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SDS Sheet 0065750Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: WHITE LIGHTNINGÂ® STOP GAP! Minimal Expanding Insulating Foam CAS No: Synonyms: Not available. 1.2. Intended Use of the Product Use of the substance/mixture: Not applicable. 1.3. Name, Address, and Telephone of the Responsible Party Company THE SHERWIN-WILLIAMS CO. Consumer Group - Industrial Cleveland, OH 44115 Phone: (800) 241-5295 1.4. Emergency Telephone Number Emergency | (216) 566-2917, (800) 424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) FLAMMABLE |Category 1 AEROSOLS | GASES UNDER |Compressed gas PRESSURE | ACUTE TOXICITY|Category 4 (inhalation) | SKIN |Category 2 CORROSION/IRRI| TATION | SERIOUS EYE |Category 2A DAMAGE/ EYE | IRRITATION | RESPIRATORY |Category 1 SENSITIZATION | SKIN |Category 1 SENSITIZATION | CARCINOGENICIT|Category 2 Y | SPECIFIC |Category 3 TARGET ORGAN | TOXICITY | (SINGLE | EXPOSURE) | (Respiratory | tract | irritation and| Narcotic | effects) | SPECIFIC |Category 1 TARGET ORGAN | TOXICITY | (REPEATED | EXPOSURE) - | Category 2 | ASPIRATION | HAZARD | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. |Contains gas under pressure; may explode if heated. |Harmful if inhaled. |Causes serious eye irritation. |Causes skin irritation. |May cause allergy or asthma symptoms or breathing |difficulties if inhaled. |May cause an allergic skin reaction. |Suspected of causing cancer. |May be fatal if swallowed and enters airways. |May cause respiratory irritation. |May cause drowsiness and dizziness. |May cause damage to organs through prolonged or |repeated exposure. Precautionary Statements |General: (GHS-US) |Read label before use. Keep out of reach of |children. If medical advice is needed, have product |container or label at hand. |Prevention: |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Use personal protective equipment as |required. Wear protective gloves. Wear eye or face |protection. In case of inadequate ventilation wear |respiratory protection. Keep away from heat, hot |surfaces, sparks, open flames and other ignition |sources. No smoking. Pressurized container: Do not |pierce or burn, even after use. Do not spray on an |open flame or other ignition source. Use only |outdoors or in a well-ventilated area. Do not |breathe vapor. Wash hands thoroughly after handling. |Contaminated work clothing should not be allowed out |of the workplace. |Response: |Get medical attention if you feel unwell. IF exposed |or concerned: Get medical |attention. IF INHALED: Remove victim to fresh air |and keep at rest in a position |comfortable for breathing. Call a POISON CENTER or |physician if you feel unwell. If experiencing |respiratory symptoms: Call a POISON CENTER or |physician. IF SWALLOWED: Immediately call a POISON |CENTER or physician. Do NOT induce vomiting. IF ON |SKIN: Wash with plenty of soap and water. Take off |contaminated clothing. Wash contaminated clothing |before reuse. If skin irritation or rash occurs: Get |medical attention. IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. If eye |irritation persists: Get medical attention. |Storage: |Store locked up. Protect from sunlight. Do not |expose to temperatures exceeding 50 Â°C/122 Â°F. Store |in a well-ventilated place. |Disposal: |Dispose of contents and container in accordance with |all local, regional, national and international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Supplemental label elements: DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. FOR INDUSTRIAL USE ONLY. Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Diphenylmethane Diisocyanate |9016-87-9 |37.5 | Polymer | | | 4, 4'-Diphenylmethane |101-68-8 |13.5 | Diisocyanate | | | Propane |74-98-6 |10.0 | 2-Methylpropane |75-28-5 |10.0 | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. In the event of any complaints or symptoms, avoid further exposure. First-aid Measures After Skin Contact: Wash with plenty of soap and water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. First-aid Measures After Eye Contact: Get medical attention. First-aid Measures After Ingestion: Get medical attention immediately. Call a poison center or physician. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Adverse symptoms may include the following: respiratory tract irritation. Coughing wheezing and breathing difficulties, Asthma nausea or vomiting. Headache drowsiness/fatigue dizziness/vertigo unconsciousness. Symptoms/Injuries After Skin Contact: Causes skin irritation. May cause an allergic skin reaction. Adverse symptoms may include the following: Irritation redness. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Adverse symptoms may include the following: pain or irritation watering redness. Symptoms/Injuries After Ingestion: Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. Adverse symptoms may include the following: nausea or vomiting. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use an extinguishing agent suitable for the surrounding fire. Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Explosion Hazard: Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Shut off all ignition sources. No flares, smoking or flames in hazard area. 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel". 6.2. Environmental Precautions No specific hazard. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Small spill: Use spark-proof tools and explosion-proof equipment. Large spill: Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50Â°C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Hygiene Measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in accordance with local regulations. Protect from sunlight. Store locked up. Eliminate all ignition sources. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: Ingredient name Exposure limits 4, 4'-Diphenylmethane Diisocyanate ACGIH TLV (United States, 4/2014). TWA: 0.005 ppm 8 hours. NIOSH REL (United States, 10/2013). TWA: 0.05 mg/mÂ³ 10 hours. TWA: 0.005 ppm 10 hours. CEIL: 0.2 mg/mÂ³ 10 minutes. CEIL: 0.02 ppm 10 minutes. OSHA PEL (United States, 2/2013). CEIL: 0.02 ppm CEIL: 0.2 mg/mÂ³ Propane NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/mÂ³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1800 mg/mÂ³ 8 hours. 2-Methylpropane NIOSH REL (United States, 10/2013). TWA: 800 ppm 10 hours. TWA: 1900 mg/mÂ³ 10 hours. ACGIH TLV (United States, 4/2014). STEL: 1000 ppm 15 minutes. 8.2. Exposure Controls Appropriate Engineering |Use only with adequate ventilation. Use process Controls |enclosures, local exhaust ventilation or other |engineering controls to keep worker exposure to |airborne contaminants below any recommended or |statutory limits. The engineering controls also need |to keep gas, vapor or dust concentrations below any |lower explosive limits. Use explosion proof |ventilation equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety eyewear complying with an approved standard |should be used when a risk assessment indicates this |is necessary to avoid exposure to liquid splashes, |mists, gases or dusts. If contact is possible, the |following protection should be worn, unless the |assessment indicates a higher degree of protection: |chemical splash goggles. Skin and Body Protection |Body protection: Personal protective equipment for |the body should be selected based on the task being |performed and the risks involved and should be |approved by a specialist before handling this |product. When there is a risk of ignition from |static electricity, wear antistatic protective |clothing. For the greatest protection from static |discharges, clothing should include anti-static |overalls, boots and gloves. |Other skin protection: Appropriate footwear and any |additional skin protection measures should be |selected based on the task being performed and the |risks involved and should be approved by a |specialist before handling this product. Respiratory Protection | Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Not available. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |Not available. Flash Point |Closed cup: -29Â°C (-20.2Â°F) [Pensky-Martens |Closed Cup] Auto-ignition Temperature |Not available. Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |13.5 kPa (101 mm Hg) [at 20Â°C] Relative Vapor Density at 20 Â°C | Relative Density |0.93 Specific Gravity | Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Kinematic (room temperature): <0.07 cm2/s (<7 |cSt) |Kinematic (40Â°C (104Â°F)): <0.07 cm2/s (<7 |cSt) Lower Flammable Limit |1.8% Upper Flammable Limit |27% 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No specific test data related to reactivity available for this product or its ingredients. 10.2 Chemical Stability The product is stable. 10.3 Possibility of Hazardous Reactions Under normal conditions of storage and use, hazardous reactions will not occur. 10.4 Conditions to Avoid Avoid all possible sources of ignition (spark or flame). 10.5 Incompatible Materials No specific data. 10.6 Hazardous Decomposition Products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Causes skin irritation. May cause an allergic skin reaction. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Not available. Germ Cell Mutagenicity: No known significant effects or critical hazards. Carcinogenicity: Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Reproductive Toxicity: Not available. Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Adverse symptoms may include the following: respiratory tract irritation coughing wheezing and breathing difficulties asthma nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness. Symptoms/Injuries After Skin Contact: Causes skin irritation. May cause an allergic skin reaction. Adverse symptoms may include the following: irritation redness. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Adverse symptoms may include the following: pain or irritation watering redness. Symptoms/Injuries After Ingestion: Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. Adverse symptoms may include the following: nausea or vomiting. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Not available. 12.2. Persistence and Degradability Not available. 12.3. Bioaccumulative Potential Product/ingredient name LogPow BCF Potential 4, 4'-Diphenylmethane Diisocyanate - 200 low 12.4. Mobility in Soil Soil/water partition coefficient (KOC) : Not available. 12.5. Other Adverse Effects No known significant effects or critical hazards. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |AEROSOLS Hazard Class |2.1 |<PICTOGRAM PHRASE> | |[pic] |UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | |[pic] Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, flammable Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |3/19/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.