aquatic Acute 1 | | |(M-Factor = 1), | | |Aquatic Chronic 1 | | |(M-Factor = 1) [3-(2,3-Epoxypropoxy)propyl]trim|2530-83-8 |1 - < 5 |Eye Dam. 1 ethoxysilane | |% | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: In case of accident or if you feel unwell, seek medical advice immediately (show safety data sheet if possible). First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. In case of irregular breathing or respiratory arrest provide artificial respiration. In case of irritation of the respiratory tract seek medical advice. In the case of lung irritation: Primary treatment using corticoide spray, eg. Auxiloson spray, Pulmicort-dosage-spray. (Auxiloson and Pulmicort are registered trademarks). First-aid Measures After Skin Contact: Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. If skin irritation or rash occurs: Get medical advice/attention. First-aid Measures After Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. In case of troubles or persistent symptoms, consult an ophthalmologist. First-aid Measures After Ingestion: Do not induce vomiting. Rinse mouth thoroughly with water. Let water be swallowed in little sips (dilution effect). Never give anything by mouth to an unconscious person or a person with cramps. Call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: No information available. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Dry extinguishing powder. Foam. Water spray. Carbon dioxide (CO2). Unsuitable Extinguishing Media: High power water jet. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Can be released in case of fire: Carbon monoxide. Carbon dioxide (CO2). Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Wear a self-contained breathing apparatus and chemical resistant suit. In case of fire and/or explosion do not breathe fumes. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Provide adequate ventilation. Do not breathe gas/vapour/spray. Avoid contact with skin, eye and clothing. Wear personal protection equipment. (refer to chapter 8) 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Do not empty into drains or the aquatic environment. Prevent spreading over great surfaces (e.g. by damming or installing oil booms). In case of leakage into waters, ground or the drainage system, the appropriate authorities must be informed. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Ventilate affected area. Treat the assimilated material according to the section on waste disposal. Clean contaminated objects and areas thoroughly observing environmental regulations. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Advice on safe handling: Provide adequate ventilation. Wear suitable protective clothing. (Refer to chapter 8.) Advice on protection against fire and explosion: Usual measures for fire prevention. Further information on handling: Do not breathe gas/vapor/spray. Avoid contact with skin, eye and clothing. General protection and hygiene measures: refer to chapter 8 Hygiene Measures: Always close containers tightly after the removal of product. Do not eat, drink, smoke or sneeze at the workplace. Wash hands before breaks and at the end of work. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing prior to re-use. Used working clothes should not be used outside the work area. Street clothing should be stored seperately from work clothing. Protect skin by using skin protective cream. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Requirements for storage rooms and vessels: Keep container tightly closed in a cool, well-ventilated place. Keep container dry. Advice on storage compatibility: Do not store together with: Explosives. Oxidizing solids. Oxidizing liquids. Radioactive substances. Infectious substances. Further information on storage conditions: Protect against: Light. UV-radiation/sunlight. heat. cooling. moisture. 7.3. Specific End Use(s) No information available. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Additional advice on limit values: To date, no national limit values exist. 8.2. Exposure Controls Appropriate Engineering |In case of open handling, use devices with built-in Controls |suction where possible. If suction of the immediate |vicinity is impossible or insufficient, adequate |airing of the working place must be ensured. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Pull-over gloves of rubber. DIN EN 374 |Suitable material: (Breakthrough time >= 480 min, |penetration time (maximum wearing period): 160 min) | |CR (polychloroprenes, Chloroprene rubber). (0,5 mm) | |FKM (fluororubber). (0,4 mm) |Butyl rubber. (0,5 mm). Before using check leak |tightness / impermeability. In case of |reutilization, clean gloves before taking off and |store in well-aired place. |In the cases of special applications, it is |recommended to check the chemical resistance with |the manufacturer of the gloves. Eye Protection |Suitable eye protection: Tightly sealed safety |glasses. DIN EN 166 Skin and Body Protection |Protective clothing. Respiratory Protection |With correct and proper use, and under normal |conditions, breathing protection is not required. |Respiratory protection required in case of: |Insufficient ventilation. Generation/formation of |aerosols. Generation/formation of mist. |Suitable respiratory protective equipment: |Combination filter device (DIN EN 141).. Type: A / |P2/P3 |The filter class must be suitable for the maximum |contaminant concentration |(gas/vapour/aerosol/particulates) that may arise |when handling the product. If the concentration is |exceeded, closed-circuit breathing apparatus must be |used! Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance | Odor |characteristic Odor Threshold | pH |not determined Relative Evaporation Rate | (butylacetate=1) | Melting Point |not determined Freezing Point | Boiling Point |not determined Flash Point |not determined Auto-ignition Temperature | Decomposition Temperature | Flammability (solid, gas) | Vapor Pressure |not determined Relative Vapor Density at 20 Â°C | Relative Density |not determined Specific Gravity | Solubility | Partition coefficient: | n-octanol/water | Viscosity |not determined Lower Flammable Limit |not determined Upper Flammable Limit |not determined 9.2. Other Information No information available. 2010/75/EU (VOC): No information available. 2004/42/EC (VOC): No information available. SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Hazardous polymerization: Protect from direct sunlight. Can polymerise exothermically if heated, exposed to air, sunlight or by addition or free radical initiators. 10.2 Chemical Stability Stable under normal storage and handling conditions. 10.3 Possibility of Hazardous Reactions No information available. 10.4 Conditions to Avoid Protect against: Light. UV-radiation/sunlight. heat. cooling. moisture. 10.5 Incompatible Materials Materials to avoid: Strong acid. Oxidizing agents, strong. Alkalis (alkalis), concentrated. 10.6 Hazardous Decomposition Products Can be released in case of fire: Carbon monoxide. Carbon dioxide (CO2). SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute toxicity: Based on available data, the classification criteria are not met. Skin Corrosion/Irritation: Causes skin irritation. Causes serious eye irritation. Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: May cause an allergic skin reaction. (2-hydroxyethyl methacrylate), (exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate) Product is: sensitizing. People who suffer from skins problems, asthma, allergies, chronic or recurring respiratory illnesses must not be deployed in processes, which use this substance. Germ Cell Mutagenicity: Carcinogenicity: Based on available data, the classification criteria are not met. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. (exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate) Specific Target Organ Toxicity (Repeated Exposure): Based on available data, the classification criteria are not met. Aspiration Hazard: Based on available data, the classification criteria are not met. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity CAS No Chemical name Aquatic toxicity Method Dose [ h] | [d] Species Source 868-77-9 2-hydroxyethyl methacrylate Acute fish toxicity LC50 227 mg/l 96 h Pimephales promelas ECHA Dossier Acute algae toxicity ErC50 836 mg/l 72h Selenastrum capricornutum ECHA Dossier Acute crustacea toxicity EC50 380 mg/l 48 h Daphnia magna ECHA Dossier 5888-33-5 exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate Acute fish toxicity LC50 0,704 mg/l 96h Danio rerio (OECD 203) ECHA Dossier Acute algae toxicity ErC50 0,596 mg/l 72 h Pseudokirchnerella ECHA Dossier subcapitata CD 201) Crustacea toxicity NOEC 0,092 mg/l 21 d Daphnia magna (OECD 211) ECHA Dossier 2530-83-8 [3-(2,3-Epoxypropoxy)propyl]trimethoxysilane Acute fish toxicity LC50 (55) mg/l 96 h Cyprinus carpio ECHA Dossier Acute crustacea toxicity EC50 324 mg/l 48 h Simocephalus vetulus ECHA Dossier Crustacea toxicity NOEC >100 mg/l 21 d Daphnia magna ECHA Dossier 12.2. Persistence and Degradability CAS No Chemical name Method Value d Source Evaluation 868-77-9 2-hydroxyethyl methacrylate OECD 301C / ISO 9408 / EWG 92/69 Anhang V, C.4-F >92% 14 ECHA Dossier Easily biodegradable (concerning to the criteria of the OECD) 5888-33-5 exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate OECD 301F / ISO 9408 / EEC 92/69 annex V, C.4-D 51% 28 ECHA Dossier Product is not easily biodegradable. 2530-83-8 [3-(2,3-Epoxypropoxy)propyl]trimethoxysilane OECD 301A / ISO 7827 / EEC 92/69 annex V, C.4-A 37% 28 ECHA Dossier Not easily bio-degradable (according to OECD-criteria). 12.3. Bioaccumulative Potential Partition coefficient n-octanol/water CAS No Chemical name Log Pow 868-77-9 2-hydroxyethyl methacrylate 0,47 5888-33-5 exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate 4,52 2530-83-8 [3-(2,3-Epoxypropoxy)propyl]trimethoxysilane -2,6 12.4. Mobility in Soil No data available 12.5. Other Adverse Effects No data available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste disposal according to official state regulations. Consult the local waste disposal expert about waste disposal. Cleaned containers may be recycled. Additional Information: Control report for waste code/ waste marking according to EAKV: Waste disposal number of waste from residues/unused products 080409: WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS; wastes from MFSU of adhesives and sealants (including waterproofing products); waste adhesives and sealants containing organic solvents or other dangerous substances. Classified as hazardous waste. Waste disposal number of used product: 080409: WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS; wastes from MFSU of adhesives and sealants (including waterproofing products); waste adhesives and sealants containing organic solvents or other dangerous substances. Classified as hazardous waste. Waste disposal number of contaminated packaging: 150110: WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging waste); packaging containing residues of or contaminated by dangerous substances. Classified as hazardous waste. Contaminated packaging: Handle contaminated packaging in the same way as the substance itself. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. |(exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate) Hazard Class |9 Identification Number|UN 3082 Label Codes |9 |<PICTOGRAM PHRASE>[pic] ntification Of The | | Substance/m | | EmS-No. (Fire) |F-A | EmS-No. (Spillage) |S-F | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |19.03.2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|H315 |Causes skin irritation. -- | | ----|H317 |May cause an allergic skin reaction. -- | | ----|H318 |Causes serious eye damage. -- | | ----|H319 |Causes serious eye irritation. -- | | ----|H335 |May cause respiratory irritation. -- | | |H400 |Very toxic to aquatic life. |H410 |Very toxic to aquatic life with long lasting | |effects. |EUH205 |Contains epoxy constituents. May produce an | |allergic reaction. Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.