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SDS Sheet 0067020Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Spray Nine Grez-OffÂ® 32 fl.oz CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Degreaser - General Purpose - Non-Aerosol 1.3. Name, Address, and Telephone of the Responsible Party Company ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Phone: 1-87-Permatex (877) 376-2839 1.4. Emergency Telephone Number Emergency |Chem-Tel: 800-255-3924 number |International Emergency: |00+1+ 813-248-0585 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2A damage/eye | irritation | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |Causes skin irritation |Causes serious eye irritation Precautionary Statements |Precautionary Statements - Prevention (GHS-US) |Wash face, hands and any exposed skin thoroughly |after handling |Wear protective gloves/protective clothing/eye |protection/face protection | |Precautionary Statements - Response |Specific treatment (see supplemental first aid |instructions on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing |If eye irritation persists: Get medical |advice/attention |IF ON SKIN: Wash with plenty of soap and water |If skin irritation occurs: Get medical |advice/attention |Take off contaminated clothing and wash before reuse | | |Precautionary Statements - Storage |Store in a well-ventilated place. Keep cool | |Precautionary Statements - Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Not applicable 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name 4.1. Description of First Aid Measures First-aid Measures General: Get medical advice/attention if you feel unwell. First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. First-aid Measures After Skin Contact: IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See section 2 for more information. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Note to physicians: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water spray (fog), Dry chemical, Carbon dioxide (CO2), Foam Unsuitable Extinguishing Media: Do not use a solid water stream as it may scatter and spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Sensitivity to Mechanical Impact: None. Sensitivity to Static Discharge: None. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Emergency Procedures: 6.2. Environmental Precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep from freezing. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear protective gloves and protective clothing. Respiratory Protection |Use NIOSH-approved air-purifying respirator with |organic vapor cartridge or canister, as appropriate. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Orange Odor |Citrus Odor Threshold |No information available pH |8-11 Relative Evaporation Rate |< 1 Butyl acetate = 1 (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |100 Â°C / 212 Â°F Flash Point |> 93 Â°C / > 200 Â°F Tag Closed Cup Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |18 mm Hg Relative Vapor Density at 20 Â°C |>1 Air = 1 Relative Density |~1.013 g/ml Specific Gravity | Solubility |Soluble in water Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information Softening point No information available Molecular weight No information available VOC Content (%) <1% Density No information available Bulk density No information available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Excessive heat. Keep from freezing. 10.5 Incompatible Materials Strong oxidizing agents 10.6 Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: No information available. Germ Cell Mutagenicity: No information available. Carcinogenicity: No information available. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: May cause irritation of respiratory tract. Symptoms/Injuries After Skin Contact: May cause skin irritation and/or dermatitis. Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Symptoms/Injuries After Ingestion: Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 WATER > 90 mL/kg ( Rat ) - - 7732-18-5 DIPROPYLENE GLYCOL = 1620 ?L/kg ( Rat ) = 5860 ?L/kg ( Rabbit ) = 42.1 ppm ( Rat ) 4 h MONONBUTYL ETHER 29911-28-2 ETHOXYLATED C9-C11 = 1378 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) - ALCOHOLS = 1400 mg/kg ( Rat ) 68439-46-3 SODIUM METASILICATE = 600 mg/kg ( Rat ) - - 6834-92-0 Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 3.2241% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea DIPROPYLENE GLYCOL MONONBUTYL ETHER 29911-28-2 - 841: 96 h Poecilia reticulata mg/L LC50 static - SODIUM METASILICATE 6834-92-0 - 210: 96 h Brachydanio rerio mg/L LC50 210: 96 h Brachydanio rerio mg/L LC50 semi-static 216: 96 h Daphnia magna mg/L EC50 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil No information available. 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal should be in accordance with applicable regional, national and local laws and regulations. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not regulated Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not regulated Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not regulated Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA Section 311/312 Hazard Classes |Acute health hazard Yes |Chronic Health Hazard No |Fire hazard No |Sudden release of pressure hazard No |Reactive Hazard No Toxic Substances Control Act (TSCA) |Complies 15.2 US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. EPA Label Information EPA Pesticide Registration Number: Not applicable SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |25-Mar-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.