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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: A07311 ZEP PRO NF SLVT DGRS R12201 20N20 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Zep Inc. 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Phone: 404-352-1680 1.4. Emergency Telephone Number Emergency |1-877-428-9937, 877-541-2016, 800-424-9300, 202-483-7616 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Gases under |Compressed gas pressure | Skin |Category 2 irritation | Eye irritation|Category 2A Carcinogenicit|Category 1A y | Specific |Category 3 target organ |(Central toxicity - |nervous single |system) exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas Cylinder |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H280 Contains gas under pressure; may explode if |heated. |H315 Causes skin irritation. |H319 Causes serious eye irritation. |H336 May cause drowsiness or dizziness. |H350 May cause cancer. Precautionary Statements |Prevention (GHS-US) |P201 Obtain special instructions before use. |P202 Do not handle until all safety precautions have |been read and understood. |P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ |spray. |P264 Wash skin thoroughly after handling. |P271 Use only outdoors or in a well-ventilated area. | |P280 Wear eye protection/ face protection. |P280 Wear protective gloves. |P281 Use personal protective equipment as required. |Response |P302 + P352 IF ON SKIN: Wash with plenty of soap and |water. |P304 + P340 + P312 IF INHALED: Remove victim to |fresh air and keep at rest in a position comfortable |for breathing. Call a POISON CENTER or doctor/ |physician if you feel unwell. |P305 + P351 + P338 IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. |P308 + P313 IF exposed or concerned: Get medical |advice/ attention. |P332 + P313 If skin irritation occurs: Get medical |advice/ attention. |P337 + P313 If eye irritation persists: Get medical |advice/ attention. |P362 Take off contaminated clothing and wash before |reuse. |Storage |P405 Store locked up. |P410 + P403 Protect from sunlight. Store in a |well-ventilated place. |Disposal |P501 Dispose of contents/container in accordance |with local regulation. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) trichloroethylene |79-01-6 |>= 90 - | | |<= 100 | carbon dioxide |124-38-9 |>= 1 - <| | |5 | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. First-aid Measures After Inhalation: Remove person to fresh air. If signs/symptoms continue, get medical attention. First-aid Measures After Skin Contact: If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes. First-aid Measures After Eye Contact: Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. Rinse immediately with plenty of water for at least 15 minutes. First-aid Measures After Ingestion: DO NOT induce vomiting unless directed to do so by a physician or poison control center. Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Dry chemical Water spray jet Alcohol-resistant foam Carbon dioxide (CO2). Hazardous combustion products: Carbon dioxide (CO2) Carbon monoxide Smoke Chlorine compounds. Unsuitable Extinguishing Media: High volume water jet. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Do not allow run-off from fire fighting to enter drains or water courses. Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Prevent fire extinguishing water from contaminating surface water or the ground water system. For safety reasons in case of fire, cans should be stored separately in closed containments. Protection During Firefighting: Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment. Ensure adequate ventilation. Refer to protective measures listed in sections 7 and 8. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Evacuate personnel to safe areas. Remove all sources of ignition. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent further leakage or spillage. Clean contaminated floors and objects thoroughly while observing environmental regulations. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Always replace cap after use. Dispose of rinse water in accordance with local and national regulations. Do not breathe vapours or spray mist. Take precautionary measures against static discharges. Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 Â°C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Observe label precautions. Keep in a dry, cool and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. No smoking. Materials to avoid: Oxidizing agents, Keep away from metals. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis trichloroethylene 79-01-6 TWA 10 ppm ACGIH STEL 25 ppm ACGIH TWA 100 ppm OSHA Z-2 CEIL 200 ppm OSHA Z-2 Peak 300 ppm OSHA Z-2 TWA 50 ppm 270 mg/m3 OSHA P0 STEL 200 ppm 1,080 mg/m3 OSHA P0 carbon dioxide 124-38-9 TWA 5,000 ppm ACGIH STEL 30,000 ppm ACGIH TWA 5,000 ppm 9,000 mg/m3 NIOSH REL ST 30,000 ppm 54,000 mg/m3 NIOSH REL TWA 5,000 ppm 9,000 mg/m3 OSHA Z-1 TWA 10,000 ppm 18,000 mg/m3 OSHA P0 STEL 30,000 ppm 54,000 mg/m3 OSHA P0 Biological occupational exposure limits: Component CAS-No. Control parameters Biological specimen Sampling time Permissible concentration Basis TRICHLOROETHENE 79-01-6 Trichloroacetic acid Urine End of shift at end of workweek 15 mg/l ACGIH BEI TRICHLOROETHENE Trichloroethanol In blood End of shift at end of workweek 0.5 mg/l ACGIH BEI TRICHLOROETHENE Trichloroethylene In blood End of shift at end of workweek ACGIH BEI TRICHLOROETHENE Trichloroethylene In end-exhaled air End of shift at end of workweek ACGIH BEI 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |The suitability for a specific workplace should be |discussed with the producers of the protective |gloves. Eye Protection |Ensure that eyewash stations and safety showers are |close to the workstation location. Tightly fitting |safety goggles. Skin and Body Protection |Impervious clothing. Choose body protection |according to the amount and concentration of the |dangerous substance at the work place. Respiratory Protection |Use respiratory protection unless adequate local |exhaust ventilation is provided or exposure |assessment demonstrates that exposures are within |recommended exposure guidelines. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Aerosol containing a compressed gas Odor |mild Odor Threshold |no data available pH |not applicable Relative Evaporation Rate |< 1 (butylacetate=1) | Melting Point |no data available Freezing Point |no data available Boiling Point |87.22 Â°C Flash Point |not applicable Auto-ignition Temperature |not determined Decomposition Temperature | Flammability (solid, gas) |The product is not flammable. Vapor Pressure |not applicable Relative Vapor Density at 20 Â°C |no data available Relative Density | Specific Gravity | Solubility |insoluble Partition coefficient: |no data available n-octanol/water | Viscosity |no data available Lower Flammable Limit |not applicable Upper Flammable Limit |not applicable 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable. 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions Vapours may form explosive mixture with air. No decomposition if stored and applied as directed. 10.4 Conditions to Avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Oxidizing agents. Light and/or alkaline metals 10.6 Hazardous Decomposition Products Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). Phosgene, Hydrogen chloride gas. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Product: Remarks: May cause skin irritation in susceptible persons. Serious Eye Damage/Irritation: Product: Remarks: Eye irritation. Respiratory or Skin Sensitization: no data available. Germ Cell Mutagenicity: no data available. Carcinogenicity: no data available. Reproductive Toxicity: no data available trichloroethylene: carbon dioxide: Specific Target Organ Toxicity (Single Exposure): no data available. Specific Target Organ Toxicity (Repeated Exposure): no data available. Aspiration Hazard: no data available. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity no data available. 12.2. Persistence and Degradability no data available. 12.3. Bioaccumulative Potential Product: Partition coefficient: n-octanol/water : Remarks: no data available Components: trichloroethylene : Partition coefficient: n-octanol/water : log Pow: 2.29 12.4. Mobility in Soil no data available. 12.5. Other Adverse Effects no data available. Product: Regulation :40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances. Remarks :This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations. Additional Information: Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, NON-FLAMMABLE Hazard Class |2.2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Cargo Air: AEROSOLS, NON-FLAMMABLE |Passenger Air: AEROSOLS, NON-FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.2 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations EPCRA - Emergency Planning and Community Right-to-Know Act: CERCLA Reportable Quantity: Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Trichloroethylene 79-01-6 100 103 SARA 304 Extremely Hazardous Substances Reportable Quantity: This material does not contain any components with a section 304 EHS RQ. SARA 302: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313: The following components are subject to reporting levels established by SARA Title III, Section 313: Trichloroethylene 79-01-6 96.83 % SARA Section 311/312 Hazard Classes |Acute Health Hazard |Chronic Health Hazard |Sudden Release of Pressure Hazard Toxic Substances Control Act (TSCA) |On TSCA Inventory 15.2 US State Regulations California Prop 65: WARNING! This product contains a chemical known to the State of California to cause cancer. Trichloroethylene 79-01-6 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |03/13/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Hazard statements |Contains gas under pressure; may explode if -- | |heated. Causes skin irritation. Causes | |serious eye irritation. May cause drowsiness | |or dizziness. May cause cancer. ----|Precautionary statements |Prevention -- | |Obtain special instructions before use. Do | |not handle until all safety precautions have | |been read and understood. Avoid breathing | |dust/ fume/ gas/ mist/ vapours/ spray. Wash | |skin thoroughly after handling. Use only | |outdoors or in a well-ventilated area. Wear | |eye protection/ face protection. Wear | |protective gloves. Use personal protective | |equipment as required. | |Response | |IF ON SKIN: Wash with plenty of soap and | |water. IF INHALED: Remove victim to fresh air | |and keep at rest in a position comfortable | |for breathing. Call a POISON CENTER or | |doctor/ physician if you feel unwell. IF IN | |EYES: Rinse cautiously with water for several | |minutes. Remove contact lenses, if present | |and easy to do. Continue rinsing. IF exposed | |or concerned: Get medical advice/ attention. | |If skin irritation occurs: Get medical | |advice/ attention. If eye irritation | |persists: Get medical advice/ attention. Take | |off contaminated clothing and wash before | |reuse. | |Storage | |Store locked up. Protect from sunlight. Store | |in a well-ventilated place. | |Disposal | |Dispose of contents/container in accordance | |with local regulation. ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.