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Safety Data Sheet Date of Issue: 09-03-2015 |Revision Date: 09-07-2015 |Revision Number: 02 Imperial Supplies Part Number: 0067291 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: CHLORINATED BRAKE PARTS CLEANER CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company Sprayway, Inc. 1005 S. Westgate Drive Addison, IL 60101 United States Phone: 1-630-628-3000 1.4. Emergency Telephone Number Emergency | Emergency telephone US 1-866-836-8855 number |Emergency telephone outside US 1-952-852-4646 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Gases under |Compressed gas pressure | Carcinogenicit|Category 2 y | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas |Health | | | | |cylinder|hazard | | | | Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |Contains gas under pressure; may explode if heated. |Suspected of causing cancer. Precautionary Statements |Prevention: (GHS-US) |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Wear protective gloves/protective |clothing/eye protection/face protection. |Response: |If exposed or concerned: Get medical |advice/attention. Collect spillage. |Storage: Store locked up. Protect from sunlight. |Store in a well-ventilated place. |Disposal: |Dispose of contents/container in accordance with |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) None. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Perchloroethylene |127-18-4 |90 - 100| Carbon Dioxide |124-38-9 |2.5 - 10| | | | | | | | | | *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. First-aid Measures After Inhalation: If symptoms develop move victim to fresh air. Get medical attention if symptoms persist. First-aid Measures After Skin Contact: Wash off with soap and water. Get medical attention if irritation develops and persists. First-aid Measures After Eye Contact: Rinse with water. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Rinse mouth. Get medical attention if symptoms occur. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Dizziness. Headache. Nausea. Irritation of eyes and mucous membranes. Irritation of nose and throat. Skin irritation. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Dry chemical powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Firefighters should wear full protective clothing including self contained breathing apparatus. In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods: Cool containers exposed to flames with water until well after the fire is out. Protection During Firefighting: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers when transferring material. Do not re-use empty containers. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Hygiene Measures: When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 1 Aerosol. Store locked up. Contents under pressure. Do not expose to heat or store at temperatures above 120�F/49�C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Carbon Dioxide (CAS 124-38-9) PEL 9000 mg/m3 5000 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) Components Type Value Perchloroethylene (CAS 127-18-4) Ceiling 200 ppm TWA 100 ppm US. ACGIH Threshold Limit Values Components Type Value Carbon Dioxide (CAS 124-38-9) STEL 30000 ppm TWA 5000 ppm Perchloroethylene (CAS 127-18-4) STEL 100 ppm TWA 25 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Carbon Dioxide (CAS 124-38-9) STEL 54000 mg/m3 30000 ppm TWA 9000 mg/m3 5000 ppm Biological limit values: ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Perchloroethylene (CAS 127-18-4) Tetrachloroethy Blood * 127-18-4) lene 3 ppm Tetrachloroethy End-exhaled * lene air * - For sampling details, please see the source document. Exposure guidelines: US - Minnesota Haz Subs: Skin designation applies: Perchloroethylene (CAS 127-18-4) Skin designation applies. 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear appropriate chemical resistant gloves. Eye Protection |If contact is likely, safety glasses with side |shields are recommended. Skin and Body Protection |Other: Use of an impervious apron is recommended. Respiratory Protection |If permissible levels are exceeded use NIOSH |mechanical filter / organic vapor cartridge or an |air-supplied respirator. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Gas Appearance |Aerosol. Compressed gas Odor |Characteristic Odor Threshold |Not available pH |Not available Relative Evaporation Rate |Not available (butylacetate=1) | Melting Point |Not available Freezing Point |Not available Boiling Point |Not available Flash Point |Not available Auto-ignition Temperature |Not available Decomposition Temperature |Not available Flammability (solid, gas) |Not available Vapor Pressure |80 psig @70F estimated Relative Vapor Density at 20 �C |Not available Relative Density |Not available Specific Gravity |1.619 estimated Solubility |Not available Partition coefficient: | n-octanol/water | Viscosity |Not available Lower Flammable Limit |Not available Upper Flammable Limit |Not available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions Hazardous polymerization does not occur. 10.4 Conditions to Avoid Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Hydrogen chloride. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation. Irritating to skin. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Irritating to eyes. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: Suspected of causing cancer. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. May cause reproductive system disorder and/or damage. Specific Target Organ Toxicity (Single Exposure): Not classified. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: Not likely, due to the form of the product. Symptoms/Injuries After Inhalation: Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: No adverse effects due to skin contact are expected. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Expected to be a low ingestion hazard. Chronic Symptoms: Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Toxic to aquatic life with long lasting effects. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols Hazard Class |2.2 | <PICTOGRAM PHRASE> | |[pic] Identification Number|UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.2 Identification Number|UN1950 Label Codes | | <PICTOGRAM PHRASE> ntification Of The | |[pic] Substance/m | | EmS-No. (Fire) |Not available | EmS-No. (Spillage) |Not available | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, non-flammable Identification Number|UN1950 | <PICTOGRAM PHRASE> | |[pic] Hazard Class |2.2 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |2L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. CERCLA Hazardous Substance List (40 CFR 302.4): Perchloroethylene (CAS 127-18-4) Listed. SARA 304 Emergency release notification: Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. SARA 302 Extremely hazardous substance: Not listed. SARA 313 (TRI reporting): Chemical name CAS number % by wt. Perchloroethylene 127-18-4 90 - 100 Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Perchloroethylene (CAS 127-18-4) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Safe Drinking Water Act (SDWA): Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - No |Delayed Hazard - Yes |Fire Hazard - No |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated 15.2 US State Regulations <COMPONENT> US. Massachusetts RTK - Substance List: Carbon Dioxide (CAS 124-38-9) Perchloroethylene (CAS 127-18-4) US. New Jersey Worker and Community Right-to-Know Act: Carbon Dioxide (CAS 124-38-9) Perchloroethylene (CAS 127-18-4) US. Pennsylvania Worker and Community Right-to-Know Law: Carbon Dioxide (CAS 124-38-9) Perchloroethylene (CAS 127-18-4) US. Rhode Island RTK: Perchloroethylene (CAS 127-18-4) US. California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance: Perchloroethylene (CAS 127-18-4) Listed: April 1, 1988 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |09-07-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.