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SDS Sheet 0075210Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Oatey X-15 PVC Solvent Adhesive CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company: Oatey Co. 4700 West 160th Street Cleveland, OH 44135 Phone: 216-267-7100 1.4. Emergency Telephone Number Emergency | 1-877-740-5015, 1-800-424-9300, 1- 703-527-3887 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 2 Liquids | Acute Toxicity|Category 4 Oral | Acute Toxicity|Category 4 Dermal | Acute Toxicity|Category 4 Inhalation | Eye |Category 2A Damage/Irritat| ion | Carcinogenicit|Category 2 y | Specific |Category 3 Target Organ | Toxicity | Single | Exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Exclamation Mark |Health Hazard Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Highly flammable liquid and vapor. |Harmful if swallowed. |Harmful in contact with skin. |Harmful if inhaled. |Causes serious eye irritation. |Contains a chemical classified by the US EPA as a |suspected possible carcinogen. |May cause respiratory irritation. |May cause drowsiness or dizziness. Precautionary Statements |Prevention: (GHS-US) |Keep away from heat/sparks/open flames and hot |surfaces. - No smoking. |Keep container tightly closed. |Use explosion-proof |electrical/ventilating/lighting/equipment. |Use only non-sparking tools. |Take precautionary measures against static |discharge. |Wear protective gloves/eye protection/face |protection. |Wash thoroughly after handling. |Do not eat, drink or smoke when using this product. |Obtain special instructions before use. |Do not handle until all safety precautions have been |read and understood. |Avoid breathing fume/gas/mist/vapors. |Use only outdoors or in a well-ventilated area. | |Response: |If on skin (or hair): Remove/Take off immediately |all contaminated clothing. Rinse skin with |water/shower. Wash contaminated clothing before |reuse. |If swallowed: Call a poison center or |doctor/physician if you feel unwell. Rinse mouth. Do |not induce vomiting. |If inhaled: Remove victim to fresh air and keep at |rest in a position comfortable for breathing. Call a |poison center or doctor/physician if you feel |unwell. |If in eyes: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. Immediately call a poison |center or doctor/physician. |If exposed or concerned Get medical |advice/attention. |In case of fire: Use dry chemical, CO2, or foam to |extinguish fire. | |Storage: |Store in a well-ventilated place. Keep cool. |Store locked up. | |Disposal: |Dispose of contents/container in accordance with |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Tetrahydrofuran |109-99-9 | |60 - 80 Acetone |67-64-1 | |5 - 15 Linear Saturated Polyester Resin|61412-73-5 | |15 - 25 | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: If symptoms of exposure develop, remove to fresh air. If breathing becomes difficult, administer oxygen. Administer artificial respiration if breathing has stopped. Seek immediate medical attention. First-aid Measures After Skin Contact: Remove contaminated clothing immediately. Wash all exposed areas with soap and water. Get medical attention if irritation develops. Remove dried cement with hand cleaner or baby oil. First-aid Measures After Eye Contact: If material gets into eyes or if fumes cause irritation, immediately flush eyes with plenty of water until chemical is removed. If irritation persists, get medical attention immediately. First-aid Measures After Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is unconscious or drowsy. Get immediate medical attention by calling a Poison Control Center, or hospital emergency room. If medical advice cannot be obtained, then take the person and product to the nearest medical emergency treatment center or hospital. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container with water. Water may be ineffective as an extinguishing agent. Unsuitable Extinguishing Media: None. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: See Section 9 for Flammability Properties. Highly flammable liquid and vapor. Keep away from heat and all sources of ignition including sparks, flames, lighted cigarettes and pilot lights. Containers may rupture or explode in the heat of a fire. Vapors are heavier than air and may travel to a remote ignition source and flash back. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. Explosion Hazard: Combustion will produce toxic and irritating vapors including carbon monoxide, carbon dioxide and hydrogen chloride. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Personnel cleaning up the spill should wear appropriate personal protective equipment, including respirators if vapor concentrations are high. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent liquid from entering watercourses, sewers and natural waterways. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Remove all sources of ignition and ventilate area. Soak up spill with an inert absorbent such as sand, earth or other noncombusting material. Put absorbent material in covered, labeled metal containers. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation (equivalent to outdoors). Wash thoroughly after handling. Do not eat, drink or smoke in the work area. Keep product away from heat, sparks, flames and all other sources of ignition. No smoking in storage or use areas. Keep containers closed when not in use. Other: "Empty" containers retain product residue and can be hazardous. Follow all SDS precautions in handling empty containers. Do not cut or weld on or near empty or full containers. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a cool, dry, well-ventilated area away from incompatible materials. Keep containers closed when not in use. Incompatibilities: Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and hydrogen peroxides. May attack plastic, resins and rubber. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Tetrahydrofuran (109-99-9) ACGIH: 50 ppm TWA 100 ppm STEL Skin - potential significant contribution to overall exposure by the cutaneous route OSHA: 200 ppm TWA; 590 mg/m3 TWA NIOSH: 200 ppm TWA; 590 mg/m3 TWA 250 ppm STEL; 735 mg/m3 STEL Acetone (67-64-1) ACGIH: 500 ppm TWA 750 ppm STEL OSHA: 1000 ppm TWA; 2400 mg/m3 TWA NIOSH: 250 ppm TWA; 590 mg/m3 TWA 8.2. Exposure Controls Appropriate Engineering |Open doors & windows. Provide ventilation capable of Controls |maintaining emissions at the point of use below |recommended exposure limits. If used in enclosed |area, use exhaust fans. Exhaust fans should be |explosion proof or set up in a way that flammable |concentrations of solvent vapors are not exposed to |electrical fixtures or hot surfaces. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Rubber gloves are suitable for normal use of the |product. For long exposures chemical resistant |gloves may be required such as 4H(tm) or Silver |Shield(tm) to avoid prolonged skin contact. Eye Protection |Safety glasses with side shields or safety goggles. Skin and Body Protection |No additional protective equipment needed. Respiratory Protection |For operations where the exposure limit may be |exceeded, a NIOSH approved organic vapor respirator |or supplied air respirator is recommended. Equipment |selection depends on contaminant type and |concentration, select in accordance with 29 CFR |1910.134 and good industrial hygiene practice. For |firefighting, use self contained breathing |apparatus. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Clear Odor |Ether-like Odor Threshold |NA pH |NA Relative Evaporation Rate |(BUAC = 1) = 5.5 - 8.0 (butylacetate=1) | Melting Point |NA Freezing Point | Boiling Point |151Â°F (66Â°C) Flash Point |14-23Â°F (-10 to -5Â°C) Auto-ignition Temperature |ND Decomposition Temperature | Flammability (solid, gas) | Vapor Pressure |145 mmHg @ 20Â°C Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |0.90 +/- 0.02 @ 20Â°C Solubility |Negligible (water) Partition coefficient: | n-octanol/water | Viscosity | Lower Flammable Limit |1.8 Upper Flammable Limit |11.8 9.2. Other Information VOC: <510 g/L (SCAQMD) SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability This is a stable material. 10.3 Possibility of Hazardous Reactions Will not occur. 10.4 Conditions to Avoid Avoid heat, sparks, flames and other sources of ignition. 10.5 Incompatible Materials Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and hydrogen peroxides. May attack plastic, resins and rubber. 10.6 Hazardous Decomposition Products Combustion will produce toxic and irritating vapors including carbon monoxide, carbon dioxide and hydrogen chloride. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Component Analysis - LD50/LC50 Tetrahydrofuran (109-99-9) Inhalation LC50 Rat 53.9 mg/L 4 h; Inhalation LC50 Rat 180 mg/L 1 h; Oral LD50 Rat 1650 mg/kg Acetone (67-64-1) Oral LD50 Rat 5800 mg/kg Skin Corrosion/Irritation: May cause irritation with redness, itching and pain. Serious Eye Damage/Irritation: Vapors may cause irritation. Direct contact may cause irritation with redness, stinging and tearing of the eyes. May cause eye damage. Respiratory or Skin Sensitization: This product is not reported to have any skin sensitization effects. Germ Cell Mutagenicity: Acetone and tetrahydrofuran are generally thought not to be mutagenic. Carcinogenicity: A: General Product Information In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female mice developed liver tumors while neither the female rats nor the male mice showed similar results. Because the carcinogenic mechanisms could not be identified clearly in either species for either tumor, the EPA determined that the male rat and female mouse findings are relevant to the assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following exposure to THF by all routes of exposure. B: Component Carcinogenicity Tetrahydrofuran (109-99-9) ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans Acetone (67-64-1) ACGIH: A4 - Not Classifiable as a Human Carcinogen Reproductive Toxicity: Acetone and tetrahydrofuran has been found to cause adverse developmental effects only when exposure levels cause other toxic effects to the mother. Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. Inhalation of high concentrations may cause central nervous system depression, narcosis and unconsciousness. May cause kidney, liver and lung damage. Specific Target Organ Toxicity (Repeated Exposure): This product is not reported to have any specific target organ toxicity repeat exposure effects. Aspiration Hazard: Aspiration during swallowing or vomiting can cause chemical pneumonia and lung damage. May cause kidney and liver damage. Symptoms/Injuries After Inhalation: Vapors or mists may cause mucous membrane and respiratory irritation, coughing, headache, dizziness, dullness, nausea, shortness of breath and vomiting. High concentrations may cause central nervous system depression, narcosis and unconsciousness. May cause kidney, liver and lung damage. Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Swallowing may cause abdominal pain, nausea, vomiting and diarrhea. Aspiration during swallowing or vomiting can cause chemical pneumonia and lung damage. May cause kidney and liver damage. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity A: General Product Information This product is not expected to be toxic to aquatic organisms. B: Component Analysis - Ecotoxicity - Aquatic Toxicity Tetrahydrofuran (109-99-9) Test & Species Conditions 96 Hr LC50 Pimephales promelas 1970-2360 mg/L [flow-through] 96 Hr LC50 Pimephales promelas 2700-3600 mg/L [static] 24 Hr EC50 Daphnia magna 5930 mg/L Acetone (67-64-1) Test & Species Conditions 96 Hr LC50 Oncorhynchus mykiss 4.74 - 6.33 mL/L 96 Hr LC50 Pimephales promelas 6210 - 8120 mg/L [static] 96 Hr LC50 Lepomis macrochirus 8300 mg/L 48 Hr EC50 Daphnia magna 10294 - 17704 mg/L [Static] 48 Hr EC50 Daphnia magna 12600 - 12700 mg/L 12.2. Persistence and Degradability No information available for the product. 12.3. Bioaccumulative Potential No information available for the product. 12.4. Mobility in Soil No information available for the product. 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations. Additional Information: Disposal of Contaminated Containers or Packaging: Dispose of contents/container in accordance with local/regional/national/international regulations. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Adhesives Hazard Class |3 |<PICTOGRAM PHRASE> Identification Number|UN1133 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Adhesives Hazard Class |3 Identification Number|UN1133 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations Component Analysis This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4). Tetrahydrofuran (109-99-9) CERCLA: 1000 lb final RQ; 454 kg final RQ Acetone (67-64-1) CERCLA: 5000 lb final RQ; 2270 kg final RQ SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) | 15.2 US State Regulations The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MA MA PA RI Tetrahydrofuran 109-99-9 Yes Yes Yes Yes Yes No Acetone 67-64-1 Yes Yes Yes Yes Yes No SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.