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SDS Sheet 0075060 Printer Friendly View
Safety Data Sheet
Date of Issue: 01/05/2015 |Revision Date: 01/05/2015 |Revision Number: 1.0
Imperial Supplies Part Number: 0075060
SECTION 1: IDENTIFICATION
1.1. Product Identifier
Product Form: Mixture
Product Name: HH-66 Vinyl Cement
CAS No:
Synonyms: Thermoplastic Polyurethane Adhesive Blend/Compound
1.2. Intended Use of the Product
Use of the substance/mixture: No additional information available
1.3. Name, Address, and Telephone of the Responsible Party
Company
RH Products Co., Inc.
308 Old High Street
Acton, MA USA 01720
Phone: 1-978-897-8000
1.4. Emergency Telephone Number
Emergency | 1-800-535-5053 INFOTRAC; 1-352-323-3500 INFOTRAC International
number |
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
Classification (GHS-US)
Flam. Liq. 2 |H225
Eye Irrit. 2A |H319
Repr. 2 |H361
STOT SE 3 |H336
STOT RE 2 |H373
2.2. Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) |Flame |Exclamat|Health | | |
|GHS02 |ion Mark|Hazard | | |
| | |GHS08 | | |
| |GHS07 | | | |
Signal Word (GHS-US) |Danger
Hazard Statements (GHS-US) |H225 - Highly flammable liquid and vapor.
|H319 - Causes serious eye irritation.
|H336 - May cause drowsiness or dizziness.
|H361 - Suspected of damaging fertility or the unborn
|child.
|H373 - May cause damage to organs through prolonged
|or repeated exposure.
Precautionary Statements |P201 - Obtain special instructions before use.
(GHS-US) |P202 - Do not handle until all safety precautions
|have been read and understood.
|P210 - Keep away from heat, hot surfaces, open
|flames, sparks. - No smoking.
|P233 - Keep container tightly closed.
|P240 - Ground/bond container and receiving
|equipment.
|P241 - Use explosion-proof electrical, lighting,
|ventilating equipment.
|P242 - Use only non-sparking tools.
|P243 - Take precautionary measures against static
|discharge.
|P260 - Do not breathe vapors, mist, spray
|P264 - Wash hands, forearms, and exposed areas
|thoroughly after handling.
|P271 - Use only outdoors or in a well-ventilated
|area.
|P280 - Wear eye protection, protective clothing,
|protective gloves.
|P303+P361+P353 - If on skin (or hair): Take off
|immediately all contaminated clothing. Rinse skin
|with water/shower.
|P304+P340 - IF INHALED: Remove person to fresh air
|and keep at rest in a position comfortable for
|breathing.
|P305+P351+P338 - IF IN EYES: Rinse cautiously with
|water for several minutes.
|Remove contact lenses, if present and easy to do.
|Continue rinsing.
|P308+P313 - If exposed or concerned: Get medical
|advice/attention.
|P312 - Call a poison center if you feel unwell.
|P337+P313 - If eye irritation persists: Get medical
|advice/attention.
|P370+P378 - In case of fire: Use dry chemical
|powder, alcohol-resistant foam, carbon dioxide (CO2)
|to extinguish.
|P403+P233 - Store in a well-ventilated place. Keep
|container tightly closed.
|P235+P405 - Keep cool. Store locked up.
|P501 - Dispose of contents/container according to
|local, regional, national, and international
|regulations.
2.3. Other Hazards
Other Hazards Not Contributing to the Classification: No additional information
available.
2.4. Unknown Acute Toxicity (GHS-US)
No data available.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
Name |Product identifier |% |Classification
| | |(GHS-US)
| | |
| | |
| | |
| | |
| | |
Full text of H-phrases: See Section 16
3.2. Mixture
Name |Product identifier |% |Classification
| | |(GHS-US)
Methyl ethyl ketone |(CAS No) 78-93-3 |44 |Flam. Liq. 2, H225
| | |
| | |Eye Irrit. 2A,
| | |H319
| | |STOT SE 3, H336
Acetone |(CAS No) 67-64-1 |34 |Flam. Liq. 2, H225
| | |
| | |Eye Irrit. 2A,
| | |H319
| | |STOT SE 3, H336
Proprietary Component |Proprietary |14.1 |Not classified
Toluene |(CAS No) 108-88-3 |7.9 |Flam. Liq. 2, H225
| | |
| | |Skin Irrit. 2,
| | |H315
| | |Repr. 2, H361
| | |STOT SE 3, H336
| | |STOT RE 2, H373
| | |Asp. Tox. 1, H304
| | |Aquatic Acute 2,
| | |H401
| | |Aquatic Chronic 3,
| | |H412
| | |
* The specific chemical identity and/or exact percentage (concentration) of
composition has been withheld as a trade secret.
SECTION 4: FIRST AID MEASURES
4.1. Description of First Aid Measures
First-aid Measures General: Never give anything by mouth to an unconscious person.
If you feel unwell, seek medical advice (show the label where possible).
First-aid Measures After Inhalation: Using proper respiratory protection,
immediately move the exposed person to fresh air. Assure fresh air breathing. Call
a physician if symptoms occur.
First-aid Measures After Skin Contact: Remove contaminated clothing. Gently wash
with plenty of soap and water followed by rinsing with water for at least 15
minutes. Call a POISON CENTER or doctor/physician if you feel unwell. Wash
contaminated clothing before reuse.
First-aid Measures After Eye Contact: Rinse cautiously with water for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Obtain medical attention.
First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting.
Immediately call a POISON CENTER or doctor/physician.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: Causes serious eye irritation. Vapors may cause drowsiness and
dizziness.
Symptoms/Injuries After Inhalation: High concentration of vapours may induce:
headache, dizziness, drowsiness, nausea and vomiting.
Symptoms/Injuries After Skin Contact: Repeated exposure may cause skin dryness or
cracking.
Symptoms/Injuries After Eye Contact: Causes serious eye irritation.
Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have
adverse effects.
Chronic Symptoms: May cause damage to organs through prolonged or repeated
exposure. May cause damage to central nervous system, liver, and kidneys.
Suspected of damaging fertility or the unborn child.
4.3. Indication of Any Immediate Medical Attention and Special Treatment
Needed
If exposed or concerned, get medical advice and attention.
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media: Dry chemical powder, alcohol-resistant foam, carbon
dioxide (CO2).
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy
stream of water may spread fire.
5.2. Special Hazards Arising From the Substance or Mixture
Fire Hazard: Highly flammable liquid and vapor.
Explosion Hazard: May form flammable/explosive vapor-air mixture. Heat may build
pressure, rupturing closed containers, spreading fire and increasing risk of burns
and injuries.
Reactivity: Reacts violently with oxidants causing fire and explosion hazard.
5.3. Advice for Firefighters
Precautionary Measures Fire: Exercise caution when fighting any chemical fire.
Firefighting Instructions: Use water spray or fog for cooling exposed containers.
Do not get water inside containers. Do not apply water stream directly at source
of leak. Fight fire from safe distance and protected location.
Protection During Firefighting: Do not enter fire area without proper protective
equipment, including respiratory protection.
Other Information: Refer to Section 9 for flammability properties.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Use special care to avoid static electric charges. Keep away
from heat/sparks/open flames/hot surfaces. - No smoking. Do not get in eyes, on
skin, or on clothing. Do not breathe vapour or mist.
6.1.1. For Non-emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
6.1.2. For Emergency Responders
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Ventilate area. Eliminate ignition sources. Stop leak if
safe to do so.
6.2. Environmental Precautions
Prevent entry to sewers and public waters.
6.3. Methods and Material for Containment and Cleaning Up
For Containment: Absorb and/or contain spill with inert material, then place in
suitable container. Do not take up in combustible material such as: saw dust or
cellulosic material.
Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely.
Use only non-sparking tools.
6.4. Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection. Concerning disposal
elimination after cleaning, see item 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Additional Hazards When Processed: Handle empty containers with care because
residual vapors are flammable.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety
procedures. Wash hands and other exposed areas with mild soap and water before
eating, drinking, or smoking and again when leaving work.
7.2. Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Proper grounding procedures to avoid static electricity should
be followed.
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container
closed when not in use. Keep in fireproof place.
Incompatible Products: Strong acids. Strong bases. Strong oxidizers.
7.3. Specific End Use(s)
No additional information available.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
Toluene (108-88-3)
USA ACGIH
ACGIH TWA (ppm)
20 ppm
USA NIOSH
NIOSH REL (TWA) (mg/m³)
375 mg/m³
USA NIOSH
NIOSH REL (TWA) (ppm)
100 ppm
USA NIOSH
NIOSH REL (STEL) (mg/m³)
560 mg/m³
USA NIOSH
NIOSH REL (STEL) (ppm)
150 ppm
USA IDLH
US IDLH (ppm)
500 ppm
USA OSHA
OSHA PEL (TWA) (ppm)
200 ppm
USA OSHA
OSHA PEL (Ceiling) (ppm)
300 ppm
Acetone (67-64-1)
USA ACGIH
ACGIH TWA (ppm)
500 ppm
USA ACGIH
ACGIH STEL (ppm)
750 ppm
USA NIOSH
NIOSH REL (TWA) (mg/m³)
590 mg/m³
USA NIOSH
NIOSH REL (TWA) (ppm)
250 ppm
USA IDLH
US IDLH (ppm)
2500 ppm (10% LEL)
USA OSHA
OSHA PEL (TWA) (mg/m³)
2400 mg/m³
USA OSHA
OSHA PEL (TWA) (ppm)
1000 ppm
Methyl ethyl ketone (78-93-3)
USA ACGIH
ACGIH TWA (ppm)
200 ppm
USA ACGIH
ACGIH STEL (ppm)
300 ppm
USA NIOSH
NIOSH REL (TWA) (mg/m³)
590 mg/m³
USA NIOSH
NIOSH REL (TWA) (ppm)
200 ppm
USA NIOSH
NIOSH REL (STEL) (mg/m³)
885 mg/m³
USA NIOSH
NIOSH REL (STEL) (ppm)
300 ppm
USA IDLH
US IDLH (ppm)
3000 ppm
USA OSHA
OSHA PEL (TWA) (mg/m³)
590 mg/m³
USA OSHA
OSHA PEL (TWA) (ppm)
200 ppm
8.2. Exposure Controls
Appropriate Engineering |Emergency eye wash fountains and safety showers
Controls |should be available in the immediate vicinity of any
|potential exposure. Gas detectors should be used
|when flammable gases/vapors may be released. Provide
|exhaust ventilation or other engineering controls to
|keep the airborne concentrations of vapor or mists
|below the applicable workplace exposure limits
|indicated above. All electrical equipment should
|comply with the National Electric Code. Ensure all
|national/local regulations are observed.
Personal Protective Equipment|Full protective flameproof clothing. Protective
|goggles. Gloves. Insufficient ventilation: wear
|respiratory protection.
|Other Information: When using, do not eat, drink or
|smoke.
Materials for Protective |Wear fire/flame resistant/retardant clothing.
Clothing |
Hand Protection |Wear chemically resistant protective gloves.
Eye Protection |Chemical goggles or safety glasses.
Skin and Body Protection |Wear suitable protective clothing.
Respiratory Protection |Use NIOSH-approved air-purifying or supplied-air
|respirator where airborne concentrations of vapor or
|mist are expected to exceed exposure limits.
Thermal Hazard Protection |
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
Physical State |Liquid
Appearance |Clear
Odor |Strong Aromatic Odor/sharp mint like
|fragrance
Odor Threshold |No data available
pH |No data available
Relative Evaporation Rate |No data available
(butylacetate=1) |
Melting Point |No data available
Freezing Point |No data available
Boiling Point |> 35 °C (95.00 °F)
Flash Point |-14 °C ASTM D-56 (6.80 °F)
Auto-ignition Temperature |No data available
Decomposition Temperature |No data available
Flammability (solid, gas) |No data available
Vapor Pressure |No data available
Relative Vapor Density at 20 °C |> 1 (heavier than air)
Relative Density |0.88 (water = 1)
Specific Gravity |
Solubility |Insoluble in water.
Partition coefficient: |No data available
n-octanol/water |
Viscosity |No data available
Lower Flammable Limit |1 %
Upper Flammable Limit |12 %
9.2. Other Information
VOC content: 51.9 % (3.59 lbs/gal or 430 g/l)
SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity
Reacts violently with oxidants causing fire and explosion hazard.
10.2 Chemical Stability
Stable under recommended handling and storage conditions (see section 7).
10.3 Possibility of Hazardous Reactions
Hazardous polymerization will not occur.
10.4 Conditions to Avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Ignition sources.
10.5 Incompatible Materials
Strong acids. Strong bases. Strong oxidizers.
10.6 Hazardous Decomposition Products
Carbon oxides (CO, CO2).
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects
Acute Toxicity: Not classified.
Skin Corrosion/Irritation: Not classified
Serious Eye Damage/Irritation: Causes serious eye irritation.
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Carcinogenicity: Not classified
Reproductive Toxicity: Suspected of damaging fertility or the unborn child.
Specific Target Organ Toxicity (Single Exposure): May cause drowsiness or
dizziness.
Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs
through prolonged or repeated exposure.
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: High concentration of vapours may induce:
headache, dizziness, drowsiness, nausea and vomiting.
Symptoms/Injuries After Skin Contact: Repeated exposure may cause skin dryness or
cracking.
Symptoms/Injuries After Eye Contact: Causes serious eye irritation.
Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have
adverse effects.
Chronic Symptoms: May cause damage to organs through prolonged or repeated
exposure. May cause damage to central nervous system, liver, and kidneys.
Suspected of damaging fertility or the unborn child.
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
Toluene (108-88-3)
LC50 Fish 1
15.22 - 19.05 mg/l (Exposure time: 96 h - Species: Pimephales promelas
[flow-through])
EC50 Daphnia 1
5.46 - 9.83 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
LC 50 Fish 2
12.6 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
EC50 Daphnia 2
11.5 mg/l (Exposure time: 48 h - Species: Daphnia magna)
NOEC chronic crustacea
0.74 mg/l (Ceriodaphnia dubia)
Acetone (67-64-1)
LC50 Fish 1
4144.846 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss)
EC50 Daphnia 1
1679.66 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])
LC 50 Fish 2
6210 (6210 - 8120) mg/l (Exposure time: 96 h - Species: Pimephales promelas
[static])
EC50 Daphnia 2
12600 (12600 - 12700) mg/l (Exposure time: 48 h - Species: Daphnia magna)
Methyl ethyl ketone (78-93-3)
LC50 Fish 1
3130 (3130 - 3320) mg/l (Exposure time: 96 h - Species: Pimephales promelas
[flow-through])
EC50 Daphnia 1
520 mg/l (Exposure time: 48 h - Species: Daphnia magna)
EC50 Daphnia 2
5091 mg/l (Exposure time: 48 h - Species: Daphnia magna)
12.2. Persistence and Degradability
Acetone (67-64-1)
Persistence and Degradability
Readily biodegradable in water.
12.3. Bioaccumulative Potential
Toluene (108-88-3)
Log Pow
2.65
Acetone (67-64-1)
BCF fish 1
0.69
Log Kow
-0.24
Methyl ethyl ketone (78-93-3)
Log Pow
0.29
12.4. Mobility in Soil
No additional information available
12.5. Other Adverse Effects
Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose of waste material in accordance with all
local, regional, national, and international regulations.
Additional Information: Handle empty containers with care because residual vapors
are flammable. RCRA Waste Number: D001.
SECTION 14: TRANSPORT INFORMATION
14.1 In Accordance with DOT
Proper Shipping Name |ADHESIVES containing a flammable liquid
Hazard Class |3 |[pic]
Identification Number|UN1133 |
Label Codes |3 |
ERG Number |128
14.2 In Accordance with IMDG
Proper Shipping Name |ADHESIVES
Hazard Class |3
Identification Number|UN1133
Label Codes |3 |[pic]
ntification Of The | |
Substance/m | |
EmS-No. (Fire) |F-E |
EmS-No. (Spillage) |S-D |
14.3 In Accordance with IATA
Proper Shipping Name |ADHESIVES
Identification Number|UN1133 |[pic]
Hazard Class |3 |
Label Codes |3 |
ntification Of The | |
Substance/m | |
ERG Code (IATA) |3L
SECTION 15: REGULATORY INFORMATION
15.1 US Federal Regulations
HH-66 Vinyl Cement
Toluene (108-88-3)
Listed on United States SARA Section 313
RQ (Reportable quantity, section 304 of EPA's List of Lists) :
1000 lb
SARA Section 313 - Emission Reporting
1.0 %
Methyl ethyl ketone (78-93-3)
SARA Section 311/312 Hazard Classes
Immediate (acute) health hazard
Fire hazard
SARA Section 311/312 Hazard Classes |Fire hazard
|Immediate (acute) health hazard
|Delayed (chronic) health hazard
|
|Methyl ethyl ketone (78-93-3)
|Immediate (acute) health hazard
|Fire hazard
Toxic Substances Control Act (TSCA) |Toluene (108-88-3)
|Listed on the United States TSCA (Toxic
|Substances Control Act) inventory
|
|Acetone (67-64-1)
|Listed on the United States TSCA (Toxic
|Substances Control Act) inventory
|
EPA TSCA Regulatory Flag |T - T - indicates a substance that is the
|subject of a Section 4 test rule under TSCA.
|
|Methyl ethyl ketone (78-93-3)
|Listed on the United States TSCA (Toxic
|Substances Control Act) inventory
|
|Proprietary Component
|Listed on the United States TSCA (Toxic
|Substances Control Act) inventory
15.2 US State Regulations
Toluene (108-88-3)
U.S. - California - Proposition 65 - Developmental Toxicity
WARNING: This product contains chemicals known to the State of California to cause
birth defects.
U.S. - California - Proposition 65 - Reproductive Toxicity - Female
WARNING: This product contains chemicals known to the State of California to cause
(Female) reproductive harm.
Toluene (108-88-3)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Acetone (67-64-1)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Methyl ethyl ketone (78-93-3)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision date |10/03/2014
Other |This document has been prepared in accordance with the SDS
Information |requirements of the OSHA Hazard Communication Standard 29 CFR
|1910.1200.Aquatic Acute 2
GHS Full Text Phrases:
----|Aquatic Acute 2 |Hazardous to the aquatic environment - Acute
-- | |Hazard Category 2
----|Aquatic Chronic 3 |Hazardous to the aquatic environment -
-- | |Chronic Hazard Category 3
----|Asp. Tox. 1 |Aspiration hazard Category 1
-- | |
----|Eye Irrit. 2A |Serious eye damage/eye irritation Category 2A
-- | |
----|Flam. Liq. 2 |Flammable liquids Category 2
-- | |
|Repr. 2 |Reproductive toxicity Category 2
|Skin Irrit. 2 |Skin corrosion/irritation Category 2
|STOT RE 2 |Specific target organ toxicity (repeated
| |exposure) Category 2
|STOT SE 3 |Specific target organ toxicity (single
| |exposure) Category 3
|H225 |Highly flammable liquid and vapor
|H304 |May be fatal if swallowed and enters airways
|H315 |Causes skin irritation
|H319 |Causes serious eye irritation
|H336 |May cause drowsiness or dizziness
|H361 |Suspected of damaging fertility or the unborn
| |child
|H373 |May cause damage to organs through prolonged
| |or repeated exposure
|H401 |Toxic to aquatic life
|H412 |Harmful to aquatic life with long lasting
| |effects
Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance. |