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Sheet 0067321 Printer Friendly View
Safety Data Sheet
Date of Issue: 02-23-2015 |Revision Date: |Revision Number: 02
Imperial Supplies Part Number: 0065880
SECTION 1: IDENTIFICATION
1.1. Product Identifier
Product Form:
Product Name: 16 OZ SPRAYWAY DE-ICER LB 12PK
CAS No:
Synonyms:
1.2. Intended Use of the Product
Use of the substance/mixture: De-Icer
1.3. Name, Address, and Telephone of the Responsible Party
Company
Sprayway, Inc.
1005 S. Westgate Drive
Addison, IL 60101 United States
Phone: 1-630-628-3000
1.4. Emergency Telephone Number
Emergency | 1-866-836-8855, 1-952-852-4646
number |
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
Classification (GHS-US)
Flammable |Category 1
aerosols |
Acute |Category 3
toxicity, oral|
Acute |Category 3
toxicity, |
dermal |
Acute |Category 3
toxicity, |
inhalation |
Reproductive |Category 1B
toxicity |
Specific |Category 1
target organ |
toxicity, |
single |
exposure |
2.2. Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) |Flame |Skull & |Health | | |
| |Crossbon|Hazard | | |
| |es | | | |
Signal Word (GHS-US) |Danger
Hazard Statements (GHS-US) |Extremely flammable aerosol. Toxic if swallowed.
|Toxic in contact with skin. Toxic if inhaled. May
|damage fertility or the unborn child. Causes damage
|to organs.
Precautionary Statements |Prevention
(GHS-US) |Obtain special instructions before use. Do not
|handle until all safety precautions have been read
|and understood. Keep away from heat/sparks/open
|flames/hot surfaces. - No smoking. Do not spray on
|an open flame or other ignition source. Pressurized
|container: Do not pierce or burn, even after use. Do
|not breathe gas. Wash thoroughly after handling. Do
|not eat, drink or smoke when using this product. Use
|only outdoors or in a well-ventilated area. Wear
|protective gloves/protective clothing/eye
|protection/face protection.
|Response
|If swallowed: Immediately call a poison
|center/doctor. If on skin: Wash with plenty of
|water. If inhaled: Remove person to fresh air and
|keep comfortable for breathing. Call a poison
|center/doctor. Specific treatment (see this label).
|Rinse mouth. Take off immediately all contaminated
|clothing and wash it before reuse.
|Storage
|Store in a well-ventilated place. Keep container
|tightly closed. Store locked up. Protect from
|sunlight. Do not expose to temperatures exceeding
|50�C/122�F.
|Disposal
|Dispose of contents/container in accordance with
|local/regional/national/international regulations.
2.3. Other Hazards
Other Hazards Not Contributing to the Classification: None known.
2.4. Unknown Acute Toxicity (GHS-US)
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
Name |Product identifier |% |Classification
| | |(GHS-US)
| | |
| | |
| | |
| | |
| | |
Full text of H-phrases: See Section 16
3.2. Mixture
Name |Product identifier |% |Classification
| | |(GHS-US)
Methanol |67-56-1 |60 - 80 |
Ethylene Glycol |107-21-1 |2.5 - 10|
Isopropyl Alcohol |67-63-0 |2.5 - 10|
Carbon Dioxide |124-38-9 |1 - 2.5 |
Propane |74-98-6 |1 - 2.5 |
Other components below | |10 - 20 |
reportable levels | | |
SECTION 4: FIRST AID MEASURES
4.1. Description of First Aid Measures
First-aid Measures General: Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Take off
immediately all contaminated clothing. IF exposed or concerned: Get medical
advice/attention. Wash contaminated clothing before reuse.
First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest
in a position comfortable for breathing. Oxygen or artificial respiration if
needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce
artificial respiration with the aid of a pocket mask equipped with a one-way valve
or other proper respiratory medical device. Call a POISON CENTER or
doctor/physician.
First-aid Measures After Skin Contact: Take off immediately all contaminated
clothing. Wash off with soap and plenty of water. Call a POISON CENTER or
doctor/physician if you feel unwell. For minor skin contact, avoid spreading
material on unaffected skin.
First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water
for at least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical attention if irritation develops and persists.
First-aid Measures After Ingestion: Call a physician or poison control center
immediately. Rinse mouth. Do not induce vomiting without advice from poison
control center. If vomiting occurs, keep head low so that stomach content doesn't
get into the lungs. Do not use mouth-to-mouth method if victim ingested the
substance. Induce artificial respiration with the aid of a pocket mask equipped
with a one-way valve or other proper respiratory medical device.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:
Symptoms/Injuries After Inhalation:
Symptoms/Injuries After Skin Contact:
Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary
irritation.
Symptoms/Injuries After Ingestion:
Chronic Symptoms:
4.3. Indication of Any Immediate Medical Attention and Special Treatment
Needed
Provide general supportive measures and treat symptomatically. In case of
shortness of breath, give oxygen. Keep victim warm. Keep victim under observation.
Symptoms may be delayed.
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media: Powder. Alcohol resistant foam. Water. Carbon
dioxide (CO2).
Unsuitable Extinguishing Media: None known.
5.2. Special Hazards Arising From the Substance or Mixture
Fire Hazard: Contents under pressure. Pressurized container may explode when
exposed to heat or flame. Extremely flammable aerosol.
Explosion Hazard:
Specific methods: Use standard firefighting procedures and consider the hazards of
other involved materials. Move container from fire area if it can be done without
risk. Cool containers exposed to flames with water until well after the fire is
out. In the event of fire and/or explosion do not breathe fumes.
Reactivity:
5.3. Advice for Firefighters
Precautionary Measures Fire:
Firefighting Instructions: Move containers from fire area if you can do so without
risk. Use water spray to cool unopened containers. Containers should be cooled
with water to prevent vapor pressure build up. For massive fire in cargo area, use
unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let
fire burn out.
Protection During Firefighting: Firefighters must use standard protective
equipment including flame retardant coat, helmet with face shield, gloves, rubber
boots, and in enclosed spaces, SCBA.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Immediately evacuate personnel to safe areas. Keep people away
from and upwind of spill/leak. Keep out of low areas. Wear appropriate personal
protective equipment. Fully encapsulating, vapor protective clothing should be
worn for spills and leaks with no fire. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Ventilate closed spaces
before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
6.1.1. For Non-emergency Personnel
Protective Equipment:
Emergency Procedures:
6.1.2. For Emergency Responders
Protective Equipment:
Emergency Procedures:
6.2. Environmental Precautions
Avoid discharge into drains, water courses or onto the ground.
6.3. Methods and Material for Containment and Cleaning Up
For Containment:
Methods for Cleaning Up: Refer to attached safety data sheets and/or instructions
for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in
immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled
material. Stop leak if you can do so without risk. Move the cylinder to a safe and
open area if the leak is irreparable. Isolate area until gas has dispersed.
Prevent entry into waterways, sewer, basements or confined areas. Following
product recovery, flush area with water. For waste disposal, see section 13 of the
SDS.
6.4. Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Additional Hazards When Processed: Obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Pressurized
container: Do not pierce or burn, even after use. Do not use if spray button is
missing or defective. Do not spray on a naked flame or any other incandescent
material. Do not smoke while using or until sprayed surface is thoroughly dry. Do
not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks,
or other sources of ignition. All equipment used when handling the product must be
grounded. Ground and bond containers when transferring material. Do not re-use
empty containers. Do not breathe gas. Do not taste or swallow. Avoid contact with
skin. Avoid contact with eyes. Avoid contact during pregnancy/while nursing. Avoid
prolonged exposure. Avoid contact with clothing. Use only outdoors or in a
well-ventilated area. Use personal protective equipment as required. Observe good
industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands
thoroughly after handling. Wash contaminated clothing before reuse.
Hygiene Measures: When using, do not eat, drink or smoke. Always observe good
personal hygiene measures, such as washing after handling the material and before
eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
7.2. Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:
Storage Conditions: Store locked up. Pressurized container. Protect from sunlight
and do not expose to temperatures exceeding 50�C/122 �F. Do not puncture,
incinerate or crush. Do not handle or store near an open flame, heat or other
sources of ignition. This material can accumulate static charge which may cause
spark and become an ignition source. Store in a well-ventilated place.
Refrigeration recommended. Store away from incompatible materials (see Section 10
of the SDS). Level 1 Aerosol (NFPA 30B).
7.3. Specific End Use(s)
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
Occupational exposure limits:
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000):
Components
Type
Value
Carbon Dioxide (CAS 124-38-9)
PEL
9000 mg/m3
5000 ppm
Isopropyl Alcohol (CAS 67-63-0)
PEL
980 mg/m3
400 ppm
Methanol (CAS 67-56-1)
PEL
260 mg/m3
200 ppm
Propane (CAS 74-98-6)
PEL
1800 mg/m3
1000 ppm
US. ACGIH Threshold Limit Values:
Components
Type
Value
Form
Carbon Dioxide (CAS 124-38-9)
STEL
TWA
30000 ppm
5000 ppm
Ethylene Glycol (CAS 107-21-1)
Ceiling
100 mg/m3
Aerosol.
Isopropyl Alcohol (CAS 67-63-0)
STEL
TWA
400 ppm
200 ppm
Methanol (CAS 67-56-1)
STEL
250 ppm
200 ppm
US. NIOSH: Pocket Guide to Chemical Hazards:
Components
Type
Value
Carbon Dioxide (CAS 124-38-9)
STEL
TWA
54000 mg/m3
30000 ppm
9000 mg/m3
5000 ppm
Isopropyl Alcohol (CAS 67-63-0)
STEL
TWA
1225 mg/m3
500 ppm
980 mg/m3
400 ppm
Methanol (CAS 67-56-1)
STEL
TWA
325 mg/m3
250 ppm
260 mg/m3
200 ppm
Propane (CAS 74-98-6)
TWA
1800 mg/m3
1000 ppm
Biological limit values:
ACGIH Biological Exposure Indices:
Components
Value
Determinant
Specimen
Sampling Time
Isopropyl Alcohol (CAS 67-63-0)
40 mg/l
Acetone
Urine
*
Methanol (CAS 67-56-1)
15 mg/l
Methanol
Urine
*
* - For sampling details, please see the source document.
Exposure guidelines:
US - California OELs: Skin designation
Methanol (CAS 67-56-1) Can be absorbed
through the skin.
US - Minnesota Haz Subs: Skin designation applies
Methanol (CAS 67-56-1) Skin designation
applies.
US - Tennesse OELs: Skin designation
Methanol (CAS 67-56-1) Can be absorbed
through the skin.
US ACGIH Threshold Limit Values: Skin designation
Methanol (CAS 67-56-1) Can be absorbed
through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
Methanol (CAS 67-56-1) Can be absorbed
through the skin.
8.2. Exposure Controls
Appropriate Engineering |Good general ventilation (typically 10 air changes
Controls |per hour) should be used. Ventilation rates should
|be matched to conditions. If applicable, use process
|enclosures, local exhaust ventilation, or other
|engineering controls to maintain airborne levels
|below recommended exposure limits. If exposure
|limits have not been established, maintain airborne
|levels to an acceptable level.
Personal Protective Equipment|
Materials for Protective |
Clothing |
Hand Protection |Wear protective gloves.
Eye Protection |Wear safety glasses with side shields (or goggles).
|Wear a full-face respirator, if needed.
Skin and Body Protection |Other: Wear appropriate chemical resistant clothing.
Respiratory Protection |If permissible levels are exceeded use NIOSH
|mechanical filter / organic vapor cartridge or an
|air-supplied respirator.
Thermal Hazard Protection |Wear appropriate thermal protective clothing, when
|necessary.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
Physical State |Liquid.
Appearance |Clear.
Odor |Solvent.
Odor Threshold |Not available.
pH |Not available.
Relative Evaporation Rate |Not available.
(butylacetate=1) |
Melting Point |Not available.
Freezing Point |Not available.
Boiling Point |212 �F (100 �C) estimated
Flash Point |-156.0 �F (-104.4 �C) Propellant estimated
Auto-ignition Temperature |857.76 �F (458.76 �C) estimated
Decomposition Temperature |Not available.
Flammability (solid, gas) |Not available.
Vapor Pressure |65 - 85 psig @70F estimated
Relative Vapor Density at 20 �C |Not available.
Relative Density |0.811 g/cm3 estimated
Specific Gravity |0.811 estimated
Solubility |Not available.
Partition coefficient: |Not available.
n-octanol/water |
Viscosity |Not available.
Lower Flammable Limit |6 % estimated
Upper Flammable Limit |33.2 % estimated
9.2. Other Information
Density: 0.81 g/cm3 estimated
Flame extension: 18 in estimated
Flammability class: Flammable IB estimated
Heat of combustion: 28.84 kJ/g estimated
Heat of combustion (NFPA 30B): 16.39 kJ/g estimated
Percent volatile: 98.49 % estimated
VOC (Weight %): 80.65 % estimated
SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity
The product is stable and non-reactive under normal conditions of use, storage and
transport.
10.2 Chemical Stability
Material is stable under normal conditions.
10.3 Possibility of Hazardous Reactions
Hazardous polymerization does not occur.
10.4 Conditions to Avoid
Avoid temperatures exceeding the flash point.
10.5 Incompatible Materials
Strong oxidizing agents. Isocyanates. Chlorine.
10.6 Hazardous Decomposition Products
No hazardous decomposition products are known.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects
Acute Toxicity: Toxic by inhalation. Toxic if swallowed. Toxic in contact with
skin.
Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation.
Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary
irritation.
Respiratory or Skin Sensitization:
Respiratory sensitization: Not available.
Skin sensitization: This product is not expected to cause skin sensitization.
Germ Cell Mutagenicity: No data available to indicate product or any components
present at greater than 0.1% are mutagenic or genotoxic.
Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH,
NTP, or OSHA.
Reproductive Toxicity: May damage fertility or the unborn child.
Specific Target Organ Toxicity (Single Exposure): Causes damage to organs.
Specific Target Organ Toxicity (Repeated Exposure): Not classified.
Aspiration Hazard: Not likely, due to the form of the product.
Symptoms/Injuries After Inhalation: Toxic by inhalation. May cause damage to
organs by inhalation.
Symptoms/Injuries After Skin Contact: Toxic in contact with skin.
Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary
irritation.
Symptoms/Injuries After Ingestion: Toxic if swallowed.
Chronic Symptoms: Prolonged inhalation may be harmful.
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
Ecotoxicity: The product is not classified as environmentally hazardous. However,
this does not exclude the possibility that large or frequent spills can have a
harmful or damaging effect on the environment.
Product
Species
Test Results
16 OZ SPRAYWAY DE-ICER LB 12PK (CAS Mixture)
Aquatic
Algae
IC50
Algae
10050.251 mg/L, 72 Hours estimated
Acute
Crustacea
EC50
Daphnia
11857.5977 mg/l, 48 hours estimated
Fish
LC50
Fish
12512.8652 mg/l, 96 hours estimated
Components
Species
Test Results
Ethylene Glycol (CAS 107-21-1)
Aquatic
Crustacea
EC50
Daphnia
46300 mg/L, 48 Hours
Fish
LC50
Fathead minnow (Pimephales promelas)
8050 mg/l, 96 hours
Isopropyl Alcohol (CAS 67-63-0)
Aquatic
Algae
IC50
Algae
1000.0001 mg/L, 72 Hours
Crustacea
EC50
Daphnia
13299 mg/L, 48 Hours
Fish
LC50
Bluegill (Lepomis macrochirus)
> 1400 mg/l, 96 hours
Methanol (CAS 67-56-1)
Aquatic
Crustacea
EC50
Water flea (Daphnia magna)
> 10000 mg/l, 48 hours
Fish
LC50
Fathead minnow (Pimephales promelas)
> 100 mg/l, 96 hours
* Estimates for product may be based on additional component data not shown.
12.2. Persistence and Degradability
No data is available on the degradability of this product.
12.3. Bioaccumulative Potential
No data available.
Partition coefficient n-octanol / water (log Kow)
Ethylene Glycol -1.36
Isopropyl Alcohol 0.05
Methanol -0.77
Propane 2.36
12.4. Mobility in Soil
No data available.
12.5. Other Adverse Effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone
creation potential, endocrine disruption, global warming potential) are expected
from this component.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations:
Disposal instructions: Collect and reclaim or dispose in sealed containers at
licensed waste disposal site. Contents under pressure. Do not puncture, incinerate
or crush. This material and its container must be disposed of as hazardous waste.
Do not allow this material to drain into sewers/water supplies. Do not contaminate
ponds, waterways or ditches with chemical or used container. Dispose of
contents/container in accordance with local/regional/national/international
regulations.
Local disposal regulations: Dispose in accordance with all applicable regulations.
Hazardous waste code: The waste code should be assigned in discussion between the
user, the producer and the waste disposal company.
US RCRA Hazardous Waste U List: Reference
Methanol (CAS 67-56-1) U154
Waste from residues / unused products: Dispose of in accordance with local
regulations. Empty containers or liners may retain some product residues. This
material and its container must be disposed of in a safe manner (see: Disposal
instructions).
Additional Information: Contaminated packaging: Empty containers should be taken
to an approved waste handling site for recycling or disposal. Since emptied
containers may retain product residue, follow label warnings even after container
is emptied. Do not re-use empty containers.
SECTION 14: TRANSPORT INFORMATION
14.1 In Accordance with DOT
Proper Shipping Name |Aerosols, flammable
Hazard Class |2.1 |<PICTOGRAM PHRASE>
| |[pic]
Identification Number|UN1950 |
Label Codes |None |
ERG Number |
14.2 In Accordance with IMDG
Proper Shipping Name |AEROSOLS
Hazard Class |2.1
Identification Number|UN1950
Label Codes |2.1, 6.1 |<PICTOGRAM PHRASE>
ntification Of The | |[pic][pic]
Substance/m | |
EmS-No. (Fire) |Not available. |
EmS-No. (Spillage) |Not available. |
14.3 In Accordance with IATA
Proper Shipping Name |Aerosols, flammable
Identification Number|UN1950 |<PICTOGRAM PHRASE>
| |[pic][pic]
Hazard Class |2.1 |
Label Codes | |
ntification Of The | |
Substance/m | |
ERG Code (IATA) |10P
SECTION 15: REGULATORY INFORMATION
15.1 US Federal Regulations
<COMPONENT>
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA Hazardous Substance List (40 CFR 302.4):
Ethylene Glycol (CAS 107-21-1) Listed.
Methanol (CAS 67-56-1) Listed.
SARA 304 Emergency release notification:
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):
Not listed.
SARA 302 Extremely hazardous substance
Not listed.
SARA 313 (TRI reporting):
Chemical name
CAS number
% by wt.
Methanol
67-56-1
60 - 80
Ethylene Glycol
107-21-1
2.5 - 10
Other federal regulations:
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List:
Ethylene Glycol (CAS 107-21-1)
Methanol (CAS 67-56-1)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
Propane (CAS 74-98-6)
Safe Drinking Water Act (SDWA): Not regulated.
SARA Section 311/312 Hazard Classes |Immediate Hazard - No
|Delayed Hazard - No
|Fire Hazard -
|No
|Pressure Hazard - No
|Reactivity Hazard - No
Toxic Substances Control Act (TSCA) |Not regulated.
15.2 US State Regulations
<COMPONENT>
US. Massachusetts RTK - Substance List:
Carbon Dioxide (CAS 124-38-9)
Ethylene Glycol (CAS 107-21-1)
Isopropyl Alcohol (CAS 67-63-0)
Methanol (CAS 67-56-1)
Propane (CAS 74-98-6)
US. New Jersey Worker and Community Right-to-Know Act:
Carbon Dioxide (CAS 124-38-9)
Ethylene Glycol (CAS 107-21-1)
Isopropyl Alcohol (CAS 67-63-0)
Methanol (CAS 67-56-1)
Propane (CAS 74-98-6)
US. Pennsylvania Worker and Community Right-to-Know Law:
Carbon Dioxide (CAS 124-38-9)
Ethylene Glycol (CAS 107-21-1)
Isopropyl Alcohol (CAS 67-63-0)
Methanol (CAS 67-56-1)
Propane (CAS 74-98-6)
US. Rhode Island RTK
Ethylene Glycol (CAS 107-21-1)
Isopropyl Alcohol (CAS 67-63-0)
Methanol (CAS 67-56-1)
Propane (CAS 74-98-6)
US. California Proposition 65: WARNING: This product contains a chemical known to
the State of California to cause birth defects or other reproductive harm.
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Methanol (CAS 67-56-1) Listed: March 16,
2012
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision date |
Other |This document has been prepared in accordance with the SDS
Information |requirements of the OSHA Hazard Communication Standard 29 CFR
|1910.1200.
GHS Full Text Phrases:
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Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance. |