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SDS Sheet 0067800Printer Friendly View
Safety Data Sheet | | Date of Issue: 04/30/14 |Revision Date: |Revision Number: 19.00 Imperial Supplies Part Number: 0067800 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: General Physical Form: Liquid Specific Physical Form: Aerosol Product Name: 3M (TM) High Power Brake Cleaner, P.N. 08880 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Automotive, Solvent Blend Cleaner for Automobile Brake Systems 1.3. Name, Address, and Telephone of the Responsible Party Company 3M - Automotive Aftermarket 3M Center, St. Paul, MN 55144-1000, USA Phone: 1-888-3M HELPS (1-888-364-3577) Supplier: Imperial Supplies LLC 1.4. Emergency Telephone Number Emergency | 1-800-364-3577 or (651) 737-6501 (24 hours) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable Aerosol |Category 1. Acute Toxicity (oral) |Category 4. Serious Eye |Category 2B. Damage/Irritation | Skin Corrosion/Irritation |Category 2. Aspiration Hazard |Category 1. Reproductive Toxicity |Category 2. Carcinogenicity |Category 2. Specific Target Organ |Category 1. Toxicity (single exposure) | Specific Target Organ |Category 3. Toxicity (central nervous | system) | Specific Target Organ |Category 1. Toxicity (repeated | exposure) | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Exclamat|Health | | | | |ion mark|hazard | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. |Harmful if swallowed. |Causes eye irritation. |Causes skin irritation. |May be fatal if swallowed and enters airways. |May cause drowsiness or dizziness. |Suspected of damaging fertility or the unborn child. | |Suspected of causing cancer. |Causes damage to organs: cardiovascular system |sensory organs |Causes damage to organs through prolonged or |repeated exposure: nervous system |May cause damage to organs through prolonged or |repeated exposure: sensory organs Precautionary Statements |Prevention: (GHS-US) |Obtain special instructions before use. |Do not handle until all safety precautions have been |read and understood. |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. |Do not spray on an open flame or other ignition |source. |Pressurized container: Do not pierce or burn, even |after use. |Do not breathe dust/fume/gas/mist/vapors/spray. |Use only outdoors or in a well-ventilated area. |Wear protective gloves. |Do not eat, drink or smoke when using this product. |Wash thoroughly after handling. |Response: |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention. |IF ON SKIN: Wash with plenty of soap and water. |If skin irritation occurs: Get medical |advice/attention. |Take off contaminated clothing and wash it before |reuse. |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician. |Rinse mouth. |Do NOT induce vomiting. |Specific treatment (see Notes to Physician on this |label). |Get medical advice/attention if you feel unwell. |Storage: |Protect from sunlight. Do not expose to temperatures |exceeding 50C/122F. |Store in a well-ventilated place. Keep container |tightly closed. |Store locked up. |Disposal: |Dispose of contents/container in accordance with |applicable local/regional/national/international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product |% |Classification |identifier | |(GHS-US) Hydrotreated Light Naptha |64742-49-0 |30 - 60 Trade | (Petroleum) | |Secret | Xylene |1330-20-7 |10 - 30 Trade | | |Secret | Propane |74-98-6 |10 - 30 Trade | | |Secret | Methyl Alcohol |67-56-1 |7 - 13 Trade | | |Secret | Ethylbenzene |100-41-4 |2 - 8 Trade | | |Secret | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove person to fresh air. Get medical attention. First-aid Measures After Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. First-aid Measures After Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. First-aid Measures After Ingestion: If Swallowed: Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: See Section 11.1. Information on toxicological effects. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed This product contains methanol. Methanol poisoning can cause metabolic acidosis, blindness, and death. Onset of signs or symptoms may be delayed for 18 to 24 hours. If methanol poisoning is confirmed, intravenous (IV) administration of ethanol should be considered. Additional pharmacologic and supportive care should be based on the treating physician's judgement. Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use a fire fighting agent suitable for the surrounding fire. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Closed containers exposed to heat from fire may build pressure and explode. Explosion Hazard: Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and Material for Containment and Cleaning Up For Containment: If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: For industrial or professional use only. Do not use in a confined area with minimal air exchange. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. distances along the ground or floor to an ignition source and flash back. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 Amer Conf of Gov. Indust. Hyg. TWA:20 ppm Ethylbenzene 100-41-4 Chemical Manufacturer Rec Guid TWA:25 ppm;STEL:75 ppm Ethylbenzene 100-41-4 US Dept of Labor - OSHA TWA:435 mg/m3(100 ppm) Xylene 1330-20-7 Amer Conf of Gov. Indust. Hyg. TWA:100 ppm;STEL:150 ppm Xylene 1330-20-7 Chemical Manufacturer Rec Guid TWA:50 ppm;STEL:75 ppm Xylene 1330-20-7 US Dept of Labor - OSHA TWA:435 mg/m3(100 ppm) Hydrotreated Light Naptha (Petroleum) 64742-49-0 Chemical Manufacturer Rec Guid TWA:50 ppm Methyl Alcohol 67-56-1 Amer Conf of Gov. Indust. Hyg. TWA:200 ppm;STEL:250 ppm Skin Notation Methyl Alcohol 67-56-1 US Dept of Labor - OSHA TWA:260 mg/m3(200 ppm) Propane 74-98-6 Amer Conf of Gov. Indust. Hyg. Limit value not established: Propane 74-98-6 US Dept of Labor - OSHA TWA:1800 mg/m3(1000 ppm) 8.2. Exposure Controls Appropriate Engineering |Use general dilution ventilation and/or local Controls |exhaust ventilation to control airborne exposures to |below relevant Exposure Limits and/or control |dust/fume/gas/mist/vapors/spray. If ventilation is |not adequate, use respiratory protection equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Select and use eye/face protection to prevent |contact based on the results of an exposure |assessment. The following eye/face protection(s) are |recommended: Indirect Vented Goggles. Skin and Body Protection |Select and use gloves and/or protective clothing |approved to relevant local standards to prevent skin |contact based on the results of an exposure |assessment. Selection should be based on use factors |such as exposure levels, concentration of the |substance or mixture, frequency and duration, |physical challenges such as temperature extremes, |and other use conditions. Consult with your glove |and/or protective clothing manufacturer for |selection of appropriate compatible |gloves/protective clothing. |Gloves made from the following material(s) are |recommended: Fluoroelastomer Polymer laminate. Respiratory Protection |An exposure assessment may be needed to decide if a |respirator is required. If a respirator is needed, |use respirators as part of a full respiratory |protection program. Based on the results of the |exposure assessment, select from the following |respirator type(s) to reduce inhalation exposure: |Half facepiece or full facepiece air-purifying |respirator suitable for organic vapors. For |questions about suitability for a specific |application, consult with your respirator |manufacturer. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |General Physical Form: Liquid |Specific Physical Form: Aerosol Appearance | Odor |Solvent odor Odor Threshold |No Data Available pH |Not Applicable Relative Evaporation Rate (butyl |No Data Available acetate=1) | Melting Point |No Data Available Freezing Point | Boiling Point |No Data Available Flash Point |-50.00 Deg F Auto-ignition Temperature |No Data Available Decomposition Temperature |No Data Available Flammability (solid, gas) |Not Applicable Vapor Pressure |40 psi [Details: Conditions: @ 70 F] Relative Vapor Density at 20 Â°C |>=1.0 [Ref Std: AIR=1] Relative Density | Specific Gravity |0.699 [Ref Std: WATER=1] Solubility |Solubility in Water: Nil |Solubility- non-water: No Data Available Partition coefficient: |No Data Available n-octanol/water | Viscosity |No Data Available Lower Flammable Limit |No Data Available Upper Flammable Limit |No Data Available 9.2. Other Information Hazardous Air Pollutants 34.72 % weight [Test Method: Calculated] Volatile Organic Compounds 699 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 100.0 % weight [Test Method: calculated per CARB title 2] Percent volatile 100 % VOC Less H2O & Exempt Solvents 699 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Heat Sparks and/or flames 10.5 Incompatible Materials Strong acids Strong oxidizing agents 10.6 Hazardous Decomposition Products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Reproductive Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Specific Target Organ Toxicity (Single Exposure): Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. May cause blindness. Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Specific Target Organ Toxicity (Repeated Exposure): Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Aspiration Hazard: Symptoms/Injuries After Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Symptoms/Injuries After Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. May cause target organ effects after skin contact. Symptoms/Injuries After Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Symptoms/Injuries After Ingestion: Harmful if swallowed. Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Contact 3M for more information. Ingredient C.A.S. No % by Wt Methyl Alcohol 67-56-1 7 - 13 Ethylbenzene 100-41-4 2 - 8 Xylene 1330-20-7 10 - 30 Xylene (Benzene, 1,2-dimethyl-) 1330-20-7 10 - 30 Xylene (Benzene, 1,3-dimethyl-) 1330-20-7 10 - 30 Xylene (Benzene, 1,4-dimethyl-) 1330-20-7 10 - 30 Xylene (Benzene, dimethyl-) 1330-20-7 10 - 30 SARA Section 311/312 Hazard Classes |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No |Immediate Hazard - Yes |Delayed Hazard - Yes Toxic Substances Control Act (TSCA) |The components of this product are in |compliance with the chemical notification |requirements of TSCA. |Contact 3M for more information. 15.2 US State Regulations <COMPONENT> Contact 3M for more information. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.