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SDS Sheet 0067810

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Safety Data Sheet | |
Date of Issue: 12/04/14    |Revision Date:             |Revision Number: 4.00     
Imperial Supplies Part Number: 0067810                                            

SECTION 1: IDENTIFICATION                                                         

1.1.  Product Identifier
Product Form:                                                                     
Product Name: 3M(TM) High Power Brake Cleaner; PN 08180                           
CAS No:                                                                           

1.2.  Intended Use of the Product
Use of the substance/mixture: Automotive, Cleaner for automotive brakes and brake 

1.3.  Name, Address, and Telephone of the Responsible Party
Company Name: 3M                                                                  
Automotive Aftermarket                                                            
3M Center                                                                         
St. Paul MN                                                                       
Phone: 1-888-3M HELPS (1-888-364-3577)                                            
Supplier: Imperial Supplies LLC                                                   

1.4.  Emergency Telephone Number
Emergency     |1-800-364-3577 or (651) 737-6501 (24 hours)                        
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 

2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flammable     |Category 1    
Aerosol       |              
Serious Eye   |Category 2A.  
ion           |              
Skin          |Category 2.   
tation        |              
Aspiration    |Category 1.   
Hazard        |              
Carcinogenicit|Category 2.   
y             |              
Specific      |Category 1.   
Target Organ  |              
Toxicity      |              
(single       |              
exposure)     |              
Specific      |Category 3.   
Target Organ  |              
Toxicity      |              
(central      |              
nervous       |              
system):      |              
Specific      |Category 1.   
Target Organ  |              
Toxicity      |              
(repeated     |              
exposure):    |              

2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame   |Exclamat|Health  |        |        |        
                             |        |ion mark|hazard  |        |        |        
Signal Word (GHS-US)         |Danger                                              
Hazard Statements (GHS-US)   |Extremely flammable aerosol.                        
                             |Causes serious eye irritation.                      
                             |Causes skin irritation.                             
                             |May be fatal if swallowed and enters airways.       
                             |May cause drowsiness or dizziness.                  
                             |Suspected of causing cancer.                        
                             |May be fatal if swallowed and enters airways.       
                             |May cause drowsiness or dizziness.                  
                             |Suspected of causing cancer.                        
                             |Causes damage to organs through prolonged or        
                             |repeated exposure:                                  
                             |nervous system                                      
                             |May cause damage to organs through prolonged or     
                             |repeated exposure:                                  
                             |sensory organs                                      
Precautionary Statements     |General:                                            
(GHS-US)                     |Keep out of reach of children.                      
                             |Obtain special instructions before use.             
                             |Do not handle until all safety precautions have been
                             |read and understood.                                
                             |Keep away from heat/sparks/open flames/hot surfaces.
                             |- No smoking.                                       
                             |Do not spray on an open flame or other ignition     
                             |Pressurized container: Do not pierce or burn, even  
                             |after use.                                          
                             |Do not breathe dust/fume/gas/mist/vapors/spray.     
                             |Use only outdoors or in a well-ventilated area.     
                             |Wear protective gloves and eye/face protection.     
                             |Do not eat, drink or smoke when using this product. 
                             |Wash thoroughly after handling.                     
                             |IF INHALED: Remove person to fresh air and keep     
                             |comfortable for breathing.                          
                             |IF IN EYES: Rinse cautiously with water for several 
                             |minutes. Remove contact lenses, if present and easy 
                             |to do.                                              
                             |Continue rinsing.                                   
                             |If eye irritation persists: Get medical             
                             |IF ON SKIN: Wash with plenty of soap and water.     
                             |If skin irritation occurs: Get medical              
                             |Take off contaminated clothing and wash it before   
                             |Do NOT induce vomiting.                             
                             |IF SWALLOWED: Immediately call a POISON CENTER or   
                             |Specific treatment (see Notes to Physician on this  
                             |Call a POISON CENTER or doctor/physician if you feel
                             |Protect from sunlight. Do not expose to temperatures
                             |exceeding 50C/122F.                                 
                             |Store in a well-ventilated place. Keep container    
                             |tightly closed.                                     
                             |Store locked up.                                    
                             |Dispose of contents/container in accordance with    
                             |applicable local/regional/national/international    

2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                             

2.4.  Unknown Acute Toxicity (GHS-US)
10% of the mixture consists of ingredients of unknown acute oral toxicity.        
10% of the mixture consists of ingredients of unknown acute dermal toxicity.      
10% of the mixture consists of ingredients of unknown acute inhalation toxicity.  


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  

Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
Acetone                         |67-64-1              |40 - 60 |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Solvent Naphtha (Petroleum),    |64742-89-8           |15 - 30 |                  
Light Aliphatic                 |                     |Trade   |                  
                                |                     |Secret *|                  
Propane                         |74-98-6              |7 - 13  |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Xylene                          |1330-20-7            |5 - 10  |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
Ethylbenzene                    |100-41-4             |0 - 3   |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  

*The specific chemical identity and/or exact percentage (concentration) of
this composition has been withheld as a trade
SECTION 4: FIRST AID MEASURES                                                     

4.1.  Description of First Aid Measures
First-aid Measures General:                                                       
First-aid Measures After Inhalation: Remove person to fresh air. Get medical      
First-aid Measures After Skin Contact:  Immediately wash with soap and water.     
Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.                                                                
First-aid Measures After Eye Contact: Immediately flush with large amounts of     
water for at least 15 minutes. Remove contact lenses if easy to do. Continue      
rinsing. Immediately get medical attention.                                       
First-aid Measures After Ingestion: If Swallowed: Do not induce vomiting. Get     
immediate medical attention.                                                      

4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: See Section 11.1. Information on toxicological effects.        
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 

4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Exposure may increase myocardial irritability. Do not administer sympathomimetic  
drugs unless absolutely necessary.                                                

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use a fire fighting agent suitable for the          
surrounding fire.                                                                 
Unsuitable Extinguishing Media:                                                   

5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Closed containers exposed to heat from fire may build pressure and   
Explosion Hazard:                                                                 

5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions: Water may not effectively extinguish fire; however, it 
should be used to keep fire-exposed containers and surfaces cool and prevent      
explosive rupture.                                                                
Protection During Firefighting:                                                   

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            

6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Keep away from heat/sparks/open flames/hot surfaces. - No       
smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to 
other sections of this SDS for information regarding physical and health hazards, 
respiratory protection, ventilation, and personal protective equipment.           

6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             

6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             

6.2.  Environmental Precautions
Avoid release to the environment. For larger spills, cover drains and build dikes 
to prevent entry into sewer systems or bodies of water.                           

6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                  
Methods for Cleaning Up:  If possible, seal leaking container. Place leaking      
containers in a well-ventilated area, preferably an operating exhaust hood, or if 
necessary outdoors on an impermeable surface until appropriate packaging for the  
leaking container or its contents is available. Contain spill. Cover spill area   
with a fire-extinguishing foam designed for use on solvents, such as alcohols and 
acetone, that can dissolve in water. An AR - AFFF type foam is recommended.       
Working from around the edges of the spill inward, cover with bentonite,          
vermiculite, or commercially available inorganic absorbent material. Mix in       
sufficient absorbent until it appears dry. Remember, adding an absorbent material 
does not remove a physical, health, or environmental hazard. Collect as much of   
the spilled material as possible using non-sparking tools. Place in a metal       
container approved for transportation by appropriate authorities. Clean up residue
with detergent and water. Seal the container. Dispose of collected material as    
soon as possible.                                                                 

6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        

SECTION 7: HANDLING AND STORAGE                                                   

7.1.  Precautions for Safe Handling
Additional Hazards When Processed:  Do not use in a confined area with minimal air
exchange. Keep out of reach of children. Do not handle until all safety           
precautions have been read and understood. Keep away from heat/sparks/open        
flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition
source. Do not pierce or burn, even after use. Do not breathe                     
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do  
not eat, drink or smoke when using this                                           
product. Wash thoroughly after handling. Avoid release to the environment. Avoid  
contact with oxidizing agents (eg.                                                
chlorine, chromic acid etc.) Use personal protective equipment (gloves,           
respirators, etc.) as required.                                                   
Hygiene Measures:                                                                 

7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Store in a well-ventilated place. Keep container tightly      
closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F.  
Store away from heat. Store away from acids. Store away from oxidizing agents.    
Storage Conditions:                                                               

7.3.  Specific End Use(s)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  

8.1.  Control Parameters
If a component is disclosed in section 3 but does not appear in the table below,  
an occupational exposure limit is not available                                   
for the component.                                                                
C.A.S. No.                                                                        
Limit type                                                                        
Additional Comments                                                               
TWA:20 ppm                                                                        
A3: Confirmed animal carcin.                                                      
TWA:435 mg/m3(100 ppm)                                                            
TWA:25 ppm;STEL:75 ppm                                                            
TWA:435 mg/m3(100 ppm)                                                            
TWA:100 ppm;STEL:150 ppm                                                          
A4: Not class. as human                                                           
TWA:50 ppm;STEL:75 ppm                                                            
Solvent Naphtha (Petroleum),                                                      
Light Aliphatic                                                                   
TWA:300 ppm                                                                       
TWA:500 ppm;STEL:750 ppm                                                          
A4: Not class. as human                                                           
TWA:2400 mg/m3(1000 ppm)                                                          
Limit value not established:                                                      
TWA:1800 mg/m3(1000 ppm)                                                          

8.2.  Exposure Controls
Appropriate Engineering      |Use general dilution ventilation and/or local       
Controls                     |exhaust ventilation to control airborne exposures to
                             |below relevant Exposure Limits and/or control       
                             |dust/fume/gas/mist/vapors/spray. If ventilation is  
                             |not adequate, use respiratory protection equipment. 
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |                                                    
Eye Protection               |Select and use eye/face protection to prevent       
                             |contact based on the results of an exposure         
                             |assessment. The following eye/face  protection(s)   
                             |are recommended:                                    
                             |Indirect Vented Goggles.                            
Skin and Body Protection     |Select and use gloves and/or protective clothing    
                             |approved to relevant local standards to prevent skin
                             |contact based on the results of an exposure         
                             |assessment. Selection should be based on use factors
                             |such as exposure levels, concentration of the       
                             |substance or mixture, frequency and duration,       
                             |physical challenges such as temperature extremes,   
                             |and other use conditions. Consult with your glove   
                             |and/or protective clothing manufacturer for         
                             |selection of appropriate compatible                 
                             |gloves/protective clothing. Gloves made from the    
                             |following material(s) are recommended: Nitrile      
Respiratory Protection       |An exposure assessment may be needed to decide if a 
                             |respirator is required. If a respirator is needed,  
                             |use respirators as part of a full respiratory       
                             |protection program. Based on the results of the     
                             |exposure assessment, select from the following      
                             |respirator type(s) to reduce inhalation exposure:   
                             |Half facepiece or full facepiece air-purifying      
                             |respirator suitable for organic vapors. For         
                             |questions about suitability for a specific          
                             |application, consult with your respirator           
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       

9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                       
Appearance                          |Aerosol                                      
Odor                                |Clear Liquid, Citrus / Acetone Odor,         
                                    |Dispensed as an Aerosol                      
Odor Threshold                      |No Data Available                            
pH                                  |Not Applicable                               
Relative Evaporation Rate (butyl    |No Data Available                            
acetate=1)                          |                                             
Melting Point                       |Not Applicable                               
Freezing Point                      |                                             
Boiling Point                       |No Data Available                            
Flash Point                         |-156 Deg F [Test Method: Tagliabue Closed    
                                    |Cup] [Details: Based on                      
Auto-ignition Temperature           |No Data Available                            
Decomposition Temperature           |No Data Available                            
Flammability (solid, gas)           |Not Applicable                               
Vapor Pressure                      |No Data Available                            
Relative Vapor Density at 20 °C     |No Data Available                            
Relative Density                    |                                             
Specific Gravity                    |0.88 [Ref Std: WATER=1]                      
Solubility                          |Appreciable                                  
Partition coefficient:              |No Data Available                            
n-octanol/water                     |                                             
Viscosity                           |No Data Available                            
Lower Flammable Limit               |                                             
Upper Flammable Limit               |                                             

9.2.  Other Information
Hazardous Air Pollutants               8.70 % weight [Test Method: Calculated]    
Volatile Organic Compounds:                44.9 % weight [Test Method: calculated 
per CARB title 2]                                                                 
Volatile Organic Compounds:                395 g/l [Test Method: calculated SCAQMD
rule 443.1]                                                                       
Percent volatile:                                       100 % weight:             
VOC Less H2O & Exempt Solvents:       1,024 g/l [Test Method: calculated SCAQMD   
rule 443.1]                                                                       

SECTION 10: STABILITY AND REACTIVITY                                              

10.1      Reactivity
This material may be reactive with certain agents under certain conditions - see  
the remaining headings in this section.                                           

10.2      Chemical Stability

10.3      Possibility of Hazardous Reactions
Hazardous polymerization will not occur.                                          

10.4      Conditions to Avoid
Sparks and/or flames                                                              

10.5      Incompatible Materials
Strong oxidizing agents                                                           
Strong acids                                                                      

10.6      Hazardous Decomposition Products
Carbon monoxide                                                               Not 
Carbon dioxide                                                                    
Not Specified                                                                     

SECTION 11: TOXICOLOGICAL INFORMATION                                             

11.1. Information on Toxicological Effects
Acute Toxicity: The information below may not be consistent with the material     
classification in Section 2 if specific ingredient                                
classifications are mandated by a competent authority. In addition, toxicological 
data on ingredients may not be reflected in the material classification and/or the
signs and symptoms of exposure, because an ingredient may be present below the    
threshold for labeling, an ingredient may not be available for exposure, or the   
data may not be relevant to the material as a whole.                              
Skin Corrosion/Irritation:                                                        
Serious Eye Damage/Irritation:                                                    
Respiratory or Skin Sensitization:                                                
Germ Cell Mutagenicity:                                                           
Carcinogenicity: Contains a chemical or chemicals which can cause cancer.         
CAS No.                                                                           
Class Description                                                                 
Grp. 2B: Possible human carc.                                                     
International Agency for Research on Cancer                                       
Reproductive Toxicity:                                                            
Specific Target Organ Toxicity (Single Exposure): Auditory Effects: Signs/symptoms
may include hearing impairment, balance dysfunction and ringing in the ears.      
Central Nervous System (CNS) Depression: Signs/symptoms may include headache,     
dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred      
speech, giddiness, and unconsciousness. Single exposure, above recommended        
guidelines, may cause:                                                            
Cardiac Sensitization: Signs/symptoms may include irregular heartbeat             
(arrhythmia), faintness, chest pain, and may be fatal.                            
Specific Target Organ Toxicity (Repeated Exposure):                               
Auditory Effects: Signs/symptoms may include hearing impairment, balance          
dysfunction and ringing in the ears.                                              
Prolonged or repeated exposure by ingestion may cause:                            
Neurological Effects: Signs/symptoms may include personality changes, lack of     
coordination, sensory loss, tingling or numbness of the extremities, weakness,    
tremors, and/or changes in blood pressure and heart rate.                         
Aspiration Hazard:                                                                
Symptoms/Injuries After Inhalation: Respiratory Tract Irritation: Signs/symptoms  
may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and  
throat pain. May cause target organ effects after inhalation.                     
Symptoms/Injuries After Skin Contact: Skin Irritation: Signs/symptoms may include 
localized redness, swelling, itching, dryness, cracking, blistering, and pain.    
Symptoms/Injuries After Eye Contact: Severe Eye Irritation: Signs/symptoms may    
include significant redness, swelling, pain, tearing, cloudy appearance of the    
cornea, and impaired vision.                                                      
Symptoms/Injuries After Ingestion:                                                
Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping,  
choking, burning of the mouth, difficulty breathing, bluish colored skin          
(cyanosis), and may be fatal. Gastrointestinal Irritation: Signs/symptoms may     
include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause   
target organ effects after ingestion.                                             
Chronic Symptoms:                                                                 

SECTION 12: ECOLOGICAL INFORMATION                                                

12.1. Toxicity
Please contact the address or phone number listed on the first page of the SDS for
additional ecotoxicological information on this material and/or its components.   

12.2. Persistence and Degradability

12.3. Bioaccumulative Potential

12.4. Mobility in Soil

12.5. Other Adverse Effects

13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose of contents/ container in accordance with 
the local/regional/national/international regulations. Incinerate in a permitted  
waste incineration facility. Facility must be capable of handling aerosol cans. As
a disposal alternative, utilize an acceptable permitted waste disposal facility.  
Empty drums/barrels/containers used for transporting and handling hazardous       
chemicals (chemical substances/mixtures/preparations classified as Hazardous as   
per applicable regulations) shall be considered, stored, treated & disposed of as 
hazardous wastes unless otherwise defined by applicable waste regulations. Consult
with the respective regulating authorities to determine the available treatment   
and disposal facilities.                                                          
Additional Information:                                                           

SECTION 14: TRANSPORT INFORMATION                                                 

14.1 In Accordance with DOT
Proper Shipping Name |                                                            
Hazard Class         |                       |<PICTOGRAM PHRASE>                  
Identification Number|                       |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            

14.2 In Accordance with IMDG
Proper Shipping Name |                                                            
Hazard Class         |                                                            
Identification Number|                                                            
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     

14.3 In Accordance with IATA
Proper Shipping Name |                                                            
Identification Number|                       |<PICTOGRAM PHRASE>                   
Hazard Class         |                       |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
Contact 3M for more information.                                                  
Section 313 Toxic Chemicals subject to the reporting requirements of that section 
and 40 CFR part 372 (EPCRA):                                                      
Ingredient                                              C.A.S. No              %  
by Wt                                                                             
Xylene                                                     1330-20-7              
5 - 10                                                                            
Xylene (Benzene, 1,2-dimethyl-)        1330-20-7                5 - 10            
Xylene (Benzene, 1,3-dimethyl-)        1330-20-7                5 - 10            
Xylene (Benzene, 1,4-dimethyl-)        1330-20-7                5 - 10            
Xylene (Benzene, dimethyl-)               1330-20-7               5 - 10          
Ethylbenzene                                           100-41-4                  0
- 3                                                                               
SARA Section 311/312 Hazard Classes |Fire Hazard - Yes                            
                                    |Pressure Hazard - No                         
                                    |Reactivity Hazard - No                       
                                    |Immediate Hazard - Yes                       
                                    |Delayed Hazard - Yes                         
Toxic Substances Control Act (TSCA) |The components of this product are in        
                                    |compliance with the chemical notification    
                                    |requirements of TSCA.                        

15.2      US State Regulations
Contact 3M for more information.                                                  
California Proposition 65                                                         
Ingredient                                    C.A.S. No.                          
Ethylbenzene                              100-41-4                                


Revision date   |                                                                 
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
GHS Full Text Phrases:                                                            
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Grainger disclaimer.

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.