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Safety Data Sheet Date of Issue: 10-15-2014 |Revision Date: |Revision Number: 01 Imperial Supplies Part Number: 0066990 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: Gasket Remover CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Gasket remover 1.3. Name, Address, and Telephone of the Responsible Party Company CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300 1.4. Emergency Telephone Number Emergency |800-424-9300 (US) number |703-527-3887 (International) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Gases under |Liquefied gas pressure | Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2 damage/eye | irritation | Carcinogenicit|Category 2 y | Reproductive |Category 2 toxicity | Specific |Category 3 target organ |respiratory toxicity, |tract single |irritation exposure | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Aspiration |Category 1 hazard | Hazardous to |Category 3 the aquatic | environment, | acute hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas |Health |Exclamat| | | |Cylinder|Hazard |ion Mark| | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Contains gas under |pressure; may explode if heated. May be fatal if |swallowed and enters airways. Causes skin |irritation. Causes serious eye irritation. May cause |respiratory irritation. May cause drowsiness or |dizziness. Suspected of causing cancer. Suspected of |damaging fertility or the unborn child. Harmful to |aquatic life. Precautionary Statements |Prevention: Obtain special instructions before use. (GHS-US) |Do not handle until all safety precautions have been |read and understood. Keep away from heat/sparks/open |flames/hot surfaces. - No smoking. Do not spray on |an open flame or other ignition source. Do not apply |while equipment is energized. Pressurized container: |Do not pierce or burn, even after use. Extinguish |all flames, pilot lights and heaters. Vapors will |accumulate readily and may ignite. Use only with |adequate ventilation; maintain ventilation during |use and until all vapors are gone. Open doors and |windows or use other means to ensure a fresh air |supply during use and while product is drying. If |you experience any symptoms listed on this label, |increase ventilation or leave the area. Avoid |breathing mist or vapor. Avoid breathing gas. Wash |thoroughly after handling. Wear protective |gloves/protective clothing/eye protection/face |protection. Avoid release to the environment. | |Response: If swallowed: Immediately call a poison |center/doctor. Do NOT induce vomiting. If on skin: |Wash with plenty of water. If skin irritation |occurs: Get medical attention. Take off contaminated |clothing and wash before reuse. If inhaled: Remove |person to fresh air and keep comfortable for |breathing. Call a poison center/doctor if you feel |unwell. If in eyes: Rinse cautiously with water for |several minutes. Remove contact lenses, if present |and easy to do. Continue rinsing. If eye irritation |persists: Get medical attention. If exposed or |concerned: Get medical attention. | |Storage: Store in a well-ventilated place. Store |locked up. Protect from sunlight. Do not expose to |temperatures exceeding 50Â°C/122Â°F. Exposure to high |temperature may cause can to burst. | |Disposal: Dispose of contents/container in |accordance with local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Acetone |67-64-1 |50 - 60 | Liquefied Petroleum Gas |68476-86-8 |20 - 30 | N-Methyl-2-pyrrolidone |872-50-4 |10 - 20 | Xylene |1330-20-7 |1 - 3 | Ethylbenzene |100-41-4 |< 1 | Specific chemical identity and/or percentage of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Explosion Hazard: Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Firefighting Instructions: In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Avoid breathing gas. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Methods for Cleaning Up: Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Prevent entry into waterways, sewer, basements or confined areas. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid breathing gas. Avoid contact with eyes, skin, and clothing. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Eye wash facilities |and emergency shower must be available when handling |this product. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Butyl rubber Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear appropriate chemical resistant clothing. Use of |an impervious apron is recommended. Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self-contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Solvent. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Fast. (butylacetate=1) | Melting Point |-138.5 Â°F (-94.7 Â°C) estimated Freezing Point |-138.5 Â°F (-94.7 Â°C) estimated Boiling Point |132.9 Â°F (56.1 Â°C) estimated Flash Point |56 Â°F (13.3 Â°C) Tag Closed Cup Auto-ignition Temperature |473 Â°F (245 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |1329.6 hPa estimated Relative Vapor Density at 20 Â°C |> 1 (air = 1) Relative Density |0.78 Specific Gravity | Solubility |Soluble. (water) Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |1 % estimated Upper Flammable Limit |12.8 % estimated 9.2. Other Information Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 47.5 % 51.100(s)) Consumer products Not regulated (40 CFR 59, Subpt. C) State Consumer products This product is regulated as a Gasket Adhesive Remover, Graffiti Remover and Paint Remover or Stripper. This product is compliant for use in all 50 states. VOC content (CA) 47.5 % VOC content (OTC) 47.5 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. Contact with incompatible materials. 10.5 Incompatible Materials Strong acids. Acids. Strong oxidizing agents. Halogens. Peroxides. Phenols. 10.6 Hazardous Decomposition Products Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation. Product Species Test Results Gasket Remover Acute Dermal LD50 Rabbit 15685.5908 mg/kg estimated Inhalation LC50 Rat 49210.4023 ppm, 4 hours estimated 21.4031 mg/l, 4 hours estimated Chronic Inhalation NOEL Rat 36812.8984 ppm, 8 weeks estimated Oral LD50 Mouse 248.0888 g/kg estimated NOEL Rat 193.7521 mg/kg, 90 days estimated * Estimates for product may be based on additional component data not shown. Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: Suspected of causing cancer. IARC Monographs. Overall Evaluation of Carcinogenicity Ethylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans. Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans. Reproductive Toxicity: Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals. Suspected of damaging fertility or the unborn child. Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Symptoms/Injuries After Inhalation: May cause drowsiness and dizziness. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Chronic Symptoms: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Harmful to aquatic life. Product Species Test Results Gasket Remover Aquatic Crustacea EC50 Daphnia 765.7355 mg/l, 48 hours estimated Acute Crustacea EC50 Daphnia 765.7355 mg/l, 48 hours estimated Fish LC50 Fish 912.7318 mg/l, 96 hours estimated Acetone (CAS 67-64-1) Aquatic Crustacea EC50 Water flea (Daphnia magna) 21.6 - 23.9 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 4740 - 6330 mg/l, 96 hours Ethylbenzene (CAS 100-41-4) Aquatic Acute Crustacea EC50 Water flea (Daphnia magna) 2.1 mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) 12.1 mg/l, 96 hours N-Methyl-2-pyrrolidone (CAS 872-50-4) Aquatic Acute Algae EC50 Freshwater algae 125 mg/l, 72 hours Crustacea EC50 Water flea (Daphnia magna) > 1000 mg/l, 24 hours Fish LC50 Bluegill (Lepomis macrochirus) 832 mg/l Fathead minnow (Pimephales promelas) 1072 mg/l Rainbow trout,donaldson trout (Oncorhynchus mykiss) > 500 mg/l, 96 hours Salmo gairdneri (new name 3048 mg/l Oncorhynchus mykiss) 3048 mg/l Xylene (CAS 1330-20-7) Aquatic Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 9.5 - 19.2 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. Partition coefficient n-octanol / water (log Kow) Acetone -0.24 Ethylbenzene 3.15 N-Methyl-2-pyrrolidone -0.46, at 25 Â°C Xylene 3.12 - 3.2 Bioconcentration factor (BCF) Xylene 15 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, Limited Quantity Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |Not available. | EmS-No. (Spillage) |Not available. | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable, Limited Quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Ethylbenzene (CAS 100-41-4) N-Methyl-2-pyrrolidone (CAS 872-50-4) Xylene (CAS 1330-20-7) US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) N-Methyl-2-pyrrolidone (CAS 872-50-4) Xylene (CAS 1330-20-7) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) N-Methyl-2-pyrrolidone (CAS 872-50-4) US. Rhode Island RTK Acetone (CAS 67-64-1) Ethylbenzene (CAS 100-41-4) N-Methyl-2-pyrrolidone (CAS 872-50-4) Xylene (CAS 1330-20-7) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 Cumene (CAS 98-82-8) Listed: April 6, 2010 Ethanal (CAS 75-07-0) Listed: April 1, 1988 Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 N-Methyl-2-pyrrolidone (CAS 872-50-4) Listed: June 15, 2001 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.