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Safety Data Sheet | | Date of Issue: 11-May-2015 |Revision Date: 11-May-2015 |Revision Number: 1.01 Imperial Supplies Part Number: 0067370 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Extremely flammable aerosol Product Name: SUPER SOLV CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: MULTI-PURPOSE SOLVENT 1.3. Name, Address, and Telephone of the Responsible Party Company Company Name: Hi-Tech Industries 33106 W. 8 Mile Farmington, MI 48336 Phone: 248-358-2626 Supplier: Imperial Supplies LLC 1.4. Emergency Telephone Number Emergency | 1-352-323-3500 (International), 1-800-535-5053 (North America) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2B damage/eye | irritation | Carcinogenicit|Category 2 y | Specific |Category 3 target organ | toxicity | (single | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 1 aerosols | Gases under |Compressed Gas pressure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamat|Health |Flame |Gas | | |ion mark|hazard | |cylinder| | Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Causes skin irritation |Causes eye irritation |Suspected of causing cancer |May cause respiratory irritation. May cause |drowsiness or dizziness |May be fatal if swallowed and enters airways |Extremely flammable aerosol |Contains gas under pressure; may explode if heated Precautionary Statements |Prevention: Obtain special instructions before use (GHS-US) |Do not handle until all safety precautions have been |read and understood |Use personal protective equipment as required |Wash face, hands and any exposed skin thoroughly |after handling |Avoid breathing dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use |Response: If exposed or concerned: Get medical |advice/attention |Specific treatment (see first aid on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention |IF ON SKIN: Wash with plenty of soap and water. |Take off contaminated clothing and wash before reuse | |If skin irritation occurs: Get medical |advice/attention |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician if you feel |unwell |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |Storage: Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Protect from sunlight. Do not expose to temperatures |exceeding 50 �C/122 �F |Disposal: Dispose of contents/container to an |approved waste disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Toxic to aquatic life with long lasting effects 2.4. Unknown Acute Toxicity (GHS-US) 0% of the mixture consists of ingredient(s) of unknown toxicity SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) PETROLEUM DISTILLATES |64742-89-8 |60-70 | PROPANE/ISOBUTANE/N-BUTANE |68476-86-8 |10-20 | XYLENE |1330-20-7 |1-10 | ETHYL BENZENE |100-41-4 |1-10 | | | | *The exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Artificial respiration and/or oxygen may be necessary. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. First-aid Measures After Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If irritation persists, call a physician. First-aid Measures After Ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or Poison Control Center immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Causes eye and skin irritation. Irritating to respiratory system. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media: Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Sensitivity to Mechanical Impact none. Sensitivity to Static Discharge Yes. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid contact with eyes,skin, and clothing. Avoid breathing vapors or mists. . Use with adequate ventilation. Keep container away from heat,flames, and all other sources of ignition. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Stop leak if you can do it without risk. Methods for Cleaning Up: After cleaning, flush away traces with water. Clean contaminated surface thoroughly. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Take precautionary measures against static discharges. Prevent product from entering drains. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Keep away from open flames, hot surfaces and sources of ignition. Keep container tightly closed in a dry and well-ventilated place. Keep in properly labeled containers. Keep out of the reach of children. Store locked up. Storage Conditions: 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 74-98-6: TWA: 1000 ppm 106-97-8: STEL: 1000 ppm 75-28-5: STEL: 1000 ppm 74-98-6:TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 106-97-8: (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 74-98-6:IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 106-97-8:TWA: 800 ppm TWA: 1900 mg/m3 75-28-5:TWA: 800 ppm TWA: 1900 mg/m3 XYLENE 1330-20-7 STEL: 150 ppm TWA: 100 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 655 mg/m3 - ETHYL BENZENE 100-41-4 TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 125 ppm (vacated) STEL: 545 mg/m3 IDLH: 800 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 8.2. Exposure Controls Appropriate Engineering |Showers. Eyewash stations. Ventilation systems. Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Aerosol Appearance |Clear Odor |Light Vanilla Scent Odor Threshold |No information available pH |0 Relative Evaporation Rate |No information available (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |-97 �C / -143 �F Based on propellant Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 �C |No information available Relative Density |No information available Specific Gravity |0.730 Solubility |Practically insoluble Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information VOC Content(%) 100 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials None known based on information supplied. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document. ATEmix (oral) 36212 mg/kg ATEmix (dermal) 11381 mg/kg ATEmix (inhalation-dust/mist) 12.5 mg/l Skin Corrosion/Irritation: Irritating to skin. Serious Eye Damage/Irritation: Irritating to eyes. Respiratory or Skin Sensitization: None known. Germ Cell Mutagenicity: None known. Carcinogenicity: The table below indicates whether each agency has evaluated a listed ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA XYLENE 1330-20-7 - Group 3 - - ETHYL BENZENE 100-41-4 A3 Group 2B - - ACGIH: (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC: (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Group 3 - Not Classifiable as to Carcinogenicity in Humans OSHA: (Occupational Safety & Health Administration) X - Present Reproductive Toxicity: This product does not contain any known or suspected reproductive hazards. Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. May cause drowsiness and dizziness. Target Organ Effects: Central nervous system, Eyes, Respiratory system, Skin. Neurological effects: Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Specific Target Organ Toxicity (Repeated Exposure): No information available. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Vapors may irritate throat and respiratory system. May cause drowsiness and dizziness based on components. May cause irritation of respiratory tract. Avoid breathing vapors or mists. Symptoms/Injuries After Skin Contact: Irritating to skin. Avoid contact with skin. Symptoms/Injuries After Eye Contact: Irritating to eyes. Avoid contact with eyes. Symptoms/Injuries After Ingestion: Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Chronic Symptoms: Symptoms of overexposure may be headache, tiredness, nausea, and vomiting. Causes respiratory irritation. Causes skin and eye irritation. Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Additional Information: Contaminated packaging Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |CONSUMER COMMODITY ORM-D |or |LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight %* SARA 313 - Threshold Values % XYLENE - 1330-20-7 1330-20-7 1-10 1.0 ETHYL BENZENE - 100-41-4 100-41-4 1-10 0.1 Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances XYLENE 1330-20-7 100 lb X ETHYL BENZENE 100-41-4 1000 lb X X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ XYLENE 1330-20-7 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ ETHYL BENZENE 100-41-4 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ SARA Section 311/312 Hazard Classes |Acute Health Hazard: Yes |Chronic Health Hazard: Yes |Fire Hazard: Yes |Sudden Release of Pressure Hazard: Yes |Reactive Hazard: no Toxic Substances Control Act (TSCA) |Chemical Name |TSCA | |PETROLEUM DISTILLATES |X | |PROPANE/ISOBUTAN E/N-BUTANE |X | |XYLENE |X | |ETHYL BENZENE |X | 15.2 US State Regulations <COMPONENT> California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name California Prop. 65 ETHYL BENZENE - 100-41-4 Carcinogen BENZENE - 71-43-2 Carcinogen Developmental Male Reproductive TOLUENE - 108-88-3 Developmental Female Reproductive Pennsylvania New Jersey Massachusetts Pennsylvania PETROLEUM DISTILLATES 64742-89-8 X XYLENE 1330-20-7 X X X ETHYL BENZENE 100-41-4 X X X SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |11-May-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.