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SDS Sheet 0066980Printer Friendly View
Safety Data Sheet Date of Issue: 11-18-2013 |Revision Date: |Revision Number: 01 Imperial Supplies Part Number: 0066980 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: Gel Engine Degreaser CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Engine degreaser 1.3. Name, Address, and Telephone of the Responsible Party Company CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300 1.4. Emergency Telephone Number Emergency |800-424-9300 (US) number |703-527-3887 (International) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 2 aerosols | Gases under |Compressed gas pressure | Skin |Category 2 corrosion/irri| tation | Serious eye |Category 1 damage/eye | irritation | Germ cell |Category 2 mutagenicity | Carcinogenicit|Category 2 y | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Aspiration |Category 1 hazard | Hazardous to |Category 2 the aquatic | environment, | acute hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas |Corrosio|Health |Exclamat| | |Cylinder|n |Hazard |ion Mark| Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Flammable aerosol. Contains gas under pressure; may |explode if heated. May be fatal if swallowed and |enters airways. Causes skin irritation. Causes |serious eye damage. May cause drowsiness or |dizziness. Suspected of causing genetic defects. |Suspected of causing cancer. Suspected of damaging |fertility or the unborn child. Precautionary Statements |Prevention: Obtain special instructions before use. (GHS-US) |Do not handle until all safety precautions have been |read and understood. Keep away from heat/sparks/open |flames/hot surfaces. - No smoking. Do not spray on |an open flame or other ignition source. Pressurized |container: Do not pierce or burn, even after use. |Use with adequate ventilation. Open doors and |windows or use other means to ensure a fresh air |supply during use and while product is drying. If |you experience any symptoms listed on this label, |increase ventilation or leave the area. Avoid |breathing gas, mist or vapor. Wear protective |gloves/protective clothing/eye protection/face |protection. Wash hands thoroughly after handling. | |Response: If swallowed: Immediately call a poison |center/doctor. If skin irritation occurs: Get |medical attention. If exposed or concerned: Get |medical attention. Do NOT induce vomiting. If on |skin: Wash with plenty of water. Take off |contaminated clothing and wash before reuse. If in |eyes: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. Immediately call a poison |center/doctor. If inhaled: Remove person to fresh |air and keep comfortable for breathing. | |Storage: Store in a well-ventilated place. Store |locked up. Protect from sunlight. Do not expose to |temperatures exceeding 50Â°C/122Â°F. Exposure to high |temperature may cause can to burst. | |Disposal: Dispose of contents/container in |accordance with |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Harmful to aquatic life. 2.4. Unknown Acute Toxicity (GHS-US) % of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Distillates (petroleum), |64742-47-8 |70 - 80 | hydrotreated light | | | Acetone |67-64-1 |5 - 10 | Diesel Fuel No. 2 |68476-34-6 |5 - 10 | Ethoxylated nonylphenol, |68412-54-4 |5 - 10 | branched | | | Carbon dioxide |124-38-9 |3 - 5 | 2-Butoxyethanol |111-76-2 |1 - 3 | Xylene |1330-20-7 |1 - 3 | Ethylbenzene |100-41-4 |< 1 | Specific chemical identity and/or percentage of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. IF exposed or concerned: Get medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing. Wash off with soap and plenty of water. If skin irritation occurs: Get medical advice/attention. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Irritation of eyes and mucous membranes. May cause temporary blindness and severe eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause drowsiness or dizziness. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Powder. Alcohol resistant foam. Water spray. Carbon dioxide (CO2). Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Flammable aerosol. Explosion Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Collect spillage. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Methods for Cleaning Up: Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Do not get this material in contact with eyes. Do not get this material in contact with skin. Avoid breathing mist or vapor. Avoid breathing gas. Avoid contact during pregnancy/while nursing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. When using, do not eat, drink or smoke. Avoid release to the environment. Do not empty into drains. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 3 Aerosol. Store in a well-ventilated place. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Keep away from heat, sparks and open flame. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Provide eyewash |station. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves. Eye Protection |Wear eye/face protection. Wear safety glasses with |side shields (or goggles). Skin and Body Protection |Wear appropriate chemical resistant clothing. Respiratory Protection |Wear positive pressure self-contained breathing |apparatus (SCBA). Air monitoring is needed to |determine actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance | Odor |Petroleum Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Slow. (butylacetate=1) | Melting Point |-138.5 Â°F (-94.7 Â°C) estimated Freezing Point |-138.5 Â°F (-94.7 Â°C) estimated Boiling Point |320 Â°F (160 Â°C) Flash Point |34 Â°F (1.1 Â°C) Setaflash Auto-ignition Temperature |446 Â°F (230 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |1730.2 hPa estimated Relative Vapor Density at 20 Â°C |> 1 (air = 1) Relative Density |0.84 Specific Gravity | Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |0.7 % Upper Flammable Limit |5 % 9.2. Other Information Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 90 % Consumer products (40 CFR 59, Subpt. C) Not regulated State Consumer products This product is regulated as an Engine Degreaser (aerosol). This product is compliant for use in all 50 states. VOC content (CA) 10 % VOC content (OTC) 10 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Contact with incompatible materials. Avoid temperatures exceeding the flash point. 10.5 Incompatible Materials Strong oxidizing agents. Strong acids. Halogens. 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. Narcotic effects. Product Product Test Results Acute Dermal LD50 Rabbit 2033.8263 mg/kg estimated Inhalation LC50 Rat 17881.0664 ppm, 4 hours estimated 817.0072 mg/l, 4 Hours estimated Oral LD50 Rat 3967.2578 mg/kg estimated TDL0 Human 57.4941 g/kg estimated Chronic Oral NOEL Rat 1982.5536 mg/kg, 90 days estimated Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye damage. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: Suspected of causing genetic defects. Carcinogenicity: Suspected of causing cancer. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. Diesel Fuel No. 2 (CAS 68476-34-6) 3 Not classifiable as to carcinogenicity to humans. Ethylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans. Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans. Reproductive Toxicity: Possible reproductive hazard. Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals. Suspected of damaging fertility or the unborn child. Specific Target Organ Toxicity (Single Exposure): Narcotic effects. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: Causes skin irritation. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Symptoms/Injuries After Eye Contact: Causes serious eye damage. Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways. Chronic Symptoms: Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Prolonged exposure may cause chronic effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Harmful to aquatic life. Product Species Test Results Gel Engine Degreaser Acute Crustacea EC50 Daphnia 23.5522 mg/l, 48 hours estimated Fish LC50 Fish 2.932 mg/l, 96 hours estimated 2-Butoxyethanol (CAS 111-76-2) Aquatic Crustacea EC50 Water flea (Daphnia magna) 1550 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) > 1000 mg/l, 96 hours Acetone (CAS 67-64-1) Aquatic Crustacea EC50 Water flea (Daphnia magna) 21.6 - 23.9 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 4740 - 6330 mg/l, 96 hours Diesel Fuel No. 2 (CAS 68476-34-6) Aquatic Acute Fish LC50 Fathead minnow (Pimephales promelas) 35 mg/l, 96 hours Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Aquatic Acute Fish LC50 Bluegill (Lepomis macrochirus) 2.2 mg/l, 96 hours Ethoxylated nonylphenol, branched (CAS 68412-54-4) Aquatic Acute Fish LC50 Bluegill (Lepomis macrochirus) > 10 mg/l, 96 hours Ethylbenzene (CAS 100-41-4) Aquatic Acute EC50 Water flea (Daphnia magna) 2.1 mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) 12.1 mg/l, 96 hours Xylene (CAS 1330-20-7) Aquatic Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 9.5 - 19.2 mg/l, 96 hours 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.81, log Pow Acetone -0.24 Ethylbenzene 3.15 Xylene 3.12 - 3.2 Bioconcentration factor (BCF) Xylene 15 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material and its container must be disposed of as hazardous waste. If discarded, this product is considered a RCRA ignitable waste, D001. Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national regulations. Additional Information: Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, limited quantity Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |D | EmS-No. (Spillage) |U | 14.3 In Accordance with IATA UN1950 Proper Shipping Name |Aerosols, flammable, limited quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> US. New Jersey RTK - Substances: Listed substance 2-Butoxyethanol (CAS 111-76-2) Acetone (CAS 67-64-1) Carbon dioxide (CAS 124-38-9) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Acetone (CAS 67-64-1) Carbon dioxide (CAS 124-38-9) Xylene (CAS 1330-20-7) US. Pennsylvania RTK - Hazardous Substances 2-Butoxyethanol (CAS 111-76-2) Acetone (CAS 67-64-1) Carbon dioxide (CAS 124-38-9) Diesel Fuel No. 2 (CAS 68476-34-6) Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) US. Rhode Island RTK 2-Butoxyethanol (CAS 111-76-2) Acetone (CAS 67-64-1) Ethylbenzene (CAS 100-41-4) Xylene (CAS 1330-20-7) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance 1,4-Dioxane (CAS 123-91-1) Listed: January 1, 1988 Benzene (CAS 71-43-2) Listed: February 27, 1987 Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004 Ethylene oxide (CAS 75-21-8) Listed: July 1, 1987 Naphthalene (CAS 91-20-3) Listed: April 19, 2002 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Ethylene oxide (CAS 75-21-8) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Ethylene oxide (CAS 75-21-8) Listed: February 27, 1987 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Ethylene oxide (CAS 75-21-8) Listed: August 7, 2009 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.