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SDS Sheet 0066330Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 3M(TM) SILICONE LUBRICANT PLUS; PN 08877 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Automotive, High Solids Silicone Lubricant 1.3. Name, Address, and Telephone of the Responsible Party Company 3M Automotive Aftermarket 3M Center, St. Paul MN 55144-1000 USA Phone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency Telephone Number Emergency | 1-800-364-3577 or (651) 737-6501 (24 hours) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1. Aerosol | Aspiration |Category 1. Hazard | Simple | Asphyxiant | Specific |Category 1. Target Organ | Toxicity | (single | exposure): | Specific |Category 3. Target Organ | Toxicity | (central | nervous | system): | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Exclamation Mark |Health Hazard Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. |Maybe falal if swallowed and enters airways. |May cause drowsiness or dizziness. |May displace oxygen and cause rapid suffocation |Causes damage to organs: cardiovascular syslem Precautionary Statements |General: (GHS-US) |Keep out of reach of children. |Prevention: |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. |Do not spray on an open flame or other ignition |source. |Pressurized container: Do not pierce or burn, even |after use. |Do not breathe dust/fume/gas/mist/vapors/spray. |Use only outdoors or in a well-ventilated area. |Do not eat, drink or smoke when using this product. |Wash thoroughly after handling. |Response: |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |IF exposed: Call a POISON CENTER or |doctor/physician. |Do NOT induce vomiting. |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician. |Specific treatment (see Notes to Physician on this |label). |Call a POISON CENTER or doctor/physician if you feel |unwell. |Storage: |Protect from sunlight. Do not expose to temperatures |exceeding 50C/122F. |Store in a well-ventilated place. |Store locked up. |Disposal: |Dispose of contents/container in accordance with |applicable Iocal/regional/national/inlemational |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Isobutane |75-28-5 |50 - 60 | | |Trade | | |Secret *| Hydrotreated Light Petroleum |64742-47-8 |20 - 40 | Distillates | |Trade | | |Secret *| Poly(Dimethylsiloxane) |6314K-62-9 |7 - 13 | | |Trade | | |Secret *| | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove person to fresh air. Get medical attention. First-aid Measures After Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. First-aid Measures After Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. First-aid Measures After Ingestion: Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use a fire fighting agent suitable for the surrounding fire. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Closed containers exposed to heat from fire may build pressure and explode. Explosion Hazard: Substance Condition Carbon monoxide During Combution Carbon dioxide During Combution Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and persona! protective equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculitc, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Vapors may travel long distances along the ground or floor to an ignition source and flash back. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a well-ventilated place. Protect from sunlight. Do not expose to temperatures exceeding 50C/I22F. Store away from heat. Store away from acids. Store away from oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Ingredient C.A.S. No. Agency Limit type Additional Comments Hydrotreated Light Petroleum Distillates 64742-47-8 CMRG TWA: 165 ppm Isobutane 75-28-5 ACGIH STEL: 1000 ppm 8.2. Exposure Controls Appropriate Engineering |Do not remain in area where available oxygen may be Controls |reduced. Use general dilution ventilation and/or |local exhaust ventilation to control airborne |exposures to below relevant Exposure Limits and/or |control dust/fume/gas/mist/vapors/spray. If |ventilation is not adequate use respiratory |protection equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Select and use eye/face protection lo prevent |contact based on the results of an exposure |assessment. The following eye/face protection(s) are |recommended: As a good industrial hygiene practice: |Wear eye/face protection. Indirect Vented Goggles. Skin and Body Protection |Select and use gloves and/or protective clothing |approved to relevant local standards to prevent skin |contact based on the results of an exposure |assessment. Selection should be based on use factors |such as exposure levels, concentration of the |substance or mixture, frequency and duration, |physical challenges such as temperature extremes, |and other use conditions. Consult with your glove |and/or protective clothing manufacturer for |selection of appropriate compatible |gloves/protective clothing. Wear protective gloves. |Gloves made from the following material(s) are |recommended: Butyl Rubber Nitrile Rubber Respiratory Protection |In case of inadequate ventilation wear respiratory |protection. An exposure assessment may be needed to |decide if a respirator is required. If a respirator |is needed, use respirators as part of a full |respiratory protection program. Based on the results |of the exposure assessment, select from the |following respirator type(s) to reduce inhalation |exposure: Half facepiece or full facepiece |supplied-air respirator For questions about |suitability for a specific application, consult with |your respirator manufacturer. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Aerosol Odor |Transparent, solvent odor Odor Threshold |No Data Available pH |Not Applicable Relative Evaporation Rate |No Data Available (butylacetate=1) | Melting Point |Not Applicable Freezing Point | Boiling Point | Flash Point |-50.00 F [Details: Flash point of propellant] Auto-ignition Temperature |No Data Available Decomposition Temperature |No Data Available Flammability (solid, gas) |No Data Applicable Vapor Pressure | Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |0.65 [RefStd: WATER=1] Solubility |Nil Partition coefficient: |No Data Available n-octanol/water | Viscosity |No Data Available Lower Flammable Limit |No Data Available Upper Flammable Limit |No Data Available | | | | | | | | 9.2. Other Information Volatile Organic Compounds 60 % weight [Test Method: calculated per CARB title 2} Volatile Organic Compounds 390 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 60 % weight VOC Less H20 & Exempt Solvents 390 g/l [Test: Method: calculated SCAQMD rule 443 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Heat Sparks and/or flames 10.5 Incompatible Materials Not determined 10.6 Hazardous Decomposition Products Substance Condition Condition None known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Serious Eye Damage/Irritation: Contact with the eyes during product use is not expected to result in significant irritation. Respiratory or Skin Sensitization: Intentional concentration and inhalation may be harmful or fatal. Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory Tract Irritation; Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Contact 3M for more information. SARA Section 311/312 Hazard Classes |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No |Immediate Hazard - Yes |Delayed Hazard - No Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> Contact 3M for more information. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.