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SDS Sheet 0066130Printer Friendly View
Safety Data Sheet Date of Issue: |Revision Date: 14-May-2015 |Revision Number: 1 Imperial Supplies Part Number: 0066130 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: SA9 BATTERY PROTECTOR & SEALER 5 OZ AE CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Battery Sealant 1.3. Name, Address, and Telephone of the Responsible Party Company ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Telephone: 1-87-Permatex (877) 376-2839 1.4. Emergency Telephone Number Emergency | Chem-Tel: 800-255-3924, 00+1+ 813-248-0585 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2 damage/eye | irritation | Carcinogenicit|Category 2 y | Specific |Category 3 target organ | toxicity | (single | exposure) | Specific |Category 2 target organ | toxicity | (repeated | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 1 aerosols | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamat|Health |Flame | | | |ion Mark|Hazard | | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Causes skin irritation |Causes serious eye irritation |Suspected of causing cancer |May cause drowsiness or dizziness |May cause damage to organs through prolonged or |repeated exposure |May be fatal if swallowed and enters airways |Extremely flammable aerosol Precautionary Statements |Precautionary Statements - Prevention (GHS-US) |Obtain special instructions before use |Do not handle until all safety precautions have been |read and understood |Use personal protective equipment as required |Wash face, hands and any exposed skin thoroughly |after handling |Wear eye/face protection |Do not breathe dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use |Precautionary Statements - Response |IF exposed or concerned: Get medical |advice/attention |Specific treatment (see supplemental first aid |instructions on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing |If eye irritation persists: Get medical |advice/attention |If skin irritation occurs: Get medical |advice/attention |IF ON SKIN (or hair): Remove/Take off immediately |all contaminated clothing. Rinse skin with |water/shower |Wash contaminated clothing before reuse |IF INHALED: Remove victim to fresh air and keep at |rest in a position comfortable for breathing |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |Precautionary Statements - Storage |Store locked up |Protect from sunlight. Do not expose to temperatures |exceeding 50 Â°C/122 Â°F |Precautionary Statements - Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Not applicable 2.4. Unknown Acute Toxicity (GHS-US) Toxic to aquatic life with long lasting effects. Unknown acute toxicity 7.5% of the mixture consists of ingredient(s) of unknown toxicity SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) XYLENE |1330-20-7 |10 - 30 | PROPANE |74-98-6 |10 - 30 | ACETONE |67-64-1 |10 - 30 | MINERAL OIL |8042-47-5 |5 - 10 | DISTILLATES (PETROLEUM), |64742-47-8 |5 - 10 | HYDROTREATED LIGHT | | | ETHYL BENZENE |100-41-4 |1 - 5 | | | | *The exact percentage | | | (concentration) of composition | | | has been withheld as a trade | | | secret. | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Get medical advice/attention if you feel unwell. First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. First-aid Measures After Skin Contact: IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: IF SWALLOWED:. Call a physician or poison control center immediately. Do NOT induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See section 2 for more information Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Self-protection of the first aider: Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Note to physicians: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Carbon dioxide (CO2), Dry chemical, Foam Unsuitable Extinguishing Media: None. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable. Keep product and empty container away from heat and sources of ignition. Vapors may travel to source of ignition and flash back. Explosion Hazard: Sensitivity to Mechanical Impact-None. Sensitivity to Static Discharge-None. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment as required. Remove all sources of ignition. Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. 6.4. Reference to Other Sections Prevention of secondary hazards: Clean contaminated objects and areas thoroughly observing environmental regulations. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling: Additional Hazards When Processed: Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials: Strong oxidizing agents, Acids 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH XYLENE 1330-20-7 STEL: 150 ppm TWA: 100 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 655 mg/m3 - PROPANE 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 ETHYL BENZENE 100-41-4 TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 125 ppm (vacated) STEL: 545 mg/m3 IDLH: 800 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear protective gloves and protective clothing. Respiratory Protection |Use NIOSH-approved air-purifying respirator with |organic vapor cartridge or canister, as appropriate. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Purple Odor |Solvent Odor Threshold |No information available pH |No information available Relative Evaporation Rate |> 1 Butyl acetate = 1 (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |> 38 Â°C / 100 Â°F Flash Point |< -18 Â°C / < 0 Â°F |Gives a flame projection at full valve |opening or flashback at any degree of valve |opening Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |Not determined Relative Vapor Density at 20 Â°C |>1 Air = 1 Relative Density |0.85 Specific Gravity | Solubility |No information available Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information Softening point: No information available Molecular weight: No information available VOC Content (%) 45% Density: No information available Bulk density: No information availabled SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Keep away from all heat sources, open flames and other sources of ignition. 10.5 Incompatible Materials Strong oxidizing agents, Acids 10.6 Hazardous Decomposition Products Carbon oxides SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: May cause skin irritation and/or dermatitis. Serious Eye Damage/Irritation: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Respiratory or Skin Sensitization: No information available. Germ Cell Mutagenicity: No information available. Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Central nervous system, Eyes, Respiratory system, Skin. Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: May be harmful by inhalation. May cause drowsiness or dizziness. Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Harmful if swallowed. Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Chemical Name Algae/aquatic plants Fish Crustacea XYLENE 1330-20-7 - 13.4: 96 h Pimephales romelas mg/L LC50 flow-through 2.661 - 4.093: 96 h Oncorhynchus mykiss mg/L LC50 static 13.5 - 17.3: 96 h Oncorhynchus mykiss mg/L LC50 13.1 - 16.5: 96 h Lepomis macrochirus mg/L LC50 flow-through 19: 96 h Lepomis macrochirus mg/L LC50 7.711 - 9.591: 96 h Lepomis macrochirus mg/L LC50 static 23.53 - 29.97: 96 h Pimephales promelas mg/L LC50 static 780: 96 h Cyprinus carpio mg/L LC50 semi-static 780: 96 h Cyprinus carpio mg/L LC50 30.26 - 40.75: 96 h Poecilia reticulata mg/L LC50 static 3.82: 48 h water flea mg/L EC50 0.6: 48 h Gammarus lacustris mg/L LC50 ACETONE 67-64-1 - 4.74 - 6.33: 96 h Oncorhynchus mykiss mL/L LC50 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 MINERAL OIL 8042-47-5 - 10000: 96 h Lepomis macrochirus mg/L LC50 - DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 - 45: 96 h Pimephales promelas mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h Oncorhynchus mykiss mg/L LC50 static 4720: 96 h Den-dronereides heteropoda mg/L LC50 ETHYL BENZENE 100-41-4 4.6: 72 h Pseudokirchneriella subcapitata mg/L EC50 438: 96 h Pseudokirchneriella subcapitata mg/L EC50 2.6 - 11.3: 72 h Pseudokirchneriella subcapitata mg/L EC50 static 1.7 - 7.6: 96 h Pseudokirchneriella subcapitata mg/L EC50 static 11.0 - 18.0: 96 h Oncorhynchus mykiss mg/L LC50 static 9.6: 96 h Poecilia reticulata mg/L LC50 static 4.2: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 7.55 - 11: 96 h Pimephales promelas mg/L LC50 flow-through 32: 96 h Lepomis macrochirus mg/L LC50 static 9.1 - 15.6: 96 h Pimephales promelas mg/L LC50 static 1.8 - 2.4: 48 h Daphnia magna mg/L EC50 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil No information available. Chemical Name Partition coefficient XYLENE 1330-20-7 2.77 - 3.15 PROPANE 74-98-6 2.3 ACETONE 67-64-1 -0.24 MINERAL OIL 8042-47-5 >6 ETHYL BENZENE 100-41-4 3.118 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Additional Information: Contaminated packaging: Do not reuse container. US EPA Waste Number D001 SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, Limited Quantity (LQ) Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|1950 | Label Codes | | ERG Number |126 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols, Limited Quantity (LQ) Hazard Class |2.1 Identification Number|1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |Consumer commodity Identification Number|ID 8000 |<PICTOGRAM PHRASE> Hazard Class |9 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |9L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % XYLENE - 1330-20-7 1.0 ETHYL BENZENE - 100-41-4 0.1 CWA (Clean Water Act): This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances XYLENE 1330-20-7 100 lb - - X ETHYL BENZENE 100-41-4 1000 lb X X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) XYLENE 1330-20-7 100 lb - RQ 100 lb final RQ RQ 45.4 kg final RQ ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ ETHYL BENZENE 100-41-4 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ SARA Section 311/312 Hazard Classes |Acute health hazard |Yes |Chronic Health Hazard |Yes |Fire hazard |Yes |Sudden release of pressure hazard No | |Reactive Hazard |No Toxic Substances Control Act (TSCA) |Complies 15.2 US State Regulations <COMPONENT> California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name California Proposition 65 ETHYL BENZENE - 100-41-4 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania XYLENE 1330-20-7 X X X ACETONE 67-64-1 X X X PROPANE 74-98-6 X X X ETHYL BENZENE 100-41-4 X X X SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |14-May-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.