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SDS Sheet 0066330

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: 3M(TM) SILICONE LUBRICANT PLUS; PN 08877                          
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Automotive, High Solids Silicone Lubricant        
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
3M Automotive Aftermarket                                                       
 
3M Center, St. Paul                                                             
 
MN 55144-1000                                                                   
 
USA                                                                             
 
Phone: 1-888-3M HELPS (1-888-364-3577)                                          
 


1.4.  Emergency Telephone Number
Emergency     | 1-800-364-3577 or (651) 737-6501 (24 hours)                     
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flammable     |Category 1.   
Aerosol       |              
Aspiration    |Category 1.   
Hazard        |              
Simple        |              
Asphyxiant    |              
Specific      |Category 1.   
Target Organ  |              
Toxicity      |              
(single       |              
exposure):    |              
Specific      |Category 3.   
Target Organ  |              
Toxicity      |              
(central      |              
nervous       |              
system):      |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame |Exclamation Mark |Health Hazard
         
Signal Word (GHS-US)         |Danger                                            
 
Hazard Statements (GHS-US)   |Extremely flammable aerosol.                      
 
                             |Maybe falal if swallowed and enters airways.     
 
                             |May cause drowsiness or dizziness.                
 
                             |May displace oxygen and cause rapid suffocation   
 
                             |Causes damage to organs: cardiovascular syslem   
 
Precautionary Statements     |General:                                          

 
(GHS-US)                     |Keep out of reach of children.                    
 
                             |Prevention:                                       
 
                             |Keep away from heat/sparks/open flames/hot
surfaces.
                             |- No smoking.                                     
 
                             |Do not spray on an open flame or other ignition   
 
                             |source.                                           
 
                             |Pressurized container: Do not pierce or burn, even
 
                             |after use.                                        
 
                             |Do not breathe dust/fume/gas/mist/vapors/spray.   
 
                             |Use only outdoors or in a well-ventilated area.   
 
                             |Do not eat, drink or smoke when using this
product. 
                             |Wash thoroughly after handling.                   
 
                             |Response:                                         
 
                             |IF INHALED: Remove person to fresh air and keep   
 
                             |comfortable for breathing.                        
 
                             |IF exposed: Call a POISON CENTER or               
 
                             |doctor/physician.                                 
 
                             |Do NOT induce vomiting.                           
 
                             |IF SWALLOWED: Immediately call a POISON CENTER or 
 
                             |doctor/physician.                                 
 
                             |Specific treatment (see Notes to Physician on this
 
                             |label).                                           
 
                             |Call a POISON CENTER or doctor/physician if you
feel
                             |unwell.                                           
 
                             |Storage:                                          
 
                             |Protect from sunlight. Do not expose to
temperatures
                             |exceeding 50C/122F.                               
 
                             |Store in a well-ventilated place.                 
 
                             |Store locked up.                                  
 
                             |Disposal:                                         
 
                             |Dispose of contents/container in accordance with  
 
                             |applicable Iocal/regional/national/inlemational   
 
                             |regulations.                                      
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None                      
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Isobutane                       |75-28-5              |50 - 60 |                
 
                                |                     |Trade   |                
 
                                |                     |Secret *|                
 
Hydrotreated Light Petroleum    |64742-47-8           |20 - 40 |                
 
Distillates                     |                     |Trade   |                
 
                                |                     |Secret *|                
 
Poly(Dimethylsiloxane)          |6314K-62-9           |7 - 13  |                
 
                                |                     |Trade   |                
 
                                |                     |Secret *|                
 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Remove person to fresh air. Get medical    
 
attention.                                                                      
 
First-aid Measures After Skin Contact: Wash with soap and water. If
signs/symptoms
develop, get medical attention.                                                 
 
First-aid Measures After Eye Contact: Flush with large amounts of water. Remove 
 
contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get  
 
medical attention.                                                              
 
First-aid Measures After Ingestion: Do not induce vomiting. Get immediate
medical 
attention.                                                                      
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Exposure may increase myocardial irritability. Do not administer sympathomimetic
 
drugs unless absolutely necessary.                                              
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use a fire fighting agent suitable for the        
 
surrounding fire.                                                               
 
Unsuitable Extinguishing Media:                                                 
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Closed containers exposed to heat from fire may build pressure and 
 
explode.                                                                        
 
Explosion Hazard:                                                               
 
Substance                              Condition                                
 
Carbon monoxide          During Combution                                       
 
Carbon dioxide               During Combution                                   
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions: Water may not effectively extinguish fire; however,
it 
should be used to keep fire-exposed containers and surfaces cool and prevent    
 
explosive rupture.                                                              
 
Protection During Firefighting:                                                 
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Evacuate area. Keep away from heat/sparks/open flames/hot     
 
surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with
fresh
air. For large spill, or spills in confined spaces, provide mechanical
ventilation
to disperse or                                                                  
 
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A 
 
motor could be an ignition source and could                                     
 
cause flammable gases or vapors in the spill area to burn or explode. Refer to  
 
other sections of this SDS for information regarding physical and health
hazards, 
respiratory protection, ventilation, and persona! protective equipment.         
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Avoid release to the environment. For larger spills, cover drains and build
dikes 
to prevent entry into sewer systems or bodies of water.                         
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up: If possible, seal leaking container. Place leaking     
 
containers in a well-ventilated area, preferably an operating exhaust hood, or
if 
necessary outdoors on an impermeable surface until appropriate packaging for the
 
leaking container or its contents is available. Contain spill. Cover spill area 
 
with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF)
is
recommended. Working from around the edges of the spill inward, cover with      
 
bentonite, vermiculitc, or commercially available inorganic absorbent material. 
 
Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent 
 
material does not remove a physical, health, or environmental hazard. Collect as
 
much of the spilled material as possible using non-sparking tools. Place in a   
 
metal container approved for transportation by appropriate authorities. Clean up
 
residue  with an appropriate solvent selected by a qualified and authorized     
 
person. Ventilate the area with fresh air. Read and follow  safety precautions
on 
the solvent label and SDS. Seal the container. Dispose of collected material as 
 
soon as possible.                                                               
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Do not use in a confined area with minimal
air 
exchange. Keep out of reach of children. Keep away from heat/sparks/open        
 
flames/hot surfaces. - No smoking. Do not spray on an open flame or other
ignition
source. Do not pierce or burn, even after use. Do not breathe                   
 
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do
 
not eat, drink or smoke when using this product. Wash thoroughly after handling.
 
Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Vapors may
 
travel long distances along the ground or floor to an ignition source and flash 
 
back.                                                                           
 
Hygiene Measures:                                                               
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Store in a well-ventilated place. Protect from sunlight. Do 
 
not expose to temperatures exceeding 50C/I22F. Store away from heat. Store away 
 
from acids. Store away from oxidizing agents.                                   
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Ingredient                                                                      
 
C.A.S. No.                                                                      
 
Agency                                                                          
 
Limit type                                                                      
 
Additional Comments                                                             
 
                                                                                
 
Hydrotreated Light Petroleum Distillates                                        
 
64742-47-8                                                                      
 
CMRG                                                                            
 
TWA: 165 ppm                                                                    
 
                                                                                
 
                                                                                
 
Isobutane                                                                       
 
75-28-5                                                                         
 
ACGIH                                                                           
 
STEL: 1000 ppm                                                                  
 
                                                                                
 
                                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Do not remain in area where available oxygen may
be 
Controls                     |reduced. Use general dilution ventilation and/or  
 
                             |local exhaust ventilation to control airborne     
 
                             |exposures to below relevant Exposure Limits and/or
 
                             |control dust/fume/gas/mist/vapors/spray.  If      
 
                             |ventilation is not adequate use respiratory       
 
                             |protection equipment.                             
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Select and use eye/face protection lo prevent     
 
                             |contact based on the results of an exposure       
 
                             |assessment. The following eye/face protection(s)
are
                             |recommended: As a good industrial hygiene
practice: 
                             |Wear eye/face protection. Indirect Vented Goggles.
 
Skin and Body Protection     |Select and use gloves and/or protective clothing  
 
                             |approved to relevant local standards to prevent
skin
                             |contact based on the results of an exposure       
 
                             |assessment. Selection should be based on use
factors
                             |such as exposure levels, concentration of the     
 
                             |substance or mixture, frequency and duration,     
 
                             |physical challenges such as temperature extremes, 
 
                             |and other use conditions. Consult with your glove 
 
                             |and/or protective clothing manufacturer for       
 
                             |selection of appropriate compatible               
 
                             |gloves/protective clothing. Wear protective
gloves. 
                             |Gloves made from the following material(s) are    
 
                             |recommended: Butyl Rubber Nitrile Rubber          
 
Respiratory Protection       |In case of inadequate ventilation wear respiratory
 
                             |protection. An exposure assessment may be needed
to 
                             |decide if a respirator is required. If a
respirator 
                             |is needed, use respirators as part of a full      
 
                             |respiratory protection program. Based on the
results
                             |of the exposure assessment, select from the       
 
                             |following respirator type(s) to reduce inhalation 
 
                             |exposure: Half facepiece or full facepiece        
 
                             |supplied-air respirator  For questions about      
 
                             |suitability for a specific application, consult
with
                             |your respirator manufacturer.                     
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                     
 
Appearance                          |Aerosol                                    
 
Odor                                |Transparent, solvent odor                  
 
Odor Threshold                      |No Data Available                          
 
pH                                  |Not Applicable                             
 
Relative Evaporation Rate           |No Data Available                          
 
(butylacetate=1)                    |                                           
 
Melting Point                       |Not Applicable                             
 
Freezing Point                      |                                           
 
Boiling Point                       |                                           
 
Flash Point                         |-50.00 F [Details: Flash point of
propellant]
Auto-ignition Temperature           |No Data Available                          
 
Decomposition Temperature           |No Data Available                          
 
Flammability (solid, gas)           |No Data Applicable                         
 
Vapor Pressure                      |                                           
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |                                           
 
Specific Gravity                    |0.65 [RefStd: WATER=1]                     
 
Solubility                          |Nil                                        
 
Partition coefficient:              |No Data Available                          
 
n-octanol/water                     |                                           
 
Viscosity                           |No Data Available                          
 
Lower Flammable Limit               |No Data Available                          
 
Upper Flammable Limit               |No Data Available                          
 
                                    |                                           
 
                                    |                                           
 
                                    |                                           
 
                                    |                                           
 
                                    |                                           
 
                                    |                                           
 
                                    |                                           
 
                                    |                                           
 


9.2.  Other Information
Volatile Organic Compounds                               60 % weight [Test
Method:
calculated per CARB title 2}                                                    
 
Volatile Organic Compounds                               390 g/l [Test Method:  
 
calculated SCAQMD rule 443.1]                                                   
 
Percent volatile                                                      60 %
weight 
VOC Less H20 & Exempt Solvents                     390 g/l [Test: Method:       
 
calculated SCAQMD rule 443                                                      
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
This material may be reactive with certain agents under certain conditions - see
 
the remaining headings in this section.                                         
 


10.2      Chemical Stability
Stable.                                                                         
 


10.3      Possibility of Hazardous Reactions
Hazardous polymerization will not occur.                                        
 


10.4      Conditions to Avoid
Heat                                                                            
 
Sparks and/or flames                                                            
 


10.5      Incompatible Materials
Not determined                                                                  
 


10.6      Hazardous Decomposition Products
Substance Condition                                        Condition            
 
None known.                                                                     
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation: Mild Skin Irritation: Signs/symptoms may include     
 
localized redness, swelling, itching, and dryness.                              
 
Serious Eye Damage/Irritation: Contact with the eyes during product use is not  
 
expected to result in significant irritation.                                   
 
Respiratory or Skin Sensitization: Intentional concentration and inhalation may
be
harmful or fatal. Simple Asphyxiation: Signs/symptoms may include increased
heart 
rate, rapid respirations, drowsiness, headache, incoordination, altered
judgement,
nausea, vomiting, lethargy, seizures, coma, and may be fatal.                   
 
Respiratory Tract Irritation; Signs/symptoms may include cough, sneezing, nasal 
 
discharge, headache, hoarseness, and nose and throat pain. May cause target
organ 
effects after inhalation.                                                       
 
Germ Cell Mutagenicity:                                                         
 
Carcinogenicity:                                                                
 
Reproductive Toxicity:                                                          
 
Specific Target Organ Toxicity (Single Exposure): Central Nervous System (CNS)  
 
Depression: Signs/symptoms may include headache, dizziness, drowsiness,         
 
incoordination, nausea, slowed reaction time, slurred speech, giddiness, and    
 
unconsciousness. Single exposure, above recommended guidelines, may cause:
Cardiac
Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia),     
 
faintness, chest pain, and may be fatal.                                        
 
Specific Target Organ Toxicity (Repeated Exposure):                             
 
Aspiration Hazard:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Please contact the address or phone number listed on the first page of the SDS
for
additional ecotoxicological information on this material and/or its components. 
 
Chemical fate information Please contact the address or phone number listed on
the
first page of the SDS for additional chemical fate information on this material 
 
and/or its components.                                                          
 


12.2. Persistence and Degradability
                                                                                
 


12.3. Bioaccumulative Potential
                                                                                
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
                                                                                
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose of contents/ container in accordance
with 
the local/regional/national/international regulations. Incinerate in a permitted
 
waste incineration facility. Facility must be capable of handling aerosol cans. 
 
Empty drums/barrels/containers used for transporting and handling hazardous     
 
chemicals (chemical substances/mixtures/preparations                            
 
classified as Hazardous as per applicable regulations) shall be considered,     
 
stored, treated & disposed of as hazardous wastes                               
 
unless otherwise defined by applicable waste regulations. Consult with the      
 
respective regulating authorities to determine the                              
 
available treatment and disposal facilities.                                    
 
Additional Information:                                                         
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |                                                          
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |                                                          
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |                                                          
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
Contact 3M for more information.                                                
 
SARA Section 311/312 Hazard Classes |Fire Hazard - Yes                          
 
                                    |Pressure Hazard - Yes                      
 
                                    |Reactivity Hazard - No                     
 
                                    |Immediate Hazard - Yes                     
 
                                    |Delayed Hazard - No                        
 
Toxic Substances Control Act (TSCA) |                                           
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
Contact 3M for more information.                                                
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |                                                               
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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