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SDS Sheet 0071750Printer Friendly View
SECTION 1: IDENTIFICATION | |1.1. Product Identifier Product Form: Product Name: ZEP PROF Z-FRESH BREEZE 1 CS 12 QTS CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company: Zep Inc. 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Phone: 404-352-1680 1.4. Emergency Telephone Number Emergency | CHEMTREC: 800-424-9300, 1-877-428-9937, 877-541-2016 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 3 liquid | Skin |Category 2 irritation | Eye irritation|Category 2A 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Exclamation Mark Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |H226 Flammable liquid and vapour. |H315 Causes skin irritation. |H319 Causes serious eye irritation. Precautionary Statements |Prevention: (GHS-US) |P210 Keep away from heat, hot surfaces, sparks, open |flames and other ignition sources. No smoking. |P233 Keep container tightly closed. |P240 Ground/bond container and receiving equipment. |P241 Use explosion-proof electrical/ ventilating/ |lighting/ equipment. |P242 Use only non-sparking tools. |P243 Take precautionary measures against static |discharge. |P264 Wash skin thoroughly after handling. |P280 Wear protective gloves/ eye protection/ face |protection. |Response: |P303 + P361 + P353 IF ON SKIN (or hair): Remove/ |Take off immediately all contaminated clothing. |Rinse skin with water/ shower. |P305 + P351 + P338 IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. |P332 + P313 If skin irritation occurs: Get medical |advice/ attention. |P337 + P313 If eye irritation persists: Get medical |advice/ attention. |P362 Take off contaminated clothing and wash before |reuse. |P370 + P378 In case of fire: Use dry sand, dry |chemical or alcohol-resistant foam for extinction. |Storage: |P403 + P235 Store in a well-ventilated place. Keep |cool. |Disposal: |P501 Dispose of contents/container in accordance |with local regulation. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Alcohol Ethoxylates |66455-15-0 |>= 5 - <| | |10 | ethanol |64-17-5 |>= 1 - <| | |5 | Allyl 3-cyclohexylpropionate |2705-87-5 |>= 1 - <| | |5 | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. First-aid Measures After Inhalation: If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. First-aid Measures After Skin Contact: If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. First-aid Measures After Eye Contact: Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. First-aid Measures After Ingestion: Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable Extinguishing Media: High volume water jet 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Hazardous combustion products Carbon dioxide (CO2) Carbon monoxide Smoke Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. Protection During Firefighting: Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid formation of aerosol. Do not breathe vapours/dust. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: No smoking. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid: Keep away from oxidising agents and strongly acid or alkaline materials. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis ethanol ethanol TWA 1,000 ppm ACGIH TWA 1,000 ppm 1,900 mg/m3 NIOSH REL TWA 1,000 ppm 1,900 mg/m3 OSHA Z-1 TWA 1,000 ppm 1,900 mg/m3 OSHA P0 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |The suitability for a specific workplace should be |discussed with the producers of the protective |gloves. Eye Protection |Eye wash bottle with pure water Tightly fitting |safety goggles Wear face-shield and protective suit |for abnormal processing problems. Skin and Body Protection |Impervious clothing Choose body protection |according to the amount and concentration of the |dangerous substance at the work place. Respiratory Protection | Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |liquid Odor |pleasant Odor Threshold |no data available pH |5 - 7 Relative Evaporation Rate |1 (butylacetate=1) | Melting Point |no data available Freezing Point |no data available Boiling Point |87.8 Â°C Flash Point |47.77 Â°C |Method: closed cup Auto-ignition Temperature |not determined Decomposition Temperature |no data available Flammability (solid, gas) | Vapor Pressure |no data available Relative Vapor Density at 20 Â°C |no data available Relative Density | Specific Gravity | Solubility |soluble in cold water, soluble in hot water Partition coefficient: |no data available n-octanol/water | Viscosity |Viscosity, kinematic |5 mm2/s (20 Â°C) Lower Flammable Limit |no data available Upper Flammable Limit |no data available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions Vapours may form explosive mixture with air. No decomposition if stored and applied as directed. 10.4 Conditions to Avoid Heat, flames and sparks. 10.5 Incompatible Materials Oxidizing agents 10.6 Hazardous Decomposition Products Carbon oxides SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Product: Remarks: May cause skin irritation in susceptible persons. Serious Eye Damage/Irritation: Product: Remarks: Moderate eye irritation Respiratory or Skin Sensitization:no data available Germ Cell Mutagenicity: no data available Carcinogenicity: no data available Reproductive Toxicity: no data available Specific Target Organ Toxicity (Single Exposure): no data available Specific Target Organ Toxicity (Repeated Exposure): no data available Aspiration Hazard: no data available Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Remarks: Solvents may degrease the skin. Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity no data available 12.2. Persistence and Degradability no data available 12.3. Bioaccumulative Potential Product: Partition coefficient: n-octanol/water: Remarks: no data available 12.4. Mobility in Soil no data available 12.5. Other Adverse Effects no data available Product: Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances. Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste from residues: Dispose of in accordance with local regulations. Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Additional Information: Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.k SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |FLAMMABLE LIQUID, N.O.S. |(ETHANOL) Hazard Class |3 Identification Number|UN1993 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-E | EmS-No. (Spillage) |S-E | 14.3 In Accordance with IATA Proper Shipping Name |Flammable liquid, n.o.s. |(ETHANOL) Identification Number|UN1993 |<PICTOGRAM PHRASE> Hazard Class |3 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA Section 311/312 Hazard Classes |Fire Hazard |Acute Health Hazard Toxic Substances Control Act (TSCA) |On TSCA Inventory 15.2 US State Regulations <COMPONENT> California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |10/10/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Hazard statements |Flammable liquid and vapour. -- | | ----| |Causes skin irritation. -- | | ----| |Causes serious eye irritation. -- | | ----|Precautionary statements |Keep away from heat, hot surfaces, sparks, -- |Prevention: |open flames and other ignition sources. ----| |No smoking. -- | | | |Keep container tightly closed. | |Ground/bond container and receiving | |equipment. | |Use explosion-proof electrical/ ventilating/ | |lighting/ equipment. | |Use only non-sparking tools. | |Take precautionary measures against static | |discharge. | |Wash skin thoroughly after handling. | |Wear protective gloves/ eye protection/ face | |protection. |Response: |IF ON SKIN (or hair): Remove/ Take off | |immediately all contaminated clothing. | |Rinse skin with water/ shower | |IF IN EYES: Rinse cautiously with water for | |several minutes. | |Remove contact lenses, if present and easy to | |do. Continue rinsing. | |If skin irritation occurs: Get medical | |advice/ attention. | |If eye irritation persists: Get medical | |advice/ attention. | |Take off contaminated clothing and wash | |before reuse. | |In case of fire: Use dry sand, dry chemical | |or alcohol-resistant foam for extinction. |Storage: |Store in a well-ventilated place. Keep cool. |Disposal: |Dispose of contents/container in accordance | |with local regulation. Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.