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Safety Data Sheet Date of Issue: 04-28-2015 |Revision Date: |Revision Number: 01 Imperial Supplies Part Number: 0066720 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: BrakleenÂ® Brake Parts Cleaner - Non-Chlorinated CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Brake cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168 1.4. Emergency Telephone Number Emergency | 800-424-9300 (US), 703-527-3887 (International) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Gases under |Compressed gas pressure | Acute |Category 3 toxicity, oral| Acute |Category 4 toxicity, | dermal | Acute |Category 4 toxicity, | inhalation | Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2 damage/eye | irritation | Reproductive |Category 2 toxicity | (fertility, | the unborn | child) | Specific |Category 1 target organ | toxicity, | single | exposure` | Specific |Category 3 target organ |respiratory toxicity, |tract single |irritation exposure | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Specific |Category 2 target organ | toxicity, | repeated | exposure | Aspiration |Category 1 hazard | Hazardous to |Category 2 the aquatic | environment, | acute hazard | Hazardous to |Category 2 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas |Skull & |Health |Exclamat| | |Cylinder|Crossbon|Hazard |ion Mark| | | |es | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Contains gas under |pressure; may explode if heated. Toxic if swallowed. |May be fatal if swallowed and enters airways. |Harmful in contact with skin. Causes skin |irritation. Causes serious eye irritation. Harmful |if inhaled. May cause respiratory irritation. May |cause drowsiness or dizziness. May cause damage to |organs (brain, kideys, liver, lungs) through |prolonged or repeated exposure. Suspected of |damaging fertility or the unborn child. Causes |damage to organs (eyes) by ingestion. Toxic to |aquatic life. Toxic to aquatic life with long |lasting effects. Precautionary Statements |Prevention: (GHS-US) |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Keep away from heat/sparks/open |flames/hot surfaces. - No smoking. Do not spray on |an open flame or other ignition source. Do not apply |while equipment is energized. Pressurized container: |Do not pierce or burn, even after use. Extinguish |all flames, pilot lights and heaters. Vapors will |accumulate readily and may ignite. Use only with |adequate ventilation; maintain ventilation during |use and until all vapors are gone. Open doors and |windows or use other means to ensure a fresh air |supply during use and while product is drying. If |you experience any symptoms listed on this label, |increase ventilation or leave the area. Do not |breathe mist or vapor. Wash thoroughly after |handling. Do not eat, drink or smoke when using this |product. Wear protective gloves/protective |clothing/eye protection/face protection. Avoid |release to the environment. |Response: |If swallowed: Immediately call a poison |center/doctor. Rinse mouth. Do NOT induce vomiting. |If on skin: Wash with plenty of water. If skin |irritation occurs: Get medical attention. Take off |contaminated clothing and wash before reuse. If |inhaled: Remove person to fresh air and keep |comfortable for breathing. If in eyes: Rinse |cautiously with water for several minutes. Remove |contact lenses, if present and easy to do. Continue |rinsing. If eye irritation persists: Get medical |attention. If exposed: Call a poison center/doctor. |If exposed or concerned: Get medical attention. |Collect spillage. |Storage: |Store in a well-ventilated place. Store locked up. |Protect from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F. Exposure to high temperature |may cause can to burst. |Disposal: |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 21.38% of the mixture consists of component(s) of unknown acute dermal toxicity. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Acetone |67-64-1 |40 - 50 | Methanol |67-56-1 |10 - 20 | Carbon dioxide |124-38-9 |5 - 10 | n-Heptane |142-82-5 |5 - 10 | Toluene |108-88-3 |5 - 10 | 3-Methylhexane |589-34-4 |3 - 5 | Methylcyclohexane |108-87-2 |3 - 5 | Naphtha (petroleum), |64742-49-0 |3 - 5 | hydrotreated light | | | Cyclohexane |110-82-7 |1 - 3 | n-Hexane |110-54-3 |< 0.2 | Specific chemical identity and/or percentage of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Explosion Hazard: General fire hazards: Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Prevent product from entering drains. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Pregnant or breastfeeding women must not handle this product. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. Wash contaminated clothing before reuse. For product usage instructions, please see the product label. Hygiene Measures: When using do not smoke. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Carbon dioxide (CAS 124-38-9) PEL 9000 mg/m3 5000 ppm Cyclohexane (CAS 110-82-7) PEL 1050 mg/m3 300 ppm Methanol (CAS 67-56-1) PEL 260 mg/m3 200 ppm Methylcyclohexane (CAS 108-87-2) PEL 2000 mg/m3 500 ppm n-Heptane (CAS 142-82-5) PEL 2000 mg/m3 500 ppm n-Hexane (CAS 110-54-3) PEL 1800 mg/m3 500 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) Components Type Value Toluene (CAS 108-88-3) Ceiling TWA 300 ppm 200 ppm US. ACGIH Threshold Limit Values Components Type Value 3-Methylhexane (CAS 589-34-4) STEL TWA 500 ppm 400 ppm Acetone (CAS 67-64-1) STEL TWA 750 ppm 500 ppm Carbon dioxide (CAS 124-38-9) STEL TWA 30000 ppm 5000 ppm Cyclohexane (CAS 110-82-7) TWA 100 ppm US. ACGIH Threshold Limit Values Components Type Value Methanol (CAS 67-56-1) STEL TWA 250 ppm 200 ppm Methylcyclohexane (CAS 108-87-2) STEL TWA 500 ppm 400 ppm n-Heptane (CAS 142-82-5) STEL TWA 500 ppm 400 ppm n-Hexane (CAS 110-54-3) TWA 50 ppm Toluene (CAS 108-88-3) TWA 20 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Acetone (CAS 67-64-1) TWA 590 mg/m3 250 ppm Carbon dioxide (CAS 124-38-9) STEL TWA 54000 mg/m3 30000 ppm 9000 mg/m3 5000 ppm Cyclohexane (CAS 110-82-7) TWA 1050 mg/m3 300 ppm Methanol (CAS 67-56-1) STEL 325 mg/m3 250 ppm TWA 260 mg/m3 200 ppm Methylcyclohexane (CAS 108-87-2) TWA 1600 mg/m3 400 ppm n-Heptane (CAS 142-82-5) Ceiling TWA 1800 mg/m3 440 ppm 350 mg/m3 85 ppm n-Hexane (CAS 110-54-3) TWA 180 mg/m3 50 ppm Toluene (CAS 108-88-3) STEL TWA 560 mg/m3 150 ppm 375 mg/m3 100 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Acetone (CAS 67-64-1) 50 mg/l Acetone Urine * Methanol (CAS 67-56-1) 15 mg/l Methanol Urine * n-Hexane (CAS 110-54-3) 0.4 mg/l 2,5-Hexanedion, without hydrolysis Urine * Toluene (CAS 108-88-3) 0.3 mg/g 0.03 mg/l 0.02 mg/l o-Cresol, with Hydrolysis Toluene Toluene Creatinine in Urine Urine Blood * Exposure guidelines US - California OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. n-Hexane (CAS 110-54-3) Can be absorbed through the skin. Toluene (CAS 108-88-3) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Methanol (CAS 67-56-1) Skin designation applies. Toluene (CAS 108-88-3) Skin designation applies. US - Tennessee OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US - Tennessee OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. n-Hexane (CAS 110-54-3) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Eye wash facilities |and emergency shower must be available when handling |this product. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Nitrile. Neoprene. |Polyvinyl alcohol (PVA). Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Other: Wear appropriate chemical resistant |clothing. Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self-contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Solvent. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Fast. (butylacetate=1) | Melting Point |-195.9 Â°F (-126.6 Â°C) estimated Freezing Point |-195.9 Â°F (-126.6 Â°C) estimated Boiling Point |132.9 Â°F (56.1 Â°C) estimated Flash Point |< 0 Â°F (< -17.8 Â°C) Tag Closed Cup Auto-ignition Temperature |539.6 Â°F (282 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |5157.4 hPa estimated Relative Vapor Density at 20 Â°C | Relative Density |0.84 estimated Specific Gravity | Solubility |Slightly soluble. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |1.1 % estimated Upper Flammable Limit |36 % estimated 9.2. Other Information Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)): 43.8 % Consumer products(40 CFR 59, Subpt. C): Not regulated State This product: is regulated as a Brake Cleaner. This product is not compliant to be sold for use in California and the following counties in Utah: Box Elder, Cache, Davis, Salt Lake, Tooele, Utah and Weber. This product is compliant in all other states. Consumer products VOC content (CA) 43.8 % VOC content (OTC) 43.8 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. Contact with incompatible materials. 10.5 Incompatible Materials Acids. Alkalies. Amines. Ammonia. Halogens. Aluminum. Magnesium. Zinc. Peroxides. Strong oxidizing agents. Reducing agents. 10.6 Hazardous Decomposition Products Carbon oxides. Formaldehyde. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. Harmful if inhaled. Harmful in contact with skin. Narcotic effects. May cause respiratory irritation. Product: BrakleenÂ® Brake Parts Cleaner - Non-Chlorinated Acute Species Test Results Dermal LD50 Rabbit 7388 mg/kg estimated Inhalation LC50 Rat 27188 ppm, 4 hours estimated 68 mg/l, 4 Hours estimated Oral LD50 Human 305 mg/kg estimated * Estimates for product may be based on additional component data not shown. Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not a respiratory sensitizer. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Toluene (CAS 108-88-3): 3 Not classifiable as to carcinogenicity to humans. Reproductive Toxicity: Suspected of damaging fertility. Suspected of damaging the unborn child. Specific Target Organ Toxicity (Single Exposure): Causes damage to organs: Eyes. May cause respiratory irritation. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure: Liver. Kidneys. Brain. Lungs. Aspiration Hazard: May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Symptoms/Injuries After Inhalation: Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure by inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Symptoms/Injuries After Skin Contact: Harmful in contact with skin. Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Toxic if swallowed. Even small amounts (30-250 ml methanol) may be fatal. Symptoms are stomach ache, nausea, vomiting, dullness, visual disorder and blindness. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Chronic Symptoms: May cause damage to organs through prolonged or repeated exposure. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Toxic to aquatic life with long lasting effects. Product: BrakleenÂ® Brake Parts Cleaner - Non-Chlorinated Aquatic Species Test Results Acute Crustacea EC50 Daphnia 25566.5273 mg/l, 48 hours estimated Fish LC50 Fish 37.7315 mg/l, 96 hours estimated Acetone (CAS 67-64-1) Aquatic Species Test Results Crustacea EC50 Water flea (Daphnia magna) 10294 - 17704 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout , (Oncorhynchus mykiss) 4740 - 6330 mg/l, 96 hours Cyclohexane (CAS 110-82-7) Aquatic Species Test Results Fish LC50 Fathead minnow (Pimephales promelas) 23.03 - 42.07 mg/l, 96 hours Methanol (CAS 67-56-1) Aquatic Species Test Results Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 18000 - 20000 mg/l, 96 hours Acute Crustacea EC50 Water flea (Daphnia magna) > 10000 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 18000 - 20000 mg/l, 96 hours Methylcyclohexane (CAS 108-87-2) Aquatic Species Test Results Fish LC50 Striped bass (Morone saxatilis) 5.8 mg/l, 96 hours n-Heptane (CAS 142-82-5) Aquatic Species Test Results Acute Fish LC50 Fathead minnow (Pimephales promelas) 2.1 - 2.98 mg/l, 96 hours n-Hexane (CAS 110-54-3) Aquatic Species Test Results Fish LC50 Fathead minnow (Pimephales promelas) 2.101 - 2.981 mg/l, 96 hours Toluene (CAS 108-88-3) Aquatic Species Test Results Crustacea EC50 Water flea (Daphnia magna) 5.46 - 9.83 mg/l, 48 hours Fish LC50 Coho salmon,silver salmon (Oncorhynchus kisutch) 8.11 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential Partition coefficient n-octanol / water (log Kow) Acetone -0.24 Cyclohexane 3.44 Methanol -0.77 Methylcyclohexane 3.61 n-Heptane 4.66 n-Hexane 3.9 Toluene 2.73 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material and its container must be disposed of as hazardous waste. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Additional Information: Hazardous waste code: D001: Waste Flammable material with a flash point <140 F F003: Waste Non-halogenated Solvent - Spent Non-halogenated Solvent F005: Waste Non-halogenated Solvent - Spent Non-halogenated Solvent Contaminated packaging: Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, Limited Quantity, MARINE POLLUTANT Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANT Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable, Limited Quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. SARA 304 Emergency release notification: Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Cyclohexane (CAS 110-82-7) Methanol (CAS 67-56-1) Toluene (CAS 108-88-3) CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) Listed. Cyclohexane (CAS 110-82-7) Listed. Methanol (CAS 67-56-1) Listed. Toluene (CAS 108-88-3) Listed. CERCLA Hazardous Substances: Reportable quantity Acetone (CAS 67-64-1) 5000 LBS Cyclohexane (CAS 110-82-7) 1000 LBS Methanol (CAS 67-56-1) 5000 LBS Toluene (CAS 108-88-3) 1000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Methanol (CAS 67-56-1) Toluene (CAS 108-88-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Safe Drinking Water Act (SDWA): Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Toluene (CAS 108-88-3) 6594 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV Toluene (CAS 108-88-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Toluene (CAS 108-88-3) 594 Food and Drug Administration (FDA): Not regulated. SARA 302 Extremely hazardous substance: No SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |TSCA Section 12(b) Export Notification (40 |CFR 707, Subpt. D): Not regulated. 15.2 US State Regulations <COMPONENT> US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Acetone (CAS 67-64-1) Naphtha (petroleum), hydrotreated light (CAS 64742-49-0) Methanol (CAS 67-56-1) n-Hexane (CAS 110-54-3) Toluene (CAS 108-88-3) US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100): Not listed. US. New Jersey Worker and Community Right-to-Know Act: 3-Methylhexane (CAS 589-34-4) Acetone (CAS 67-64-1) Carbon dioxide (CAS 124-38-9) Methylcyclohexane (CAS 108-87-2) n-Heptane (CAS 142-82-5) Cyclohexane (CAS 110-82-7) Methanol (CAS 67-56-1) Toluene (CAS 108-88-3) US. Massachusetts RTK - Substance List: 3-Methylhexane (CAS 589-34-4) Acetone (CAS 67-64-1) Carbon dioxide (CAS 124-38-9) Cyclohexane (CAS 110-82-7) Methanol (CAS 67-56-1) Methylcyclohexane (CAS 108-87-2) n-Heptane (CAS 142-82-5) Toluene (CAS 108-88-3) US. Pennsylvania Worker and Community Right-to-Know Law: Acetone (CAS 67-64-1) Cyclohexane (CAS 110-82-7) Methanol (CAS 67-56-1) Toluene (CAS 108-88-3) Benzene (CAS 71-43-2) 3-Methylhexane (CAS 589-34-4) Carbon dioxide (CAS 124-38-9) Methylcyclohexane (CAS 108-87-2) n-Heptane (CAS 142-82-5) US. Rhode Island RTK: Acetone (CAS 67-64-1) Cyclohexane (CAS 110-82-7) Methanol (CAS 67-56-1) Toluene (CAS 108-88-3) US. California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 Cumene (CAS 98-82-8) Listed: April 6, 2010 Ethanal (CAS 75-07-0) Listed: April 1, 1988 Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Methanol (CAS 67-56-1) Listed: March 16, 2012 Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.