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Safety Data Sheet Date of Issue: 11-19-2013 |Revision Date: 06-11-2014 |Revision Number: 02 Imperial Supplies Part Number: 0066820 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: Knock'er LooseÂ® Penetrating Solvent CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Penetrant 1.3. Name, Address, and Telephone of the Responsible Party Company: CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300 1.4. Emergency Telephone Number Emergency |800-424-9300 (US) number |703-527-3887 (International) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Gases under |Compressed gas pressure | Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2A damage/eye | irritation | Sensitization,|Category 1 skin | Specific |Category 3 target organ |respiratory toxicity, |tract single |irritation exposure | Specific |Category 2 target organ | toxicity, | repeated | exposure | Aspiration |Category 1 hazard | Hazardous to |Category 3 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas |Health |Exclamat| | | |Cylinder|Hazard |ion Mark| | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Contains gas under pressure; may explode if heated. |May be fatal if swallowed and enters airways. |Causes skin irritation. May cause an allergic skin |reaction. Causes serious eye irritation. May cause |respiratory irritation. Suspected of causing cancer. |May cause damage to organs through prolonged or |repeated exposure. Harmful to aquatic life with long |lasting effects. Precautionary Statements |Prevention: (GHS-US) |Do not puncture or incinerate container. Do not |expose to heat or store at temperatures above |49Â°C/120Â°F. Use with adequate ventilation. Open |doors and windows or use other means to ensure a |fresh air supply during use and while product is |drying. If you experience any symptoms listed on |this label, increase ventilation or leave the area. |Do not breathe gas, mist or vapor. Wear protective |gloves/protective clothing/eye protection/face |protection. Contaminated work clothing must not be |allowed out of the workplace. Wash hands thoroughly |after handling. Avoid release to the environment. | |Response: |If swallowed: Immediately call a poison |center/doctor. Do NOT induce vomiting. If on skin: |Wash with plenty of water. If skin irritation or |rash occurs: Get medical attention. Take off |contaminated clothing and wash before reuse. If |inhaled: Remove person to fresh air and keep |comfortable for breathing. Call a poison |center/doctor if you feel unwell. If in eyes: Rinse |cautiously with water for several minutes. Remove |contact lenses, if present and easy to do. Continue |rinsing. If eye irritation persists: Get medical |attention. | |Storage: |Store locked up. Protect from sunlight. Store in a |well-ventilated place. Exposure to high temperature |may cause can to burst. | |Disposal: |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) 90.18% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Distillates (petroleum), |64742-46-7 |40 - 50 | hydrotreated middle | | | Dipropylene glycol monomethyl |88917-22-0 |5 - 10 | ether acetate | | | Dipropylene glycol monopropyl |29911-27-1 |5 - 10 | ether (dpmp) | | | Turpentine, oil |8006-64-2 |5 - 10 | 2,6-Dimethyl-4-heptanone |108-83-8 |3 - 5 | Fatty ester |Proprietary |3 - 5 | Stoddard Solvent |8052-41-3 |3 - 5 | Carbon dioxide |124-38-9 |1 - 3 | Pine oil |8002-09-3 |1 - 3 | Pinus sylvestris extract |94266-48-5 |1 - 3 | Specific chemical identity and/or percentage of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing immediately and wash skin with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion:Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause an allergic skin reaction. Dermatitis. Rash. May cause redness and pain. Prolonged exposure may cause chronic effects. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water. Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. ALWAYS stay away from tanks engulfed in flame. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Do not breathe mist or vapor. Do not breathe gas. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Methods for Cleaning Up: Large Spills: Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Scoop up used absorbent into drums or other appropriate container. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not re-use empty containers. Do not breathe mist or vapor. Do not breathe gas. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For product usage instructions, please see the product label. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 1 Aerosol. Store in a well-ventilated place. Contents under pressure. Do not expose to heat or store at temperatures above 120Â°F/49Â°C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store away from incompatible materials (see Section 10 of the SDS). Keep out of the reach of children. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Form 2,6-Dimethyl-4-heptanone CAS 108-83-8) PEL 290 mg/m3 50 ppm Carbon dioxide (CAS 124-38-9) PEL 9000 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Form Distillates (petroleum), hydrotreated middle (CAS 64742-46-7) PEL 5000 ppm 5 mg/m3 Mist. Stoddard Solvent (CAS 8052-41-3) PEL 2900 mg/m3 500 ppm Turpentine, oil (CAS 8006-64-2) PEL 560 mg/m3 100 ppm US. ACGIH Threshold Limit Values Components Type Value 2,6-Dimethyl-4-heptanone (CAS 108-83-8) TWA 25 ppm Carbon dioxide (CAS 124-38-9) STEL TWA 30000 ppm 5000 ppm Stoddard Solvent (CAS 8052-41-3) TWA 100 ppm Turpentine, oil (CAS 8006-64-2) TWA 20 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form 2,6-Dimethyl-4-heptanone (CAS 108-83-8) TWA 150 mg/m3 25 ppm Carbon dioxide (CAS 124-38-9) STEL TWA 54000 mg/m3 30000 ppm 9000 mg/m3 5000 ppm Distillates (petroleum), hydrotreated middle (CAS 64742-46-7) STEL TWA 10 mg/m3 5 mg/m3 Mist. Stoddard Solvent (CAS 8052-41-3) Ceiling TWA 1800 mg/m3 350 mg/m3 Mist. Turpentine, oil (CAS 8006-64-2) TWA 560 mg/m3 100 ppm Biological limit values No biological exposure limits noted for the ingredient(s). 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Eye wash facilities |and emergency shower must be available when handling |this product. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Nitrile. Rubber. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear appropriate chemical resistant clothing. Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Pleasant pine. Odor Threshold |Not available pH |Not available Relative Evaporation Rate |Moderate (butylacetate=1) | Melting Point |-121 Â°F (-85 Â°C) estimated Freezing Point |-121 Â°F (-85 Â°C) estimated Boiling Point |311 Â°F (155 Â°C) estimated Flash Point |147 Â°F (63.9 Â°C) Tag Closed Cup Auto-ignition Temperature |401 Â°F (205 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |1958.7 hPa estimated Relative Vapor Density at 20 Â°C |> 1 (air = 1) Relative Density |0.86 Specific Gravity | Solubility |Negligible. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |0.7 % estimated Upper Flammable Limit |7.1 % estimated 9.2. Other Information Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 98.4 % 51.100(s)) Consumer products Not regulated (40 CFR 59, Subpt. C) State Consumer products This product is regulated as a Penetrant. This product is compliant for use in all 50 states. VOC content (CA) 23.6 % VOC content (OTC) 23.6 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. Chlorine. 10.6 Hazardous Decomposition Products Carbon monoxide. Irritating and/or toxic fumes and gases may be emitted upon the products decomposition. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. May cause an allergic skin reaction. May cause respiratory irritation. Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: ACGIH sensitization Turpentine, oil (CAS 8006-64-2) Sensitizer. Respiratory sensitization: Not available. Skin sensitization: May cause an allergic skin reaction. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): Respiratory tract irritation. Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Prolonged inhalation may be harmful. May cause damage to organs by inhalation. May cause irritation to the respiratory system. Symptoms/Injuries After Skin Contact: Causes skin irritation. May cause an allergic skin reaction. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways. Chronic Symptoms: Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. May cause damage to organs through prolonged or repeated exposure. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected. Product Species Test Results Knock'er LooseÂ® Penetrating Solvent Aquatic Acute Crustacea EC50 Daphnia 433.5422 mg/l, 48 hours estimated Fish LC50 Fish 2032.5204 ?g/l, 96 hours estimated Components Species Test Results Dipropylene glycol monomethyl ether acetate (CAS 88917-22-0) Aquatic Acute Crustacea LC50 Water flea (Daphnia magna) 2701 mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) 151 mg/l, 96 hours Rainbow trout,donaldson trout 111 mg/l, 96 hours (Oncorhynchus mykiss) Dipropylene glycol monopropyl ether (dpmp) (CAS 29911-27-1) Aquatic Acute Crustacea EC50 Water flea (Daphnia magna) > 100 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout > 100 mg/l, 96 hours (Oncorhynchus mykiss) * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations:The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33). Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national regulations. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, non-flammable, limited quantity Hazard Class |2.2 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.2 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |D | EmS-No. (Spillage) |U | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, non-flammable, limited quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.2 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |2L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. CERCLA Hazardous Substances: Reportable quantity Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Food and Drug Administration (FDA) Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - No |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. New Jersey Worker and Community Right-to-Know Act 2,6-Dimethyl-4-heptanone (CAS 108-83-8) Carbon dioxide (CAS 124-38-9) Pine oil (CAS 8002-09-3) Stoddard Solvent (CAS 8052-41-3) Turpentine, oil (CAS 8006-64-2) US. Massachusetts RTK - Substance List 2,6-Dimethyl-4-heptanone (CAS 108-83-8) Carbon dioxide (CAS 124-38-9) Stoddard Solvent (CAS 8052-41-3) Turpentine, oil (CAS 8006-64-2) US. Pennsylvania Worker and Community Right-to-Know Law 2,6-Dimethyl-4-heptanone (CAS 108-83-8) Carbon dioxide (CAS 124-38-9) Stoddard Solvent (CAS 8052-41-3) US. Rhode Island RTK None. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |06-11-2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.