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MATERIAL SAFETY DATA SHEET 3M(TM) Rocker Panel Spray - Clear, PN 05911 05/10/11 3M Material Safety Data Sheet Copyright, 2011, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M (TM) Rocker Panel Spray - Clear, PN 05911 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 05/10/11 Supercedes Date: 12/14/06 Document Group: 10-2858-8 Product Use: Intended Use: Automotive Specific Use: Automotive Coating SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt ETHYL ACETATE 141-78-6 15-40 ETHYL ALCOHOL 64-17-5 10-30 POLYURETHANE POLYMER Trade Secret 7-15 PROPANE 74-98-6 7-13 BUTYL ALCOHOL 71-36-3 5-10 N-BUTYL ACETATE 123-86-4 5-10 1-METHOXY-2-PROPYL ACETATE 108-65-6 3-7 DIMETHYL ETHER 115-10-6 3-7 VINYL CHLORIDE-VINYL-ACETATE-MALEIC ACID 9005-09-8 3-7 POLYMER 2,6-DI-TERT-BUTYL-P-CRESOL 128-37-0 <=0.0001569505 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Aerosol Odor, Color, Grade: clear, fruity odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Aerosol container contains flammable material under pressure. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing and blurred or hazy vision. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. May be absorbed through skin and cause target organ effects. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia,), faintness, chest pain, and may be fatal. Single exposure, above recommended guidelines, may cause: Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy , seizures, coma, and may be fatal. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss or appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Dermal Effects: Signs/symptoms may include localized redness, itching, drying and cracking of skin. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. NOTE: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. Ingredient C.A.S. No. Class Description Regulations ETHYL ALCOHOL 64-17-5 Grp. 1: International Carcinogenic to Agency for Research humans on Cancer SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: Remove person to fresh air. Get immediate medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. 4.2 NOTE TO PHYSICIANS Exposure may increase myocardial irritability. Do not administer sympathomimetric drugs unless absolutely necessary. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Date Available Flash Point -156 Â°F [Details: Flammable gas] Flammable Limits (LEL) 2.30 % Flammable Limits (UEL) 26.70 % OSHA Flammability Class IA Flammable Liquid Classification: 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Aerosol container contains flammable material under pressure. NOTE: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2 Environmental precautions Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF )is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Aerosol container contains flammable gas under pressure. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Do not breathe vapors. 7.2 STORAGE Store away from heat. Store out of direct sunlight. Do not store containers on their sides. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in an enclosed process area is recommended. Use with functioning spray booth or local exhaust. If exhaust ventilation is not available, use appropriate respiratory protection. Do not use in a confined area or areas with little or no air movement. Do not remain in area where available oxygen may be reduced. Provide ventilation adequate to maintain dust concentration below minimum explosive concentrations. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields. Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Fluoroelastomer Polyvinyl Alcohol (PVA) . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Do not breathe vapors. Select one of the following NIOSH approved respirators based on airborne concentration of contaminates and in accordance with OSHA regulations. Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Select and use respiratory protection to prevent an inhalation exposure based on the results of an exposure assessment. Consult with your respirator manufacturer for selection of appropriate types of respirators. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information 1-METHOXY-2-PROPYL ACETATE AIHA TWA 50 ppm 1-METHOXY-2-PROPYL ACETATE CMRG TWA 10 mg/m3 1-METHOXY-2-PROPYL ACETATE CMRG STEL 90 ppm 2,6-DI-TERT-BUTYL-P-CRESOL ACGIH TWA, inhalable 2 mg/m3 fraction and vapor BUTYL ALCOHOL ACGIH TWA 20 ppm BUTYL ALCOHOL OSHA TWA 300 mg/m3 DIMETHYL ETHER AIHA TWA 1880 mg/m3 DIMETHYL ETHER CMRG TWA 1000 ppm ETHYL ACETATE ACGIH TWA 400 ppm ETHYL ACETATE OSHA TWA 1400 mg/m3 ETHYL ALCOHOL ACGIH STEL 1000 ppm ETHYL ALCOHOL OSHA TWA 1900 mg/m3 N-BUTYL ACETATE ACGIH TWA 150 ppm N-BUTYL ACETATE ACGIH STEL 200 ppm N-BUTYL ACETATE OSHA TWA 710 mg/m3 PROPANE OSHA TWA 1800 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Aerosol Odor, Color, Grade: Clear, fruity odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point -156Â°F [Details: Flammable gas] Flammable Limits (LEL) 2.30% Flammable Limits (UEL) 26.70% Boiling Point No Data Available Density 0.899 g/ml Vapor Density >=1.00 [Ref Std: Air=1] Vapor Pressure No Data Available Specific Gravity 0.899 [Ref Std: Water=1] [Details: Liquid portion] pH Not Applicable Melting point No Data Available Solubility in Water Negligible Evaporation rate No Data Available Hazardous Air Pollutants 0.702 % weight [Test Method: Calculated] Volatile Organic Compounds 767 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 6.40 lb/gal [Test Method: SCAQMD rule 443.1] Volatile Organic Compounds 85.4 % weight [Test Method: calculated per CARB title 2] Kow - Oct/Water partition coef No Data Available Percent volatile 85.53% VOC Less H20 & Exempt Solvents 768 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity Approximately 60 centipoise [Details: Liquid portion] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Material and Conditions to Avoid: 10.1 Conditions to avoid Heat 10.2 Materials to avoid None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Hydrogen Chloride Not Specified SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMCIAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. Facility must be capable of handling aerosol cans. Combustion products will include HCI. Facility must be capable of handling halogenated materials. Dispose of empty product containers in a sanitary landfill. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14: TRANSPORT INFORMATION ID Number(s): 60-9800-0986-8 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt BUTYL ALCOHOL 71-63-3 5-10 STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. WHMIS: Hazardous ADDITIONAL INFORMATION Coating Category: Automotive Bumper and Trim Products. VOC Standard = 95%. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 4 Reactivity: O Special Hazards: None Aerosol Storage Code: 2 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 16: Disclaimer (second paragraph) was modified. Section 8: Eye/face protection information was modified. Section 8: Skin protection - recommended gloves information was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section3: Immediate other hazard(s) was modified. Section 14: Transportation legal text was modified. Section 15: Inventories information was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 9: Property description for optional properties was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Density information was added. Section 5: Flash point information was added. Section 9: Flash point information was added. Section 14: ID Number Heading Template 1 was added. Section 14: ID Number(s) Template 1 was added. Section 2: Ingredient table was added. Section 15: EPCRA 313 information was added. Section 15: EPCRA 313 text was added. Section 8: Exposure guidelines ingredient information was added. Section 8: Exposure guidelines data source legend was added. Section 3: Carcinogenicity table was added. Section 3: Carcinogenicity heading was added. Section 6: 6.2. Environmental precautions heading was added. Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was added. Section 10.1 Conditions to avoid heading was added. Section 10.2 Materials to avoid heading was added. Section 16: Web address was added. Section 6: Personal precautions information was added. Section 6: Environmental procedures information was added. Section 6: Methods of cleaning up information was added. Section 10: Materials to avoid physical property was added. Section 10: Conditions to avoid physical property was added. Section 1: Address was added. Copyright was added. Company logo was added. Section 6: Clean-up methods heading was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. Section 1: Emergency phone information was deleted. Company Logo was deleted. Copyright was deleted. Section 16: Web address heading was deleted. Section 6: Release measures information was deleted. Section 6: Release measures heading was deleted. Section 10: Materials and conditions to avoid physical property and deleted. Section 1: Address line 1 was deleted. Section 2: Address line 2 was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMTED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OF COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA MSDSs are available at www.3M.com
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.