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SDS Sheet 0071360Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: A00736 ZEP PRO CARB CLNR R19301 20n14 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Zep Inc. 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Phone: 404-352-1680 1.4. Emergency Telephone Number Emergency | 1-877-428-9937, 877-541-2016, 800-424-9300, 202-483-7616 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Gases under |Compressed gas pressure | Skin |Category 2 irritation | Eye irritation|Category 2A Reproductive |Category 2 toxicity | Specific |Category 3 target organ |(Central toxicity - |nervous single |system) exposure | Specific |Category 2 target organ | toxicity - | repeated | exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H222 Extremely flammable aerosol. |H280 Contains gas under pressure; may explode if |heated. |H315 Causes skin irritation. |H319 Causes serious eye irritation. |H336 May cause drowsiness or dizziness. |H361 Suspected of damaging fertility or the unborn |child. |H373 May cause damage to organs through prolonged or |repeated exposure if inhaled. Precautionary Statements |Prevention: (GHS-US) |P201 Obtain special instructions before use. |P202 Do not handle until all safety precautions have |been read and understood. |P210 Keep away from heat, hot surfaces, sparks, open |flames and other ignition sources. No smoking. |P211 Do not spray on an open flame or other ignition |source. |P251 Pressurized container: Do not pierce or burn, |even after use. |P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ |spray. |P264 Wash skin thoroughly after handling. |P271 Use only outdoors or in a well-ventilated area. | |P280 Wear eye protection/ face protection. |P280 Wear protective gloves. |P281 Use personal protective equipment as required. |Response: |P302 + P352 IF ON SKIN: Wash with plenty of soap and |water. |P304 + P340 + P312 IF INHALED: Remove victim to |fresh air and keep at rest in a position comfortable |for breathing. Call a POISON CENTER or doctor/ |physician if you feel unwell. |P305 + P351 + P338 IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. |P308 + P313 IF exposed or concerned: Get medical |advice/ attention. |P332 + P313 If skin irritation occurs: Get medical |advice/ attention. |P337 + P313 If eye irritation persists: Get medical |advice/ attention. |P362 Take off contaminated clothing and wash before |reuse. |Storage: |P405 Store locked up. |P410 + P412 Protect from sunlight. Do not expose to |temperatures exceeding 50 Â°C/ 122 Â°F. |Disposal: |P501 Dispose of contents/container in accordance |with local regulation. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Acetone |67-64-1 |>= 50 - | | |< 70 | Distillates (petroleum), |64742-47-8 |>= 20 - | hydrotreated light (Vapour and | |< 30 | gas) | | | Toluene |108-88-3 |>= 5 - <| | |10 | Carbon dioxide |124-38-9 |>= 5 - <| | |10 | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. First-aid Measures After Inhalation: Consult a physician after significant exposure. If unconscious place in recovery position and seek medical advice. First-aid Measures After Skin Contact: If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes. First-aid Measures After Eye Contact: Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If in eyes, rinse with water for 15 minutes. First-aid Measures After Ingestion: Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. DO NOT induce vomiting unless directed to do so by a physician or poison control center. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol-resistant foam, Carbon dioxide (CO2), Dry chemical. Unsuitable Extinguishing Media: High volume water jet. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Carbon dioxide (CO2), Carbon monoxide, Smoke Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Do not allow run-off from fire fighting to enter drains or water courses. Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. Protection During Firefighting: Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Sweep up or vacuum up spillage and collect in suitable container for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 Â°C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid: Do not store near acids. Strong oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Acetone 67-64-1 TWA STEL TWA TWA TWA STEL 500 ppm 750 ppm 250 ppm 590 mg/m3 1,000 ppm 2,400 mg/m3 750 ppm 1,800 mg/m3 1,000 ppm 2,400 mg/m3 ACGIH ACGIH NIOSH REL OSHA Z-1 OSHA P0 OSHA P0 Toluene 108-88-3 TWA TWA ST TWA CEIL Peak TWA STEL 20 ppm 100 ppm 375 mg/m3 150 ppm 560 mg/m3 200 ppm 300 ppm 500 ppm 100 ppm 375 mg/m3 150 ppm 560 mg/m3 ACGIH NIOSH REL NIOSH REL OSHA Z-2 OSHA Z-2 OSHA Z-2 OSHA P0 OSHA P0 Carbon dioxide 124-38-9 TWA STEL TWA ST TWA TWA STEL 5,000 ppm 30,000 ppm 5,000 ppm 9,000 mg/m3 30,000 ppm 54,000 mg/m3 5,000 ppm 9,000 mg/m3 10,000 ppm 18,000 mg/m3 30,000 ppm 54,000 mg/m3 ACGIH ACGIH NIOSH REL NIOSH REL OSHA Z-1 OSHA P0 OSHA P0 Biological occupational exposure limits: Component CAS-No. Control parameters Biological specimen Sampling time Permissible concentration Basis 2-PROPANONE 67-64-1 Acetone Urine End of shift (As soon as possible after exposure ceases) 50 mg/l ACGIH BEI METHYLBENZENE 108-88-3 Toluene In blood Prior to last shift of workweek 0.02 mg/l ACGIH BEI METHYLBENZENE Toluene Urine End of shift (As soon as possible after exposure ceases) 0.03 mg/l ACGIH BEI METHYLBENZENE o-Cresol Urine End of shift (As soon as possible after exposure ceases) 0.3 mg/g ACGIH BEI Remarks: Creatinine 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Remarks: The suitability for a specific workplace |should be discussed with the producers of the |protective gloves. Eye Protection |Safety glasses. Skin and Body Protection |Impervious clothing Choose body protection according |to the amount and concentration of the dangerous |substance at the work place. Respiratory Protection |In case of insufficient ventilation, wear suitable |respiratory equipment. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Aerosol containing a compressed gas Odor |Solvent-like Odor Threshold | pH |Not applicable Relative Evaporation Rate |No data available (butylacetate=1) | Melting Point |No data available Freezing Point |No data available Boiling Point |No data available Flash Point |No data available Auto-ignition Temperature |Not determined Decomposition Temperature |No data available Flammability (solid, gas) |Extremely flammable aerosol. Vapor Pressure |No data available Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity | Solubility |partly soluble Partition coefficient: |No data available n-octanol/water | Viscosity |No data available Lower Flammable Limit |No data available Upper Flammable Limit |No data available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions Vapours may form explosive mixture with air. 10.4 Conditions to Avoid Heat, flames and sparks. 10.5 Incompatible Materials Acids, Strong oxidizing agents 10.6 Hazardous Decomposition Products Carbon oxides SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: no data available Skin Corrosion/Irritation: Remarks: Irritating to skin. Serious Eye Damage/Irritation: Remarks: Severe eye irritation Respiratory or Skin Sensitization: No data available Germ Cell Mutagenicity: No data available Carcinogenicity: No data available Reproductive Toxicity: no data available Specific Target Organ Toxicity (Single Exposure): no data available Specific Target Organ Toxicity (Repeated Exposure): no data available Aspiration Hazard: No data available Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity no data available 12.2. Persistence and Degradability no data available 12.3. Bioaccumulative Potential Product: Partition coefficient: n-octanol/water: Remarks: no data available Components: Toluene : Partition coefficient: n-octanol/water: Pow: 2.73 12.4. Mobility in Soil No data available 12.5. Other Adverse Effects No data available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company.. Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. Additional Information: Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Vessel: AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Cargo Air: Aerosols |Passenger Air: Aerosols Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> EPCRA - Emergency Planning and Community Right-to-Know Act: CERCLA Reportable Quantity: Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Acetone 67-64-1 5000 * SARA 304 Extremely Hazardous Substances Reportable Quantity: This material does not contain any components with a section 304 EHS RQ. SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313:The following components are subject to reporting levels established by SARA Title III, Section 313: Toluene 108-88-3 9.975 % SARA Section 311/312 Hazard Classes |Fire Hazard |Sudden Release of Pressure Hazard |Acute Health Hazard |Chronic Health Hazard Toxic Substances Control Act (TSCA) |On TSCA Inventory 15.2 US State Regulations <COMPONENT> California Prop 65: WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |02/12/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Hazard statements |Extremely flammable aerosol. Contains gas -- | |under pressure; may explode if heated. Causes | |skin irritation. Causes serious eye | |irritation. May cause drowsiness or | |dizziness. Suspected of damaging fertility or | |the unborn child. May cause damage to organs | |through prolonged or repeated exposure if | |inhaled. ----|Precautionary statements |Prevention: Obtain special instructions -- | |before use. Do not handle until all safety | |precautions have been read and understood. | |Keep away from heat, hot surfaces, sparks, | |open flames and other ignition sources. No | |smoking. Do not spray on an open flame or | |other ignition source. Pressurized container: | |Do not pierce or burn, even after use. Do not | |breathe dust/ fume/ gas/ mist/ vapours/ | |spray. Wash skin thoroughly after handling. | |Use only outdoors or in a well-ventilated | |area. Wear eye protection/ face protection. | |Wear protective gloves. Use personal | |protective equipment as required. ----| |Response: IF ON SKIN: Wash with plenty of -- | |soap and water. IF INHALED: Remove victim to | |fresh air and keep at rest in a position | |comfortable for breathing. Call a POISON | |CENTER or doctor/ physician if you feel | |unwell. IF IN EYES: Rinse cautiously with | |water for several minutes. Remove contact | |lenses, if present and easy to do. Continue | |rinsing. IF exposed or concerned: Get medical | |advice/ attention. If skin irritation occurs: | |Get medical advice/ attention. If eye | |irritation persists: Get medical advice/ | |attention. Take off contaminated clothing and | |wash before reuse. ----| |Storage: Store locked up. Protect from -- | |sunlight. Do not expose to temperatures | |exceeding 50 Â°C/ 122 Â°F. ----| |Disposal: Dispose of contents/container in -- | |accordance with local regulation. Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.