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SDS Sheet 0066880

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form: Aerosol.                                                          
 
Product Name: Freeze-Off® Super Penetrant                                       
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Penetrant                                         
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company :                                                                       
 
CRC Industries, Inc.                                                            
 
885 Louis Dr.                                                                   
 
Warminster, PA 18974 US                                                         
 
T-215-674-4300, 800-521-3168                                                    
 
                                                                                
 


1.4.  Emergency Telephone Number
Emergency     | 800-424-9300 (US), 800-424-9300 (US)                            
 
number        |703-527-3887 (International)                                     
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flammable     |Category 1    
aerosols      |              
Gases under   |Liquefied gas 
pressure      |              
Skin          |Category 2    
corrosion/irri|              
tation        |              
Serious eye   |Category 2A   
damage/eye    |              
irritation    |              
Sensitization,|Category 1    
skin          |              
Specific      |Category 3    
target organ  |respiratory   
toxicity,     |tract         
single        |irritation    
exposure      |              
Specific      |Category 2    
target organ  |              
toxicity,     |              
repeated      |              
exposure      |              
Aspiration    |Category 1    
hazard        |              
Hazardous to  |Category 3    
the aquatic   |              
environment,  |              
long-term     |              
hazard        |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame |Gas Cylinder |Health Hazard |Exclamation
Mark
         
Signal Word (GHS-US)         |Danger                                            
 
Hazard Statements (GHS-US)   |Extremely flammable aerosol. Contains gas under   
 
                             |pressure; may explode if heated. May be fatal if  
 
                             |swallowed and enters airways. Causes skin         
 
                             |irritation. May cause an allergic skin reaction.  
 
                             |Causes serious eye irritation. May cause
respiratory
                             |irritation. May cause damage to organs through    
 
                             |prolonged or repeated exposure. Harmful to aquatic
 
                             |life with long lasting effects.                   
 
Precautionary Statements     |Prevention:                                       
 
(GHS-US)                     |Keep away from heat/sparks/open flames/hot
surfaces.
                             |- No smoking. Do not spray on an open flame or
other
                             |ignition source. Do not apply while equipment is  
 
                             |energized. Pressurized container: Do not pierce or
 
                             |burn, even after use. Extinguish all flames, pilot
 
                             |lights and heaters. Vapors will accumulate readily
 
                             |and may ignite. Use only with adequate
ventilation; 
                             |maintain ventilation during                       
 
                             |use and until all vapors are gone. Open doors and 
 
                             |windows or use other means to ensure a fresh air  
 
                             |supply during use and while product is drying. If 
 
                             |you experience any symptoms listed on this label, 
 
                             |increase ventilation or leave the area. Do not    
 
                             |breathe gas, mist or vapor. Contaminated work     
 
                             |clothing must not be allowed out of the workplace.
 
                             |Wear protective gloves and eye/face protection.
Wash
                             |hands thoroughly after handling. Avoid release to 
 
                             |the environment.                                  
 
                             |Response:                                         
 
                             |If swallowed: Immediately call a poison           
 
                             |center/doctor. Do NOT induce vomiting. If on skin:
 
                             |Wash with plenty of water. If skin irritation or  
 
                             |rash occurs: Get medical attention. Take off      
 
                             |contaminated clothing and wash before reuse. If   
 
                             |inhaled: Remove person to fresh air and keep      
 
                             |comfortable for breathing. Call a poison          
 
                             |center/doctor if you feel unwell. If in eyes:
Rinse 
                             |cautiously with water for several minutes. Remove 
 
                             |contact lenses, if present and easy to do.
Continue 
                             |rinsing. If eye irritation persists: Get medical  
 
                             |attention.                                        
 
                             |Storage:                                          
 
                             |Store locked up. Store in a well-ventilated place.
 
                             |Protect from sunlight. Do not expose to
temperatures
                             |exceeding 50°C/122°F. Exposure to high temperature
 
                             |may cause can to burst.                           
 
                             |Disposal:                                         
 
                             |Dispose of contents/container in accordance with  
 
                             |local/regional/national regulations               
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Static accumulating       
 
flammable liquid can become electrostatically charged even in bonded and
grounded 
equipment. Sparks may ignite liquid and vapor. May cause flash fire or
explosion. 


2.4.  Unknown Acute Toxicity (GHS-US)
87.51% of the mixture consists of component(s) of unknown long-term hazards to
the
aquatic environment.                                                            
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
1,1-Difluoroethane              |75-37-6              |40 - 50 |                
 
Distillates (petroleum),        |64742-46-7           |20 - 30 |                
 
hydrotreated middle             |                     |        |                
 
Distillates (petroleum),        |64742-47-8           |5 - 10  |                
 
hydrotreated light              |                     |        |                
 
Turpentine, oil                 |8006-64-2            |5 - 10  |                
 
COzol® 306                      |Proprietary          |4 - 6   |                
 
Stoddard Solvent                |8052-41-3            |3 - 5   |                
 
2-Butoxyethanol                 |111-76-2             |1 - 3   |                
 
4-Hydroxy-4-methylpentan-2-one  |123-42-2             |1 - 3   |                
 
(Diacetone alcohol)             |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General: Ensure that medical personnel are aware of the      
 
material(s) involved, and take precautions to                                   
 
protect themselves. Wash contaminated clothing before reuse.                    
 
First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest
 
in a position comfortable for breathing. Call a POISON CENTER or
doctor/physician 
if you feel unwell.                                                             
 
First-aid Measures After Skin Contact: Remove contaminated clothing immediately 
 
and wash skin with soap and water. In case of eczema or other skin disorders:
Seek
medical attention and take along these instructions. Wash contaminated clothing 
 
before reuse.                                                                   
 
First-aid Measures After Eye Contact: Immediately flush eyes with plenty of
water 
for at least 15 minutes. Remove contact lenses, if present and easy to do.      
 
Continue rinsing. Get medical attention if irritation develops and persists.    
 
First-aid Measures After Ingestion: Call a physician or poison control center   
 
immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head 
 
low so that stomach content doesn't get into the lungs. Aspiration may cause    
 
pulmonary edema and pneumonitis.                                                
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: Symptoms may include stinging, tearing, redness, swelling,
and 
blurred vision. May cause an allergic skin reaction. Dermatitis. Rash. May cause
 
redness and pain. Prolonged exposure may cause chronic effects.                 
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Provide general supportive measures and treat symptomatically. Keep victim under
 
observation. Symptoms may be delayed.                                           
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Water spray. Water fog. Foam. Dry chemical powder,
 
carbon dioxide, sand or earth may be used                                       
 
for small fires only.                                                           
 
Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this
 
will spread the fire.                                                           
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Extremely flammable aerosol.                                       
 
Explosion Hazard: Contents under pressure. Pressurized container may explode
when 
exposed to heat or flame. This product is a poor conductor of electricity and
can 
become electrostatically charged. If sufficient charge is accumulated, ignition
of
flammable mixtures can occur. Static electricity accumulation may be
significantly
increased by the presence of small quantities of water or other contaminants.   
 
Material will float and may ignite on surface of water.                         
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions: In case of fire: Stop leak if safe to do so. Do not  
 
move cargo or vehicle if cargo has been exposed to heat. If tank, rail car or
tank
truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all
directions; 
also consider initial evacuation for 800 meters (1/2 mile) in all directions.   
 
ALWAYS stay away from tanks engulfed in flame. Move containers from fire area if
 
you can do so without risk. Containers should be cooled with water to prevent   
 
vapor pressure build up. For massive fire in cargo area, use unmanned hose
holder 
or monitor nozzles, if possible. If not, withdraw and let fire burn out.        
 
Protection During Firefighting: Firefighters must use standard protective       
 
equipment including flame retardant coat, helmet with                           
 
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.                
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Emergency Procedures: Keep unnecessary personnel away. Keep   
 
people away from and upwind of spill/leak. Keep out of low areas. Remove all    
 
possible sources of ignition in the surrounding area. Wear appropriate
protective 
equipment and clothing during clean-up. Do not touch damaged containers or
spilled
material unless wearing appropriate protective clothing. Do not breathe gas,
mist 
or vapor. Ventilate closed spaces before entering them. Use appropriate         
 
containment to avoid environmental contamination. Transfer by mechanical means  
 
such as vacuum truck to a salvage tank or other suitable container for recovery
or
safe disposal. Local authorities should be advised if significant spillages
cannot
be contained. For personal protection, see section 8 of the SDS.                
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
                                                                                
 


6.2.  Environmental Precautions
Avoid release to the environment. Contact local authorities in case of spillage
to
drain/aquatic environment. Prevent further leakage or spillage if safe to do so.
 
Do not contaminate water. Avoid discharge into drains, water courses or onto the
 
ground. Use appropriate containment to avoid environmental contamination.       
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares,    
 
sparks, or flames in immediate area). Keep                                      
 
combustibles (wood, paper, oil, etc.) away from spilled material.               
 
Large Spills: Stop leak if you can do so without risk. Move the cylinder to a
safe
and open area if the leak is irreparable. Isolate area until gas has dispersed. 
 
Dike the spilled material, where this is possible. Cover with plastic sheet to  
 
prevent spreading. Absorb in vermiculite, dry sand or earth and place into      
 
containers. Scoop up used absorbent into drums or other appropriate container.  
 
Prevent entry into waterways, sewer, basements or confined areas. Following     
 
product recovery, flush area with water.                                        
 
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean
surface 
thoroughly to remove residual contamination.  Never return spills to original   
 
containers for re-use. For waste disposal, see section 13 of the SDS.           
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Minimize fire risks from flammable and       
 
combustible materials (including combustible dust and static accumulating
liquids)
or dangerous reactions with incompatible materials. Handling operations that can
 
promote accumulation of static charges include but are not limited to: mixing,  
 
filtering, pumping at high flow rates, splash filling, creating mists or sprays,
 
tank and container filling, tank cleaning, sampling, gauging, switch loading,   
 
vacuum truck operations. Pressurized container: Do not pierce or burn, even
after 
use. Do not use if spray button is missing or defective. Do not spray on a naked
 
flame or any other incandescent material. Do not smoke while using or until     
 
sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or   
 
expose containers to heat, flame, sparks, or other sources of ignition. Use     
 
caution around energized equipment. The metal container will conduct electricity
 
if it contacts a live source. This may result in injury to the user from        
 
electrical shock and/or flash fire. Do not re-use empty containers. Do not
breathe
mist or vapor. Do not breathe gas. Do not get this material in contact with
skin. 
Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. 
 
Use only in well-ventilated areas. Wear appropriate personal protective
equipment.
Wash hands thoroughly after handling. Observe good industrial hygiene practices.
 
Avoid release to the environment. Do not empty into drains. For product usage   
 
instructions, please see the product label.                                     
 
Hygiene Measures: When using, do not eat, drink or smoke. Always observe good   
 
personal hygiene measures, such as washing after handling the material and
before 
eating, drinking, and/or smoking. Routinely wash work clothing and protective   
 
equipment to remove contaminants. Contaminated work clothing should not be
allowed
out of the workplace.                                                           
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Store in a well-ventilated place. Pressurized container.    
 
Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F.
Do 
not puncture, incinerate or crush. Do not handle or store near an open flame,
heat
or other sources of ignition. This material can accumulate static charge which
may
cause spark and become an ignition source. Avoid spark promoters. These alone
may 
be insufficient to remove static electricity. Store away from incompatible      
 
materials (see Section 10 of the SDS). Keep out of the reach of children.       
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Occupational exposure limits                                                    
 
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)               
 
Components                                                        Type          
 
Value                                         Form                              
 
2-Butoxyethanol (CAS 111-76-2)                      PEL                         
 
240 mg/m3                                                                       
 
50 ppm                                                                          
 
                                                                                
 
4-Hydroxy-4-methylpentan-                              PEL                      
 
240 mg/m3                                                                       
 
2-one (Diacetone alcohol)(CAS 123-42-2)                                         
 
                                                                                
 
Distillates (petroleum),                                       PEL              
 
5 mg/m3                                          Mist.                          
 
hydrotreated middle (CAS64742-46-7)                                             
 
                                                                                
 
Distillates (petroleum),                                      PEL               
 
5 mg/m3                                          Mist.                          
 
hydrotreated middle (CAS 64742-46-7)                                            
 
                                                                                
 
Stoddard Solvent (CAS  8052-41-3)                 PEL                           
 
2900 mg/m3                                                                      
 
500 ppm                                                                         
 
                                                                                
 
Turpentine, oil (CAS 8006-64-2)                       PEL                       
 
560 mg/m3                                                                       
 
100 ppm                                                                         
 
                                                                                
 
US. ACGIH Threshold Limit Values                                                
 
Components                                                     Type             
 
Value                                             Form                          
 
2-Butoxyethanol (CAS 111-76-2)                  TWA                             
 
20 ppm                                                                          
 
                                                                                
 
4-Hydroxy-4-methylpentan-                          TWA                          
 
50 ppm                                                                          
 
2-one (Diacetone alcohol)                                                       
 
(CAS 123-42-2)                                                                  
 
                                                                                
 
Distillates (petroleum),                                  TWA                   
 
5 mg/m3                                   Inhalable fraction.                   
 
hydrotreated middle (CAS 64742-46-7)                                            
 
                                                                                
 
Stoddard Solvent (CAS 8052-41-3)               TWA                              
 
100 ppm                                                                         
 
Turpentine, oil (CAS 8006-64-2)                    TWA                          
 
20 ppm                                                                          
 
                                                                                
 
US. NIOSH: Pocket Guide to Chemical Hazards                                     
 
Components                                                     Type             
 
Value                                              Form                         
 
2-Butoxyethanol (CAS 111-76-2)                  TWA                             
 
24 mg/m3                                                                        
 
5 ppm                                                                           
 
                                                                                
 
4-Hydroxy-4-methylpentan-                           TWA                         
 
240 mg/m3                                                                       
 
2-one (Diacetone alcohol)(CAS 123-42-2)                                         
 
50 ppm                                                                          
 
                                                                                
 
Distillates (petroleum),                                    TWA                 
 
100 mg/m3                                                                       
 
hydrotreated light (CAS64742-47-8)                                              
 
                                                                                
 
Distillates (petroleum),                                    STEL                
 
10 mg/m3                                       Mist.                            
 
hydrotreated middle (CAS64742-46-7)                                             
 
TWA                                   5 mg/m3                                   
 
Mist.                                                                           
 
                                                                                
 
Stoddard Solvent (CAS 8052-41-3)                Ceiling                         
 
1800 mg/m3                                                                      
 
TWA                                   350 mg/m3                                 
 
                                                                                
 
Turpentine, oil (CAS 8006-64-2)                     TWA                         
 
560 mg/m3                                                                       
 
100 ppm                                                                         
 
                                                                                
 
US. AIHA Workplace Environmental Exposure Level (WEEL) Guides                   
 
Components                                                      Type            
 
Value                                                                           
 
1,1-Difluoroethane (CAS 75-37-6)                 TWA                            
 
2700 mg/m3                                                                      
 
1000 ppm                                                                        
 


 8.2. Exposure Controls
Appropriate Engineering      |Good general ventilation (typically 10 air changes
 
Controls                     |per hour) should be used. Ventilation rates should
 
                             |be matched to conditions. If applicable, use
process
                             |enclosures, local exhaust ventilation, or other   
 
                             |engineering controls to maintain airborne levels  
 
                             |below recommended exposure limits. If exposure    
 
                             |limits have not been established, maintain
airborne 
                             |levels to an acceptable level. Eye wash facilities
 
                             |and emergency shower must be available when
handling
                             |this product.                                     
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Wear protective gloves: Nitrile. Rubber.          
 
Eye Protection               |Wear safety glasses with side shields (or
goggles). 
Skin and Body Protection     |Wear appropriate chemical resistant clothing.     
 
Respiratory Protection       |Wear positive pressure self-contained breathing   
 
                             |apparatus (SCBA). Air monitoring is needed to     
 
                             |determine actual employee exposure levels.        
 
Thermal Hazard Protection    |Wear appropriate thermal protective clothing, when
 
                             |necessary.                                        
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid.                                    
 
Appearance                          |                                           
 
Odor                                |Pine.                                      
 
Odor Threshold                      |Not available.                             
 
pH                                  |Not available.                             
 
Relative Evaporation Rate           |Slow.                                      
 
(butylacetate=1)                    |                                           
 
Melting Point                       |-103 °F (-75 °C) estimated                 
 
Freezing Point                      |-103 °F (-75 °C) estimated                 
 
Boiling Point                       |311 °F (155 °C) estimated                  
 
Flash Point                         |126 °F (52.2 °C) Tag Closed Cup            
 
Auto-ignition Temperature           |446 °F (230 °C) estimated                  
 
Decomposition Temperature           |Not available.                             
 
Flammability (solid, gas)           |Not available.                             
 
Vapor Pressure                      |5273.9 hPa estimated                       
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |0.88 estimated                             
 
Specific Gravity                    |                                           
 
Solubility                          |Not available.                             
 
Partition coefficient:              |Not available.                             
 
n-octanol/water                     |                                           
 
Viscosity                           |Not available.                             
 
Lower Flammable Limit               |0.6 % estimated                            
 
Upper Flammable Limit               |10.6 % estimated                           
 


9.2.  Other Information
Percent volatile 100 % estimated                                                
 
VOC content (CA) 24.1 %                                                         
 
VOC content (OTC) 24.1 %                                                        
 
VOC content (40 CFR 51.100(s)): 50 %                                            
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
The product is stable and non-reactive under normal conditions of use, storage
and
transport.                                                                      
 


10.2      Chemical Stability
Material is stable under normal conditions.                                     
 


10.3      Possibility of Hazardous Reactions
No dangerous reaction known under conditions of normal use.                     
 


10.4      Conditions to Avoid
Avoid temperatures exceeding the flash point. Contact with incompatible
materials.


10.5      Incompatible Materials
Strong oxidizing agents. Chlorine.                                              
 


10.6      Hazardous Decomposition Products
Carbon oxides.                                                                  
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity: May be fatal if swallowed and enters airways. May cause an      
 
allergic skin reaction. May cause respiratory irritation.                       
 
Skin Corrosion/Irritation: Causes skin irritation.                              
 
Serious Eye Damage/Irritation: Causes serious eye irritation.                   
 
Respiratory or Skin Sensitization: Not available.                               
 
Germ Cell Mutagenicity: No data available to indicate product or any components 
 
present at greater than 0.1% are mutagenic or genotoxic.                        
 
Carcinogenicity: This product is not considered to be a carcinogen by IARC,
ACGIH,
NTP, or OSHA.                                                                   
 
Reproductive Toxicity: This product is not expected to cause reproductive or    
 
developmental effects.                                                          
 
Specific Target Organ Toxicity (Single Exposure): Respiratory tract irritation. 
 
Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs  
 
through prolonged or repeated exposure.                                         
 
Aspiration Hazard: May be fatal if swallowed and enters airways.                
 
Symptoms/Injuries After Inhalation: Prolonged inhalation may be harmful. May
cause
damage to organs by inhalation. May cause irritation to the respiratory system. 
 
Symptoms/Injuries After Skin Contact: Causes skin irritation. May cause an      
 
allergic skin reaction.                                                         
 
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is
 
repeated and prolonged. These effects have not been observed in humans.         
 
Symptoms/Injuries After Eye Contact: Causes serious eye irritation.             
 
Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways.
 
Chronic Symptoms: Prolonged inhalation may be harmful. May be harmful if
absorbed 
through skin.                                                                   
 
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is
 
repeated and prolonged. These effects have not been observed in humans.         
 
May cause damage to organs through prolonged or repeated exposure.              
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Harmful to aquatic life with long lasting effects. Accumulation in aquatic      
 
organisms is expected.                                                          
 
Product                                                                         
 
Species                                                                     Test
 
Results                                                                         
 
Freeze-Off® Super Penetrant                                                     
 
Crustacea                                     EC50                              
 
Daphnia                                           22847.4102 mg/l, 48 hours     
 
estimated                                                                       
 
Fish                                                LC50                        
 
Fish                                                   1029.5527 mg/l, 96 hours 
 
estimated                                                                       
 
                                                                                
 
Components                                                                      
 
Species                                                                      
Test
Results                                                                         
 
2-Butoxyethanol (CAS 111-76-2)                                                  
 
Aquatic                                                                         
 
Acute                                                                           
 
Crustacea                                     EC50                              
 
Water flea (Daphnia magna)                   1550 mg/l, 48 hours                
 
Fish                                                LC50                        
 
Rainbow trout,donaldson trout               >1000 mg/l, 96 hours                
 
(Oncorhynchus mykiss)                                                           
 
                                                                                
 
4-Hydroxy-4-methylpentan-2-one (Diacetone alcohol) (CAS 123-42-2)               
 
Aquatic                                                                         
 
Crustacea                                      EC50                             
 
Water flea (Daphnia magna)                     8750 mg/l, 48 hours              
 
Fish                                                 LC50                       
 
Bluegill (Lepomis macrochirus)                 420 mg/l, 96 hours               
 
Goldfish (Carassius auratus)                      > 5000 mg/l, 24 hours         
 


12.2. Persistence and Degradability
No data is available on the degradability of this product.                      
 


12.3. Bioaccumulative Potential
No data available.                                                              
 


12.4. Mobility in Soil
No data available.                                                              
 


12.5. Other Adverse Effects
No other adverse environmental effects (e.g. ozone depletion, photochemical
ozone 
creation potential, endocrine disruption, global warming potential) are expected
 
from this component.                                                            
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: This material and its container must be disposed
 
of as hazardous waste. If discarded, this product is considered a RCRA ignitable
 
waste, D001. Consult authorities before disposal. Contents under pressure. Do
not 
puncture, incinerate or crush. Do not allow this material to drain into         
 
sewers/water supplies. Do not contaminate ponds, waterways or ditches with      
 
chemical or used container. Dispose of contents/container in accordance with    
 
local/regional/national regulations.                                            
 
Additional Information: Contaminated packaging Empty containers should be taken
to
an approved waste handling site for recycling or disposal. Since emptied        
 
containers may retain product residue, follow label warnings even after
container 
is emptied. Do not re-use empty containers.                                     
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |Aerosols, flammable, limited quantity                     
 
Hazard Class         |2.1                    |<PICTOGRAM PHRASE>                
 
Identification Number|UN1950                 |                                  
 
Label Codes          |2.1                    |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |AEROSOLS, LIMITED QUANTITY                                
 
Hazard Class         |2                                                         
 
Identification Number|UN1950                                                    
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |F-D                   |                                   
 
EmS-No. (Spillage)   |S-U                   |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Aerosols, flammable, limited quantity                     
 
Identification Number|UN1950                 |<PICTOGRAM PHRASE>                
  
Hazard Class         |2.1                    |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |10L                                                       
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard
 
Communication Standard, 29 CFR 1910.1200.                                       
 
SARA 304 Emergency release notification: Not regulated.                         
 
                                                                                
 
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. 
 
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance:       
 
2-Butoxyethanol (CAS 111-76-2)                                                  
 
                                                                                
 
CERCLA Hazardous Substance List (40 CFR 302.4): 2-Butoxyethanol (CAS 111-76-2)  
 
CERCLA Hazardous Substances: Reportable quantity: Not listed.                   
 
Spills or releases resulting in the loss of any ingredient at or above its RQ   
 
require immediate notification to the National                                  
 
Response Center (800-424-8802) and to your Local Emergency Planning Committee.  
 
                                                                                
 
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not       
 
regulated.                                                                      
 
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR
68.130): 
1,1-Difluoroethane (CAS 75-37-6)                                                
 
SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes                     
 
                                    |Delayed Hazard - Yes                       
 
                                    |Fire Hazard - Yes                          
 
                                    |Pressure Hazard - Yes                      
 
                                    |Reactivity Hazard - No                     
 
Toxic Substances Control Act (TSCA) |Not regulated.                             
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
US. New Jersey RTK - Substances: Listed substance                               
 
1,1-Difluoroethane (CAS 75-37-6)                                                
 
2-Butoxyethanol (CAS 111-76-2)                                                  
 
4-Hydroxy-4-methylpentan-2-one (Diacetone alcohol) (CAS 123-42-2)               
 
Stoddard Solvent (CAS 8052-41-3)                                                
 
Turpentine, oil (CAS 8006-64-2)                                                 
 
                                                                                
 
US. Massachusetts RTK - Substance List                                          
 
1,1-Difluoroethane (CAS 75-37-6)                                                
 
2-Butoxyethanol (CAS 111-76-2)                                                  
 
4-Hydroxy-4-methylpentan-2-one (Diacetone alcohol) (CAS 123-42-2)               
 
Stoddard Solvent (CAS 8052-41-3)                                                
 
Turpentine, oil (CAS 8006-64-2)                                                 
 
                                                                                
 
US. Pennsylvania RTK - Hazardous Substances                                     
 
2-Butoxyethanol (CAS 111-76-2)                                                  
 
4-Hydroxy-4-methylpentan-2-one (Diacetone alcohol) (CAS 123-42-2)               
 
Stoddard Solvent (CAS 8052-41-3)                                                
 
                                                                                
 
US. Rhode Island RTK                                                            
 
1,1-Difluoroethane (CAS 75-37-6)                                                
 
2-Butoxyethanol (CAS 111-76-2)                                                  
 
                                                                                
 
US. California Proposition 65                                                   
 
WARNING: This product contains a chemical known to the State of California to   
 
cause cancer.                                                                   
 
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance        
 
Cumene (CAS 98-82-8) Listed: April 6, 2010                                      
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |                                                               
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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