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SDS Sheet 0066930Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: Battery Cleaner with Acid Indicator CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Battery cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company: CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168, 800-272-4620 1.4. Emergency Telephone Number Emergency | 800-424-9300, 703-527-3887 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Gases under |Liquefied gas pressure | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas Cylinder Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |Contains gas under pressure; may explode if heated. Precautionary Statements |Prevention (GHS-US) |Do not puncture or incinerate container. Do not |expose to heat or store at temperatures above |49Â°C/120Â°F. Use with adequate ventilation. Open |doors and windows or use other means to ensure a |fresh air supply during use and while product is |drying. |Response |Wash hands after handling. |Storage |Protect from sunlight. Store in a well-ventilated |place. Exposure to high temperature may cause can to |burst. |Disposal |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Water |7732-18-5 |80 - 90 | Liquefied Petroleum Gas |68476-86-8 |5 - 10 | 2-Butoxyethanol |111-76-2 |1 - 3 | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. First-aid Measures After Inhalation: Move to fresh air. Call a physician if symptoms develop or persist. First-aid Measures After Skin Contact: Rinse skin with water/shower. Get medical attention if irritation develops and persists. First-aid Measures After Eye Contact: Rinse with water. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: During fire, gases hazardous to health may be formed. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Protection During Firefighting: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not get in eyes, on skin, or on clothing. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Hygiene Measures: When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 1 Aerosol. Contents under pressure. Do not expose to heat or store at temperatures above 120Â°F/49Â°C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value 2-Butoxyethanol (CAS 111-76-2) PEL 240 mg/m3 50 ppm US. ACGIH Threshold Limit Values Components Type Value 2-Butoxyethanol (CAS 111-76-2) TWA 20 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2-Butoxyethanol (CAS 111-76-2) TWA 24 mg/m3 5 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time 2-Butoxyethanol (CAS 200 mg/g Butoxyacetic Creatinine in * 111-76-2) acid (BAA), urine with hydrolysis * - For sampling details, please see the source document. Exposure guidelines: US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennessee OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Nitrile. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Other: Wear suitable protective clothing. Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Odorless. Odor Threshold |Not available. pH |8.5 Relative Evaporation Rate |Slow. (butylacetate=1) | Melting Point |-103 Â°F (-75 Â°C) estimated Freezing Point |-103 Â°F (-75 Â°C) estimated Boiling Point |212 Â°F (100 Â°C) estimated Flash Point |None (Tag Closed Cup) Auto-ignition Temperature |446 Â°F (230 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |265.9 hPa estimated Relative Vapor Density at 20 Â°C | Relative Density |1.01 Specific Gravity | Solubility |Soluble. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |1.3 % estimated Upper Flammable Limit |10.6 % estimated 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Not available. Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not a respiratory sensitizer. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity: 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. US. National Toxicology Program (NTP) Report on Carcinogens: Not available. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): Not classified. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: Not an aspiration hazard. Symptoms/Injuries After Inhalation: Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: May cause discomfort if swallowed. Chronic Symptoms: May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Product Species Test Results Battery Cleaner with Acid Indicator Aquatic Acute Crustacea EC50 Daphnia 54385.9648 mg/l, 48 hours estimated Fish LC50 Fish 5472.7153 mg/l, 96 hours estimated Components Species Test Results 2-Butoxyethanol (CAS 111-76-2) Aquatic Acute Crustacea EC50 Water flea (Daphnia magna) 1550 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout >= 1000 mg/l, 96 hours (Oncorhynchus mykiss) * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.81, log Pow 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 261.33). Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national regulations. Additional Information: Hazardous waste code: Not regulated. Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, non-flammable, limited quantity Hazard Class |2.2 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.2 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |Not available. | EmS-No. (Spillage) |Not available. | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, non-flammable, limited quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.2 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. SARA 304 Emergency release notification: Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance: 2-Butoxyethanol (CAS 111-76-2) CERCLA Hazardous Substance List (40 CFR 302.4): 2-Butoxyethanol (CAS 111-76-2) Listed. CERCLA Hazardous Substances: Reportable quantity: Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Food and Drug Administration (FDA) Not regulated. SARA 302 Extremely: No hazardous substance SARA Section 311/312 Hazard Classes |Immediate Hazard - No |Delayed Hazard - No |Fire Hazard - No |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Liquefied Petroleum Gas (CAS 68476-86-8) 2-Butoxyethanol (CAS 111-76-2) US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) US. Pennsylvania Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) US. Rhode Island RTK 2-Butoxyethanol (CAS 111-76-2) US. California Proposition 65: California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. Volatile organic compounds (VOC) regulations: EPA VOC content (40 CFR 51.100(s)) 7.9 % Consumer products: Not regulated (40 CFR 59, Subpt. C) State Consumer products: Not regulated VOC content (CA) 7.9 % VOC content (OTC) 7.9 % SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.