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SECTION 1: IDENTIFICATION | |1.1. Product Identifier Product Form: Product Name: IMPENATRATOR CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Imperial Supplies LLC 789 Armed Forces Dr. P.O.Box 11008 Green Bay, WI 54307-1008 Phone: (216) 566-2902, (800) 558-2808 1.4. Emergency Telephone Number Emergency | (216) 566-2917, (800) 424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) FLAMMABLE |Category 1 AEROSOLS | GASES UNDER |Compressed gas PRESSURE | ACUTE TOXICITY|Category 3 (inhalation) | SKIN |Category 2 CORROSION/IRRI| TATION | SERIOUS EYE |Category 2A DAMAGE/ EYE | IRRITATION | CARCINOGENICIT|Category 2 Y | SPECIFIC |Category 3 TARGET ORGAN | TOXICITY | (SINGLE | EXPOSURE) | (Respiratory | tract | irritation and| Narcotic | effects) | SPECIFIC |Category 2 TARGET ORGAN | TOXICITY | (REPEATED | EXPOSURE) | ASPIRATION |Category 1 HAZARD | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Skull and Crossbones |Health Hazard Hazard Statements (GHS-US) |Extremely flammable aerosol. |Contains gas under pressure; may explode if heated. |Toxic if inhaled. |Causes serious eye irritation. |Causes skin irritation. |Suspected of causing cancer. |May be fatal if swallowed and enters airways. |May cause respiratory irritation. |May cause drowsiness and dizziness. |May cause damage to organs through prolonged or |repeated exposure. Precautionary Statements |General: Read label before use. Keep out of reach of (GHS-US) |children. If medical advice is needed, have product |container or label at hand. |Prevention: Obtain special instructions before use. |Do not handle until all safety precautions have been |read and understood. Use personal protective |equipment as required. Wear protective gloves. Wear |eye or face protection. Keep away from heat, hot |surfaces, sparks, open flames and other ignition |sources. No smoking. Pressurized container: Do not |pierce or burn, even after use. Do not spray on an |open flame or other ignition source. Use only |outdoors or in a well-ventilated area. Do not |breathe dust or mist. Wash hands thoroughly after |handling. |Response: Get medical attention if you feel unwell. |IF exposed or concerned: Get medical attention. IF |INHALED: Remove victim to fresh air and keep at rest |in a position comfortable for breathing. Call a |POISON CENTER or physician. IF SWALLOWED: |Immediately call a POISON CENTER or physician. Do |NOT induce vomiting. IF ON SKIN: Wash with plenty of |soap and water. Take off contaminated clothing. Wash |contaminated clothing before reuse. If skin |irritation occurs: Get medical attention. IF IN |EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. If eye irritation persists: |Get medical attention. |Storage: Store locked up. Protect from sunlight. Do |not expose to temperatures exceeding 50�C/122 �F. |Store in a well-ventilated place. |Disposal: Dispose of contents and container in |accordance with all local, regional, national and |international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) Middle Petroleum Distillate |64741-44-2 |30.0 | Methyl Acetate |79-20-9 |25.0 | Aliphatic Solvent |64742-47-8 |16.2 | Medium Aromatic Hydrocarbons |64742-94-5 |15.1 | Mineral Spirits 140-Flash |64742-88-7 |5.0 | Naphthalene |91-20-3 |2.3 | 2-Methoxymethylethoxypropanol |34590-94-8 |2.0 | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. First-aid Measures After Skin Contact: Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. First-aid Measures After Ingestion: Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Toxic if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Adverse symptoms may include the following: Respiratory tract irritation, coughing, nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness Symptoms/Injuries After Skin Contact: Causes skin irritation. Adverse symptoms may include the following: Irritation, redness Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Eye contact: Adverse symptoms may include the following: pain or irritation, watering, redness. Symptoms/Injuries After Ingestion: Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. Adverse symptoms may include the following: Nausea or vomiting. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments: No specific treatment. Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use an extinguishing agent suitable for the surrounding fire. Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". 6.2. Environmental Precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Small Spill: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50�C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Hygiene Measures: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Use only with adequate ventilation. Use process Controls |enclosures, local exhaust ventilation or other |engineering controls to keep worker exposure to |airborne contaminants below any recommended or |statutory limits. The engineering controls also need |to keep gas, vapor or dust concentrations below any |lower explosive limits. Use explosion proof |ventilation equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Chemical-resistant, impervious gloves complying with |an approved standard should be worn at all times |when handling chemical products if a risk assessment |indicates this is necessary. Considering the |parameters specified by the glove manufacturer, |check during use that the gloves are still retaining |their protective properties. It should be noted that |the time to breakthrough for any glove material may |be different for different glove manufacturers. In |the case of mixtures, consisting of several |substances, the protection time of the gloves cannot |be accurately estimated. Eye Protection |Safety eyewear complying with an approved standard |should be used when a risk assessment indicates this |is necessary to avoid exposure to liquid splashes, |mists, gases or dusts. If contact is possible, the |following protection should be worn, unless the |assessment indicates a higher degree of protection: |chemical splash goggles. Skin and Body Protection |Body protection: Personal protective equipment for |the body should be selected based on the task being |performed and the risks involved and should be |approved by a specialist before handling this |product. When there is a risk of ignition from |static electricity, wear antistatic protective |clothing. For the greatest protection from static |discharges, clothing should include anti-static |overalls, boots and gloves. |Other skin protection: Appropriate footwear and any |additional skin protection measures should be |selected based on the task being performed and the |risks involved and should be approved by a |specialist before handling this product. Respiratory Protection |Use a properly fitted, air-purifying or air-fed |respirator complying with an approved standard if a |risk assessment indicates this is necessary. |Respirator selection must be based on known or |anticipated exposure levels, the hazards of the |product and the safe working limits of the selected |respirator. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Not available Odor Threshold |Not available pH |7 Relative Evaporation Rate |5.3 (butyl acetate = 1) (butylacetate=1) | Melting Point | Freezing Point | Boiling Point |Not available Flash Point |Closed cup: 60�C (140�F) [Pensky-Martens |Closed Cup] Auto-ignition Temperature |Not available Decomposition Temperature |Not available Flammability (solid, gas) |Not available Vapor Pressure |13.5 kPa (101.325 mm Hg) [at 20�C] Relative Vapor Density at 20 �C |2.6 [Air = 1] Relative Density |0.85 Specific Gravity | Solubility |Not available Partition coefficient: |Not available n-octanol/water | Viscosity |Kinematic (room temperature): <0.07 cm2/s (<7 |cSt) |Kinematic (40�C (104�F)): <0.07 cm2/s (<7 |cSt) Lower Flammable Limit |0.7% Upper Flammable Limit |16% 9.2. Other Information Aerosol product Type of aerosol : Spray Heat of combustion : 0.0000402 kJ/g SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No specific test data related to reactivity available for this product or its ingredients. 10.2 Chemical Stability The product is stable. 10.3 Possibility of Hazardous Reactions Under normal conditions of storage and use, hazardous reactions will not occur. 10.4 Conditions to Avoid Avoid all possible sources of ignition (spark or flame). 10.5 Incompatible Materials No specific data. 10.6 Hazardous Decomposition Products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Reproductive Toxicity: Not available Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Toxic if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Adverse symptoms may include the following: Respiratory tract irritation, coughing, nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsciousness Symptoms/Injuries After Skin Contact: Causes skin irritation. Adverse symptoms may include the following: Irritation, redness. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Adverse symptoms may include the following: pain or irritation, watering redness. Symptoms/Injuries After Ingestion: Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. Adverse symptoms may include the following: nausea or vomiting . Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability Not available. 12.3. Bioaccumulative Potential 12.4. Mobility in Soil Not available. 12.5. Other Adverse Effects No known significant effects or critical hazards. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |AEROSOLS Hazard Class |2.1 |[pic] Identification Number|UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes | |[pic] ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, flammable Identification Number|UN1950 |[pic] Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations California Prop. 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |4/6/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer. It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.