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SDS Sheet 0067020

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: Spray Nine Grez-Off® 32 fl.oz                                     
 
CAS No:                                                                         
 
Synonyms: None                                                                  
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Degreaser - General Purpose - Non-Aerosol         
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
ITW Permatex                                                                    
 
10 Columbus Blvd.                                                               
 
Hartford, CT 06106 USA                                                          
 
Phone: 1-87-Permatex                                                            
 
(877) 376-2839                                                                  
 


1.4.  Emergency Telephone Number
Emergency     |Chem-Tel: 800-255-3924                                           
 
number        |International Emergency:                                         
 
              |00+1+ 813-248-0585                                               
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Skin          |Category 2    
corrosion/irri|              
tation        |              
Serious eye   |Category 2A   
damage/eye    |              
irritation    |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamation Mark
        
Signal Word (GHS-US)         |Warning                                           
 
Hazard Statements (GHS-US)   |Causes skin irritation                            
 
                             |Causes serious eye irritation                     
 
Precautionary Statements     |Precautionary Statements - Prevention             
 
(GHS-US)                     |Wash face, hands and any exposed skin thoroughly  
 
                             |after handling                                    
 
                             |Wear protective gloves/protective clothing/eye    
 
                             |protection/face protection                        
 
                             |                                                  
 
                             |Precautionary Statements - Response               
 
                             |Specific treatment (see supplemental first aid    
 
                             |instructions on this label)                       
 
                             |IF IN EYES: Rinse cautiously with water for
several 
                             |minutes. Remove contact lenses, if present and
easy 
                             |to do. Continue rinsing                           
 
                             |If eye irritation persists: Get medical           
 
                             |advice/attention                                  
 
                             |IF ON SKIN: Wash with plenty of soap and water    
 
                             |If skin irritation occurs: Get medical            
 
                             |advice/attention                                  
 
                             |Take off contaminated clothing and wash before
reuse
                             |                                                  
 
                             |                                                  
 
                             |Precautionary Statements - Storage                
 
                             |Store in a well-ventilated place. Keep cool       
 
                             |                                                  
 
                             |Precautionary Statements - Disposal               
 
                             |Dispose of contents/container to an approved waste
 
                             |disposal plant                                    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Not applicable            
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                                                                            
 


4.1.  Description of First Aid Measures
First-aid Measures General: Get medical advice/attention if you feel unwell.    
 
First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and 
 
keep at rest in a position comfortable for breathing. If symptoms persist, call
a 
physician.                                                                      
 
First-aid Measures After Skin Contact: IF ON SKIN:. Wash skin with soap and
water.
If skin irritation persists, call a physician. Wash contaminated clothing before
 
reuse.                                                                          
 
First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water
for 
several minutes. Remove contact lenses, if present and easy to do. Continue     
 
rinsing. If eye irritation persists: Get medical advice/attention.              
 
First-aid Measures After Ingestion: IF SWALLOWED. Do NOT induce vomiting. Never 
 
give anything by mouth to an unconscious person. Call a physician.              
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: See section 2 for more information.                          
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Note to physicians: Treat symptomatically.                                      
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Water spray (fog), Dry chemical, Carbon dioxide   
 
(CO2), Foam                                                                     
 
Unsuitable Extinguishing Media: Do not use a solid water stream as it may
scatter 
and spread fire.                                                                
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:                                                                    
 
Explosion Hazard:                                                               
 
Sensitivity to Mechanical Impact: None.                                         
 
Sensitivity to Static Discharge: None.                                          
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: As in any fire, wear self-contained breathing   
 
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective
gear.                                                                           
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Ensure adequate ventilation, especially in confined areas.
Avoid
contact with eyes and skin. Use personal protective equipment as required.      
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment: Ensure adequate ventilation, especially in confined areas.
 
Avoid contact with eyes and skin. Use personal protective equipment as required.
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Do not flush into surface water or sanitary sewer system. See Section 12 for    
 
additional ecological information.                                              
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Prevent further leakage or spillage if safe to do so.          
 
Methods for Cleaning Up: Ensure adequate ventilation. Soak up with inert
absorbent
material. Sweep up and shovel into suitable containers for disposal.            
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Handle in accordance with good industrial    
 
hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with
 
skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated
clothing
before reuse. Use personal protective equipment as required.                    
 
Hygiene Measures: Handle in accordance with good industrial hygiene and safety  
 
practice. Regular cleaning of equipment, work area and clothing is recommended. 
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Keep container tightly closed in a dry and well-ventilated  
 
place. Keep from freezing.                                                      
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
                                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Showers                                           
 
Controls                     |Eyewash stations                                  
 
                             |Ventilation systems                               
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Wear safety glasses with side shields (or
goggles). 
Skin and Body Protection     |Wear protective gloves and protective clothing.   
 
Respiratory Protection       |Use NIOSH-approved air-purifying respirator with  
 
                             |organic vapor cartridge or canister, as
appropriate.
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                     
 
Appearance                          |Orange                                     
 
Odor                                |Citrus                                     
 
Odor Threshold                      |No information available                   
 
pH                                  |8-11                                       
 
Relative Evaporation Rate           |< 1 Butyl acetate = 1                      
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No information available                   
 
Freezing Point                      |No information available                   
 
Boiling Point                       |100 °C / 212 °F                            
 
Flash Point                         |> 93 °C / > 200 °F Tag Closed Cup          
 
Auto-ignition Temperature           |No information available                   
 
Decomposition Temperature           |No information available                   
 
Flammability (solid, gas)           |No information available                   
 
Vapor Pressure                      |18 mm Hg                                   
 
Relative Vapor Density at 20 °C     |>1 Air = 1                                 
 
Relative Density                    |~1.013 g/ml                                
 
Specific Gravity                    |                                           
 
Solubility                          |Soluble in water                           
 
Partition coefficient:              |No information available                   
 
n-octanol/water                     |                                           
 
Viscosity                           |No information available                   
 
Lower Flammable Limit               |No information available                   
 
Upper Flammable Limit               |No information available                   
 


9.2.  Other Information
Softening point                                                                 
 
No information available                                                        
 
                                                                                
 
Molecular weight                                                                
 
No information available                                                        
 
                                                                                
 
VOC Content (%)                                                                 
 
<1%                                                                             
 
                                                                                
 
Density                                                                         
 
No information available                                                        
 
                                                                                
 
Bulk density                                                                    
 
No information available                                                        
 
                                                                                
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No data available                                                               
 


10.2      Chemical Stability
Stable under recommended storage conditions.                                    
 


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                   
 


10.4      Conditions to Avoid
Excessive heat. Keep from freezing.                                             
 


10.5      Incompatible Materials
Strong oxidizing agents                                                         
 


10.6      Hazardous Decomposition Products
Carbon oxides                                                                   
 
Nitrogen oxides (NOx)                                                           
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation:                                                      
 
Serious Eye Damage/Irritation:                                                  
 
Respiratory or Skin Sensitization: No information available.                    
 
Germ Cell Mutagenicity: No information available.                               
 
Carcinogenicity: No information available.                                      
 
Reproductive Toxicity:                                                          
 
Specific Target Organ Toxicity (Single Exposure):                               
 
Specific Target Organ Toxicity (Repeated Exposure):                             
 
Aspiration Hazard:                                                              
 
Symptoms/Injuries After Inhalation: May cause irritation of respiratory tract.  
 
Symptoms/Injuries After Skin Contact: May cause skin irritation and/or
dermatitis.
Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May
 
cause redness and tearing of the eyes.                                          
 
Symptoms/Injuries After Ingestion: Ingestion may cause irritation to mucous     
 
membranes.                                                                      
 
Chemical Name                        Oral LD50                             
Dermal
LD50                                           Inhalation LC50                  
 
WATER                                       > 90 mL/kg ( Rat )                  
 
-                                                                    -          
 
7732-18-5                                                                       
 
DIPROPYLENE GLYCOL            = 1620 ?L/kg ( Rat )             = 5860 ?L/kg (   
 
Rabbit )                           = 42.1 ppm ( Rat ) 4 h                       
 
MONONBUTYL ETHER                                                                
 
29911-28-2                                                                      
 
ETHOXYLATED C9-C11           = 1378 mg/kg ( Rat )             > 2 g/kg ( Rabbit
) 
-                                                                               
 
ALCOHOLS                                   = 1400 mg/kg ( Rat )                 
 
                                                                                
 
68439-46-3                                                                      
 
SODIUM METASILICATE              = 600 mg/kg ( Rat )                   -        
 
-                                                                               
 
6834-92-0                                                                       
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
3.2241% of the mixture consists of components(s) of unknown hazards to the
aquatic
environment                                                                     
 
Chemical Name                                                                   
 
Algae/aquatic plants                                                            
 
Fish                                                                            
 
Crustacea                                                                       
 
                                                                                
 
DIPROPYLENE GLYCOL                                                              
 
MONONBUTYL ETHER                                                                
 
29911-28-2                                                                      
 
-                                                                               
 
841: 96 h Poecilia reticulata mg/L                                              
 
LC50 static                                                                     
 
-                                                                               
 
                                                                                
 
SODIUM METASILICATE                                                             
 
6834-92-0                                                                       
 
-                                                                               
 
210: 96 h Brachydanio rerio mg/L                                                
 
LC50 210: 96 h Brachydanio rerio                                                
 
mg/L LC50 semi-static                                                           
 
216: 96 h Daphnia magna mg/L                                                    
 
EC50                                                                            
 
                                                                                
 


12.2. Persistence and Degradability
No information available.                                                       
 


12.3. Bioaccumulative Potential
No information available.                                                       
 


12.4. Mobility in Soil
No information available.                                                       
 


12.5. Other Adverse Effects
No information available.                                                       
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Disposal should be in accordance with applicable
 
regional, national and local laws and regulations.                              
 
Additional Information:                                                         
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |Not regulated                                             
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |Not regulated                                             
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Not regulated                                             
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
SARA 313                                                                        
 
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 
 
1986 (SARA). This product does not contain any chemicals which are subject to
the 
reporting requirements of the Act and Title 40 of the Code of Federal
Regulations,
Part 372.                                                                       
 
SARA Section 311/312 Hazard Classes |Acute health hazard Yes                    
 
                                    |Chronic Health Hazard No                   
 
                                    |Fire hazard No                             
 
                                    |Sudden release of pressure hazard No       
 
                                    |Reactive Hazard No                         
 
Toxic Substances Control Act (TSCA) |Complies                                   
 

15.2      US State Regulations
California Proposition 65                                                       
 
This product does not contain any Proposition 65 chemicals                      
 
                                                                                
 
U.S. EPA Label Information                                                      
 
EPA Pesticide Registration Number: Not applicable                               
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |25-Mar-2015                                                    
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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