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SDS Sheet 0067360Printer Friendly View
Safety Data Sheet | | Date of Issue: |Revision Date: June 15, |Revision Number: |2015 | Imperial Supplies Part Number: 0067360 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: AEROKROIL CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Penetrant/Lubricant for Industrial Use 1.3. Name, Address, and Telephone of the Responsible Party Company: Kano Laboratories, Inc. 1000 E. Thompson Lane Nashville, TN 37211 Phone: 615-833-4101 Supplier: Imperial Supplies LLC 1.4. Emergency Telephone Number Emergency | 1 (800) 424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 Irritation | Eye Irritation|Category 2A Specific |Category 3 Target Organ |(Respiratory Toxicity - |Irritation, Single |CNS) Exposure | Aspiration |Category 1 Hazard | Flammable |Category 2 Aerosol | Gas Under |Compressed Gas Pressure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Exclamat|Health |Gas | | | |ion mark|hazard |cylinder| | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Flammable aerosol. |Contains gas under pressure; may explode if heated. |Causes skin irritation. |Causes serious eye irritation. |May be fatal if swallowed and enters airways. |May cause respiratory irritation. |May cause drowsiness or dizziness. Precautionary Statements |Keep away from heat, sparks, open flames, and hot (GHS-US) |surfaces. No smoking. |Do not spray on an open flame or other ignition |source. |Pressurized container. Do not pierce or burn, even |after use. |Avoid breathing mist, vapors or spray. |Wash thoroughly after handling. |Use only outdoors or in a well-ventilated area. |Wear protective gloves, eye protection and face |protection. |IF SWALLOWED: Immediately call a POISON CENTER. Do |NOT induce vomiting. |IF ON SKIN: Wash with plenty of soap and water. If |skin irritation occurs: Get medical attention. |Take off contaminated clothing and wash it before |reuse. |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. If eye irritation persists: |Get medical attention. |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. Call a POISON CENTER if |you feel unwell. |In case of fire: Use carbon dioxide, dry chemical or |foam to extinguish. |Protect from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F. |Store in a well-ventilated place. |Store locked up. |Dispose of contents and container in accordance with |local and national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Severely Hydrotreated Petroleum |64742-52-5 |30-50 | Distillates | | | Light Petroleum Distillates |64742-95-6 |30-50 | |64742-88-7 | | |64742-47-8 | | |64742-96-7 | | Proprietary Ingredients |Proprietary |1-10 | Dipropylene Glycol Monopropyl |29911-27-1 |1-5 | Ether | | | Diisobutyl Ketone |108-83-8 |0-15 | Dipropylene Glycol Methyl Ether |88917-22-0 |88917-22| | |-0 | Aliphatic Alcohol #1 |123-42-2 |<3 | Aliphatic Alcohol #2 |78-83-1 |<3 | Carbon Dioxide Propellant |124-38-9 |1-15 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove victim to fresh air. Give artificial respiration if needed. If breathing is difficult, oxygen should be administered by qualified personnel. Get medical attention if symptoms develop. First-aid Measures After Skin Contact: Remove contaminated clothing. Wash contact area thoroughly with soap and water. Get medical attention if irritation or symptoms of exposure develop. Launder clothing before re-use. First-aid Measures After Eye Contact: Rinse thoroughly with water for several holding the eye lids open to be sure the material is washed out. Get medical attention if irritation develops or persists. First-aid Measures After Ingestion: DO NOT induce vomiting. Keep the victim calm and warm. Never give anything by mouth to an unconscious or drowsy person. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: May cause eye and skin irritation. Inhalation of vapors or mist may cause respiratory irritation and central nervous system effects such as headache, dizziness, nausea and vomiting. Harmful or fatal if swallowed. Aspiration into the lungs during ingestion or vomiting may cause lung damage. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If swallowed, get immediate medical attention. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use carbon dioxide, dry chemical or foam. Water may be ineffective but can be used to cool containers and structures. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Contents under pressure. Keep away from heat and open flames. Container may rupture or explode in the heat of a fire. Prolonged exposure to temperatures above 120ÂºF may cause cans to burst. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. Never use welding or cutting torch on or near containers (even empty) because product can ignite explosively. Combustion products may be hazardous: Oxides of carbon, organic compounds, smoke and fumes. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Wear NIOSH approved positive pressure, self-contained breathing apparatus and full protective clothing. Cool fire exposed containers with water. Protect against bursting cans. Firefighting Instructions: Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Wear appropriate protective clothing to prevent eye and skin contact including impervious gloves, safety goggles and respirator if needed. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Report spills and releases as required to appropriate authorities. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Remove all ignition sources such as open flames, spark producing equipment, pilot lights, etc. Ventilate area. Cover with an inert absorbent material and collect into an appropriate container for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid breathing vapors, aerosols and mists. Use with adequate ventilation. Avoid contact with the eyes, skin and clothing. Wash exposed skin thoroughly with soap and water after use. Keep product away from heat, sparks, flames and all other sources of ignition. No smoking in storage or use areas. Do not cut, braze, solder, grind or weld on or near containers. Contents under pressure. Do not puncture or incinerate container. Hygiene Measures: Suitable eye wash and washing facilities should be available in the work area. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a cool, well ventilated area at temperatures below 120ÂºF. Do not store in direct sunlight. Store as a Level 3 aerosol. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Chemical Name Exposure Limits Severely Hydrotreated Petroleum Distillates 5 mg/m3 TWA OSHA PEL 5 mg/m3 TWA ACGIH TLV(inhalable fraction) Light Petroleum Distillates 500 ppm TWA OSHA PEL (As stoddard solvent) 200 ppm TWA ACGIH TLV (as kerosene) Dipropylene Glycol Monopropyl Ether None Established Proprietary Ingredients None Established Diisobutyl Ketone 25 ppm TWA OSHA PEL 50 ppm TWA ACGIH TLV Dipropylene Glycol Methyl Ether None Established Aliphatic Alcohol #1 50 ppm OSHA TWA PEL- 50 ppm TWA ACGIH TLV Aliphatic Alcohol #2 100 ppm TWA OSHA PEL 50 ppm TWA ACGIH TLV Carbon Dioxide Propellant 5000 ppm OSHA PEL-TWA 5000 ppm ACGIH TLV-TWA 30000 ppm ACGIH TLV-STEL 8.2. Exposure Controls Appropriate Engineering |Use with adequate general or local exhaust Controls |ventilation to maintain concentrations below the |occupational exposure limits. Use explosion proof |electrical equipment and wiring where required. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Impervious gloves are recommended when needed to |avoid skin contact. Based on available test data, 4H |or Silver Shield gloves are suggested. Eye Protection |Chemical safety goggles recommended. Skin and Body Protection |Impervious clothing as required to prevent skin |contact and contamination of personal clothing. Respiratory Protection |If the exposure limits listed above are exceeded, a |NIOSH approved respirator with organic vapor |cartridges may be used. For higher exposures, a |supplied air respirator may be required. Respirator |selection and use should be based on contaminant |type, form and concentration. Follow OSHA 1910.134, |ANSI Z88.2 and good Industrial Hygiene practice. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Slightly reddish liquid packaged as an |aerosol Odor |Solvent Odor Threshold |Not available. pH |Not available Relative Evaporation Rate |Not available (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |Not available Flash Point |132Â°F (55.5Â°C) TOC Auto-ignition Temperature |Not available Decomposition Temperature |Not available Flammability (solid, gas) |Not applicable Vapor Pressure |Not available Relative Vapor Density at 20 Â°C |Not available Relative Density |0.8596 Specific Gravity | Solubility |Negligible in Water Partition coefficient: |Not available n-octanol/water | Viscosity |Not available Lower Flammable Limit |0.7% (light petroleum distillates) Upper Flammable Limit |10.9% (aliphatic alcohol #2) 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity None known. 10.2 Chemical Stability Stable under normal conditions of storage or use. 10.3 Possibility of Hazardous Reactions None known. 10.4 Conditions to Avoid Avoid heat, sparks, flames and all other sources of ignition. 10.5 Incompatible Materials Avoid strong oxidizing agents, reducing agents, acids and bases. 10.6 Hazardous Decomposition Products Combustion will produce oxides of carbon, acetone, acrid fumes and smoke. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Toxicological testing has not been performed on this product as a mixture. Severely Hydrotreated Petroleum Distillates: Oral rat LD50 > 5000 mg/kg; Dermal rat LD50 > 5000 mg/kg Inhalation rat LC50 > 2.18 mg/L/4 hr. Light Petroleum Distillates: Oral rat LD50 >5000 mg/kg, Inhalation rat LC50 >5.28 mg/L/4 hr, Dermal rabbit LD50 >2000 mg/kg. Proprietary Ingredients: Oral rat LD50 2760 mg/kg; Dermal rabbit LD50 >2000 mg/kg. Dipropylene Glycol Monopropyl Ether: Oral rat LD50 >2000 mg/kg Dermal rabbit LD50 >2000 mg/kg. Diisobutyl Ketone: Oral rat LD50 5233 mg/kg; Dermal rat LD50 > 2000 mg/kg; Inhalation rat LC50 14.5 mg/L/4 hr. Dipropylene Glycol Methyl Ether: Oral rat LD50 >5000 mg/kg, Dermal rat LD50 >2000 mg/kg, Inhalation rat LD50 >5.7 mg/L/4 hr. Aliphatic Alcohol #1: Oral rat LD50 3002 mg/kg; Dermal rat LD50 > 1875 mg/kg; Inhalation rat LC50> 7.6 mg/L/4 hr. Aliphatic Alcohol #2: Oral rat LD50 > 2830 mg/kg; Inhalation rat LC50 24.6 mg/L/4 hr.; Dermal rabbit LD50 > 2000 mg/kg. Carbon Dioxide: Inhalation rat LC50 167857 ppm/4 hr. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: None of the components of this product at greater than 0.1% are listed as carcinogens by OSHA, IARC or NTP. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Inhalation of vapors or mists may cause mucous membrane and upper respiratory tract irritation and central nervous system depression. Symptoms may include coughing, wheezing, shortness of breath, headache, dizziness, drowsiness, nausea, fatigue and unconsciousness. Symptoms/Injuries After Skin Contact: May cause irritation with redness, rash, swelling. Prolonged or repeated contact may result in defatting and dermatitis. Symptoms/Injuries After Eye Contact: May cause eye irritation with redness, tearing and stinging. Symptoms/Injuries After Ingestion: Ingestion is an unlikely route of exposure for aerosol products. Swallowing may cause gastrointestinal irritation with abdominal pain, nausea, vomiting and diarrhea and central nervous system depression with symptoms including headache, dizziness, intoxication, weakness, nausea, and vomiting. Aspiration into the lungs during ingestion or vomiting may cause lung damage. Chronic Symptoms: Prolonged or repeated exposure may cause effects on the central nervous system, kidney and liver. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: No toxicity data available for the product. Severely Hydrotreated Petroleum Distillates: 96 hr. LC50 Pimephales promelas > 100 mg/L; 48 hr. EC50 daphnia magna>1000 mg/L; 72 hr. EC50 Pseudokirchnerella subcapitata > 100 mg/L. Light Petroleum Distillates: 96 hr LL50 Oncorhynchus mykiss 2.5 mg/kg, 48 hr EL50 daphnia magna 1.4 mg/L, 72 hr EL50 Pseudokirchnerella subcapitata 1.3 mg/L. Proprietary Ingredients: 96 hr. LC50 Oncorhynchus mykiss 18350 ug/L. Dipropylene Glycol Monopropyl Ether: 96 hr LC50 Oncorhynchus mykiss >100 mg/L, 48 hr EC50 daphnia magna >100 mg/L, 96 hr EC50 Pseudokirchneriella subcapitata >1000 mg/L. Diisobutyl Ketone: 96 hr. LC50 Oncorhynchus mykiss 30 mg/L; 48 hr. EC50 daphnia magna 37.2 mg/L, 72 hr. EC50 Pseudokirchnerella subcapitata 46.9 mg/L. Dipropylene Glycol Methyl Ether: 96 hr LC50 Oncorhynchus mykiss 110.2 mg/L, 48 hr LC50 daphnia magna 2701 mg/L, 72 hr EC50 Pseudokirchneriella subcapitata >1000 mg/L. Aliphatic Alcohol #1: 96 hr. LC50 Oryzias latipes >100 mg/L; 48 hr. EC50 daphnia magna >1000 mg/L; 72 hr. EC50 Pseudokirchnerella subcapitata>1000 mg/L. 96 hr LC50 Pimephales promelas 1430 mg/L; 48 hr EC50 daphnia pulex 1100 mg/L; 72 hr EC50 Pseudokirchnerella subcapitata 1799 mg/L. Carbon Dioxide: 96 hr LC50 Oncorhynchus mykiss 35 mg/L. 12.2. Persistence and Degradability Aliphatic alcohol #1 and aliphatic alcohol #2 are readily biodegradable. . Light petroleum distillates is not readily biodegradable. Severely hydrotreated petroleum distillates is inherently biodegradable based on structurally similar chemicals. 12.3. Bioaccumulative Potential Aliphatic alcohol #1 has a calculated BCF of 0.5. Diisobutyl Ketone has a calculated BCF of 7. Aliphatic alcohol #2 has a calculated BCF of 3. 12.4. Mobility in Soil Aliphatic alcohol #1, aliphatic alcohol #2 and diisobutyl ketone have a high to very high mobility in soil. 12.5. Other Adverse Effects None known. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of product in accordance with all local, state/provincial and federal regulations. Additional Information: Contaminated packaging: Offer empty packaging material to local recycling facilities. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |DOT Ground: Consumer Commodity ORM-D or Limited Quantity | |Aerosols, Flammable, Limited Quantity Hazard Class | |<PICTOGRAM PHRASE> |2.1 | Identification Number| | |UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols, Limited Quantity Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, Flammable, Limited Quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills are reportable to the National Response Center under the Clean Water Act and many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: None. Section 302 Extremely Hazardous Substances (TPQ): None. SARA Section 311/312 Hazard Classes |Acute Health, Fire Hazard, Sudden Release of |Pressure Toxic Substances Control Act (TSCA) |All of the components of this product are |listed on the TSCA inventory. 15.2 US State Regulations <COMPONENT> SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |June 15, 2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.