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SDS Sheet 0067820Printer Friendly View
Safety Data Sheet Date of Issue: 02/23/16 |Revision Date: |Revision Number: 17.00 Imperial Supplies Part Number: 0067820 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Scotchgard Fabric Protector (Cat. No. 4101, 4106) CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Oil, water and stain repellent for fabrics in consumer market 1.3. Name, Address, and Telephone of the Responsible Party Company: 3M DIVISION: Home Care Division 3M Center, St. Paul, MN 55144-1000, USA Phone: 1-888-3M HELPS (1-888-364-3577) Supplier: Imperial Supplies LLC 1.4. Emergency Telephone Number Emergency | 1-800-364-3577 or (651) 737-6501 (24 hours) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1. Aerosol | Gas Under |Liquefied gas. Pressure | Simple | Asphyxiant. | Specific |Category 3. Target Organ | Toxicity | (central | nervous | system) | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas |Exclamat| | | | |cylinder|ion mark| | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. |Contains gas under pressure; may explode if heated. |May cause drowsiness or dizziness. |May displace oxygen and cause rapid suffocation. Precautionary Statements |Prevention: (GHS-US) |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. |Do not spray on an open flame or other ignition |source. |Pressurized container: Do not pierce or burn, even |after use. |Avoid breathing dust/fume/gas/mist/vapors/spray. |Use only outdoors or in a well-ventilated area. |Response: |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician if you feel |unwell. |Storage: |Protect from sunlight. Do not expose to temperatures |exceeding 50C/122F. |Store in a well-ventilated place. Keep container |tightly closed. |Store locked up. |Disposal: |Dispose of contents/container in accordance with |applicable local/regional/national/international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. 26% of the mixture consists of ingredients of unknown acute oral toxicity. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Acetone |67-64-1 |37 - 41 | | |Trade | | |Secret *| Isopropyl Alcohol |67-63-0 |31 - 35 | | |Trade | | |Secret *| Light Alkylate Petroleum Naphtha|64741-66-8 |17 - 21 | | |Trade | | |Secret *| Carbon Dioxide |124-38-9 |2 - 6 | Fluorochemical Urethane |Trade Secret* |< 3 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. First-aid Measures After Skin Contact:Wash with soap and water. If signs/symptoms develop, get medical attention. First-aid Measures After Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. First-aid Measures After Ingestion: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Not applicable SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use a fire fighting agent suitable for the surrounding fire. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Closed containers exposed to heat from fire may build pressure and explode. Exposure to extreme heat can give rise to thermal decomposition. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Do not breathe thermal decomposition products. Do not use in a confined area with minimal air exchange. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Vapors may travel long distances along the ground or floor to an ignition source and flash back. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Carbon Dioxide 124-38-9 ACGIH TWA:5000 ppm; STEL:30000 ppm Carbon Dioxide 124-38-9 OSHA TWA:9000 mg/m3 (5000 ppm) Isopropyl Alcohol 67-63-0 ACGIH TWA:200 ppm; STEL:400 ppm A4: Not class. as human carcin Isopropyl Alcohol 67-63-0 OSHA TWA:980 mg/m3(400 ppm) A4: Not class. as human carcin Acetone 67-64-1 ACGIH TWA:250 ppm; STEL:500 ppm Acetone 67-64-1 OSHA TWA:2400 mg/m3 (1000 ppm) 8.2. Exposure Controls Appropriate Engineering |Curing enclosures must be exhausted to outdoors or Controls |to a suitable emission control device. Provide |appropriate local exhaust when product is heated. Do |not remain in area where available oxygen may be |reduced. Use general dilution ventilation and/or |local exhaust ventilation to control airborne |exposures to below relevant Exposure Limits and/or |control dust/fume/gas/mist/vapors/spray. If |ventilation is not adequate, use respiratory |protection equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Select and use eye/face protection to prevent |contact based on the results of an exposure |assessment. The following eye/face protection(s) are |recommended: Indirect Vented Goggles. Skin and Body Protection |Select and use gloves and/or protective clothing |approved to relevant local standards to prevent skin |contact based on the results of an exposure |assessment. Selection should be based on use factors |such as exposure levels, concentration of the |substance or mixture, frequency and duration, |physical challenges such as temperature extremes, |and other use conditions. Consult with your glove |and/or protective clothing manufacturer for |selection of appropriate compatible |gloves/protective Clothing. Gloves made from the |following material(s) are recommended: Butyl Rubber. Respiratory Protection |An exposure assessment may be needed to decide if a |respirator is required. If a respirator is needed, |use respirators as part of a full respiratory |protection program. Based on the results of the |exposure assessment, select from the following |respirator type(s) to reduce inhalation exposure: |During heating: Use a positive pressure supplied-air |respirator if there is a potential for over exposure |from an uncontrolled release, exposure levels are |not known, or under any other circumstances where |air-purifying respirators may not provide adequate |protection. Half facepiece or full facepiece |air-purifying respirator suitable for organic vapors |and particulates. For questions about suitability |for a specific application, consult with your |respirator manufacturer. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Aerosol Odor |Liquid with chemical odor, contents under |pressure. Odor Threshold |No Data Available pH |No Data Available Relative Evaporation Rate |No Data Available (butylacetate=1) | Melting Point |No Data Available Freezing Point | Boiling Point |>=134 Deg F Flash Point |-2 Deg F [Test Method: Closed Cup] Auto-ignition Temperature |> 700 Deg F [Details: For liquid only] Decomposition Temperature |No Data Available Flammability (solid, gas) |Not Applicable Vapor Pressure |<=187 mmHg [@ 20 ÂºC] Relative Vapor Density at 20 Â°C |No Data Available Relative Density |No Data Available Specific Gravity |0.8 [Ref Std: WATER=1] [Details: (Liquid fill |only)] Solubility |No Data Available Partition coefficient: |No Data Available n-octanol/water | Viscosity |No Data Available Lower Flammable Limit |0.9% Upper Flammable Limit |12.7% 9.2. Other Information Volatile Organic Compounds Approximately 54 % weight Percent volatile Approximately 93.2 % weight SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity This material is considered to be non reactive under normal use conditions. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Heat 10.5 Incompatible Materials None known. 10.6 Hazardous Decomposition Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Fluoride During Combustion Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition product. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: For the component/components, either no data are currently available or the data are not sufficient for classification. Symptoms/Injuries After Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Symptoms/Injuries After Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Symptoms/Injuries After Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Symptoms/Injuries After Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Additional Information: EPA Hazardous Waste Number (RCRA): D001 (Ignitable) SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This material contains one or more substances that are subject to a TSCA Consent Order. Contact 3M for more information. SARA Section 311/312 Hazard Classes |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No |Immediate Hazard - Yes |Delayed Hazard - No Toxic Substances Control Act (TSCA) |Ingredient (Category if applicable) |C.A.S. No |Regulation |Status | |Fluorochemical Urethane |Trade Secret |Toxic Substances Control Act (TSCA) 5 |SNUR or Consent Order Chemicals |Applicable | |The components of this product are in |compliance with the chemical notification |requirements of TSCA. 15.2 US State Regulations <COMPONENT> Contact 3M for more information. Chemical Inventories: The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.