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SDS Sheet 0066960Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: Citrus Degreaser CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: General purpose degreaser 1.3. Name, Address, and Telephone of the Responsible Party Company CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168, 800-272-4620 1.4. Emergency Telephone Number Emergency | 800-424-9300, 703-527-3887 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Gases under |Compressed gas pressure | Acute |Category 4 toxicity, | inhalation | Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2A damage/eye | irritation | Sensitization,|Category 1 skin | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Aspiration |Category 1 hazard | Hazardous to |Category 2 the aquatic | environment, | acute hazard | Hazardous to |Category 2 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Contains gas under |pressure; may explode if heated. May be fatal if |swallowed and enters airways. Causes skin |irritation. May cause an allergic skin reaction. |Causes serious eye irritation. Harmful if inhaled. |May cause drowsiness or dizziness. Toxic to aquatic |life. Toxic to aquatic life with long lasting |effects Precautionary Statements |Prevention (GHS-US) |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. Do not spray on an open flame or other |ignition source. Do not apply while equipment is |energized. Pressurized container: Do not pierce or |burn, even after use. Extinguish all flames, pilot |lights and heaters. Vapors will accumulate readily |and may ignite. Use only with adequate ventilation; |maintain ventilation during use and until all vapors |are gone. Open doors and windows or use other means |to ensure a fresh air supply during use and while |product is drying. If you experience any symptoms |listed on this label, increase ventilation or leave |the area. Avoid breathing mist or vapor. Avoid |breathing gas. Wash thoroughly after handling. |Contaminated work clothing must not be allowed out |of the workplace. Wear protective gloves. Wear |eye/face protection. Avoid release to the |environment. |Response |If swallowed: Immediately call a poison |center/doctor. Do NOT induce vomiting. If on skin: |Wash with plenty of water. If skin irritation or |rash occurs: Get medical attention. Take off |contaminated clothing and wash before reuse. If |inhaled: Remove person to fresh air and keep |comfortable for breathing. Call a poison |center/doctor if you feel unwell. If in eyes: Rinse |cautiously with water for several minutes. Remove |contact lenses, if present and easy to do. Continue |rinsing. If eye irritation persists: Get medical |attention. Collect spillage. |Storage |Store in a well-ventilated place. Store locked up. |Protect from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F. Exposure to high temperature |may cause can to burst. |Disposal |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Distillates (petroleum), |64742-47-8 |70 - 80 | hydrotreated light | | | Dipropylene glycol monopropyl |29911-27-1 |5 - 10 | ether (dpmp) | | | d-Limonene |5989-27-5 |5 - 10 | Carbon dioxide |124-38-9 |1 - 3 | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Diarrhea. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Rash. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol resistant foam. Water fog. Dry chemical powder. Dry chemicals. Carbon dioxide (CO2). Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Extremely flammable aerosol. Contents under pressure. Pressurized container may explode when exposed to heat or flame. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Vapors are heavier than air and may spread along floors. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors and spray mists. Avoid breathing gas. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Prevent entry into waterways, sewer, basements or confined areas. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid inhalation of vapors and spray mists. Avoid breathing gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Hygiene Measures: When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000): Components Type Value Carbon dioxide (CAS 124-38-9) PEL 9000 mg/m3 US. ACGIH Threshold Limit Values Components Type Value Carbon dioxide (CAS 124-38-9) STEL 30000 ppm TWA 5000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Material Type Value Citrus Degreaser TWA 100 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Carbon dioxide (CAS 124-38-9) STEL 54000 mg/m3 30000 ppm TWA 9000 mg/m3 5000 ppm Distillates (petroleum), TWA 100 mg/m3 hydrotreated light (CAS 64742-47-8) US. AIHA Workplace Environmental Exposure Level (WEEL) Guides Components Type Value d-Limonene (CAS 5989-27-5) TWA 165.5 mg/m3 30 ppm Biological limit values: No biological exposure limits noted for the ingredient(s). 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Eye wash facilities |and emergency shower must be available when handling |this product. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Nitrile. Neoprene. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Other: Wear appropriate chemical resistant clothing. Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self-contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Citrus. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Slow. (butylacetate=1) | Melting Point |-139.9 Â°F (-95.5 Â°C) estimated Freezing Point |-139.9 Â°F (-95.5 Â°C) estimated Boiling Point |347.9 Â°F (175.5 Â°C) estimated Flash Point |170 Â°F (76.7 Â°C) Tag Closed Cup Auto-ignition Temperature |401 Â°F (205 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |1432 hPa estimated Relative Vapor Density at 20 Â°C | Relative Density |0.83 Specific Gravity | Solubility |Negligible Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |0.6 % estimated Upper Flammable Limit |6.1 % estimated 9.2. Other Information Volatile organic compounds (VOC) regulations: EPA VOC content (40 CFR 51.100(s)): 97.5 % Consumer products (40 CFR 59, Subpt. C): Not regulated State Consumer products: This product is regulated as a General Purpose Degreaser (aerosol). This product is compliant for use in all 50 states. VOC content (CA): 9.8 % VOC content (OTC): 9.8 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatibl materials. 10.5 Incompatible Materials Strong acids. Strong bases. Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. Harmful if inhaled. Narcotic effects. May cause an allergic skin reaction. Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: May cause an allergic skin reaction. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity: d-Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Symptoms/Injuries After Inhalation: Harmful if inhaled. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Symptoms/Injuries After Skin Contact: Causes skin irritation. May cause an allergic skin reaction. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Chronic Symptoms: Diarrhea. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Rash. Prolonged inhalation may be harmful. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: Toxic to aquatic life with long lasting effects. Product Species Test Results Citrus Degreaser Aquatic Crustacea Acute Fish EC50 LC50 Daphnia Fish 715.2767 mg/l, 48 hours estimated 2.8128 mg/l, 96 hours estimated Components Species Test Results Dipropylene glycol monopropyl ether (dpmp) (CAS 29911-27-1) Aquatic Acute Crustacea EC50 Water flea (Daphnia magna) > 100 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) > 100 mg/l, 96 hours Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Aquatic Acute Fish LC50 Bluegill (Lepomis macrochirus) 2.2 mg/l, 96 hours d-Limonene (CAS 5989-27-5) Aquatic Crustacea EC50 Water flea (Daphnia pulex) 69.6 mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) 0.619 - 0.796 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. Partition coefficient n-octanol / water (log Kow) Dipropylene glycol monopropyl ether (dpmp) 0.87 OECD 107 d-Limonene 4.232 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal of waste from residues / unused products: This product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33). Empty containers may be recycled. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Hazardous waste code: Not regulated. Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, Limited Quantity Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANT Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |Not available. | EmS-No. (Spillage) |Not available. | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable, Limited Quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> All components are on the U.S. EPA TSCA Inventory List. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SARA 304 Emergency release notification: Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance: Not listed. CERCLA Hazardous Substance List (40 CFR 302.4): Not listed. CERCLA Hazardous Substances: Reportable quantity: Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Safe Drinking Water Act (SDWA): Not regulated. Food and Drug Administration (FDA): Not regulated. SARA 302 Extremely hazardous substance: No SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - No |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100): Not listed. US. New Jersey Worker and Community Right-to-Know Act: Carbon dioxide (CAS 124-38-9) Distillates (petroleum), hydrotreated light (CAS 64742-47-8) US. Massachusetts RTK - Substance List: Carbon dioxide (CAS 124-38-9) US. Pennsylvania Worker and Community Right-to-Know Law: Carbon dioxide (CAS 124-38-9) Distillates (petroleum), hydrotreated light (CAS 64742-47-8) US. Rhode Island RTK: None. US. California Proposition 65: California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.