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SDS Sheet 0067230Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: Cable CleanÂ® RD CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Cable cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company CRC Industries, Inc 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168, 800-272-4620 1.4. Emergency Telephone Number Emergency | 800-424-9300, 703-527-3887 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Gases under |Compressed gas pressure | Skin |Category 2 corrosion/irri| tation | Carcinogenicit|Category 1B y | Reproductive |Category 1B toxicity | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Specific |Category 2 target organ | toxicity, | repeated | exposure | Hazardous to |Category 2 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas Cylinder |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Contains gas under pressure; may explode if heated. |Causes skin irritation. May cause drowsiness or |dizziness. May cause cancer. May damage fertility or |the unborn child. May cause damage to organs (liver, |kidneys) through prolonged or repeated exposure. |Toxic to aquatic life with long lasting effects. Precautionary Statements |Prevention (GHS-US) |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Do not puncture or incinerate |container. Do not expose to heat or store at |temperatures above 49Â°C/120Â°F. Use with adequate |ventilation. Open doors and windows or use other |means to ensure a fresh air supply during use and |while product is drying. If you experience |any symptoms listed on this label, increase |ventilation or leave the area. Do not breathe gas. |Do not breathe mist or vapor. Wash thoroughly after |handling. Wear protective gloves/protective |clothing/eye protection/face protection. Avoid |release to the environment. |Response |If on skin: Wash with plenty of water. If skin |irritation occurs: Get medical attention. Take off |contaminated clothing and wash before reuse. If |inhaled: Remove person to fresh air and keep |comfortable for breathing. Call a poison |center/doctor if you feel unwell. If exposed or |concerned: Get medical attention. Collect spillage. |Storage |Store locked up. Protect from sunlight. Store in a |well-ventilated place. Exposure to high temperature |may cause can to burst. |Disposal |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) Supplemental information: When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen bromide, hydrogen chloride and possibly phosgene. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Tetrachloroethylene |127-18-4 |90 - 100| Carbon dioxide |124-38-9 |1 - 3 | n-Propyl bromide |106-94-5 |1 - 3 | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: If ingestion of a large amount does occur, call a poison control center immediately. Rinse mouth. Do not induce vomiting without advice from poison control center. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: During fire, gases hazardous to health may be formed. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen bromide, hydrogen chloride and possibly phosgene. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Protection During Firefighting: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not breathe gas. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor. Do not breathe gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 1 Aerosol. Contents under pressure. Do not expose to heat or store at temperatures above 120Â°F/49Â°C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Carbon dioxide (CAS 124-38-9) PEL 9000 mg/m3 5000 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) Components Type Value Tetrachloroethylene (CAS 127-18-4) Ceiling 200 ppm TWA 100 ppm US. ACGIH Threshold Limit Values Components Type Value Carbon dioxide (CAS 124-38-9) STEL 30000 ppm TWA 5000 ppm n-Propyl bromide (CAS 106-94-5) TWA 0.1 ppm Tetrachloroethylene (CAS 127-18-4) TWA 25 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Carbon dioxide (CAS 124-38-9) STEL 54000 mg/m3 30000 ppm TWA 9000 mg/m3 5000 ppm Biological limit values: ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Tetrachloroethylene 0.5 mg/l Tetrachloroethy Blood * (CAS 127-18-4) lene 3 ppm Tetrachloroethy End-exhaled * lene air * - For sampling details, please see the source document. Exposure guidelines: US - California OELs: Skin designation n-Propyl bromide (CAS 106-94-5) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Tetrachloroethylene (CAS 127-18-4) Skin designation applies. 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Eye wash facilities |and emergency shower must be available when handling |this product. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Polyvinyl alcohol |(PVA). VitonÂ®. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Other: Wear appropriate chemical resistant clothing. |Use of an impervious apron is recommended. Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self-contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Irritating. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Fast. (butylacetate=1) | Melting Point |-166 Â°F (-110 Â°C) estimated Freezing Point |-166 Â°F (-110 Â°C) estimated Boiling Point |159.8 Â°F (71 Â°C) estimated Flash Point |None (Tag Closed Cup Auto-ignition Temperature |914 Â°F (490 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |1278.5 hPa estimated Relative Vapor Density at 20 Â°C | Relative Density |1.61 estimated Specific Gravity | Solubility |Negligible. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |3.8 % estimated Upper Flammable Limit |8 % estimated 9.2. Other Information Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)): 2 % Consumer products (40 CFR 59, Subpt. C): Not regulated State Consumer products: Not regulated VOC content (CA): 2 % VOC content (OTC): 2 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen bromide, hydrogen chloride and possibly phosgene. Contact with incompatible materials. 10.5 Incompatible Materials Acids. Bases. Strong oxidizing agents. Powdered metal. Sodium. Amines. Oxygen. Peroxide. 10.6 Hazardous Decomposition Products Hydrogen chloride. Hydrogen bromide. Chlorine. Phosgene. Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Narcotic effects. Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: May cause cancer. IARC Monographs. Overall Evaluation of Carcinogenicity Tetrachloroethylene (CAS 127-18-4) 2A Probably carcinogenic to humans. US. National Toxicology Program (NTP) Report on Carcinogens n-Propyl bromide (CAS 106-94-5) Reasonably Anticipated to be a Human Carcinogen. Tetrachloroethylene (CAS 127-18-4) Reasonably Anticipated to be a Human Carcinogen. Reproductive Toxicity: May damage fertility or the unborn child. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure: Liver. Kidneys. Aspiration Hazard: Not available. Symptoms/Injuries After Inhalation: May cause damage to organs through prolonged or repeated exposure by inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Single dose oral toxicity is considered to be extremely low. Swallowing large amounts may cause injury if aspirated into the lungs. This may be rapidly absorbed through the lungs and result in injury to other body systems. Chronic Symptoms: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Skin irritation. May cause redness and pain. Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. May cause damage to organs through prolonged or repeated exposure. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: Toxic to aquatic life with long lasting effects. Product Species Test Results Cable CleanÂ® RD Aquatic Fish LC50 Fish 19.4397 mg/l, 96 hours estimated Components Species Test Results n-Propyl bromide (CAS 106-94-5) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 67.3 mg/l, 96 hours Tetrachloroethylene (CAS 127-18-4) Aquatic Fish LC50 Rainbow trout,donaldson trout 4.73 - 5.27 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. Partition coefficient n-octanol / water (log Kow) n-Propyl bromide 2.1 Tetrachloroethylene 2.88 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material and its container must be disposed of as hazardous waste. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Hazardous waste code: F001: Waste Tetrachloroethylene - Spent halogenated solvent used in degreasing F002: Waste Tetrachloroethylene - Spent halogenated solvent D039: Waste Tetrachloroethylene US RCRA Hazardous Waste U List: Reference Tetrachloroethylene (CAS 127-18-4) U210 Additional Information: Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, poison, Limited Quantity, MARINE POLLUTANT |(Tetrachloroethylene) Hazard Class |2.2 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.2, 6.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, MARINE POLLUTANT Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |Not available. | EmS-No. (Spillage) |Not available. | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, non-flammable Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.2 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |2P SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. SARA 304 Emergency release notification: Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance: Tetrachloroethylene (CAS 127-18-4) CERCLA Hazardous Substance List (40 CFR 302.4): n-Propyl bromide (CAS 106-94-5) Tetrachloroethylene (CAS 127-18-4) CERCLA Hazardous Substances: Reportable quantity: n-Propyl bromide (CAS 106-94-5) 100 LBS Tetrachloroethylene (CAS 127-18-4) 100 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Tetrachloroethylene (CAS 127-18-4) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Safe Drinking Water Act: Not regulated. (SDWA) Food and Drug: Not regulated. Administration (FDA) SARA 302 Extremely hazardous substance: No SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - No |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100): Not listed. US. New Jersey Worker and Community Right-to-Know Act: Carbon dioxide (CAS 124-38-9) n-Propyl bromide (CAS 106-94-5) Tetrachloroethylene (CAS 127-18-4) US. Massachusetts RTK - Substance List: Carbon dioxide (CAS 124-38-9) n-Propyl bromide (CAS 106-94-5) Tetrachloroethylene (CAS 127-18-4) US. Pennsylvania Worker and Community Right-to-Know Law: Tetrachloroethylene (CAS 127-18-4) Carbon dioxide (CAS 124-38-9) n-Propyl bromide (CAS 106-94-5) US. Rhode Island RTK Tetrachloroethylene (CAS 127-18-4) US. California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Tetrachloroethylene (CAS 127-18-4) Listed: April 1, 1988 US - California Proposition 65 - CRT: Listed date/Developmental toxin n-Propyl bromide (CAS 106-94-5) Listed: December 7, 2004 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Isopropyl bromide (CAS 75-26-3) Listed: May 31, 2005 n-Propyl bromide (CAS 106-94-5) Listed: December 7, 2004 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Isopropyl bromide (CAS 75-26-3) Listed: May 31, 2005 n-Propyl bromide (CAS 106-94-5) Listed: December 7, 2004 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |12-10-2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.