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SDS Sheet 0075250Printer Friendly View
Safety Data Sheet Date of Issue: 03/27/15 |Revision Date: |Revision Number: 5.00 Imperial Supplies Part Number: 0075250 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 3M Brand Super Trim Adhesive, PN 08090 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Automotive, Adhesive Aerosol 1.3. Name, Address, and Telephone of the Responsible Party Company: 3M Automotive Aftermarket 3M Center, St. Paul, MN 55144-1000, USA Phone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency Telephone Number Emergency | 1-800-364-3577 or (651) 737-6501 (24 hours) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1. Aerosol | Serious Eye |Category 2B Damage/Irritat| ion | Reproductive |Category 1B Toxicity | Simple | Asphyxiant | Specific |Category 3 Target Organ | Toxicity | (central | nervous | system) | Specific |Category 3 Target Organ | Toxicity | (respiratory | irritation) | Specific |Category 1 Target Organ | Toxicity | (repeated | exposure) | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | |Flame |Exclamat|Health | | | | |ion mark|Hazard | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. |Causes eye irritation. |May cause respiratory irritation. |May cause drowsiness or dizziness. |May damage fertility or the unborn child. |May displace oxygen and cause rapid suffocation. |Causes damage to organs through prolonged or |repeated exposure: |nervous system l |sensory organs | Precautionary Statements |General: (GHS-US) |Keep out of reach of children. | |Prevention: |Obtain special instructions before use. |Do not handle until all safety precautions have been |read and understood. |Keep away from heat/sparks/open flames/hot surfaces. |No smoking. |Do not spray on an open flame or other ignition |source. |Pressurized container: Do not pierce or burn, even |after use. |Do not breathe dust/fume/gas/mist/vapors/spray. |Use only outdoors or in a well-ventilated area. |Wear protective gloves. |Do not eat, drink or smoke when using this product. |Wash thoroughly a?er handling. | |Response: |IF INHALED: Remove person to Fresh air and keep |comfortable for breathing. |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention. |Call a POISON CENTER or doctor/physician if you feel |unwell. | |Storage: |Protect from sunlight. Do not expose to temperatures |exceeding 50C/ 122F. |Store in a well-ventilated place. Keep container |tightly closed. |Store locked up. | |Disposal: |Dispose of contents/container in accordance with |applicable local/regional/national/international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. 2.4. Unknown Acute Toxicity (GHS-US) 34% of the mixture consists of ingredients of unknown acute oral toxicity. 41% of the mixture consists of ingredients of unknown acute dermal toxicity. 47% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classifica | | |tion | | |(GHS-US) Methyl Acetate |79-20-9 |30 - 40 Trade | | |Secret* | Dimethyl Ether |115-10-6 |25 - 35 Trade | | |Secret* | Non-hazardous components (NJTSRN|Trade Secret* |10 - 30 Trade | 04499600-7374) | |Secret* | Cyclohexane |110-82-7 |10 - 20 Trade | | |Secret* | Toluene |108-88-3 |3 - 7 Trade | | |Secret* | Hydrotreated Heavy Naphtha |64742-48-9 |1 - 5 Trade | (Petroleum) | |Secret* | Rosin |8050-09-7 |<0.5 Trade | | |Secret* | NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. First-aid Measures After Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. First-aid Measures After Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. First-aid Measures After Ingestion: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See Section 11.1. information on toxicological effects. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Not applicable. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use a ?re fighting agent suitable for the surrounding ?re. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Closed containers exposed to heat from ?re may build pressure and explode. Explosion Hazard: Hazardous decomposition or By Products Substance Condition Formaldehyde During Combustion Carbon Monoxide During Combustion Carbon dioxide During Combustion Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Water may not effectively extinguish ?re; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon. as possible. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even alter use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 5OC/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Toluene 108-88-3 OSHA TWA:200 PPM; CEIL:300 PPM Toluene 108-88-3 ACGIH TWA:20 PPM A4: Not class. As human carcin Toluene 108-88-3 CMRG STEL: 75ppm Skin Notation Cyclohexane 108-88-3 OSHA TWA: 1050 MG/M3 (300 ppm) Cyclohexane 108-88-3 ACGIH TWA: 100 ppm Dimethyl Ether 115-10-6 AIHA TWA: 1880 MG/M3(1000 ppm) Dimethyl Ether 115-10-6 CMRG TWA: 1000 PPM Hydrotreated Heavy Naphtha (Petroleum) 64742-48-9 Manufacturer determined TWA: 100 ppm Methyl Acetate 79-20-9 OSHA TWA: 610 mg/m3(200 ppm) Methyl Acetate 79-20-9 ACGIH TWA: 200 ppm; STEL: 250ppm Rosin 8050-09-7 ACGIH Limit value not established: Cntrl all export-low as possib, Dermal/Respiratory Sensitizer 8.2. Exposure Controls Appropriate Engineering |Do not remain in area where available oxygen may be Controls |reduced. Use general dilution ventilation and/or |local exhaust ventilation to control airborne |exposures to below relevant Exposure Limits and/or |control dust/fume/gas/mist/vapors/spray. If |ventilation is not adequate, use respiratory |protection equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Select and use eye/face protection to prevent |contact based on the results of an exposure |assessment. The following eye/face protection(s) are |recommended: Indirect Vented Goggles. Skin and Body Protection |Select and use gloves and/or protective clothing |approved to relevant local standards to prevent skin |contact based on the results of an exposure |assessment. Selection should be based on use factors |such as exposure levels, concentration of the |substance or mixture, frequency and duration, |physical challenges such as temperature extremes, |and other use conditions. Consult with your glove |and/or protective clothing manufacturer for |selection of appropriate compatible |gloves/protective clothing. |Gloves made from the following material(s) are |recommended: Fluoroelastomer. Respiratory Protection |An exposure assessment may be needed to decide if a |respirator is required. if a respirator is needed, |use respirators as part of a full respiratory |protection program. Based on the results of the |exposure assessment, select from the following |respirator type(s) to reduce inhalation exposure: |Half facepiece or full facepiece air-purifying |respirator suitable for organic vapors. |For questions about suitability fora specific |application, consult with your respirator |manufacturer. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Aerosol Odor |Mild solvent smell Odor Threshold |No Data Available pH |Not Applicable Relative Evaporation Rate |1.90 [Ref Std: Ether=1] (butylacetate=1) | Melting Point |Not Applicable Freezing Point |Not Applicable Boiling Point |Not Applicable Flash Point |-42 Â°F Auto-ignition Temperature |No Data Available Decomposition Temperature |No Data Available Flammability (solid, gas) |Not Applicable [pic]Vapor Pressure |Not Applicable Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |0.835 [Ref Std: WATER=1] Solubility |Negligible Partition coefficient: |No Data Available n-octanol/water | Viscosity |Not Applicable Lower Flammable Limit |No Data Available Upper Flammable Limit |No Data Available 9.2. Other Information Volatile Organic Compounds: 53.7 % weight [Test Method: calculated per CARB title 2], Volatile Organic Compounds: 448 g/l [Test Method: calculated SCAQMD rule 443.1] VOC Less H20 & Exempt Solvents: 631 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Heat, Sparks and/or flames 10.5 Incompatible Materials Strong acids, Strong oxidizing agents 10.6 Hazardous Decomposition Products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Specific Target Organ Toxicity (Single Exposure): Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Specific Target Organ Toxicity (Repeated Exposure): Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Aspiration Hazard: Symptoms/Injuries After Inhalation: May be harmful if inhaled. Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fetal Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Symptoms/Injuries After Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Symptoms/Injuries After Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Symptoms/Injuries After Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Chemical Fate information Please contact the address or phone number listed on the first page of the SDS for additional Chemical Fate information on this material and/or its components. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |For Transport Information, Please visit |http://3M.com/Transportinfo or call 1-800-364-3577 or |651-737-6501 Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations Contact 3M for more information. Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CI R part 372 (F.PCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 3 - 7 Cyclohexane 110-82-7 10 - 20 SARA Section 311/312 Hazard Classes |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No |Immediate Hazard - Yes |Delayed Hazard - Yes Toxic Substances Control Act (TSCA) |The components of this product are in |compliance with the chemical notification |requirements of TSCA. |Contact 3M for more information. 15.2 US State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Toluene 108-88-3 Female reproductive toxin Toluene 108-88-3 Developmental Toxin WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.