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SDS Sheet 0067570Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: WD-40 Multi-Use Product Aerosol (25% VOC) CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Lubricant, Penetrant, Drives Out Moisture, Removes and Protects Surfaces From Corrosion 1.3. Name, Address, and Telephone of the Responsible Party Company: WD-40 Company 1061 Cudahy Place (92110) P.O. Box 80607 San Diego, California, USA 92138 -0607 Phone: 1-888-324-7596, 1.4. Emergency Telephone Number Emergency | 1-888-324-7596 (PROSAR), 1-800-424-9300 (Chemtrec), 1-703-527-3887 number |(International Calls) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 Aerosol | Gas Under |Compressed Gas Pressure | Aspiration |Category 1 Toxicity | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Health Hazard Signal Word (GHS-US) |DANGER! Hazard Statements (GHS-US) |Extremely Flammable Aerosol. |Contains gas under pressure; may explode if heated. |May be fatal if swallowed and enters airways. Precautionary Statements |Prevention (GHS-US) |Keep away from heat, sparks, open flames, hot |surfaces - No smoking. |Do not spray on an open flame or other ignition |source. |Pressurized container: Do not pierce or burn, even |after use. |Response |IF SWALLOWED: Immediately call a POISON CENTER or |physician. Do NOT induce vomiting. |Storage |Store locked up. |Protect from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F. Store in a well-ventilated |place. |Disposal |Dispose of contents and container in accordance with |local and national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) LVP Aliphatic Hydrocarbon |64742-47-8 |45-50 |Flammable Liquid | | |Category 3 | | |Aspiration | | |Toxicity Category | | |1 Aliphatic Hydrocarbon |64742-47-8 |<25 |Aspiration | | |Toxicity Category | | |1 Petroleum Base Oil |64742-56-9 |<25 |Not Hazardous |64742-65-0 | | |64742-53-6 | | |64742-54-7 | | |64742-71-8 | | Non-Hazardous Ingredients |Mixture |<10 |Not Hazardous Carbon Dioxide |124-38-9 |2-3 |Simple Asphyxiant Note: The exact percentages are a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms develop and persist. First-aid Measures After Skin Contact: Wash with soap and water. If irritation develops and persists, get medical attention. First-aid Measures After Eye Contact: Flush thoroughly with water. Remove contact lenses if present after the first 5 minutes and continue flushing for several more minutes. Get medical attention if irritation persists. First-aid Measures After Ingestion: Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the WD-40 Safety Hotline at 1-888-324-7596 immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: May cause eye and respiratory irritation. Inhalation may cause coughing, headache and dizziness. Skin contact may cause drying of the skin. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Immediate medical attention is needed for ingestion. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Unsuitable Extinguishing Media: Do not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Contents under pressure. Keep away from ignition sources and open flames. Exposure of containers to extreme heat and flames can cause them to rupture often with violent force. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. Combustion will produce oxides of carbon and hydrocarbons. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Firefighters should always wear positive pressure self-contained breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Use shielding to protect against bursting containers. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Wear appropriate protective (see Section 8). Emergency Procedures: Eliminate all sources of ignition and ventilate area. 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Leaking cans should be placed in a plastic bag or open pail until the pressure has dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report spills to authorities as required. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use only with adequate ventilation. Keep away from heat, sparks, pilot lights, hot surfaces and open flames. Unplug electrical tools, motors and appliances before spraying or bringing the can near any source of electricity. Electricity can burn a hole in the can and cause contents to burst into flames. To avoid serious burn injury, do not let the can touch battery terminals, electrical connections on motors or appliances or any other source of electricity. Wash thoroughly with soap and water after handling. Keep containers closed when not in use. Keep out of the reach of children. Do not puncture, crush or incinerate containers, even when empty. Hygiene Measures: Wash with soap and water after handling. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a cool, well-ventilated area, away from incompatible materials Do not store above 120Â°F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol. Store away from oxidizers. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Chemical Occupational Exposure Limits LVP Aliphatic Hydrocarbon 1200 mg/m3 TWA (manufacturer recommended) Aliphatic Hydrocarbon 1200 mg/m3 TWA (manufacturer recommended) Petroleum Base Oil 5 mg/m3 TWA, 10 mg/m3 STEL ACGIH TLV 5 mg/m3 TWA OSHA PEL Carbon Dioxide 5000 ppm TWA (OSHA/ACGIH), 30,000 ppm STEL (ACGIH) Non-Hazardous Ingredients None Established 8.2. Exposure Controls Appropriate Engineering |The Following Controls are Recommended for Normal Controls |Consumer Use of this Product: Use in a |well-ventilated area. |For Bulk Processing or Workplace Use the Following |Controls are Recommended: Use adequate general and |local exhaust ventilation to maintain exposure |levels below that occupational exposure limits. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |The Following Controls are Recommended for Normal |Consumer Use of this Product: Avoid eye contact. |Always spray away from your face. | |For Bulk Processing or Workplace Use the Following |Controls are Recommended: Safety goggles recommended |where eye contact is possible. Skin and Body Protection |The Following Controls are Recommended for Normal |Consumer Use of this Product: Avoid prolonged skin |contact. Chemical resistant gloves recommended for |operations where skin contact is likely. | |For Bulk Processing or Workplace Use the Following |Controls are Recommended: Wear chemical resistant |gloves. Respiratory Protection |The Following Controls are Recommended for Normal |Consumer Use of this Product: None needed for normal |use with adequate ventilation. | |For Bulk Processing or Workplace Use the Following |Controls are Recommended: None required if |ventilation is adequate. If the occupational |exposure limits are exceeded, wear a NIOSH approved |respirator. Respirator selection and use should be |based on contaminant type, form and concentration. |Follow OSHA 1910.134, ANSI Z88.2 and good Industrial |Hygiene practice. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Light amber liquid Odor |Mild petroleum odor Odor Threshold |Not established pH |Not Applicable Relative Evaporation Rate |Not established (butylacetate=1) | Melting Point |Not established Freezing Point |Not established Boiling Point |361 - 369 Deg F (183 - 187 Deg C) Flash Point |138 Deg F (59 Deg C) Tag Closed Cup (liquid) Auto-ignition Temperature |Not established Decomposition Temperature |Not established Flammability (solid, gas) |Flammable Aerosol Vapor Pressure |95-115 PSI @ 70 Deg F Relative Vapor Density at 20 Â°C | Relative Density |0.8 - 0.82 @ 60 Deg F Specific Gravity | Solubility |Insoluble in water Partition coefficient: |Not established n-octanol/water | Viscosity |2.79-2.96 cSt @ 100 Deg F Lower Flammable Limit |LEL: 0.6% Upper Flammable Limit |UEL: 8% 9.2. Other Information VOC: 206 grams/liter (25%) SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Not reactive under normal conditions. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions May react with strong oxidizers generating heat. 10.4 Conditions to Avoid Avoid heat, sparks, flames and other sources of ignition. Do not puncture or incinerate containers. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon monoxide and carbon dioxide. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: The oral toxicity of this product is estimated to be greater than 5,000 mg/kg and the dermal toxicity greater than 2,000 mg/kg based on an assessment of the ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: None of the components are listed as a carcinogen or suspect carcinogen by IARC, NTP, ACGIH or OSHA. Reproductive Toxicity: None of the components is considered a reproductive hazard. Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: High concentrations may cause nasal and respiratory irritation and central nervous system effects such as headache, dizziness and nausea. Intentional abuse may be harmful or fatal. Symptoms/Injuries After Skin Contact: Prolonged and/or repeated contact may produce mild irritation and defatting with possible dermatitis. Symptoms/Injuries After Eye Contact: Contact may be irritating to eyes. May cause redness and tearing. Symptoms/Injuries After Ingestion: This product has low oral toxicity. Swallowing may cause gastrointestinal irritation, nausea, vomiting and diarrhea. This product is an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis, severe lung damage and death. Chronic Symptoms: None expected. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity No specific aquatic toxicity data is currently available, however components of this product are not expected to be harmful to aquatic organisms. 12.2. Persistence and Degradability Component are readily biodegradable. 12.3. Bioaccumulative Potential Bioaccumulation is not expected based on an assessment of the ingredients. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects None known. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: If this product becomes a waste, it would be expected to meet the criteria of a RCRA ignitable hazardous waste (D001). However, it is the responsibility of the generator to determine at the time of disposal the proper classification and method of disposal. Do not puncture or incinerate containers, even empty. Dispose in accordance with federal, state, and local regulations. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols Hazard Class |2.1 Identification Number|Un1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations U.S. Federal Regulations: CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills are reportable to the National Response Center under the Clean Water Act and many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: None Section 302 Extremely Hazardous Substances (TPQ): None Section 302 Extremely Hazardous Substances (TPQ): None SARA Section 311/312 Hazard Classes |Acute Health, Fire Hazard, Sudden Release of |Pressure Toxic Substances Control Act (TSCA) |All of the components of this product are |listed on the TSCA inventory. 15.2 US State Regulations California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product does not contain chemicals regulated under California Proposition 65. VOC Regulations: This product complies with the consumer product VOC limits of CARB, the US EPA and states adopting the OTC VOC rules. Canadian Environmental Protection Act: One of the components is listed on the NDSL. All of the other ingredients are listed on the Canadian Domestic Substances List or exempt from notification. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |July 20, 2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.