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SDS Sheet 0066970Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: HydroForceÂ® Super Citrus Heavy Duty Degreaser CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: General purpose degreaser 1.3. Name, Address, and Telephone of the Responsible Party Company CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168, 800-272-4620 1.4. Emergency Telephone Number Emergency | 800-424-9300, 703-527-3887 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Gases under |Liquefied gas pressure | Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2A damage/eye | irritation | Sensitization,|Category 1 skin | Hazardous to |Category 2 the aquatic | environment, | acute hazard | Hazardous to |Category 2 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas Cylinder |Exclamation Mark Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |Contains gas under pressure; may explode if heated. |Causes skin irritation. May cause an allergic skin |reaction. Causes serious eye irritation. Toxic to |aquatic life. Toxic to aquatic life with long |lasting effects. Precautionary Statements |Prevention (GHS-US) |Do not puncture or incinerate container. Do not |expose to heat or store at temperatures above |49Â°C/120Â°F. Use with adequate ventilation. Open |doors and windows or use other means to ensure a |fresh air supply during use and while product is |drying. If you experience any symptoms listed on |this label, increase ventilation or leave the area. |Avoid breathing mist or vapor. Wash thoroughly after |handling. Contaminated work clothing must not be |allowed out of the workplace. Wear protective gloves |and eye/face protection. Avoid release to the |environment. |Response |If on skin: Wash with plenty of water. If skin |irritation or rash occurs: Get medical attention. |Take off contaminated clothing and wash before |reuse. If in eyes: Rinse cautiously with water for |several minutes. Remove contact lenses, if present |and easy to do. Continue rinsing. If eye irritation |persists: Get medical attention. Collect spillage. |Storage |Protect from sunlight. Store in a well-ventilated |place. Exposure to high temperature may cause can to |burst. |Disposal |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Water |7732-18-5 |60 - 70 | 1,1-Difluoroethane |75-37-6 |10 - 20 | d-Limonene |5989-27-5 |5 - 10 | Soybean oil, Methyl ester |67784-80-9 |5 - 10 | Tallow alkyl amines, ethoxylated|67784-80-9 |1 - 3 | Tallow alkyl amines |61790-33-8 |< 0.1 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting without advice from poison control center. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: May cause an allergic skin reaction. Dermatitis. Rash. Irritation of eyes and mucous membranes. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: During fire, gases hazardous to health may be formed. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Protection During Firefighting: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Avoid breathing gas. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid breathing gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Hygiene Measures: When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 1 Aerosol. Contents under pressure. Do not expose to heat or store at temperatures above 120Â°F/49Â°C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: US. AIHA Workplace Environmental Exposure Level (WEEL) Guides: Components Type Value 1,1-Difluoroethane (CAS 75-37-6) TWA 2700 mg/m3 1000 ppm d-Limonene (CAS 5989-27-5) TWA 165.5 mg/m3 30 ppm Biological limit values: No biological exposure limits noted for the ingredient(s). 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Eye wash facilities |and emergency shower must be available when handling |this product. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Rubber. Nitrile. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Other: Wear appropriate chemical resistant clothing. |Use of an impervious apron is recommended. Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Citrus. Odor Threshold |Not available. pH |10 Relative Evaporation Rate |Slow. (butylacetate=1) | Melting Point |-139.9 Â°F (-95.5 Â°C) estimated Freezing Point |-139.9 Â°F (-95.5 Â°C) estimated Boiling Point |212 Â°F (100 Â°C) estimated Flash Point |None (Tag Closed Cup) Auto-ignition Temperature |302 Â°F (150 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |1191.4 hPa estimated Relative Vapor Density at 20 Â°C | Relative Density |0.96 Specific Gravity | Solubility |Soluble. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |0.7 % estimated Upper Flammable Limit |23.5 % estimated 9.2. Other Information Volatile organic compounds (VOC) regulations: EPA VOC content (40 CFR 51.100(s)): 19.6 % Consumer products (40 CFR 59, Subpt. C): Not regulated. State Consumer products This product is regulated as a General Purpose Degreaser (aerosol). This product is compliant for use in all 50 states. VOC content (CA): 9.8 % VOC content (OTC): 9.8 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. Strong acids. 10.6 Hazardous Decomposition Products Oxides of orange terpenes. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May cause an allergic skin reaction. Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: May cause an allergic skin reaction. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity: d-Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): Not classified. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: Based on available data, the classification criteria are not met. Symptoms/Injuries After Inhalation: Material is not likely to present an inhalation hazard at ambient conditions. However, if material is heated or high vapor concentrations are attained, central nervous system depression may occur, which is characterized by drowsiness, dizziness, confusion or loss of coordination. Symptoms/Injuries After Skin Contact: Causes skin irritation. May cause an allergic skin reaction. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea. Chronic Symptoms: Dermatitis. Diarrhea. Irritation of nose and throat. Rash. Irritation of eyes and mucous membranes. May cause redness and pain. May cause an allergic skin reaction. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Prolonged exposure may cause chronic effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: Toxic to aquatic life with long lasting effects. Product Species Test Results HydroForceÂ® Super Citrus Heavy Duty Degreaser Aquatic Fish LC50 Fish 6.9494 mg/l, 96 hours estimated Acute Crustacea EC50 Daphnia 9.9928 mg/l, 48 hours estimated Components Species Test Results d-Limonene (CAS 5989-27-5) Aquatic Crustacea EC50 Water flea (Daphnia pulex) 69.6 mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) 0.619 - 0.796 mg/l, 96 hours Tallow alkyl amines, ethoxylated (CAS 61791-26-2) Aquatic Crustacea EC50 Water flea (Daphnia magna) 3.7 - 7.2 mg/l, 48 hours Fish LC50 Bluegill (Lepomis macrochirus) 1.1 - 1.6 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability * Estimates for product may be based on additional component data not shown. 12.3. Bioaccumulative Potential No data available. Partition coefficient n-octanol / water (log Kow) 1,1-Difluoroethane 0.75 d-Limonene 4.232 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal of waste from residues / unused products: This product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33). Empty containers may be recycled. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Hazardous waste code: Not regulated. Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, non-flammable, Limited Quantity Hazard Class |2.2 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.2 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANT Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |Not available. | EmS-No. (Spillage) |Not available. | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, non-flammable, Limited Quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.2 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |2L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. SARA 304 Emergency release notification: Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance: Not listed. CERCLA Hazardous Substance List (40 CFR 302.4): Not listed. CERCLA Hazardous Substances: Reportable quantity: Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): 1,1-Difluoroethane (CAS 75-37-6) Safe Drinking Water Act (SDWA): Not regulated. Food and Drug Administration (FDA): Not regulated. SARA 302 Extremely hazardous substance: No SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - No |Fire Hazard - |No |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100): Not listed. US. New Jersey Worker and Community Right-to-Know Act: 1,1-Difluoroethane (CAS 75-37-6) US. Massachusetts RTK - Substance List: 1,1-Difluoroethane (CAS 75-37-6) US. Pennsylvania Worker and Community Right-to-Know Law: Not listed. US. Rhode Island RTK: 1,1-Difluoroethane (CAS 75-37-6) US. California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance: 1,3-Dichloropropene (CAS 542-75-6) Listed: January 1, 1989 Dichloromethane (CAS 75-09-2) Listed: April 1, 1988 Diethanolamine (CAS 111-42-2) Listed: June 22, 2012 US - California Proposition 65 - CRT: Listed date/Developmental toxin: Methanol (CAS 67-56-1) Listed: March 16, 2012 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.