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Safety Data Sheet Date of Issue: 07/27/11 |Revision Date: |Revision Number: Imperial Supplies Part Number: 0071560 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: GLASS CLEANER R.T.U. CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Glass Cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company Zep Inc. 1310 Seaboard Industrial Blvd. Atlanta, GA 30318 Phone: 1-877-793-7776 1.4. Emergency Telephone Number Emergency |For MSDS Information: Compliance Services 1-877-793-7776, For number |Medical Emergency: (877) 541-2016 Toll Free - All Calls Recorded, |For Transportation Emergency: CHEMTREC: (800) 424-9300 - All Calls |Recorded |In the District of Columbia (202) 483-7616 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | Signal Word (GHS-US) | Hazard Statements (GHS-US) | Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) ETHANOL; ethyl alcohol; grain |64-17-5 |1 - 10 | alcohol | | | ETHYLENE GLYCOL MONOBUTYL ETHER;|111-76-2 |1 - 5 | 2-butoxyethanol; butyl | | | cellosolve | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Routes of Entry: Absorbed through skin. Eye contact. Inhalation. First-aid Measures After Inhalation: Move exposed person to fresh air. Get medical attention immediately. First-aid Measures After Skin Contact: Rinse with plenty of running water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Wash clothing before reuse. Get medical attention if irritation develops. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. First-aid Measures After Ingestion: Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If affected person is conscious, give plenty of water to drink. Get medical attention immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Avoid breathing vapors, spray or mists. Over-exposure by inhalation may cause respiratory irritation. Can cause central nervous system (CNS) depression. Symptoms/Injuries After Skin Contact: May cause skin irritation. May be harmul if absorbed through the skin. Skin inflammation is characterized by itching, scaling, or reddening. Symptoms/Injuries After Eye Contact: Causes eye irritation. Inflammation of the eye is characterized by redness, watering and itching. Symptoms/Injuries After Ingestion: May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. Chronic Symptoms: May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use dry chemical, CO2, water spray (fog) or foam. Fire-fighters should wear appropriate protective equipment. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Spill Clean up: Eliminate all ignition sources. Put on appropriate personal protective equipment (see section 8). Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Put on appropriate personal protective equipment (see section 8). Store and use away from heat, sparks, open flame or any other ignition source. Avoid contact with eyes, skin and clothing. Avoid breathing vapors, spray or mists. Use only with adequate ventilation. Do not ingest. Observe label precautions. Wash thoroughly after handling. Empty containers retain product residue and can be hazardous. Do not reuse container. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Keep out of the reach of children. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Product name Exposure limits ETHANOL; ethyl alcohol; grain alcohol NIOSH REL (United States, 6/2009). TWA: 1000 ppm 10 hour(s). TWA: 1900 mg/mÂ³ 10 hour(s). OSHA PEL (United States, 11/2006). TWA: 1000 ppm 8 hour(s). TWA: 1900 mg/mÂ³ 8 hour(s). ACGIH TLV (United States, 1/2009). STEL: 1000 ppm 15 minute(s). OSHA PEL 1989 (United States, 3/1989). TWA: 1000 ppm 8 hour(s). TWA: 1900 mg/mÂ³ 8 hour(s). ETHYLENE GLYCOL MONOBUTYL ETHER; 2-butoxyethanol; butyl cellosolve NIOSH REL (United States, 6/2009). Absorbed through skin. TWA: 5 ppm 10 hour(s). TWA: 24 mg/mÂ³ 10 hour(s). ACGIH TLV (United States, 1/2009). TWA: 20 ppm 8 hour(s). OSHA PEL (United States, 11/2006). Absorbed through skin. TWA: 50 ppm 8 hour(s). TWA: 240 mg/mÂ³ 8 hour(s). OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 25 ppm 8 hour(s). TWA: 120 mg/mÂ³ 8 hour(s). 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses. Skin and Body Protection |For prolonged or repeated handling, use gloves. |Recommended: Neoprene gloves. Nitrile gloves. Rubber |gloves. Respiratory Protection |Use with adequate ventilation. A respirator is not |needed under normal and |intended conditions of product use. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Pleasant. Odor Threshold | pH |10.5 - 11.5 Relative Evaporation Rate |1 (Water = 1) (butylacetate=1) | Melting Point | Freezing Point | Boiling Point |100Â°C (212Â°F) Flash Point |Closed cup: 67.8Â°C (154Â°F) [Tagliabue.] Auto-ignition Temperature | Decomposition Temperature | Flammability (solid, gas) | Vapor Pressure |Not determined. Relative Vapor Density at 20 Â°C |Not determined. Relative Density | Specific Gravity |0.99 Solubility |Easily soluble in the following materials: |cold water and hot water. Partition coefficient: | n-octanol/water | Viscosity | Lower Flammable Limit |Not determined. Upper Flammable Limit |Not determined. 9.2. Other Information VOC (Consumer): 39 (g/l). 0.33 lbs/gal (3.95%) SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable. 10.2 Chemical Stability The product is stable. 10.3 Possibility of Hazardous Reactions Hazardous Polymerization: Under normal conditions of storage and use, hazardous polymerization will not occur. 10.4 Conditions to Avoid 10.5 Incompatible Materials Keep away from heat, sparks and flame. Slightly reactive or incompatible with the following materials: oxidizing materials. 10.6 Hazardous Decomposition Products carbon oxides (CO, CO2). SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Product/ingredient name Result Species Dose Exposure Ethanol LC50 Inhalation Vapor LD50 Oral Rat Rat 20000 mg/mÂ³ 7 g/kg 4 hours - ethylene glycol monobutyl ether LC50 Inhalation Gas. LC50 Inhalation Vapor LD50 Dermal LD50 Dermal LD50 Oral LD50 Oral Rat Guinea pig Guinea pig Rabbit Guinea pig Rat 450 ppm >633 ppm >2000 mg/kg 220 mg/kg 1200 mg/kg 250 mg/kg 4 hours 1 hours - - - - Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Ingredients: Not listed as carcinogen by OSHA, NTP or IARC. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Environmental Effects: No known significant effects or critical hazards. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste Information: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities for additional information. Waste Stream: Non-hazardous waste Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not a DOT controlled material (United States). Hazard Class | |<PICTOGRAM PHRASE> Identification Number|Not applicable. | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number|Not determined. Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313 toxic chemical notification and release reporting: Product name No products were found. Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. United States inventory (TSCA 8b): All components are listed or exempted. SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |United States inventory (TSCA 8b): All |components are listed or exempted. 15.2 US State Regulations <COMPONENT> California Prop 65: No products were found. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.