Register Now    |    Login

National Distributor of Quality Maintenance Supplies Since 1958

1-800-558-2808

Track Order Status
Order No:
Zip Code:

SDS Sheet 0067380

Printer Friendly View
        

Safety Data Sheet                                                                 
Date of Issue: 04/04/2006  |Revision Date:             |Revision Number: 1        
Imperial Supplies Part Number: 0067380                                            

SECTION 1: IDENTIFICATION                                                         


1.1.  Product Identifier
Product Form:                                                                     
Product Name: Snake-A-Way                                                         
CAS No:                                                                           
Synonyms: Not applicable                                                          


1.2.  Intended Use of the Product
Use of the substance/mixture: Snake repellent                                     


1.3.  Name, Address, and Telephone of the Responsible Party
Company:                                                                          
Dr. T's Nature Products, Inc.                                                     
P. O. Box 682, 2658 US Hwy 19 North                                               
Pelham, GA 31779                                                                  
Phone:                                                                            
                                                                                  
Supplier: Imperial Supplies LLC                                                   


1.4.  Emergency Telephone Number
Emergency     | 1-800-299-6288                                                    
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
              |              
              |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |        |        |        |        |        |        
Signal Word (GHS-US)         |WARNING!                                            
Hazard Statements (GHS-US)   |Harmful if swallowed.                               
                             |Causes skin and eye irritation.                     
                             |May cause allergic skin reaction.                   
                             |Dust or vapor causes irritation to eyes and         
                             |respiratory tract.                                  
Precautionary Statements     |                                                    
(GHS-US)                     |                                                    


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                             


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                  

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
Sulfur                          |7704-34-9            |28      |                  
Naphthalene                     |91-20-3              |7       |                  
Inert ingredients               |not applicable       |65      |                  
                                |                     |        |                  
                                |                     |        |                  


SECTION 4: FIRST AID MEASURES                                                     


4.1.  Description of First Aid Measures
First-aid Measures General:                                                       
First-aid Measures After Inhalation: Move to fresh air. Get medical attention if  
symptoms occur.                                                                   
First-aid Measures After Skin Contact: In case of contact, immediately flush skin 
with plenty of water. Remove contaminated                                         
clothing and shoes. Get medical attention. Wash clothing before reuse.            
First-aid Measures After Eye Contact: In case of contact, immediately flush eyes  
with plenty of water for at least 15 minutes. If                                  
easy to do, remove contact lenses, if worn. Get medical attention.                
First-aid Measures After Ingestion: If swallowed, induce vomiting as directed by  
medical personnel. Never give anything by mouth to an unconscious person. Get     
medical attention.                                                                


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                                
Symptoms/Injuries After Inhalation: Causes irritation. Inhalation of dust or      
vapors can cause headache, nausea, vomiting, and disorientation.                  
Symptoms/Injuries After Skin Contact: Causes irritation. May cause sensitization  
by skin contact. Exposure may cause redness, itching and inflammation.            
Symptoms/Injuries After Eye Contact: Causes irritation. Exposure may cause eye    
tearing, redness and discomfort.                                                  
Symptoms/Injuries After Ingestion: Harmful if swallowed. May cause systemic       
effects. Extremely large oral dosages may produce gastrointestinal disturbances.  
Chronic Symptoms: Possible cancer hazard - may cause cancer based on animal data. 
Repeated or prolonged exposure can cause target organ damage. Effects may be      
delayed. Chronic inhalation, skin absorption or ingestion of naphthalene has      
caused severe hemolytic anemia.                                                   


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
                                                                                  

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Water spray, dry chemical, carbon dioxide           
Unsuitable Extinguishing Media: None known                                        


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:                                                                      
Explosion Hazard: None known                                                      
Reactivity:                                                                       


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions: Wear self-contained breathing apparatus and protective 
clothing.                                                                         
Protection During Firefighting: Keep away from strong oxidizing agents. Minimize  
dust generation and accumulation. In the United States of America, refer to NFPA® 
Pamphlet No. 654, "Prevention of Fire and Dust Explosions in the Chemical, Dye,   
Pharmaceutical, and Plastics Industries."                                         

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Wear appropriate personal protective equipment. See Section 8.  


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.2.  Environmental Precautions
Wear appropriate personal protective equipment. See Section 8.                    


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                  
Methods for Cleaning Up: Minimize dust generation and accumulation. Sweep up and  
place in a clearly labeled container for chemical waste. Do not allow material to 
enter drains or streams.                                                          


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        


SECTION 7: HANDLING AND STORAGE                                                   


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Wear appropriate personal protective equipment.
Avoid breathing dust or vapor. Avoid contact with eyes, skin and clothing. Do not 
taste or swallow. Use only with adequate ventilation. Wash thoroughly after       
handling.                                                                         
Hygiene Measures: Eye bath, washing facilities                                    


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                               
Storage Conditions: Keep container tightly closed until ready for use. Keep in a  
cool, well-ventilated place. Keep away from moisture.                             


7.3.  Specific End Use(s)
                                                                                  

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  


8.1.  Control Parameters
Chemical Name                                                                     
Source                                                                            
Type                                                                              
Exposure Limits                                                                   
Notes                                                                             
                                                                                  
Naphthalene                                                                       
ACGIH                                                                             
TWA                                                                               
10 ppm                                                                            
Irritation; ocular; blood                                                         
                                                                                  
Naphthalene                                                                       
ACGIH                                                                             
STEL                                                                              
15 ppm                                                                            
Irritation; ocular; blood                                                         
                                                                                  
Naphthalene                                                                       
OSHA Z-1                                                                          
TWA                                                                               
10 ppm                                                                            
--                                                                                
                                                                                  
Naphthalene                                                                       
NIOSH                                                                             
IDLH                                                                              
250 ppm                                                                           
--                                                                                
                                                                                  


8.2.  Exposure Controls
Appropriate Engineering      |Use process enclosures, local exhaust ventilation,  
Controls                     |or other engineering controls                       
                             |to keep airborne contaminants below established     
                             |exposure limits.                                    
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |Wear protective gloves and clothing. Contact health 
                             |and safety professionals for                        
                             |additional information.                             
Eye Protection               |Wear safety glasses with side shields (or goggles). 
Skin and Body Protection     |Wear disposable coveralls, lab coat, or apron to    
                             |prevent skin contact.                               
Respiratory Protection       |If engineering controls do not keep airborne        
                             |concentrations below established                    
                             |exposure limits, wear a NIOSH-approved respirator   
                             |equipped with high-efficiency particulate filter(s).
                             |Contact health and safety professionals for specific
                             |information.                                        
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Solid                                        
Appearance                          |Light tan                                    
Odor                                |Mothball                                     
Odor Threshold                      |No data available                            
pH                                  |No data available                            
Relative Evaporation Rate           |No data available                            
(butylacetate=1)                    |                                             
Melting Point                       |No data available                            
Freezing Point                      |No data available                            
Boiling Point                       |444 Deg C (831 Deg F)                        
Flash Point                         |Not applicable, combustible solid            
Auto-ignition Temperature           |Not applicable                               
Decomposition Temperature           |No data available                            
Flammability (solid, gas)           |Not applicable                               
Vapor Pressure                      |0.04 mmHg @ 21 Deg C                         
Relative Vapor Density at 20 °C     |No data available                            
Relative Density                    |No data available                            
Specific Gravity                    |0.432                                        
Solubility                          |No data available                            
Partition coefficient:              |Insoluble                                    
n-octanol/water                     |                                             
Viscosity                           |No data available                            
Lower Flammable Limit               |No data available                            
Upper Flammable Limit               |No data available                            


9.2.  Other Information
                                                                                  

SECTION 10: STABILITY AND REACTIVITY                                              


10.1      Reactivity
                                                                                  


10.2      Chemical Stability
Stable                                                                            


10.3      Possibility of Hazardous Reactions
Hazardous Polymerizations: Will not occur.                                        


10.4      Conditions to Avoid
The reaction between water and molten naphthalene may be violent.                 


10.5      Incompatible Materials
Strong oxidizing agents                                                           


10.6      Hazardous Decomposition Products
Carbon oxides, sulfur oxides                                                      

SECTION 11: TOXICOLOGICAL INFORMATION                                             


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                   
Skin Corrosion/Irritation:                                                        
Serious Eye Damage/Irritation:                                                    
Respiratory or Skin Sensitization:                                                
Germ Cell Mutagenicity:                                                           
Carcinogenicity:                                                                  
Naphthalene                                                                       
                                                                                  
IARC: 2B (Possible Carcinogenic to humans)                                        
NTP: Anticipated carcinogen                                                       
OSHA:                                                                             
ACGIH: A4 (Not classifiable as a human carcinogen)                                
Reproductive Toxicity:                                                            
Specific Target Organ Toxicity (Single Exposure):                                 
Specific Target Organ Toxicity (Repeated Exposure):                               
Aspiration Hazard:                                                                
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 

SECTION 12: ECOLOGICAL INFORMATION                                                


12.1. Toxicity
                                                                                  


12.2. Persistence and Degradability
                                                                                  


12.3. Bioaccumulative Potential
                                                                                  


12.4. Mobility in Soil
                                                                                  


12.5. Other Adverse Effects
This material has not been tested for environmental effects.                      

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose in accordance with applicable federal,    
state, and local regulations.                                                     
Disposal Methods: No specific disposal method required.                           
Additional Information:Container: Since emptied containers retain product residue,
follow label warnings even after container is                                     
emptied.                                                                          

SECTION 14: TRANSPORT INFORMATION                                                 


14.1 In Accordance with DOT
Proper Shipping Name |Not Regulated                                               
Hazard Class         |                       |<PICTOGRAM PHRASE>                  
Identification Number|                       |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            


14.2 In Accordance with IMDG
Proper Shipping Name |Not Regulated                                               
Hazard Class         |                                                            
Identification Number|                                                            
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     


14.3 In Accordance with IATA
Proper Shipping Name |Not Regulated                                               
Identification Number|                       |<PICTOGRAM PHRASE>                   
Hazard Class         |                       |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
<COMPONENT>                                                                       
US Regulations                                                                    
CERCLA Hazardous Substance List (40 CFR 302.4):                                   
Component                                                                         
CAS No.                                                                           
Concentration                                                                     
                                                                                  
Naphthalene                                                                       
91-20-3                                                                           
99.95%                                                                            
                                                                                  
Clean Air Act (CCA) Section 112, 1990 Amendments, Statutory Hazardous Air         
Pollutants:                                                                       
Naphthalene                                                                       
Clean Air Act (CAA) Section 112(i) High-Risk Hazardous Air Pollutants (40CFR      
63.74): None                                                                      
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40CFR 68.130):  
None                                                                              
Clean Water Act Section 307 Toxic Pollutants (40 CFR 401.15): Naphthalene         
Clean Water Act Section 311 Hazardous Chemical (40 CFR 116.4): Naphthalene        
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Naphthalene      
                                                                                  
Drug Enforcement Act:                                                             
Drug Enforcement Administration (21 CFR 1310.02(b) and 1310.04 (f)(2)): None      
Drug Enforcement Administration (21 CFR 1310.12(c)): None                         
SARA Section 311/312 Hazard Classes |X Acute (Immediate)                          
                                    |X Chronic (Delayed)                          
                                    |Fire                                         
                                    |Reactive                                     
                                    |Pressure Generating                          
Toxic Substances Control Act (TSCA) |This product or all components are listed on 
                                    |the following inventory: TSCA.               

15.2      US State Regulations
<COMPONENT>                                                                       
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
                                                                                  
WARNING: This product contains a chemical known to the State of California to     
cause cancer or                                                                   
reproductive toxicity:                                                            
California Prop 65 chemical: Naphthalene                                          
Massachusetts Right-To-Know List: Naphthalene; sulfur                             
Michigan Critical Materials List (Michigan Natural Resources and Environmental    
Protection                                                                        
Act (Act. 451 of 1994)): None                                                     
Minnesota Hazardous Substances List: Naphthalene                                  
New Jersey Right-To-Know List: Naphthalene; sulfur                                
Pennsylvania Right-To-Know List: Naphthalene; sulfur                              
Rhode Island Right-To-Know List: Naphthalene; sulfur                              
Component                                                                         
Reportable Quantity                                                               
                                                                                  
Naphthalene                                                                       
100 lbs                                                                           
                                                                                  
                                                                                  

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION     

Revision date   |                                                                 
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
                |1910.1200.                                                       
GHS Full Text Phrases:                                                            
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

Feedback