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SDS Sheet 0066890Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Grease. Product Name: White Lithium Grease CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Lubricating grease 1.3. Name, Address, and Telephone of the Responsible Party Company: CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US T-215-674-4300, 800-521-3168 1.4. Emergency Telephone Number Emergency |800-424-9300 (US) number |703-527-3887 (International) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable | Category 1 aerosols | Gases under |Liquefied gas pressure | Skin |Category 2 corrosion/irri| tation | Reproductive |Category 2 toxicity | (fertility) | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Specific |Category 2 target organ | toxicity, | repeated | exposure | Aspiration |Category 1 hazard | Hazardous to |Category 3 the aquatic | environment,ac| ute hazard | Hazardous to |Category 3 the aquatic | environment, | long-term | hazard | Hazardous to the aquatic environment2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Contains gas under |pressure; may explode if heated. May be fatal if |swallowed and enters airways. Causes skin |irritation. May cause drowsiness or dizziness. May |cause damage to organs (nervous system, upper |respiratory tract, skin, eyes) through prolonged or |repeated exposure. Suspected of damaging fertility. |Harmful to aquatic life. Harmful to aquatic life |with long lasting effects. Precautionary Statements |Prevention: (GHS-US) |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Keep away from heat/sparks/open |flames/hot surfaces. - No smoking. Do not spray on |an open flame or other ignition source. Do not apply |while equipment is energized. Pressurized container: |Do not pierce or burn, even after use. Extinguish |all flames, pilot lights and heaters. Vapors will |accumulate readily and may ignite. Use only with |adequate ventilation; maintain ventilation during |use and until all vapors are gone. Do not breathe |dust/fume/gas/mist/vapors/spray. Open doors and |windows or use other means to ensure a fresh air |supply during use and while product is drying. If |you experience any symptoms listed on this label, |increase ventilation or leave the area. Wash |thoroughly after handling. Wear protective |gloves/protective clothing/eye protection/face |protection. Avoid release to the environment. | |Response: |If swallowed: Immediately call a poison |center/doctor. Do NOT induce vomiting. If on skin: |Wash with plenty of water. If skin irritation |occurs: Get medical attention. Take off contaminated |clothing and wash before reuse. If inhaled: Remove |person to fresh air and keep comfortable for |breathing. Call a poison center/doctor if you feel |unwell. If exposed or concerned: Get medical |attention. | |Storage: |Store in a well-ventilated place. Store locked up. |Protect from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F. Exposure to high temperature |may cause can to burst. | |Disposal: |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Liquefied Petroleum Gas |68476-86-8 | 30 - | | |40 | Naphtha (petroleum), |64742-49-0 |30 - 40 | hydrotreated light | | | Distillates (petroleum), |64742-52-5 |10 - 20 | hydrotreated heavy naphthenic | | | 2-Methylpentane |107-83-5 | 5 - 10| n-Hexane |110-54-3 | 1 - 3 | Zinc oxide |1314-13-2 | < 1 | Calcium |57855-77-3 | < 0.2 | bis(dinonylnaphthalenesulphonate| | | ) | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Rinse with water. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may cause pulmonary edema and pneumonitis. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Explosion Hazard: Contents under pressure. Pressurized container may rupture when exposed to heat or flame. During fire, gases hazardous to health may be formed. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do not breathe dust/fume/gas/mist/vapors/spray. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible with water and will spread on the water surface. Stop the flow of material, if this is without risk. For waste disposal, see section 13 of the SDS. Prevent entry into waterways, sewer, basements or confined areas. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Form Distillates (petroleum), PEL 5 mg/m3 Mist. hydrotreated heavy naphthenic (CAS64742-52-5) 2000 mg/m3 500 ppm n-Hexane (CAS 110-54-3) PEL 1800 mg/m3 500 ppm Zinc oxide (CAS 1314-13-2) PEL 5 mg/m3 Respirable fraction. 5 mg/m3 Fume. 15 mg/m3 Total dust. US. ACGIH Threshold Limit Values Components Type Value Form 2-Methylpentane (CAS 107-83-5) STEL 1000 ppm TWA 500 ppm Distillates (petroleum), TWA 5 mg/m3 Inhalable fraction. hydrotreated heavy naphthenic (CAS64742-52-5) n-Hexane (CAS 110-54-3) TWA 50 ppm Zinc oxide (CAS 1314-13-2) STEL 10 mg/m3 Respirable fraction. TWA 2 mg/m3 Respirable fraction. US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form 2-Methylpentane (CAS 107-83-5) Ceiling 1800 mg/m3 510 ppm TWA 350 mg/m3 100 ppm Distillates (petroleum), Ceiling 1800 mg/m3 hydrotreated heavy naphthenic (CAS 64742-52-5) STEL 10mg/m3 Mist. TWA 5 mg/m3 Mist. n-Hexane (CAS 110-54-3) TWA 180 mg/m3 50 ppm Zinc oxide (CAS 1314-13-2) Ceiling 15 mg/m3 Dust. STEL 10 mg/m3 Fume. TWA 5 mg/m3 Fume. 5 mg/m3 Dust 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Eye wash facilities |and emergency shower must be available when handling |this product. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Nitrile. Polyvinyl |chloride (PVC). VitonÂ®. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear appropriate chemical resistant clothing. Use of |an impervious apron is recommended. Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Solid. Appearance | Odor |Solvent. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Fast. (butylacetate=1) | Melting Point |-244.7 Â°F (-153.7 Â°C) estimated Freezing Point |-244.7 Â°F (-153.7 Â°C) estimated Boiling Point |118.4 Â°F (48 Â°C) estimated Flash Point |< 0 Â°F (< -17.8 Â°C) Tag Closed Cup Auto-ignition Temperature |437 Â°F (225 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available Vapor Pressure |2217.9 hPa estimated Relative Vapor Density at 20 Â°C | Relative Density |0.64 estimated Specific Gravity | Solubility |Insoluble. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |1 % estimated Upper Flammable Limit |8 % estimated 9.2. Other Information VOC content (40 CFR 51.100(s): 100 % VOC content (CA) 84.7 % VOC content (OTC) 84.7 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. Chlorine. 10.6 Hazardous Decomposition Products Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. Narcotic effects. Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive Toxicity: Suspected of damaging fertility. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure):May cause damage to organs through prolonged or repeated exposure. Aspiration Hazard: May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Symptoms/Injuries After Inhalation: May cause damage to organs through prolonged or repeated exposure by inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Chronic Symptoms: Prolonged exposure may cause chronic effects. May cause damage to organs through prolonged or repeated exposure. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: Harmful to aquatic life with long lasting effects. Product Species Test Results White Lithium Grease: Aquatic Acute Crustacea EC50 Daphnia 21.9728 mg/l, 48 hours estimated Fish LC50 Fish 246.6337 ppm, 96 hours estimated Components Species Test Results Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) Aquatic Crustacea EC50 Water flea (Daphnia magna) 1000 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 5000 mg/l, 96 hours (Oncorhynchus mykiss) Components Species Test Results n-Hexane (CAS 110-54-3) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 2.101 - 2.981 mg/l, 96 hours Zinc oxide (CAS 1314-13-2) Aquatic Acute Crustacea EC50 Water flea (Daphnia magna) 0.098 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 1.1 ppm, 96 hours (Oncorhynchus mykiss) 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, Limited Quantity Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable, Limited Quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. SARA 304 Emergency release notification: Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance n-Hexane (CAS 110-54-3) Zinc oxide (CAS 1314-13-2) CERCLA Hazardous Substance List (40 CFR 302.4) n-Hexane (CAS 110-54-3): Listed. CERCLA Hazardous Substances: Reportable quantity n-Hexane (CAS 110-54-3): 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: n-Hexane (CAS 110-54-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Safe Drinking Water Act (SDWA): Not regulated. Food and Drug Administration (FDA): Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - Yes |Pressure Hazard -Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Liquefied Petroleum Gas (CAS 68476-86-8) Naphtha (petroleum), hydrotreated light (CAS 64742-49-0) Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) n-Hexane (CAS 110-54-3) US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100): Not listed. US. New Jersey Worker and Community Right-to-Know Act 2-Methylpentane (CAS 107-83-5) n-Hexane (CAS 110-54-3) Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) US. Massachusetts RTK - Substance List 2-Methylpentane (CAS 107-83-5) n-Hexane (CAS 110-54-3) US. Pennsylvania Worker and Community Right-to-Know Law Zinc oxide (CAS 1314-13-2) 2-Methylpentane (CAS 107-83-5) n-Hexane (CAS 110-54-3) US. Rhode Island RTK: n-Hexane (CAS 110-54-3) US. California Proposition 65: California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.