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SDS Sheet 0065891Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol Product Name: 13.5 OZ SW PRECISION CONTCT CLNR LB 12PK CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: CLEANER 1.3. Name, Address, and Telephone of the Responsible Party Company: Sprayway, Inc. 1005 S. Westgate Drive Addison, IL 60101 United States Phone: General Assistance 1-630-628-3000 1.4. Emergency Telephone Number Emergency | 1-866-836-8855, Emergency telephone outside US: 1-952-852-4646 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Skin |Category 2 corrosion/irri| tation | Germ cell |Category 1B mutagenicity | Carcinogenicit|Category 1B y | Reproductive |Category 2 toxicity | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Specific |Category 2 target organ | toxicity, | repeated | exposure | Aspiration |Category 1 hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. May be fatal if |swallowed and enters airways. Causes skin |irritation. May cause drowsiness or dizziness. May |cause genetic defects. May cause cancer. Suspected |of damaging fertility or the unborn child. May cause |damage to organs through prolonged or repeated |exposure. Precautionary Statements |Prevention Obtain special instructions before use. (GHS-US) |Do not handle until all safety precautions have been |read and understood. Keep away from heat/sparks/open |flames/hot surfaces. - No smoking. Do not spray on |an open flame or other ignition source. Pressurized |container: Do not pierce or burn, even after use. Do |not breathe gas. Use only outdoors or in a |well-ventilated area. Avoid release to the |environment. Wear protective gloves/protective |clothing/eye protection/face protection. |Response If inhaled: Remove person to fresh air and |keep comfortable for breathing. If exposed or |concerned: Get medical advice/attention. Do NOT |induce vomiting. If skin irritation occurs: Get |medical advice/attention. Take off contaminated |clothing and wash before reuse. Collect spillage. |Storage Store in a well-ventilated place. Keep |container tightly closed. Store locked up. Protect |from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F. |Disposal Not available. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Naphtha (petroleum), |64742-49-0 |40 - 60 | hydrotreated light | | | 1,1-Difluoroethane |75-37-6 |20 - 40 | n-Hexane |110-54-3 |20 - 40 | Isopropyl Alcohol |67-63-0 |2.5 - 10| Cyclohexane |110-82-7 |0.1 - 1 | Other components below | |0.01 - | reportable levels | |0.1 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Call a physician or Poison Control Center immediately. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Call a physician or Poison Control Center immediately. First-aid Measures After Eye Contact: Call a physician or Poison Control Center immediately. First-aid Measures After Ingestion: Rinse mouth. Get medical attention if symptoms occur. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of eyes and mucous membranes. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Powder. Foam. Carbon dioxide (CO2). Unsuitable Extinguishing Media: Do not use a solid water stream as it may scatter and spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. Fire may produce irritating, corrosive and/or toxic gases. Explosion Hazard: Extremely flammable aerosol Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods: Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. In the event of fire and/or explosion do not breathe fumes. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective clothing will only provide limited protection. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Refer to attached safety data sheets and/or instructions for use. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Keep out of low areas. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. This material and its container must be disposed of as hazardous waste. Methods for Cleaning Up: Refer to attached safety data sheets and/or instructions for use. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Keep out of low areas. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. This material and its container must be disposed of as hazardous waste. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not breathe gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Should be handled in closed systems, if possible. Pregnant or breastfeeding women must not handle this product. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. Hygiene Measures: When using, do not eat, drink or smoke. Do not get in eyes. Do not get this material in contact with skin. Avoid contact with skin. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 3 Aerosol. Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 3 Aerosol. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Cyclohexane (CAS 110-82-7) PEL 1050 mg/m3 Isopropyl Alcohol (CAS 67-63-0) PEL 300 ppm 980 mg/m3 n-Hexane (CAS 110-54-3) PEL 400 ppm 1800 mg/m3 500 ppm US. ACGIH Threshold Limit Values Components Type Value Cyclohexane (CAS 110-82-7) TWA 100 ppm Isopropyl Alcohol (CAS 67-63-0) STEL TWA 400 ppm 200 ppm n-Hexane (CAS 110-54-3) TWA 50 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Cyclohexane (CAS 110-82-7) TWA 1050 mg/m3 300 ppm Isopropyl Alcohol (CAS 67-63-0) STEL TWA 1225 mg/m3 500 ppm 980 mg/m3 400 ppm n-Hexane (CAS 110-54-3) TWA 180 mg/m3 50 ppm US. Workplace Environmental Exposure Level (WEEL) Guides Components Type Value 1,1-Difluoroethane (CAS 75-37-6) TWA 2700 mg/m3 1000 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Isopropyl Alcohol (CAS 67-63-0) 40 mg/l Acetone Urine * n-Hexane (CAS 110-54-3) 0.4 mg/l 2,5-Hexanedio n, without Hydrolysis Urine * 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Eye wash facilities |and emergency shower must be available when handling |this product. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear appropriate chemical resistant gloves. Eye Protection |Wear tight-fitting goggles or face shield. Wear |safety glasses with side shields (or goggles). Skin and Body Protection |Wear chemical protective equipment that is |specifically recommended by the manufacturer. Use of |an impervious apron is recommended. It may provide |little or no thermal protection. Respiratory Protection |If permissible levels are exceeded use NIOSH |mechanical filter / organic vapor cartridge or an |air-supplied respirator. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Gas. Appearance |Clear. Odor |Solvent. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |-12.46 Â°F (-24.7 Â°C) estimated Flash Point |-58.0 Â°F (-50.0 Â°C) Propellant estimated Auto-ignition Temperature |580.77 Â°F (304.87 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available Vapor Pressure |40 - 50 psig @70F estimated Relative Vapor Density at 20 Â°C |Not available. Relative Density |Not available. Specific Gravity |0.673 - 0.693 estimated Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |3.9 % estimated Upper Flammable Limit |15.6 % estimated 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Risk of ignition. 10.3 Possibility of Hazardous Reactions Hazardous polymerization does not occur. 10.4 Conditions to Avoid Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 10.5 Incompatible Materials Acids. Strong oxidizing agents. Isocyanates. Chlorine. 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. Narcotic effects. Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: Not available. This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: May cause genetic defects. Carcinogenicity: May cause cancer. Reproductive Toxicity: Suspected of damaging fertility or the unborn child. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): Respiratory system. Skin. Central nervous system. Eyes. Peripheral nervous system. May cause damage to organs through prolonged or repeated exposure. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: May cause damage to organs through prolonged or repeated exposure by inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Narcotic effects. Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Irritation of eyes and mucous membranes. Skin irritation. May cause redness and pain. Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Toxic to aquatic life with long lasting effects. Product Species Test Results -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- ------- 13.5 OZ SW PRECISION CONTCT CLNR LB 12PK (CAS Mixture) Aquatic Algae IC50 Algae 11111 mg/L, 72 Hours Fish LC50 Fish 10.2822 mg/L, 96 Hours Components Species Test Results -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- ------- Cyclohexane (CAS 110-82-7) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 23.03 - 42.07 mg/l, 96 hours Isopropyl Alcohol (CAS 67-63-0) Aquatic Algae IC50 Algae 1000.0001 mg/L, 72 Hours Crustacea EC50 Daphnia 13299 mg/L, 48 Hours Fish LC50 Bluegill (Lepomis macrochirus) > 1400 mg/l, 96 hours n-Hexane (CAS 110-54-3) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 2.101 - 2.981 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Partition coefficient n-octanol / water (log Kow) 1,1-Difluoroethane 0.75 Cyclohexane 3.44 Isopropyl Alcohol 0.05 n-Hexane 3.9 SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class |Aerosols, flammable, |<PICTOGRAM PHRASE> |(each not exceeding 1 L|[pic] |capacity) | Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | |[pic] Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable Identification Number|UN1950 |<PICTOGRAM PHRASE> | |[pic] Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List n-Hexane (CAS 110-54-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) 1,1-Difluoroethane (CAS 75-37-6) Safe Drinking Water Act (SDWA): Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |All components are on the U.S. EPA TSCA |Inventory List. |TSCA Section 12(b) Export Notification (40 |CFR 707, Subpt. D) |Not regulated. 15.2 US State Regulations <COMPONENT> US. Massachusetts RTK - Substance List 1,1-Difluoroethane (CAS 75-37-6) Cyclohexane (CAS 110-82-7) Isopropyl Alcohol (CAS 67-63-0) n-Hexane (CAS 110-54-3) US. New Jersey Worker and Community Right-to-Know Act 1,1-Difluoroethane (CAS 75-37-6) Cyclohexane (CAS 110-82-7) Isopropyl Alcohol (CAS 67-63-0) n-Hexane (CAS 110-54-3) US. Pennsylvania Worker and Community Right-to-Know Law Cyclohexane (CAS 110-82-7) Isopropyl Alcohol (CAS 67-63-0) n-Hexane (CAS 110-54-3) US. Rhode Island RTK 1,1-Difluoroethane (CAS 75-37-6) Cyclohexane (CAS 110-82-7) Isopropyl Alcohol (CAS 67-63-0) n-Hexane (CAS 110-54-3) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |01-22-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.