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Safety Data Sheet Date of Issue: 02-23-2015 |Revision Date: |Revision Number: 02 Imperial Supplies Part Number: 0065880 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 16 OZ SPRAYWAY DE-ICER LB 12PK CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: De-Icer 1.3. Name, Address, and Telephone of the Responsible Party Company Sprayway, Inc. 1005 S. Westgate Drive Addison, IL 60101 United States Phone: 1-630-628-3000 1.4. Emergency Telephone Number Emergency | 1-866-836-8855, 1-952-852-4646 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Acute |Category 3 toxicity, oral| Acute |Category 3 toxicity, | dermal | Acute |Category 3 toxicity, | inhalation | Reproductive |Category 1B toxicity | Specific |Category 1 target organ | toxicity, | single | exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Skull & |Health | | | | |Crossbon|Hazard | | | | |es | | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Toxic if swallowed. |Toxic in contact with skin. Toxic if inhaled. May |damage fertility or the unborn child. Causes damage |to organs. Precautionary Statements |Prevention (GHS-US) |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Keep away from heat/sparks/open |flames/hot surfaces. - No smoking. Do not spray on |an open flame or other ignition source. Pressurized |container: Do not pierce or burn, even after use. Do |not breathe gas. Wash thoroughly after handling. Do |not eat, drink or smoke when using this product. Use |only outdoors or in a well-ventilated area. Wear |protective gloves/protective clothing/eye |protection/face protection. |Response |If swallowed: Immediately call a poison |center/doctor. If on skin: Wash with plenty of |water. If inhaled: Remove person to fresh air and |keep comfortable for breathing. Call a poison |center/doctor. Specific treatment (see this label). |Rinse mouth. Take off immediately all contaminated |clothing and wash it before reuse. |Storage |Store in a well-ventilated place. Keep container |tightly closed. Store locked up. Protect from |sunlight. Do not expose to temperatures exceeding |50Â°C/122Â°F. |Disposal |Dispose of contents/container in accordance with |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Methanol |67-56-1 |60 - 80 | Ethylene Glycol |107-21-1 |2.5 - 10| Isopropyl Alcohol |67-63-0 |2.5 - 10| Carbon Dioxide |124-38-9 |1 - 2.5 | Propane |74-98-6 |1 - 2.5 | Other components below | |10 - 20 | reportable levels | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Take off immediately all contaminated clothing. IF exposed or concerned: Get medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a POISON CENTER or doctor/physician. First-aid Measures After Skin Contact: Take off immediately all contaminated clothing. Wash off with soap and plenty of water. Call a POISON CENTER or doctor/physician if you feel unwell. For minor skin contact, avoid spreading material on unaffected skin. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Powder. Alcohol resistant foam. Water. Carbon dioxide (CO2). Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. Extremely flammable aerosol. Explosion Hazard: Specific methods: Use standard firefighting procedures and consider the hazards of other involved materials. Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. In the event of fire and/or explosion do not breathe fumes. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate personal protective equipment. Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Ground and bond containers when transferring material. Do not re-use empty containers. Do not breathe gas. Do not taste or swallow. Avoid contact with skin. Avoid contact with eyes. Avoid contact during pregnancy/while nursing. Avoid prolonged exposure. Avoid contact with clothing. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. Observe good industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Wash contaminated clothing before reuse. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 1 Aerosol (NFPA 30B). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000): Components Type Value Carbon Dioxide (CAS 124-38-9) PEL 9000 mg/m3 5000 ppm Isopropyl Alcohol (CAS 67-63-0) PEL 980 mg/m3 400 ppm Methanol (CAS 67-56-1) PEL 260 mg/m3 200 ppm Propane (CAS 74-98-6) PEL 1800 mg/m3 1000 ppm US. ACGIH Threshold Limit Values: Components Type Value Form Carbon Dioxide (CAS 124-38-9) STEL TWA 30000 ppm 5000 ppm Ethylene Glycol (CAS 107-21-1) Ceiling 100 mg/m3 Aerosol. Isopropyl Alcohol (CAS 67-63-0) STEL TWA 400 ppm 200 ppm Methanol (CAS 67-56-1) STEL 250 ppm 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards: Components Type Value Carbon Dioxide (CAS 124-38-9) STEL TWA 54000 mg/m3 30000 ppm 9000 mg/m3 5000 ppm Isopropyl Alcohol (CAS 67-63-0) STEL TWA 1225 mg/m3 500 ppm 980 mg/m3 400 ppm Methanol (CAS 67-56-1) STEL TWA 325 mg/m3 250 ppm 260 mg/m3 200 ppm Propane (CAS 74-98-6) TWA 1800 mg/m3 1000 ppm Biological limit values: ACGIH Biological Exposure Indices: Components Value Determinant Specimen Sampling Time Isopropyl Alcohol (CAS 67-63-0) 40 mg/l Acetone Urine * Methanol (CAS 67-56-1) 15 mg/l Methanol Urine * * - For sampling details, please see the source document. Exposure guidelines: US - California OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Methanol (CAS 67-56-1) Skin designation applies. US - Tennesse OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves. Eye Protection |Wear safety glasses with side shields (or goggles). |Wear a full-face respirator, if needed. Skin and Body Protection |Other: Wear appropriate chemical resistant clothing. Respiratory Protection |If permissible levels are exceeded use NIOSH |mechanical filter / organic vapor cartridge or an |air-supplied respirator. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance |Clear. Odor |Solvent. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |212 Â°F (100 Â°C) estimated Flash Point |-156.0 Â°F (-104.4 Â°C) Propellant estimated Auto-ignition Temperature |857.76 Â°F (458.76 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |65 - 85 psig @70F estimated Relative Vapor Density at 20 Â°C |Not available. Relative Density |0.811 g/cm3 estimated Specific Gravity |0.811 estimated Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |6 % estimated Upper Flammable Limit |33.2 % estimated 9.2. Other Information Density: 0.81 g/cm3 estimated Flame extension: 18 in estimated Flammability class: Flammable IB estimated Heat of combustion: 28.84 kJ/g estimated Heat of combustion (NFPA 30B): 16.39 kJ/g estimated Percent volatile: 98.49 % estimated VOC (Weight %): 80.65 % estimated SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions Hazardous polymerization does not occur. 10.4 Conditions to Avoid Avoid temperatures exceeding the flash point. 10.5 Incompatible Materials Strong oxidizing agents. Isocyanates. Chlorine. 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Toxic by inhalation. Toxic if swallowed. Toxic in contact with skin. Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive Toxicity: May damage fertility or the unborn child. Specific Target Organ Toxicity (Single Exposure): Causes damage to organs. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: Not likely, due to the form of the product. Symptoms/Injuries After Inhalation: Toxic by inhalation. May cause damage to organs by inhalation. Symptoms/Injuries After Skin Contact: Toxic in contact with skin. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Toxic if swallowed. Chronic Symptoms: Prolonged inhalation may be harmful. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Product Species Test Results 16 OZ SPRAYWAY DE-ICER LB 12PK (CAS Mixture) Aquatic Algae IC50 Algae 10050.251 mg/L, 72 Hours estimated Acute Crustacea EC50 Daphnia 11857.5977 mg/l, 48 hours estimated Fish LC50 Fish 12512.8652 mg/l, 96 hours estimated Components Species Test Results Ethylene Glycol (CAS 107-21-1) Aquatic Crustacea EC50 Daphnia 46300 mg/L, 48 Hours Fish LC50 Fathead minnow (Pimephales promelas) 8050 mg/l, 96 hours Isopropyl Alcohol (CAS 67-63-0) Aquatic Algae IC50 Algae 1000.0001 mg/L, 72 Hours Crustacea EC50 Daphnia 13299 mg/L, 48 Hours Fish LC50 Bluegill (Lepomis macrochirus) > 1400 mg/l, 96 hours Methanol (CAS 67-56-1) Aquatic Crustacea EC50 Water flea (Daphnia magna) > 10000 mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) > 100 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. Partition coefficient n-octanol / water (log Kow) Ethylene Glycol -1.36 Isopropyl Alcohol 0.05 Methanol -0.77 Propane 2.36 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal instructions: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company. US RCRA Hazardous Waste U List: Reference Methanol (CAS 67-56-1) U154 Waste from residues / unused products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable Hazard Class |2.1 |<PICTOGRAM PHRASE> | |[pic] Identification Number|UN1950 | Label Codes |None | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes |2.1, 6.1 |<PICTOGRAM PHRASE> ntification Of The | |[pic][pic] Substance/m | | EmS-No. (Fire) |Not available. | EmS-No. (Spillage) |Not available. | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable Identification Number|UN1950 |<PICTOGRAM PHRASE> | |[pic][pic] Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |10P SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. CERCLA Hazardous Substance List (40 CFR 302.4): Ethylene Glycol (CAS 107-21-1) Listed. Methanol (CAS 67-56-1) Listed. SARA 304 Emergency release notification: Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. SARA 302 Extremely hazardous substance Not listed. SARA 313 (TRI reporting): Chemical name CAS number % by wt. Methanol 67-56-1 60 - 80 Ethylene Glycol 107-21-1 2.5 - 10 Other federal regulations: Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Ethylene Glycol (CAS 107-21-1) Methanol (CAS 67-56-1) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA): Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - No |Delayed Hazard - No |Fire Hazard - |No |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. Massachusetts RTK - Substance List: Carbon Dioxide (CAS 124-38-9) Ethylene Glycol (CAS 107-21-1) Isopropyl Alcohol (CAS 67-63-0) Methanol (CAS 67-56-1) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act: Carbon Dioxide (CAS 124-38-9) Ethylene Glycol (CAS 107-21-1) Isopropyl Alcohol (CAS 67-63-0) Methanol (CAS 67-56-1) Propane (CAS 74-98-6) US. Pennsylvania Worker and Community Right-to-Know Law: Carbon Dioxide (CAS 124-38-9) Ethylene Glycol (CAS 107-21-1) Isopropyl Alcohol (CAS 67-63-0) Methanol (CAS 67-56-1) Propane (CAS 74-98-6) US. Rhode Island RTK Ethylene Glycol (CAS 107-21-1) Isopropyl Alcohol (CAS 67-63-0) Methanol (CAS 67-56-1) Propane (CAS 74-98-6) US. California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Developmental toxin Methanol (CAS 67-56-1) Listed: March 16, 2012 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.