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SDS Sheet 0066520

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: WHITE LITHIUM GREASE 10.75OZ AE                                   
 
CAS No:                                                                         
 
Synonyms: None                                                                  
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Aerosol Lubricant                                 
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
ITW Permatex                                                                    
 
10 Columbus Blvd.                                                               
 
Hartford, CT 06106 USA                                                          
 
Phone: (877) 376-2839                                                           
 


1.4.  Emergency Telephone Number
Emergency     | 800-255-3924, 00+1+ 813-248-0585                                
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Aspiration    |Category 1    
toxicity      |              
Flammable     |Category 1    
liquids       |              
Flammable     |              
aerosols      |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Health Hazard |Flame 
        
Signal Word (GHS-US)         |Danger                                            
 
Hazard Statements (GHS-US)   |May be fatal if swallowed and enters airways      
 
                             |Extremely flammable aerosol                       
 
Precautionary Statements     |Prevention                                        
 
(GHS-US)                     |Keep away from heat/sparks/open flames/hot
surfaces.
                             |- No smoking                                      
 
                             |Do not spray on an open flame or other ignition   
 
                             |source                                            
 
                             |Pressurized container: Do not pierce or burn, even
 
                             |after use                                         
 
                             |IF SWALLOWED: Immediately call a POISON CENTER or 
 
                             |doctor/physician                                  
 
                             |Do NOT induce vomiting                            
 
                             |Storage                                           
 
                             |Store locked up                                   
 
                             |Protect from sunlight. Do not expose to
temperatures
                             |exceeding 50 °C/122 °F                            
 
                             |Disposal                                          
 
                             |Dispose of contents/container to an approved waste
 
                             |disposal plant                                    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Toxic to aquatic life with
 
long lasting effects. The classification as a carcinogen need not apply if it
can 
be shown that the substance contains less than 3 % DMSO extract as measured by
IP 
346. This note applies only to certain complex oil derived substances in Annex
I. 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
DISTILLATES (PETROLEUM),        |64741-96-4           |15 - 40 |                
 
SOLVENT-REFINED HEAVY NAPHTHENIC|                     |        |                
 
DISTILLATES (PETROLEUM),        |64742-52-5           |15 - 40 |                
 
HYDROTREATED                    |                     |        |                
 
HEAVY NAPHTHENIC                |                     |        |                
 
PROPANE                         |74-98-6              |10 - 30 |                
 
DISTILLATES (PETROLEUM),        |64742-47-8           |10 - 30 |                
 
HYDROTREATED                    |                     |        |                
 
LIGHT                           |                     |        |                
 
HEPTANE                         |142-82-5             |5 - 10  |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General: Get medical advice/attention if you feel unwell.    
 
First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and 
 
keep at rest in a position comfortable for                                      
 
breathing. If symptoms persist, call a physician.                               
 
First-aid Measures After Skin Contact: IF ON SKIN:. Wash skin with soap and
water.
If skin irritation persists, call a physician. Wash contaminated clothing before
 
reuse.                                                                          
 
First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water
for 
several minutes. Remove contact lenses, if                                      
 
present and easy to do. Continue rinsing. If eye irritation persists: Get
medical 
advice/attention.                                                               
 
First-aid Measures After Ingestion: IF SWALLOWED:. Do NOT induce vomiting. Never
 
give anything by mouth to an unconscious person. Call a physician.              
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: See section 2 for more information.                          
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Note to physicians: Treat symptomatically.                                      
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Carbon dioxide (CO2), Dry chemical, Foam.         
 
Unsuitable Extinguishing Media: None.                                           
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Extremely flammable. Keep product and empty container away from
heat 
and sources of ignition. Vapors may travel to source of ignition and flash back.
 
Explosion Hazard:                                                               
 
Sensitivity to Mechanical Impact: None.                                         
 
Sensitivity to Static Discharge: None.                                          
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: As in any fire, wear self-contained breathing   
 
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective
gear.                                                                           
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Ensure adequate ventilation, especially in confined areas.
Avoid
contact with eyes and skin. Use personal protective equipment as required.
Remove 
all sources of ignition. Contents under pressure. Do not puncture or incinerate 
 
cans.                                                                           
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
See Section 12 for additional ecological information. Do not flush into surface 
 
water or sanitary sewer system.                                                 
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Prevent further leakage or spillage if safe to do so.          
 
Methods for Cleaning Up: Eliminate all ignition sources if safe to do so. Ensure
 
adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel
 
into suitable containers for disposal.                                          
 
Prevention of secondary hazards: Clean contaminated objects and areas thoroughly
 
observing environmental regulations.                                            
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Handle in accordance with good industrial    
 
hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with
 
skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated
clothing
before reuse. Use personal protective equipment as required. Take precautionary 
 
measures against static discharges. Keep away from heat/sparks/open flames/hot  
 
surfaces. - No smoking. Contents under pressure. Do not puncture or incinerate  
 
cans.                                                                           
 
Hygiene Measures: Handle in accordance with good industrial hygiene and safety  
 
practice. Regular cleaning of equipment, work area and clothing is recommended. 
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Keep away from heat, sparks, flame and other sources of     
 
ignition (i.e., pilot lights, electric motors and static electricity).          
 
Incompatible materials: Strong oxidizing agents.                                
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Exposure Guidelines:                                                            
 
Chemical Name                                                                   
 
ACGIH TLV                                                                       
 
OSHA PEL                                                                        
 
NIOSH IDLH                                                                      
 
                                                                                
 
PROPANE                                                                         
 
74-98-6                                                                         
 
TWA: 1000 ppm                                                                   
 
TWA: 1000 ppm                                                                   
 
TWA: 1800 mg/m3                                                                 
 
(vacated) TWA: 1000 ppm                                                         
 
(vacated) TWA: 1800 mg/m3                                                       
 
IDLH: 2100 ppm                                                                  
 
TWA: 1000 ppm                                                                   
 
TWA: 1800 mg/m3                                                                 
 
                                                                                
 
HEPTANE                                                                         
 
142-82-5                                                                        
 
STEL: 500 ppm                                                                   
 
TWA: 400 ppm                                                                    
 
TWA: 500 ppm                                                                    
 
TWA: 2000 mg/m3                                                                 
 
(vacated) TWA: 400 ppm                                                          
 
(vacated) TWA: 1600 mg/m3                                                       
 
(vacated) STEL: 500 ppm                                                         
 
(vacated) STEL: 2000 mg/m3                                                      
 
IDLH: 750 ppm                                                                   
 
Ceiling: 440 ppm 15 min                                                         
 
Ceiling: 1800 mg/m3 15 min                                                      
 
TWA: 85 ppm                                                                     
 
TWA: 350 mg/m3                                                                  
 
                                                                                
 
Other Information: Vacated limits revoked by the Court of Appeals decision in   
 
AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Showers                                           
 
Controls                     |Eyewash stations                                  
 
                             |Ventilation systems.                              
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Wear safety glasses with side shields (or
goggles). 
Skin and Body Protection     |Wear protective gloves and protective clothing.   
 
Respiratory Protection       |Use NIOSH-approved air-purifying respirator with  
 
                             |organic vapor cartridge or canister, as
Appropriate.
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid; Aerosol                            
 
Appearance                          |White                                      
 
Odor                                |Solvent                                    
 
Odor Threshold                      |No information available                   
 
pH                                  |No information available                   
 
Relative Evaporation Rate           |No information available                   
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No information available                   
 
Freezing Point                      |No information available                   
 
Boiling Point                       |> 38 °C / >100 °F                          
 
Flash Point                         |< -18 °C / < 0 °F, Gives a flame projection
 
                                    |at full valve opening or flashback at any  
 
                                    |degree of valve opening                    
 
Auto-ignition Temperature           |No information available                   
 
Decomposition Temperature           |No information available                   
 
Flammability (solid, gas)           |No information available                   
 
Vapor Pressure                      |Not Determined                             
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |0.905-0.915                                
 
Specific Gravity                    |                                           
 
Solubility                          |Negligible                                 
 
Partition coefficient:              |No information available                   
 
n-octanol/water                     |                                           
 
Viscosity                           |No information available                   
 
Lower Flammable Limit               |No information available                   
 
Upper Flammable Limit               |No information available                   
 


9.2.  Other Information
Softening point: No information available                                       
 
Molecular weight: No information available                                      
 
VOC Content (%): 24.5%                                                          
 
Density: No information available                                               
 
Bulk density: No information available                                          
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No data available.                                                              
 


10.2      Chemical Stability
Stable under recommended storage conditions.                                    
 


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                   
 


10.4      Conditions to Avoid
Heat, flames and sparks. Temperatures >50 °C / 122 °F.                          
 


10.5      Incompatible Materials
Strong oxidizing agents.                                                        
 


10.6      Hazardous Decomposition Products
Carbon oxides.                                                                  
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation:                                                      
 
Serious Eye Damage/Irritation:                                                  
 
Respiratory or Skin Sensitization: No information available.                    
 
Germ Cell Mutagenicity: No information available.                               
 
Carcinogenicity: The table below indicates whether each agency has listed any   
 
ingredient as a carcinogen.                                                     
 
Reproductive Toxicity:                                                          
 
Specific Target Organ Toxicity (Single Exposure): Central nervous system,       
 
Respiratory system, Skin.                                                       
 
Specific Target Organ Toxicity (Repeated Exposure):                             
 
Aspiration Hazard:                                                              
 
Symptoms/Injuries After Inhalation: May cause irritation of respiratory tract.  
 
Symptoms/Injuries After Skin Contact: May cause skin irritation and/or
dermatitis.
Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May
 
cause redness and tearing of the eyes.                                          
 
Symptoms/Injuries After Ingestion: Potential for aspiration if swallowed.       
 
Aspiration may cause pulmonary edema and pneumonitis.                           
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Ecotoxicity: 20% of the mixture consists of components(s) of unknown hazards to 
 
the aquatic environment                                                         
 
Chemical Name                                                                   
 
Algae/aquatic plants                                                            
 
Fish                                                                            
 
Crustacea                                                                       
 
                                                                                
 
DISTILLATES (PETROLEUM),                                                        
 
SOLVENT-REFINED HEAVY                                                           
 
NAPHTHENIC                                                                      
 
64741-96-4                                                                      
 
-                                                                               
 
5000: 96 h Oncorhynchus mykiss mg/L LC50                                        
 
1000: 48 h Daphnia magna mg/L EC50                                              
 
                                                                                
 
DISTILLATES (PETROLEUM),                                                        
 
HYDROTREATED HEAVY                                                              
 
NAPHTHENIC                                                                      
 
64742-52-5                                                                      
 
-                                                                               
 
5000: 96 h Oncorhynchus mykiss mg/L LC50                                        
 
1000: 48 h Daphnia magna mg/L EC50                                              
 
                                                                                
 
DISTILLATES (PETROLEUM),                                                        
 
HYDROTREATED LIGHT                                                              
 
64742-47-8                                                                      
 
-                                                                               
 
45: 96 h Pimephales promelas mg/L LC50 flow-through 2.2: 96 h Lepomis
macrochirus 
mg/L LC50 static 2.4: 96 h Oncorhynchus mykiss mg/L LC50 static                 
 
4720: 96 h Den-dronereides heteropoda mg/L LC50                                 
 
                                                                                
 
HEPTANE                                                                         
 
142-82-5                                                                        
 
-                                                                               
 
375.0: 96 h Cichlid fish mg/L LC50                                              
 
10: 24 h Daphnia magna mg/L EC50                                                
 
                                                                                
 


12.2. Persistence and Degradability
No information available.                                                       
 


12.3. Bioaccumulative Potential
No information available.                                                       
 


12.4. Mobility in Soil
No information available.                                                       
 
Chemical Name                                                                   
 
Partition coefficient                                                           
 
                                                                                
 
PROPANE                                                                         
 
74-98-6                                                                         
 
2.3                                                                             
 
                                                                                
 
HEPTANE                                                                         
 
142-82-5                                                                        
 
4.66                                                                            
 
                                                                                
 


12.5. Other Adverse Effects
No information available.                                                       
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations:                                                 
 
Disposal of wastes: This material, as supplied, is a hazardous waste according
to 
federal regulations (40 CFR 261).                                               
 
Additional Information:                                                         
 
Contaminated packaging: Do not reuse container.                                 
 
US EPA Waste Number: D001                                                       
 
                                                                                
 
This product contains one or more substances that are listed with the State of  
 
California as a hazardous waste.                                                
 
Chemical Name                                                                   
 
California Hazardous Waste Status                                               
 
                                                                                
 
HEPTANE                                                                         
 
142-82-5                                                                        
 
Toxic                                                                           
 
Ignitable                                                                       
 
                                                                                
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |Aerosols, Limited Quantity (LQ)                           
 
Hazard Class         |2.1                    |<PICTOGRAM PHRASE>                
 
Identification Number|UN1950                 |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |126                                                       
 


14.2 In Accordance with IMDG
Proper Shipping Name |Aerosols, Limited Quantity (LQ)                           
 
Hazard Class         |2.1                                                       
 
Identification Number|UN1950                                                    
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |F-D                   |                                   
 
EmS-No. (Spillage)   |S-U                   |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Consumer commodity                                        
 
Identification Number|ID 8000                |<PICTOGRAM PHRASE>                
  
Hazard Class         |9                      |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |9L                                                        
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA 313: Section 313 of Title III of the Superfund Amendments and
Reauthorization
Act of 1986 (SARA). This product contains a chemical or chemicals which are     
 
subject to the reporting requirements of the Act and Title 40 of the Code of    
 
Federal Regulations, Part 372.                                                  
 
Chemical Name                                                                   
 
SARA 313 - Threshold Values %                                                   
 
                                                                                
 
ZINC OXIDE - 1314-13-2                                                          
 
1.0                                                                             
 
                                                                                
 
                                                                                
 
CWA (Clean Water Act): This product does not contain any substances regulated as
 
pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).   
 
CERCLA: This material, as supplied, does not contain any substances regulated as
 
hazardous substances under the Comprehensive Environmental Response Compensation
 
and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and         
 
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting        
 
requirements at the local, regional, or state level pertaining to releases of
this
material.                                                                       
 
SARA Section 311/312 Hazard Classes |Acute health hazard: Yes                   
 
                                    |Chronic Health Hazard: No                  
 
                                    |Fire hazard: Yes                           
 
                                    |Sudden release of pressure hazard: No      
 
                                    |Reactive Hazard: No                        
 
Toxic Substances Control Act (TSCA) |Complies                                   
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Proposition 65: This product does not contain any Proposition 65     
 
chemicals.                                                                      
 
                                                                                
 
U.S. State Right-to-Know Regulations:                                           
 
Chemical Name                                                                   
 
New Jersey                                                                      
 
Massachusetts                                                                   
 
Pennsylvania                                                                    
 
                                                                                
 
PROPANE                                                                         
 
74-98-6                                                                         
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
HEPTANE                                                                         
 
142-82-5                                                                        
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
ZINC OXIDE                                                                      
 
1314-13-2                                                                       
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
                                                                                
 
U.S. EPA Label Information:                                                     
 
EPA Pesticide Registration Number: Not applicable.                              
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |26-May-2015                                                    
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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--  |                               |                                           
 
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--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
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--  |                               |                                           
 


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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