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SDS Sheet 0075810

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Safety Data Sheet                                                                 
Date of Issue:             |Revision Date: 19.03.2015  |Revision Number: 1,00     
Imperial Supplies Part Number: 0075810                                            

SECTION 1: IDENTIFICATION                                                         


1.1.  Product Identifier
Product Form:                                                                     
Product Name: Parlite 4220                                                        
CAS No:                                                                           
Synonyms:                                                                         


1.2.  Intended Use of the Product
Use of the substance/mixture: Adhesives, sealants                                 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                           
Parson Adhesives, Inc.                                                            
MI 48309 Rochester                                                                
Phone: +1 248-299-5585                                                            


1.4.  Emergency Telephone Number
Emergency     |+1 248-299-5585 (Mo-Fr, 08:00-16:00)                               
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Skin          |Skin Irrit. 2 
corrosion/irri|              
tation        |              
Serious eye   |Eye Irrit. 2  
damage/eye    |              
irritation    |              
Respiratory/sk|Skin Sens. 1  
in            |              
sensitization |              
Specific      |STOT SE 3     
target organ  |              
toxicity -    |              
single        |              
exposure      |              
Hazardous to  |Aquatic Acute 
the aquatic   |1             
environment   |              
Hazardous to  |Aquatic       
the aquatic   |Chronic 1     
environment   |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamat|Environm|        |        |        |        
                             |ion Mark|ent     |        |        |        |        
Signal Word (GHS-US)         |Warning                                             
Hazard Statements (GHS-US)   |H315 Causes skin irritation.                        
                             |H317 May cause an allergic skin reaction.           
                             |H319 Causes serious eye irritation.                 
                             |H335 May cause respiratory irritation.              
                             |H410 Very toxic to aquatic life with long lasting   
                             |effects.                                            
Precautionary Statements     |P280 Wear protective gloves/protective clothing/eye 
(GHS-US)                     |protection/face protection.                         
                             |P312 Call a POISON CENTER/doctor if you feel unwell.
                             |                                                    
                             |P333+P313 If skin irritation or rash occurs: Get    
                             |medical advice/attention.                           
                             |P337+P313 If eye irritation persists: Get medical   
                             |advice/attention.                                   
                             |P362+P364 Take off contaminated clothing and wash it
                             |before reuse.                                       
                             |P501 Dispose of contents/container to in accordance 
                             |with official regulations.                          


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: No information available.   


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                  

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
2-hydroxyethyl methacrylate     |868-77-9             |45 - <  |Eye Irrit. 2, Skin
                                |                     |50 %    |Irrit. 2, Skin    
                                |                     |        |Sens. 1           
exo-1,7,7-trimethylbicyclo[2.2.1|5888-33-5            |45 - <  |Skin Irrit. 2, Eye
]hept-2-yl acrylate             |                     |50 %    |Irrit. 2, Skin    
                                |                     |        |Sens. 1B, STOT SE 
                                |                     |        |3, Aquatic Acute 1
                                |                     |        |(M-Factor = 1),   
                                |                     |        |Aquatic Chronic 1 
                                |                     |        |(M-Factor = 1)    
[3-(2,3-Epoxypropoxy)propyl]trim|2530-83-8            |1 - < 5 |Eye Dam. 1        
ethoxysilane                    |                     |%       |                  
                                |                     |        |                  
                                |                     |        |                  


SECTION 4: FIRST AID MEASURES                                                     


4.1.  Description of First Aid Measures
First-aid Measures General: In case of accident or if you feel unwell, seek       
medical advice immediately (show safety data sheet if possible).                  
First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest  
in a position comfortable for breathing. In case of irregular breathing or        
respiratory arrest provide artificial respiration. In case of irritation of the   
respiratory tract seek medical advice.                                            
In the case of lung irritation: Primary treatment using corticoide spray, eg.     
Auxiloson spray, Pulmicort-dosage-spray. (Auxiloson and Pulmicort are registered  
trademarks).                                                                      
First-aid Measures After Skin Contact: Take off immediately all contaminated      
clothing. After contact with skin, wash immediately with plenty of water and soap.
If skin irritation or rash occurs: Get medical advice/attention.                  
First-aid Measures After Eye Contact: Rinse cautiously with water for several     
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. In   
case of troubles or persistent symptoms, consult an ophthalmologist.              
First-aid Measures After Ingestion: Do not induce vomiting. Rinse mouth thoroughly
with water. Let water be swallowed in little sips (dilution effect). Never give   
anything by mouth to an unconscious person or a person with cramps. Call a POISON 
CENTER or doctor/physician.                                                       


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: No information available.                                      
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Treat symptomatically.                                                            

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Dry extinguishing powder. Foam. Water spray. Carbon 
dioxide (CO2).                                                                    
Unsuitable Extinguishing Media: High power water jet.                             


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:                                                                      
Explosion Hazard: Can be released in case of fire: Carbon monoxide. Carbon dioxide
(CO2).                                                                            
Reactivity:                                                                       


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions: Wear a self-contained breathing apparatus and chemical 
resistant suit. In case of fire and/or explosion do not breathe fumes.            
Protection During Firefighting:                                                   

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Provide adequate ventilation. Do not breathe gas/vapour/spray.  
Avoid contact with skin, eye and clothing. Wear personal protection equipment.    
(refer to chapter 8)                                                              


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.2.  Environmental Precautions
Do not empty into drains or the aquatic environment. Prevent spreading over great 
surfaces (e.g. by damming or installing oil booms). In case of leakage into       
waters, ground or the drainage system, the appropriate authorities must be        
informed.                                                                         


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                  
Methods for Cleaning Up: Absorb with liquid-binding material (e.g. sand,          
diatomaceous earth, acid- or universal binding agents). Ventilate affected area.  
Treat the assimilated material according to the section on waste disposal. Clean  
contaminated objects and areas thoroughly observing environmental regulations.    


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        


SECTION 7: HANDLING AND STORAGE                                                   


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Advice on safe handling: Provide adequate      
ventilation. Wear suitable protective clothing. (Refer to chapter 8.)             
Advice on protection against fire and explosion: Usual measures for fire          
prevention.                                                                       
Further information on handling: Do not breathe gas/vapor/spray. Avoid contact    
with skin, eye and clothing. General protection and hygiene measures: refer to    
chapter 8                                                                         
Hygiene Measures: Always close containers tightly after the removal of product. Do
not eat, drink, smoke or sneeze at the workplace. Wash hands before breaks and at 
the end of work. Remove/Take off immediately all contaminated clothing. Wash      
contaminated clothing prior to re-use. Used working clothes should not be used    
outside the work area. Street clothing should be stored seperately from work      
clothing. Protect skin by using skin protective cream.                            


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                               
Storage Conditions: Requirements for storage rooms and vessels: Keep container    
tightly closed in a cool, well-ventilated place. Keep container dry.              
Advice on storage compatibility: Do not store together with: Explosives. Oxidizing
solids. Oxidizing liquids. Radioactive substances. Infectious substances.         
Further information on storage conditions: Protect against: Light.                
UV-radiation/sunlight. heat. cooling. moisture.                                   


7.3.  Specific End Use(s)
No information available.                                                         

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  


8.1.  Control Parameters
Additional advice on limit values: To date, no national limit values exist.       


8.2.  Exposure Controls
Appropriate Engineering      |In case of open handling, use devices with built-in 
Controls                     |suction where possible. If suction of the immediate 
                             |vicinity is impossible or insufficient, adequate    
                             |airing of the working place must be ensured.        
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |Pull-over gloves of rubber. DIN EN 374              
                             |Suitable material: (Breakthrough time >= 480 min,   
                             |penetration time (maximum wearing period): 160 min) 
                             |                                                    
                             |CR (polychloroprenes, Chloroprene rubber). (0,5 mm) 
                             |                                                    
                             |FKM (fluororubber). (0,4 mm)                        
                             |Butyl rubber. (0,5 mm). Before using check leak     
                             |tightness / impermeability. In case of              
                             |reutilization, clean gloves before taking off and   
                             |store in well-aired place.                          
                             |In the cases of special applications, it is         
                             |recommended to check the chemical resistance with   
                             |the manufacturer of the gloves.                     
Eye Protection               |Suitable eye protection: Tightly sealed safety      
                             |glasses. DIN EN 166                                 
Skin and Body Protection     |Protective clothing.                                
Respiratory Protection       |With correct and proper use, and under normal       
                             |conditions, breathing protection is not required.   
                             |Respiratory protection required in case of:         
                             |Insufficient ventilation. Generation/formation of   
                             |aerosols. Generation/formation of mist.             
                             |Suitable respiratory protective equipment:          
                             |Combination filter device (DIN EN 141).. Type: A /  
                             |P2/P3                                               
                             |The filter class must be suitable for the maximum   
                             |contaminant concentration                           
                             |(gas/vapour/aerosol/particulates) that may arise    
                             |when handling the product. If the concentration is  
                             |exceeded, closed-circuit breathing apparatus must be
                             |used!                                               
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                       
Appearance                          |                                             
Odor                                |characteristic                               
Odor Threshold                      |                                             
pH                                  |not determined                               
Relative Evaporation Rate           |                                             
(butylacetate=1)                    |                                             
Melting Point                       |not determined                               
Freezing Point                      |                                             
Boiling Point                       |not determined                               
Flash Point                         |not determined                               
Auto-ignition Temperature           |                                             
Decomposition Temperature           |                                             
Flammability (solid, gas)           |                                             
Vapor Pressure                      |not determined                               
Relative Vapor Density at 20 °C     |                                             
Relative Density                    |not determined                               
Specific Gravity                    |                                             
Solubility                          |                                             
Partition coefficient:              |                                             
n-octanol/water                     |                                             
Viscosity                           |not determined                               
Lower Flammable Limit               |not determined                               
Upper Flammable Limit               |not determined                               


9.2.  Other Information
No information available.                                                         
2010/75/EU (VOC): No information available.                                       
2004/42/EC (VOC): No information available.                                       

SECTION 10: STABILITY AND REACTIVITY                                              


10.1      Reactivity
Hazardous polymerization: Protect from direct sunlight. Can polymerise            
exothermically if heated, exposed to air, sunlight or by addition or free radical 
initiators.                                                                       


10.2      Chemical Stability
Stable under normal storage and handling conditions.                              


10.3      Possibility of Hazardous Reactions
No information available.                                                         


10.4      Conditions to Avoid
Protect against: Light. UV-radiation/sunlight. heat. cooling. moisture.           


10.5      Incompatible Materials
Materials to avoid: Strong acid. Oxidizing agents, strong. Alkalis (alkalis),     
concentrated.                                                                     


10.6      Hazardous Decomposition Products
Can be released in case of fire: Carbon monoxide. Carbon dioxide (CO2).           

SECTION 11: TOXICOLOGICAL INFORMATION                                             


11.1. Information on Toxicological Effects
Acute toxicity: Based on available data, the classification criteria are not met. 
Skin Corrosion/Irritation: Causes skin irritation. Causes serious eye irritation. 
Serious Eye Damage/Irritation:                                                    
Respiratory or Skin Sensitization: May cause an allergic skin reaction.           
(2-hydroxyethyl methacrylate), (exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl        
acrylate) Product is: sensitizing. People who suffer from skins problems, asthma, 
allergies, chronic or recurring respiratory illnesses must not be deployed in     
processes, which use this substance.                                              
Germ Cell Mutagenicity:                                                           
Carcinogenicity: Based on available data, the classification criteria are not met.
Reproductive Toxicity:                                                            
Specific Target Organ Toxicity (Single Exposure): May cause respiratory           
irritation. (exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate)                 
Specific Target Organ Toxicity (Repeated Exposure): Based on available data, the  
classification criteria are not met.                                              
Aspiration Hazard: Based on available data, the classification criteria are not   
met.                                                                              
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 

SECTION 12: ECOLOGICAL INFORMATION                                                


12.1. Toxicity
CAS No                                                                            
Chemical name                                                                     
                                                                                  
                                                                                  
Aquatic toxicity                         Method        Dose          [ h] | [d]   
Species                               Source                                      
                                                                                  
868-77-9                                                                          
2-hydroxyethyl methacrylate                                                       
                                                                                  
                                                                                  
Acute fish toxicity                       LC50          227 mg/l         96 h     
Pimephales promelas              ECHA Dossier                                     
                                                                                  
                                                                                  
Acute algae toxicity                   ErC50         836 mg/l         72h         
Selenastrum capricornutum   ECHA Dossier                                          
                                                                                  
                                                                                  
Acute crustacea toxicity            EC50          380 mg/l        48 h            
Daphnia magna                         ECHA Dossier                                
                                                                                  
5888-33-5                                                                         
exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate                               
                                                                                  
                                                                                  
Acute fish toxicity                       LC50           0,704 mg/l       96h     
Danio rerio (OECD 203)          ECHA Dossier                                      
                                                                                  
                                                                                  
Acute algae toxicity                   ErC50          0,596 mg/l       72 h       
Pseudokirchnerella   ECHA Dossier                                                 
subcapitata CD 201)                                                               
                                                                                  
                                                                                  
Crustacea toxicity    NOEC           0,092 mg/l     21 d         Daphnia magna    
(OECD 211)   ECHA Dossier                                                         
                                                                                  
2530-83-8                                                                         
[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane                                      
                                                                                  
                                                                                  
Acute fish toxicity LC50            (55) mg/l    96 h              Cyprinus carpio
ECHA Dossier                                                                      
                                                                                  
                                                                                  
Acute crustacea toxicity           EC50            324 mg/l        48 h           
Simocephalus vetulus              ECHA Dossier                                    
                                                                                  
                                                                                  
Crustacea toxicity NOEC           >100 mg/l     21 d          Daphnia magna ECHA  
Dossier                                                                           
                                                                                  


12.2. Persistence and Degradability
                                                                                  
CAS No                                                                            
Chemical name                                                                     
                                                                                  
                                                                                  
Method                                                                            
Value                                                                             
d                                                                                 
Source                                                                            
                                                                                  
                                                                                  
Evaluation                                                                        
                                                                                  
868-77-9                                                                          
2-hydroxyethyl methacrylate                                                       
                                                                                  
                                                                                  
OECD 301C / ISO 9408 / EWG 92/69 Anhang V, C.4-F                                  
>92%                                                                              
14                                                                                
ECHA Dossier                                                                      
                                                                                  
                                                                                  
Easily biodegradable (concerning to the criteria of the OECD)                     
                                                                                  
5888-33-5                                                                         
exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate                               
                                                                                  
                                                                                  
OECD 301F / ISO 9408 / EEC 92/69 annex V, C.4-D                                   
51%                                                                               
28                                                                                
ECHA Dossier                                                                      
                                                                                  
                                                                                  
Product is not easily biodegradable.                                              
                                                                                  
2530-83-8                                                                         
[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane                                      
                                                                                  
                                                                                  
OECD 301A / ISO 7827 / EEC 92/69 annex V, C.4-A                                   
37%                                                                               
28                                                                                
ECHA Dossier                                                                      
                                                                                  
                                                                                  
Not easily bio-degradable (according to OECD-criteria).                           
                                                                                  


12.3. Bioaccumulative Potential
Partition coefficient n-octanol/water                                             
                                                                                  
CAS No             Chemical name                                                  
Log Pow                                                                           
                                                                                  
868-77-9            2-hydroxyethyl methacrylate                                   
0,47                                                                              
                                                                                  
5888-33-5          exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate            
4,52                                                                              
                                                                                  
2530-83-8         [3-(2,3-Epoxypropoxy)propyl]trimethoxysilane                    
-2,6                                                                              


12.4. Mobility in Soil
No data available                                                                 


12.5. Other Adverse Effects
No data available                                                                 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Waste disposal according to official state        
regulations. Consult the local waste disposal expert about waste disposal. Cleaned
containers may be recycled.                                                       
Additional Information:  Control report for waste code/ waste marking according to
EAKV:                                                                             
Waste disposal number of waste from residues/unused products                      
080409: WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF        
COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND        
PRINTING INKS; wastes from MFSU of adhesives and sealants (including waterproofing
products); waste adhesives and sealants containing organic solvents or other      
dangerous substances. Classified as hazardous waste.                              
Waste disposal number of used product: 080409: WASTES FROM THE MANUFACTURE,       
FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS    
ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS; wastes from MFSU of adhesives and
sealants (including waterproofing products); waste adhesives and sealants         
containing organic solvents or other dangerous substances. Classified as hazardous
waste.                                                                            
Waste disposal number of contaminated packaging: 150110: WASTE PACKAGING;         
ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE 
SPECIFIED; packaging (including separately collected municipal packaging waste);  
packaging containing residues of or contaminated by dangerous substances.         
Classified as hazardous waste.                                                    
Contaminated packaging: Handle contaminated packaging in the same way as the      
substance itself.                                                                 

SECTION 14: TRANSPORT INFORMATION                                                 


14.1 In Accordance with DOT
Proper Shipping Name |                                                            
Hazard Class         |                       |<PICTOGRAM PHRASE>                  
Identification Number|                       |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            


14.2 In Accordance with IMDG
Proper Shipping Name |ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.         
                     |(exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate)       
Hazard Class         |9                                                           
Identification Number|UN 3082                                                     
Label Codes          |9                     |<PICTOGRAM PHRASE>[pic]              
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |F-A                   |                                     
EmS-No. (Spillage)   |S-F                   |                                     


14.3 In Accordance with IATA
Proper Shipping Name |                                                            
Identification Number|                       |<PICTOGRAM PHRASE>                   
Hazard Class         |                       |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
<COMPONENT>                                                                       
SARA Section 311/312 Hazard Classes |                                             
Toxic Substances Control Act (TSCA) |                                             

15.2      US State Regulations
<COMPONENT>                                                                       
                                                                                  

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION     

Revision date   |19.03.2015                                                       
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
                |1910.1200.                                                       
GHS Full Text Phrases:                                                            
----|H315                           |Causes skin irritation.                      
--  |                               |                                             
----|H317                           |May cause an allergic skin reaction.         
--  |                               |                                             
----|H318                           |Causes serious eye damage.                   
--  |                               |                                             
----|H319                           |Causes serious eye irritation.               
--  |                               |                                             
----|H335                           |May cause respiratory irritation.            
--  |                               |                                             
    |H400                           |Very toxic to aquatic life.                  
    |H410                           |Very toxic to aquatic life with long lasting 
    |                               |effects.                                     
    |EUH205                         |Contains epoxy constituents. May produce an  
    |                               |allergic reaction.                           


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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