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SDS Sheet 0067380Printer Friendly View
Safety Data Sheet Date of Issue: 04/04/2006 |Revision Date: |Revision Number: 1 Imperial Supplies Part Number: 0067380 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Snake-A-Way CAS No: Synonyms: Not applicable 1.2. Intended Use of the Product Use of the substance/mixture: Snake repellent 1.3. Name, Address, and Telephone of the Responsible Party Company: Dr. T's Nature Products, Inc. P. O. Box 682, 2658 US Hwy 19 North Pelham, GA 31779 Phone: Supplier: Imperial Supplies LLC 1.4. Emergency Telephone Number Emergency | 1-800-299-6288 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | Signal Word (GHS-US) |WARNING! Hazard Statements (GHS-US) |Harmful if swallowed. |Causes skin and eye irritation. |May cause allergic skin reaction. |Dust or vapor causes irritation to eyes and |respiratory tract. Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Sulfur |7704-34-9 |28 | Naphthalene |91-20-3 |7 | Inert ingredients |not applicable |65 | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Move to fresh air. Get medical attention if symptoms occur. First-aid Measures After Skin Contact: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. First-aid Measures After Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention. First-aid Measures After Ingestion: If swallowed, induce vomiting as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Causes irritation. Inhalation of dust or vapors can cause headache, nausea, vomiting, and disorientation. Symptoms/Injuries After Skin Contact: Causes irritation. May cause sensitization by skin contact. Exposure may cause redness, itching and inflammation. Symptoms/Injuries After Eye Contact: Causes irritation. Exposure may cause eye tearing, redness and discomfort. Symptoms/Injuries After Ingestion: Harmful if swallowed. May cause systemic effects. Extremely large oral dosages may produce gastrointestinal disturbances. Chronic Symptoms: Possible cancer hazard - may cause cancer based on animal data. Repeated or prolonged exposure can cause target organ damage. Effects may be delayed. Chronic inhalation, skin absorption or ingestion of naphthalene has caused severe hemolytic anemia. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water spray, dry chemical, carbon dioxide Unsuitable Extinguishing Media: None known 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: None known Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Wear self-contained breathing apparatus and protective clothing. Protection During Firefighting: Keep away from strong oxidizing agents. Minimize dust generation and accumulation. In the United States of America, refer to NFPAÂ® Pamphlet No. 654, "Prevention of Fire and Dust Explosions in the Chemical, Dye, Pharmaceutical, and Plastics Industries." SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Wear appropriate personal protective equipment. See Section 8. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Wear appropriate personal protective equipment. See Section 8. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Minimize dust generation and accumulation. Sweep up and place in a clearly labeled container for chemical waste. Do not allow material to enter drains or streams. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Wear appropriate personal protective equipment. Avoid breathing dust or vapor. Avoid contact with eyes, skin and clothing. Do not taste or swallow. Use only with adequate ventilation. Wash thoroughly after handling. Hygiene Measures: Eye bath, washing facilities 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed until ready for use. Keep in a cool, well-ventilated place. Keep away from moisture. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Chemical Name Source Type Exposure Limits Notes Naphthalene ACGIH TWA 10 ppm Irritation; ocular; blood Naphthalene ACGIH STEL 15 ppm Irritation; ocular; blood Naphthalene OSHA Z-1 TWA 10 ppm -- Naphthalene NIOSH IDLH 250 ppm -- 8.2. Exposure Controls Appropriate Engineering |Use process enclosures, local exhaust ventilation, Controls |or other engineering controls |to keep airborne contaminants below established |exposure limits. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves and clothing. Contact health |and safety professionals for |additional information. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear disposable coveralls, lab coat, or apron to |prevent skin contact. Respiratory Protection |If engineering controls do not keep airborne |concentrations below established |exposure limits, wear a NIOSH-approved respirator |equipped with high-efficiency particulate filter(s). |Contact health and safety professionals for specific |information. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Solid Appearance |Light tan Odor |Mothball Odor Threshold |No data available pH |No data available Relative Evaporation Rate |No data available (butylacetate=1) | Melting Point |No data available Freezing Point |No data available Boiling Point |444 Deg C (831 Deg F) Flash Point |Not applicable, combustible solid Auto-ignition Temperature |Not applicable Decomposition Temperature |No data available Flammability (solid, gas) |Not applicable Vapor Pressure |0.04 mmHg @ 21 Deg C Relative Vapor Density at 20 Â°C |No data available Relative Density |No data available Specific Gravity |0.432 Solubility |No data available Partition coefficient: |Insoluble n-octanol/water | Viscosity |No data available Lower Flammable Limit |No data available Upper Flammable Limit |No data available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability Stable 10.3 Possibility of Hazardous Reactions Hazardous Polymerizations: Will not occur. 10.4 Conditions to Avoid The reaction between water and molten naphthalene may be violent. 10.5 Incompatible Materials Strong oxidizing agents 10.6 Hazardous Decomposition Products Carbon oxides, sulfur oxides SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Naphthalene IARC: 2B (Possible Carcinogenic to humans) NTP: Anticipated carcinogen OSHA: ACGIH: A4 (Not classifiable as a human carcinogen) Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects This material has not been tested for environmental effects. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose in accordance with applicable federal, state, and local regulations. Disposal Methods: No specific disposal method required. Additional Information:Container: Since emptied containers retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not Regulated Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not Regulated Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not Regulated Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> US Regulations CERCLA Hazardous Substance List (40 CFR 302.4): Component CAS No. Concentration Naphthalene 91-20-3 99.95% Clean Air Act (CCA) Section 112, 1990 Amendments, Statutory Hazardous Air Pollutants: Naphthalene Clean Air Act (CAA) Section 112(i) High-Risk Hazardous Air Pollutants (40CFR 63.74): None Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40CFR 68.130): None Clean Water Act Section 307 Toxic Pollutants (40 CFR 401.15): Naphthalene Clean Water Act Section 311 Hazardous Chemical (40 CFR 116.4): Naphthalene Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Naphthalene Drug Enforcement Act: Drug Enforcement Administration (21 CFR 1310.02(b) and 1310.04 (f)(2)): None Drug Enforcement Administration (21 CFR 1310.12(c)): None SARA Section 311/312 Hazard Classes |X Acute (Immediate) |X Chronic (Delayed) |Fire |Reactive |Pressure Generating Toxic Substances Control Act (TSCA) |This product or all components are listed on |the following inventory: TSCA. 15.2 US State Regulations <COMPONENT> California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING: This product contains a chemical known to the State of California to cause cancer or reproductive toxicity: California Prop 65 chemical: Naphthalene Massachusetts Right-To-Know List: Naphthalene; sulfur Michigan Critical Materials List (Michigan Natural Resources and Environmental Protection Act (Act. 451 of 1994)): None Minnesota Hazardous Substances List: Naphthalene New Jersey Right-To-Know List: Naphthalene; sulfur Pennsylvania Right-To-Know List: Naphthalene; sulfur Rhode Island Right-To-Know List: Naphthalene; sulfur Component Reportable Quantity Naphthalene 100 lbs SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.